Search results

This study aims to identify the bioactive compounds in the Onion (Allium burdickii [A.B]) bulb using Raman and Fourier transform infrared spectroscopy (FTIR) spectroscopy. It assessed the extraction conditions of bioactive compounds from A.B. while evaluating the best extraction conditions.

The research opted for an experimental qualitative approach. It examined the extraction conditions of A.B., namely, temperature (°C), time (min) and mass-to-liquor ratio (M:R) using ultraviolet-visible spectrophotometry. Identification of bioactive compounds present in the dye was performed using Raman spectroscopy and the validation of the results was done by FTIR spectroscopy.

The study determined the best extraction conditions (time, temperature, M:R) for A.B bulb. The study confirmed the presence of bioactive compounds.

The limitation was quantification of bioactive compounds in A.B bulb.

The findings prove that the A.B. bulb can provide a sustainable source of bioactive compounds (functionalized compounds). The study provides suitable extraction conditions for A.B. and further elaborates on the techniques for identifying bioactive compounds in A.B. bulb extracts.

The study provides A.B. as a source of bioactive compounds and a clean dye for textile coloration.

To the best of the authors’ knowledge, there is no documented study on the qualitative analysis of bioactive compounds in A.B using Raman and FTIR. Therefore, the study fulfils the identified need to ascertain alternative procedures for the analysis of bioactive compounds.

Gourd fibres (GF) are a natural biodegradable fibre material with excellent mechanical properties and high tensile strength. The use of natural fibres in composite materials has gained popularity in recent years due to their various advantages, including renewability, low cost, low density and biodegradability. Gourd fibre is one such natural fibre that has been identified as a potential reinforcement material for composites. However, it has low surface energy and hydrophobic nature, which makes it difficult to bond with matrix materials such as polyester. To overcome this problem, chemically adapted gourd fibre has been proposed as a solution. Chemical treatment is one of the most widely used methods to improve the properties of natural fibres. This research evaluates the feasibility and effectiveness of incorporating chemically adapted gourd fibre into polyester composites for industrial fabrication. The purpose of this study is to examine the application of chemically modified GF in the production of polyester composite engineering materials.

This work aims to evaluate the effectiveness of chemically adapted gourd fibre in improving the adhesion of gourd fibre with polyester resin in composite fabrication by varying the GF from 5 to 20 wt.%. The study involves the preparation of chemically treated gourd fibre through surface modification using sodium hydroxide (NaOH), permanganate (KMnO₄) and acetic acid (CH₃COOH) coupling agents. The mechanical properties of the modified fibre and composites were investigated. It was then characterized using scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) to determine the changes in surface morphology and functional groups.

FTIR characterization showed that NaOH treatment caused cellulose depolymerization and caused a significant increase in the hydroxyl and carboxyl groups, showing improved surface functional groups; KMnO₄ treatment oxidized the fibre surface and caused the formation of surface oxide groups; and acetic acid treatment induced changes that primarily affected the ester and hydroxyl groups. SEM study showed that NaOH treatment changed the surface morphology of the gourd fibre, introduced voids and reduced hydrophilic tendencies. The tensile strength of the modified gourd fibres increased progressively as the concentration of the modification chemicals increased compared to the untreated fibres.

This work presents the designed composite with density, mechanical properties and microstructure, showing remarkable improvements in the engineering properties. An 181.5% improvement in tensile strength and a 56.63% increase in flexural strength were got over that of the unreinforced polyester. The findings from this work will contribute to the understanding of the potential of chemically adapted gourd fibre as a reinforcement material for composites and provide insights into the development of sustainable composite materials.

The novelty addressed here is undertaken by using tailor-made and fully characterized starch nanoparticles (SNPs) having a particle size ranging from 80 to 100 nm with a larger surface area, biodegradability and high reactivity as a starting substrate for cadmium ions and basic dye removal from wastewater effluent. This was done via carboxylation of SNPs with citric acid via esterification reaction using the dry preparation technique, in which a simple, energy-safe and sustainable process concerning a small amount of water, energy and toxic chemicals was used. The obtained adsorbent is designated as cross-linked esterified starch nanoparticles (CESNPs).

The batch technique was used to determine the CESNPs adsorption capacity, whereas atomic adsorption spectrometry was used to determine the residual cadmium ions concentration in the filtrate before and after adsorption. Different factors affecting adsorption were examined concerning pH, contact time, adsorbent dose and degree of carboxylation. Besides, to validate the esterification reaction and existence of carboxylic groups in the adsorbent, CESNPs were characterized metrologically via analytical tools for carboxyl content estimation and instrumental tools using Fourier-transform infrared spectroscopy (FTIR) spectra and scanning electron microscopy (SEM) morphological analysis.

The overall adsorption potential of CESNPs was found to be 136 mg/g when a 0.1 g adsorbent dose having 190.8 meq/100 g sample carboxyl content at pH 5 for 60 min contact time was used. Besides, increasing the degree of carboxylation of the CESNPs expressed as carboxyl content would lead to the higher adsorption capacity of cadmium ions. FTIR spectroscopy analysis elucidates the esterification reaction with the appearance of a new intense peak C=O ester at 1,700 cm⁻¹, whereas SEM observations reveal some atomic/molecules disorder after esterification.

The innovation addressed here is undertaken by studying the consequence of altering the extent of carboxylation reaction expressed as carboxyl contents on the prepared CESNPs via a simple dry technique with a small amount of water, energy and toxic chemicals that were used as a sustainable bio nano polymer for cadmium ions and basic dye removal from wastewater effluent in comparison with other counterparts published in the literature.

This study aims to evaluate the state of preservation of one of the most famous manuscripts dated back to the 15th century using some analytical techniques to identify the manuscript components, explain its deterioration mechanisms and produce some solutions for conservation processes in future studies.

The analytical techniques used were visual assessment, digital microscope, scanning electron microscope (SEM) with EDX, pH measurement, attenuated total reflection – Fourier transform infrared spectroscopy (ATR/FTIR) and cellulose crystallinity.

Stains, missed parts and scratching were the most common aspects of deterioration. Some insects were observed by digital microscope. The SEM showed that linen fibers and goat skin were used to manufacture paper sheets and leather binding. Energy dispersive X-ray analysis proved that niobium and tantalum were added during the manufacture of paper sheets. Carbon black ink was the main writing material. The other pigments used were cinnabar in red ink, gold color from brass and blue color from lapis lazuli. FTIR analysis proved that some chemical changes were noticed. Low crystallinity of the historical paper was obtained. There was a reduction in the pH value of the historical bookbinding.

The importance of the analytical techniques used to detect the main components, forms and mechanism of deterioration of the studied manuscript. The elements of niobium and tantalum were added to paper sheets, which protected them from deterioration. The insects such as house flies and Sitophilus granarius were found in the manuscripts.

This study aims to investigate the ammonia-sensing performance of polyaniline/polyethylene oxide (PANI/PEO) and polyaniline/polyethylene oxide/zinc oxide (PANI/PEO-ZnO) composite nanofibers at room temperature.

Gas sensor structures were fabricated using microfabrication techniques. First, onto the SiO₂ wafer, gold electrodes were fabricated via thermal evaporation. PANI/PEO nanofibers were produced by the electrospinning method, and the ZnO layer was deposited by using radio frequency (RF) magnetron sputtering on the electrospun nanofibers as a sensing layer. Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and X-ray diffraction were performed to characterize the analysis of nanofibers. After all, gas sensing analysis of PANI/PEO and PANI/PEO/ZnO nanofibers was conducted using an experimental setup at room temperature conditions. Furthermore, the impact of humidity (17%–90% RH) on the sensor resistance was actively investigated.

FTIR analysis confirms the presence of functional groups of PANI, PEO and ZnO in nanofiber structure. SEM micrographs demonstrate beads-free, thinner and smooth nanofibers with ZnO contribution to electrospun PANI/PEO nanofibers. Moreover, according to the gas sensing results, the PANI/PEO nanofibers exhibit 115 s and 457 s response time and recovery time, respectively. However, the PANI/PEO/ZnO nanofibers exhibit 245 s and 153 s response time and recovery time, respectively. PANI/PEO/MOx composite nanofibers ensure stability to the NH₃ gas owing to the high surface/volume ratio and decrease in the humidity dependence of gas sensors, making gas sensors more stable to the environment.

In this study, ZnO was deposited via RF magnetron sputtering techniques on PANI/PEO nanofibers as a different approach instead of in situ polymerization to investigate and enhance the sensor response and recovery time of the PANI/PEO/ZnO and PANI/PEO composite nanofibers to ammonia. These results indicated that ZnO can enhance the sensing properties of conductive polymer-based resistive sensors.

The purpose of this study is to investigate surface treatments and fiber types on adhesion properties polylactic acid (PLA) three-dimensional (3D) parts printed on woven fabrics.

The cotton, flax and jute fabrics were exposed to alkali, hydrogen peroxide, stearic acid and ionic liquid treatments to modify surface characteristics before PLA 3D printing. The modification efficiency was assessed with Fourier transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM) analyses. Then, fused deposition modeling (FDM) printer and PLA filament were used for 3D printing onto the untreated and treated fabrics. The adhesion strength between the fabrics and PLA 3D parts were tested according to DIN 53530 via universal tensile tester.

The fabric structure is effective on adhesion force and greater values were observed for plain weave fabrics. Maximum separation forces were obtained for alkali pretreated fabrics among jute and cotton. Hydrogen peroxide treatment also increased adhesion forces for jute and cotton fabrics while decreasing for flax fabrics. Stearic acid and ionic liquid treatments reduced adhesion forces compared to untreated fabrics. Treatments are effective to alter adhesion via changing surface chemistry, surface morphology and fabric physical properties but display different effects related to fabric material.

This study provides experimental information about effects of different fiber types and surface treatments on adhesion strength of PLA 3D parts. There is limited research about comprehensive observation on 3D printing on cellulosic-woven fabrics.

The purpose of this article is to determine the parameters of the preparation process for devulcanized and pyrolytic crumb rubber modified asphalt (DCRMA) and then study the rheological and microscopic properties of DCRMA through experiments.

In this study, a new preparation process for DCRMA was developed, then the penetration, softening point and viscosity tests were employed to determine the parameters of the preparation process. The crumb rubber (CR) solubility, Fluorescence microscopy (FM), Fourier Transform Infrared (FTIR) spectroscopy and thermogravimetric analysis tests were conducted to verify the devulcanized and pyrolytic effectiveness of the preparation process. Furthermore, dynamic shear rheometer and bending beam rheometer were used to characterize the high and low-temperature rheological properties of DCRMA.

The results showed that the penetration balanced the CR degradation and the virgin asphalt aging well and thus could be used as a main parameters control indicator. The CR solubility, FM and FTIR tests proved that the CR has been fully devulcanized and pyrolytic via the preparation process. The DCRMA exhibited better low-temperature and fatigue performance and lower rutting performance than the conventional crumb rubber modified asphalt (CRMA) with the same CR content. Finally, the time–temperature superposition principle could be employed for all binders in this study.

A new preparation process for DCRMA was developed.

This study aims to investigate the potential use of potato peel extracts as antibacterial finishes for cotton fabrics against Staphylococcus aureus and Escherichia coli. Potato peels are abundant as waste and provide a natural, cheaper and sustainable alternative means of preventing the spread of bacterial infections on cotton fabric.

This research included the characterization of potato peel extracts, application of the extract onto cotton fabric and efficacy testing of the treated cotton fabric against bacteria. Phytochemical screening, agar well diffusion antibacterial test, minimum inhibitory concentration and Fourier transform infrared (FTIR) tests were used to characterize the extract. Antibacterial efficacy of the treated fabric was determined qualitatively using the disc diffusion assay and quantitatively using the bacteria reduction test.

Phytochemical screening confirmed the presence of several secondary metabolites including phenols and flavonoids. Antibacterial tests revealed a positive response in Escherichia coli and Staphylococcus aureus with a zone of inhibition of 6.50 mm and 5.60 mm, respectively. Additional peaks on the FTIR spectroscopy confirmed the presence of potato peel extract on the treated cotton fabric. The treated cotton fabrics showed efficacy against Staphylococcus aureus and Escherichia coli up to 20 washes.

This study introduced the application of potato peel extracts onto cotton fabrics and assessment of the antibacterial properties before and after washing. Results of this study suggest that potato peel extracts can be used as an organic eco-friendly antibacterial finish for cotton fabrics.

To extend the reuse method and rate of straw biomass, this paper investigated the effect of lignin synthetic phenolic resin (LPF) on the rheological properties of asphalt binder.

Four LPFs with 25%, 50%, 75% and 100% substitution rates were prepared by replacing phenol with lignin in synthetic resins and using it as a modifier to prepare a bio-asphalt binder. Temperature sweep tests were conducted to evaluate aging resistance and temperature sensitivity of the bio-asphalt binder. The rutting resistance of the bio-asphalt binder was evaluated by frequency sweeps and multiple stress creep recovery (MSCR) test. Linear amplitude sweep (LAS) tests were conducted to evaluate the fatigue resistance of the bio-asphalt binder. A master curve was constructed to further analyze the rheological properties of the bio-asphalt binder at different frequencies. The low-temperature cracking resistance of the binder was evaluated by G-R parameters, critical temperatures and ΔTc. Fourier transform infrared spectroscopy (FTIR) was performed to investigate the changes in the functional groups of the binder before and after aging.

The results indicated that adding LPF could improve the high-temperature rutting resistance, fatigue resistance, aging resistance of asphalt and the binders are less affected by temperature. Additionally, LPF slightly prohibited the low-temperature performance of the asphalt binder, which, however, was significantly lower than the base asphalt degradation during aging. Compared with base asphalt binders, the bio-asphalt binder showed no new absorption peaks generated after adding LPF, identifying that the improved asphalt binder performance by LPF was a mainly physical modification.

The main objective of this paper is to further improve the substitution rate (i.e. the mass substitution ratio of lignin to phenol) of lignin and broaden the application of biomass resins, thus realizing resource sustainability.

The main aim of this study is to study the effect of alkyl dimethyl benzyl ammonium chloride on removing stains, yellowness and harmful metal ions on historical printed paper, as well as the effect of this cleaner on optical and chemical properties of treated paper.

The assessments after and before treatment were carried out using digital microscopy, infrared spectroscopy (FTIR), pH measurement, color change and finally scanning electron microscopy.

The results showed that the concentrations used under study (1% and 3%) cleaned the paper efficiently without any observed effect on the chemical composition of cellulose, which was confirmed by IR spectra. The most stains that completely disappeared were the soil spots, also the pH values had improved significantly after treatment, which confirms that the detergent is effective in neutralizing the acidity of cellulose. Moreover, the color change revealed an increase in the chromatic lightness of the paper after treatment, which agreed with the results of the scanning electron microscopy examination, as the paper appeared free of dirt, and the fibers and bundles became more cohesive.

To the best of the authors’ knowledge, this study is a unique study, as there is no previous literature that has indicated the use of the effect of alkyl dimethyl benzyl ammonium chloride washing treatments for printed historical paper, as it was limited only to making disinfection materials and water purification products.