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1 – 10 of 174Saeid Masoumi, Hassan Hajghassem, Alireza Erfanian and Ahmad Molaei Rad
Smart sensors based on graphene field effect transistor (GFET) and biological receptors are regarded as a promising nanomaterial that could be the basis for future generation of…
Abstract
Purpose
Smart sensors based on graphene field effect transistor (GFET) and biological receptors are regarded as a promising nanomaterial that could be the basis for future generation of low-power, faster, selective real-time monitoring of target analytes and smaller electronics. So, the purpose of this paper is to provide details of sensors based on selective nanocoatings by combining trinitrotoluene (TNT) receptors (Trp-His-Trp) bound to conjugated polydiacetylene polymers on a graphene channel in GFET for detecting explosives TNT.
Design/methodology/approach
Following an introduction, this paper describes the way of manufacturing of the GFET sensor by using investigation methods for transferring graphene sheet from Cu foil to target substrates, which is functionalized by the TNT peptide receptors, to offer a system which has the capability of answering the presence of related target molecules (TNT). Finally, brief conclusions are drawn.
Findings
In a word, shortly after graphene discovery, it has been explored with a variety of methods gradually. Because of its exceptional electrical properties (e.g. extremely high carrier mobility and capacity), electrochemical properties such as high electron transfer rate and structural properties, graphene has already showed great potential and success in chemical and biological sensing fields. Therefore, the authors used a biological receptor with a field effect transistor (FET) based on graphene to fabricate sensor for achieving high sensitivity and selectivity that can detect explosive substances such as TNT. The transport property changed compared to that of the FET made by intrinsic graphene, that is, the Dirac point position moved from positive Vg to negative Vg, indicating the transition of graphene from p-type to n-type after annealing in TNT, and the results show the bipolar property change of GFET with the TNT concentration and the possibility to develop a robust, easy-to-use and low-cost TNT detection method for performing a sensitive, reliable and semi-quantitative detection in a wide detection range.
Originality/value
In this timeframe of history, TNT is a common explosive used in both military and industrial settings. Its convenient handling properties and explosive strength make it a common choice in military operations and bioterrorism. TNT and other conventional explosives are the mainstays of terrorist bombs and the anti-personnel mines that kill or injure more than 15,000 people annually in war-torn countries. In large, open-air environments, such as airports, train stations and minefields, concentrations of these explosives can be vanishingly small – a few parts of TNT, for instance, per trillion parts of air. That can make it impossible for conventional bomb and mine detectors to detect the explosives and save lives. So, in this paper, the authors report a potential solution with design and manufacture of a GFET sensor based on a biological receptor for real-time detection of TNT explosives specifically.
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Saeid Masoumi, Hassan Hajghassem, Alireza Erfanian and Ahmad Molaei Rad
Miniaturized smart sensors that can perform sensitive and selective real-time monitoring of target analytes are tremendously valuable for various sensing applications. So, the…
Abstract
Purpose
Miniaturized smart sensors that can perform sensitive and selective real-time monitoring of target analytes are tremendously valuable for various sensing applications. So, the purpose of this paper is to provide details of sensors based on selective nanocoatings by combining trinitrotoluene (TNT) receptors bound to conjugated polydiacetylene (PDA) polymers with single-walled carbon nanotube field-effect transistors (CNTFETs) for detecting explosives TNT.
Design/methodology/approach
Following an introduction, this paper describes the way of creating an FET with CNTs, which are functionalized by the peptide based on TNT molecule recognition elements and PDA, to offer a system which has the capability of answering the presence of related target molecules (TNT). Finally, brief conclusions are drawn.
Findings
Single-wall nanotubes and reduced graphene oxide are interesting materials for creating biosensors of FETs at nanoscale because of unique electrical, mechanical, geometrical and biocompatible properties. Therefore, this sensor is designed and manufactured, and the results of applying TNT to sensor show good sensitivity and selectivity response.
Originality/value
In this timeframe of history, sensors based on CNTFET are required for different uses, including clinical diagnosis technologies, environmental tests and bioterrorism recognition technologies, that correspond to the military conflicts and terrorism. So, CNTFET sensor design provides real-time detection of TNT explosives.
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Saeid Masoumi and Hassan Hajghassem
Smart biosensors that can perform sensitive and selective monitoring of target analytes are tremendously valuable for trinitrotoluene (TNT) explosive detection. In this research…
Abstract
Purpose
Smart biosensors that can perform sensitive and selective monitoring of target analytes are tremendously valuable for trinitrotoluene (TNT) explosive detection. In this research, the pre-developed sensor was integrated with biological receptors in which they enhanced the sensitivity of the sensor. This is due to conjugated polydiacetylene onto a peptide-based molecular recognition element (Trp-His-Trp) for TNT molecules in graphene field-effect transistors (GR-FETs) as biosensor that is capable of responding to the presence of a TNT target with a colorimetric response. The authors confirmed the efficacy of the receptor while being attached to polydiacetylene (PDA) by observing the binding ability between the Trp-His-Trp and TNT to alter the electronic band structure of the PDA conjugated backbones. The purpose of this paper is to demonstrate a modular system capable of transducing small-molecule TNT binding into a detectable signal. The details of the real-time and selective TNT biosensor have been reported.
Design/methodology/approach
Following an introduction, this paper describes the way of fabrication GR-FETs with conventional photolithography techniques and the other processes, which is functionalized by the TNT peptide receptors. The authors first determined the essential TNT recognition elements from UV-visible spectrophotometry spectroscopy for PDA sensor unit fabrication. In particular, the blue percentage and the chromic response were used to characterize the polymerization parameter of the conjugated p backbone. A continuous-flow trace vapor source of nitroaromatics (two, four, six-TNT) was designed and evaluated in terms of temperature dependence. The TNT concentration was measured by liquid/gas extraction in acetonitrile using bubbling sequence. The sensor test is performed using a four-point probe and semiconductor analyzer. Finally, brief conclusions are drawn.
Findings
Because of their unique optical and stimuli-response properties, the polydiacetylene and peptide-based platforms have been explored as an alternative to complex mechanical and electrical sensing systems. Therefore, the authors have used GR-FETs with biological receptor-PDAs as a biosensor for achieving high sensitivity and selectivity that can detect explosive substances such as TNT. The transport property changed compared to that of the field-effect transistors made by intrinsic graphene, that is, the Dirac point position moved from positive Vg to negative Vg, indicating the transition of graphene from p-type to n-type after annealing in TNT, and when the device was tested from RT, the response of the device was found to increase linearly with increasing concentrations. Average shifting rate of the Dirac peak was obtained as 0.1-0.3 V/ppm. The resulting sensors exhibited at the limit ppm sensitivity toward TNT in real-time, with excellent selectivity over various similar aromatic compounds. The biological receptor coating may be useful for the development of sensitive and selective micro and nanoelectronic sensor devices for various other target analytes.
Originality/value
The detection of illegally transported explosives has become important as the global rise in terrorism subsequent to the events of September 11, 2001, and is at the forefront of current analytical problems. It is essential that a detection method has the selectivity to distinguish among compounds in a mixture of explosives. So, the authors are reporting a potential solution with the designing and manufacturing of electrochemical biosensor using polydiacetylene conjugated with peptide receptors coated on GR-FETs with the colorimetric response for real-time detection of TNT explosives specifically.
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This paper aims to provide a review of the uses of gas sensors to detect explosives' vapours and chemical warfare agents (CWAs).
Abstract
Purpose
This paper aims to provide a review of the uses of gas sensors to detect explosives' vapours and chemical warfare agents (CWAs).
Design/methodology/approach
Following a brief introduction, this paper first considers the use of gas sensors to detect explosives. Second, gas sensors that respond to CWAs are discussed. Some mentioned is made of commercial devices but the emphasis is on emerging technologies and recent research.
Findings
Detecting explosives is an emerging application for gas sensors. Despite some commercial products, it is the topic of a major research effort and poses a significant technological challenge due to the very low vapour concentrations involved. Many optical and solid‐state techniques are under development and some have shown ppt levels of resolution to TNT and allied compounds. Detecting CWAs is a far more mature application and many products exist, often based on analytical methods. Nevertheless, research into improved sensing techniques continues, frequently aimed at detecting ppb concentrations of nerve agents. Much of this research is aimed at meeting the needs of, and is being funded by, the US military and security agencies.
Originality/value
This paper provides a technical review of recent developments in the use of gas sensors to detect explosives and CWAs.
Details
Keywords
– The purpose of this paper is to provide details of recent developments in sensors for detecting explosives and chemical warfare agents.
Abstract
Purpose
The purpose of this paper is to provide details of recent developments in sensors for detecting explosives and chemical warfare agents.
Design/methodology/approach
Following an introduction, this paper first discusses a selection of new sensing techniques aimed at detecting explosives and explosive devices. It then considers new developments in sensors for detecting chemical warfare agents. Brief concluding comments are drawn.
Findings
This paper shows that a diversity of sensor technologies is being investigated, including various advanced optical methods, nanomaterials, microelectromechanical system, electronic noses, biosensors and electrochemical techniques, several of which offer levels of sensitivity in the parts-per-trillion region. These not only have the potential to yield improved devices for detecting explosives and chemical weapons but may also play a role in health care, environmental monitoring, drug detection and industrial health and safety.
Originality/value
In an era of escalating terrorism and military conflicts, this provides a timely review of new technologies for detecting explosives and chemical warfare agents.
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Roemi Fernández, Héctor Montes, Carlota Salinas, Pablo González de Santos and Manuel Armada
The purpose of this paper is to introduce the design of a training tool intended to improve deminers' technique during close‐in detection tasks.
Abstract
Purpose
The purpose of this paper is to introduce the design of a training tool intended to improve deminers' technique during close‐in detection tasks.
Design/methodology/approach
Following an introduction that highlights the impact of mines and improvised explosive devices (IEDs), and the importance of training for enhancing the safety and the efficiency of the deminers, this paper considers the utilization of a sensory tracking system to study the skill of the hand‐held detector expert operators. With the compiled information, some critical performance variables can be extracted, assessed, and quantified, so that they can be used afterwards as reference values for the training task. In a second stage, the sensory tracking system is used for analysing the trainee skills. The experimentation phase aims to test the effectiveness of the elements that compose the sensory system to track the hand‐held detector during the training sessions.
Findings
The proposed training tool will be able to evaluate the deminers' efficiency during the scanning tasks and will provide important information for improving their competences.
Originality/value
This paper highlights the need of introducing emerging technologies for enhancing the current training techniques for deminers and proposes a sensory tracking system that can be successfully utilised for evaluating trainees' performance with hand‐held detectors.
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There is a widespread belief that the global land‐mine problem can be solved using a combination of advanced robotics, sophisticated sensors and powerful computing devices. Recent…
Abstract
There is a widespread belief that the global land‐mine problem can be solved using a combination of advanced robotics, sophisticated sensors and powerful computing devices. Recent research results suggest that this confidence is misplaced. There is little likelihood of sensing improvements in the short‐term and all the proposed robotic solutions are too expensive to be practical for humanitarian demining operations in countries like Angola, Afghanistan and Cambodia. However, simple equipment improvements and low‐cost robotic devices might provide some useful improvements in safety and cost‐effectiveness in the short‐ to medium‐term. Reviews contributions in robotics and sensing technology, and proposes some practical directions for future work.
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The paper aims to provide a technical review of the application of quantum dot (QD) technology to sensors.
Abstract
Purpose
The paper aims to provide a technical review of the application of quantum dot (QD) technology to sensors.
Design/methodology/approach
Following a brief introduction to QD technology, this paper considers recent research on QD‐based physical, chemical and gas sensors.
Findings
This shows that QDs are being exploited in a range of experimental sensors for detecting physical variables, notably radiant/electromagnetic quantities and temperature; chemical compounds, such as metals and many species of clinical interest; and a variety of gases and vapours. Prospects also exist to develop improved sources and detectors for use in optical gas sensors.
Research limitations/implications
The paper does not consider biomedical uses of QDs such as cellular imaging, bioassays and biosensors.
Originality/value
This provides a detailed insight into recent research on physical, chemical and gas sensors based on QD technology.
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