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The purpose of this study is to assess the performance of fuel blends containing ethanol and gasoline in spark ignition engines. The aim is to explore alternative fuels that can enhance performance while minimizing or eliminating adverse environmental impacts, particularly in the context of limited fossil fuel availability and the need for sustainable alternatives.

The authors used the Ricardo Wave software to evaluate the performance of fuel blends with varying ethanol content (represented as E0, E10, E25, E40, E55, E70, E85 and E100) in comparison to gasoline. The assessment involved different composition percentages and was conducted at various engine speeds (1,500, 3,000, 4,500 and 6,000 rpm). This methodology aims to provide a comprehensive understanding of how different ethanol-gasoline blends perform under different conditions.

The study found that, across all fuel blends, the highest brake power (BP) and the highest brake-specific fuel consumption (BSFC) were observed at 6,000 rpm. Additionally, it was noted that the presence of ethanol in gasoline fuel blends has the potential to increase both the BP and BSFC. These findings suggest that ethanol can positively impact the performance of spark-ignition engines, highlighting its potential as an alternative fuel.

This research contributes to the ongoing efforts in the automotive industry to find sustainable alternative fuels. The use of Ricardo Wave software for performance assessment and the comprehensive exploration of various ethanol-gasoline blends at different engine speeds add to the originality of the study. The emphasis on the potential of ethanol to enhance engine performance provides valuable insights for motor vehicle manufacturers and researchers working on alternative fuel solutions.

The study aims to verify and establish the result of the most suitable optimization approach for higher performance and lower emission of a variable compression ratio (VCR) diesel engine. In this study, three types of test fuels are taken and tested in a variable compression ratio diesel engine (compression ignition). The fuels used are conventional diesel fuel, e-diesel (85% diesel-15% bioethanol) and nano-fuel (85% diesel-15% bioethanol-25 ppm Al₂O₃). The effect of bioethanol and nano-particles on performance, emission and cost-effectiveness is investigated at different load and compression ratios (CRs). The optimum performance and lower emission of the engine are evaluated and compared with other optimization methods.

The test engine is run by diesel, e-diesel (85% diesel-15% bioethanol) and nano-fuel (85% diesel-15% bioethanol-25 ppm Al₂O₃) in three different loadings (4 kg, 8 kg and 12 kg) and CR of 14, 16 and 18, respectively. The optimum value of energy efficiency, exergy efficiency, NO_X emission and relative cost variation are determined against the input parameters using Taguchi-Grey method and confirmed by response surface methodology (RSM) technique.

Using Taguchi-Grey method, the maximum energy and exergy efficiency, minimum % relative cost variation and NO_X emission are 24.64%, 59.52%, 0 and 184 ppm, respectively, at 4 kg load, 18 CR and fuel type of nano-fuel. Using RSM technique, maximum energy and exergy efficiency are 24.8% and 62.9%, and minimum NO_X emission and % cost variation are 208.4 ppm and –6.5, respectively, at 5.2 kg load, 18 CR and nano-fuel. The RSM is suggested as the most appropriate technique for obtaining maximum energy and exergy efficiency, and minimum % relative cost; however, for lowest possible NO_X emission, the Taguchi-Grey method is the most appropriate.

Waste rice straw is used to produce bioethanol. 4-E analysis, i.e. energy, exergy, emission and economic analysis, has been carried out, optimized and compared.

The study aims to determine the the optimal value of output parameters of a variable compression ratio (CR) diesel engine are investigated at different loads, CR and fuel modes of operation experimentally. The output parameters of a variable compression ratio (CR) diesel engine are investigated at different loads, CR and fuel modes of operation experimentally. The performance parameters like brake thermal efficiency (BTE) and brake specific energy consumption (BSEC), whereas CO emission, HC emission, CO₂ emission, NO_x emission, exhaust gas temperature (EGT) and opacity are the emission parameters measured during the test. Tests are conducted for 2, 6 and 10 kg of load, 16.5 and 17.5 of CR.

In this investigation, the first engine was fueled with 100% diesel and 100% Calophyllum inophyllum oil in single-fuel mode. Then Calophyllum inophyllum oil with producer gas was fed to the engine. Calophyllum inophyllum oil offers lower BTE, CO and HC emissions, opacity and higher EGT, BSEC, CO₂ emission and NO_x emissions compared to diesel fuel in both fuel modes of operation observed. The performance optimization using the Taguchi approach is carried out to determine the optimal input parameters for maximum performance and minimum emissions for the test engine. The optimized value of the input parameters is then fed into the prediction techniques, such as the artificial neural network (ANN).

From multiple response optimization, the minimum emissions of 0.58% of CO, 42% of HC, 191 ppm NO_x and maximum BTE of 21.56% for 16.5 CR, 10 kg load and dual fuel mode of operation are determined. Based on generated errors, the ANN is also ranked for precision. The proposed ANN model provides better prediction with minimum experimental data sets. The values of the R² correlation coefficient are 1, 0.95552, 0.94367 and 0.97789 for training, validation, testing and all, respectively. The said biodiesel may be used as a substitute for conventional diesel fuel.

The blend of Calophyllum inophyllum oil-producer gas is used to run the diesel engine. Performance and emission analysis has been carried out, compared, optimized and validated.

This study aims to determine the antecedents that influence attitudes towards the use of environmentally friendly household appliance products and consumers' green purchase intention among consumers in Harare, Zimbabwe.

Data were collected from 329 consumers in Harare, Zimbabwe's commercial capital who were served from five using a structured questionnaire via an online web-based cross-sectional survey. Hypothesised relationships were tested through structural equation modelling with the aid of Smart PLS software.

Green product awareness, social influence, perceived benefit and attitude towards green appliances were found to have a significant positive effect on green purchase intention.

The study's findings may not be generalised to other contexts as sample data was only collected in Zimbabwe. Complementary cross-sectional research studies can be done in other parts of the world to enable cross-cultural comparisons and methodological validations.

The green appliance and energy saving practices are vastly growing, with many multinational appliance companies introducing green products within their product lines and adopting the concept of sustainability through modifications in production, design and consumption of household appliance products that encompass fewer harmful consequences on the environment in response to their concerns about the scarcity of natural resources, environmental well-being and the potential detriment of future generations.

Notwithstanding the limitations of the current study, the results have the potential to contribute to an improved understanding of influence attitudes towards the use of environmentally friendly household appliance products.

The demand for energy is increasing massively due to urbanization and industrialization. Due to the massive usage of diesel engines in the transportation sector, global warming is increasing rapidly. The purpose of this paper is to use hydrogen as the potential alternative for diesel engine.

A series of tests conducted in the twin cylinder four stroke diesel engine at various engine speeds. In addition to the hydrogen, the ultrasonication is applied to add the nanoparticles to the neat diesel. The role of nanoparticles on engine performance is effective owing to its physicochemical properties. Here, neat diesel mixed 30% of biodiesel along with the hydrogen at the concentration of 10%, 20% and 30% and 50 ppm of graphite oxide to form the blends DNH10, DNH20 and DNH30.

Inclusion of both hydrogen and nanoparticles increases the brake power and brake thermal efficiency (BTE) of the engine with relatively less fuel consumption. Compared to all blends, the maximum BTE of 33.3% has been reported by 30% hydrogen-based fuel. On the contrary, the production of the pollutants also reduces as the hydrogen concentration increases.

Majority of the pollutants such as carbon monoxide, carbon dioxide and hydrocarbon were dropped massively compared to diesel. On the contrary, there is no reduction in nitrogen of oxides (NOx). Highest production of NOx was witnessed for 30% hydrogen fuel due to the premixed combustion phase and cylinder temperatures.

This study aims to assess the effect of water variation on bioethanol production from cassava peels (CP) using Saccharomyces cerevisiae yeast as the ethanologenic agent.

The milled CP was divided into three treatment groups in a small-scale flask experiment where each 20 g CP was subjected to two-stage hydrolysis. Different amount of water was added to the fermentation process of CP. The fermented samples were collected every 24 h for various analyses.

The results of the fermentation revealed that the highest ethanol productivity and fermentation efficiency was obtained at 17.38 ± 0.30% and 0.139 ± 0.003 gL⁻¹ h⁻¹. The study affirmed that ethanol production was increased for the addition of water up to 35% for the CP hydrolysate process.

The finding of this study demonstrates that S. cerevisiae is the key player in industrial ethanol production among a variety of yeasts that produce ethanol through sugar fermentation. In order to design truly sustainable processes, it should be expanded to include a thorough analysis and the gradual scaling-up of this process to an industrial level.

This paper is an original research work dealing with bioethanol production from CP using S. cerevisiae microbe.

1. Hydrolysis of cassava peels using 13.1 M H₂SO₄ at 100 ^oC for 110 min gave high Glucose productivity

2. Highest ethanol production was obtained at 72 h of fermentation using Saccharomyces cerevisiae

3. Optimal bioethanol concentration and yield were obtained at a hydration level of 35% agitation

4. Highest ethanol productivity and fermentation efficiency were 17.3%, 0.139 g.L⁻¹.h⁻¹

Hydrolysis of cassava peels using 13.1 M H₂SO₄ at 100 ^oC for 110 min gave high Glucose productivity

Highest ethanol production was obtained at 72 h of fermentation using Saccharomyces cerevisiae

Optimal bioethanol concentration and yield were obtained at a hydration level of 35% agitation

Highest ethanol productivity and fermentation efficiency were 17.3%, 0.139 g.L⁻¹.h⁻¹

This paper aims to improve the permeability and antifouling of polysulfone (PSF) ultrafiltration membranes, the PSF matrix was modified by incorporating sulfonated polysulfone (SPSF).

Systematic investigations were conducted on the synergistic effects of a pore-forming agent, coagulation bath temperature and SPSF doping in the casting solution on blended ultrafiltration membranes. The chemical composition of the membranes was analyzed using Fourier transform infrared spectroscopy. The morphology and surface roughness of the membranes were characterized using scanning electron microscopy and atomic force microscopy. The hydrophilicity of the membrane surface was analyzed using a contact angle meter. The permeability and antifouling properties of the blended membranes were also investigated through filtration experiments.

The results indicated that the blended ultrafiltration membranes demonstrated an optimal overall performance when PVP-K30 content was 5.0 Wt.%, coagulation bath temperature was 30°C and SPSF content was 2.4 Wt.%. In comparison to a pure PSF ultrafiltration membrane, there was a significant increase in pure water flux (390.7 L·m⁻²·h⁻¹) by 2.2 times, while bovine serum albumin retention slightly decreased to 93.8%. In addition, the flux recovery rate improved by 2.1 times (71.4%) compared to that of the original PSF ultrafiltration membrane.

The method provided a simple and practical solution for improving the antifouling and permeability of PSF ultrafiltration membranes.

SPSF was anticipated to serve as an excellent modification additive for the preparation of ultrafiltration membranes with superior properties.

The paper aims to design the optimum formulation of the nano-titanium dioxide (TiO2) hydrophilic coating system using the synthetic polypropylene glycol (PPG), which can create the reflection and absorption property.

TiO2 nanoparticles are used as fillers, and PPG has been blended at the proper ratio of 1PPG: 0.2TiO2. The prepared resin has been applied onto the glass substrate at different numbers of glass immersions during the dip-coating fabrication process. One-time glass immersion is labeled as T1 coating, two-time glass immersion is labeled as T2 coating and three-time glass immersion is labeled as T3 coating. All the prepared coating systems were left dry at ambient temperature.

T3 coating showed the lowest reading of WCA value at 40.50°, due to higher surface energy at 61.73 mN/m. The T3 coating also shows the greatest absorbance property among the prepared coating systems among the prepared coating. In terms of reflectance property, the T2 coating system has great reflectance in UV region and near-infrared region, which is 16.47% and 2.77 and 2.73%, respectively. The T2 coating also has great optical transmission about 75.00% at the visible region.

The development of thermal insulation coating by studying the relationship between convection heat and reflectance at different wavelengths of incident light.

The developed coating shows high potential for glass window application.

The application of the hydrophilic coating on light absorption, reflectance and transmission at different wavelengths.

This study aims to synthesize two different benzoxazines (Bz) monomers using bio-based and petroleum-based primary amines, respectively, and they have been compared to study their thermal and mechanical performances.

A bio-based bisphenol, Divanillin (DiVa), was formed by reacting two moles of vanillin with one mole of ethylenediamine (EDA) which was then reacted firstly with paraformaldehyde and EDA to form the benzoxazine DiVa-EDA-Bz, and secondly with paraformaldehyde and furfuryl amine (FFA) to form the benzoxazine DiVa-FFA-Bz. The molecular structure and thermal properties of the benzoxazines were characterized by fourier transform infrared spectroscopy and nuclear magnetic resonance (1H,13C) spectroscopies, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), respectively. The benzoxazines were further coated on mild steel panels to evaluate their mechanical properties and chemical resistance.

The DSC results of DiVa-FFA-Bz showed two exothermic peaks related to crosslinking compared to the one in DiVa-EDA-Bz. The DiVa-FFA-Bz also showed a higher heat of polymerization than DiVa-EDA-Bz. The TGA results showed that DiVa-FFA-Bz exhibited higher thermal stability with a residual char of 54.10% than 43.24% for DiVa-EDA-Bz. The chemical resistance test results showed that DiVa-FFA-Bz showed better chemical resistance and mechanical properties due to its higher crosslinking density.

This study shows the use of bio-based materials, vanillin and FFA, for synthesizing a benzoxazine resin and its application at high temperatures.

This study aims to describe the design and synthesis of two novel azo and imine chromophores-based dyes derived from two different aldehydes with intramolecular colour matching that are pH sensitive.

The visible absorption wavelength (λ_max) was extended when azo chromophore was included in imine-based systems. The dyed patterns created sophisticated colour-changing paper packaging sensors with pH-sensitive chromophores using alum as a mediator or mordant. Due to the tight adhesive bonding, the dyes on paper’s cellulose fibres could not be removed by ordinary water even at extremely high or low pH, which was confirmed by scanning electron microscopy analysis. The dyed patterns demonstrated an evident, sensitive and fast colour-changing mechanism with varying pH, from pale yellow to red for Dye-I and from pale yellow to brown-violet for Dye-II.

The λ_max for colour changing was recorded from 400 to 490 nm for Dye-I, whereas from 400 to 520 for Dye-II. The freshness judgement of food was checked using actual experiments with cooked crab spoilage, where the cooked crab was incubated at 37 ^oC for 6 h to see the noticeable colour change from yellow to brown-violet with Dye-II. The colour-changing mechanism was studied with Fourier transform infrared (FTIR) spectra at different pH, and thin layer chromatography, nuclear magnetic resonance and FTIR spectroscopy studied the desired structure formation of the dyes. Potential uses for smart packaging sensors include quickly detecting food freshness during transportation or right before consumption.

1. Two novel azo-imine dyes have been synthesized with a pH-responsive effect. 2. The pH-responsive mechanism was studied. 3. The study was supported by computational chemistry using density functional theory. 4. The obtained dyes were used to make pH-responsive sensors for seafood packaging to judge the freshness.