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Article
Publication date: 2 January 2024

Sabiha Sezgin Bozok

This study aims to embed anatase, rutile and brookite TiO2 nanoparticles (NPs) with different crystal phases into cotton fabrics by epoxy silane and to examine the effect of these…

Abstract

Purpose

This study aims to embed anatase, rutile and brookite TiO2 nanoparticles (NPs) with different crystal phases into cotton fabrics by epoxy silane and to examine the effect of these applications on the photocatalytic and mechanical properties of the fabric.

Design/methodology/approach

Different aqueous dispersions which contain anatase, rutile and brookite were prepared at three different concentrations (5%, 10% and 15%). These NPs were embedded in cotton fabrics by using GPTS [(3-glycidyloxypropyl) trimethoxysilane]. Characterization tests were performed by scanning electron microscopy (SEM), Raman and Fourier-transform infrared spectroscopy (FT/IR). Samples were stained with methylene blue (MB) and then exposed to solar light for different periods. Color changes of the samples were examined with a spectrophotometer. Air permeability, abrasion and tear strength tests were applied to all samples.

Findings

According to SEM images, the NPs were successfully attached to the cotton fabrics, and epoxy silane coating surrounded the fiber surfaces. The presence of the coating was also confirmed by Raman spectroscopy and FT/IR. The treatments reduced the stainability of the samples. The most effective applications for ensuring photocatalytic activity in cotton fabrics were suspensions as 10% brookite, 10% anatase and 5% anatase, in descending order. The applied coating slightly reduced the samples’ air permeability, and wear and tear strength.

Originality/value

The importance of this study is to determine the optimal crystal phase and its concentration by using epoxy silane to ensure self-cleaning properties on cotton fabrics. The sample treated with 10% brookite is the most approached its original white color by 99.65% as a result of degradation of MB (after 120 min). On the other hand, using the pure rutile with epoxy silane was not suitable for removing MB from the fabric.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 28 February 2023

Goksel Saracoglu, Ferhat Ceritbinmez, Vildan Özkan and Ahmet Yapici

This study aims to systematically compare the effect of increasing fiber–matrix interface adhesion and matrix toughness in layered composite materials.

Abstract

Purpose

This study aims to systematically compare the effect of increasing fiber–matrix interface adhesion and matrix toughness in layered composite materials.

Design/methodology/approach

Silane ((3-glycidyloxypropyl) trimethoxysilane) was applied to strengthen the fiber–matrix interface connection in e-glass/epoxy laminated composite material. Using a cationic surfactant, 0.1% multi-walled carbon nanotubes (CNTs) were added to the matrix in two different ways, by with and without chemical functionalization using the vacuum infusion method.

Findings

In the results obtained from the three-point bending test specimens, it was determined that the synergistic effect of silane application and non-functionalized CNT in the matrix was higher in terms of flexural modulus and strength values.

Practical implications

The functionalization of multi-walled CNT did not give the expected results because of reasons such as viscosity increase and agglomeration in the matrix.

Originality/value

In this study, a simple model for normalization and prediction purposes was developed, which allows the determination of the flexural modulus and un-notched flexural strength values from one test result of the notched specimen. A systematic comparison was performed by varying each parameter in the composite material.

Details

Aircraft Engineering and Aerospace Technology, vol. 95 no. 7
Type: Research Article
ISSN: 1748-8842

Keywords

Article
Publication date: 10 October 2023

Fatma Bakal Gumus and Ahmet Yapici

The purpose of this paper is to investigate the effect of doping element on the structural, thermal properties, mechanical performance and the failure mechanism of hexagonal nano…

Abstract

Purpose

The purpose of this paper is to investigate the effect of doping element on the structural, thermal properties, mechanical performance and the failure mechanism of hexagonal nano boron nitride (h-BN)-reinforced basalt fabric (BF)/epoxy composites produced by hand lay-up and vacuum bagging technique. h-BN particles doped to composite materials increased the tensile, bending and impact strength of the composite at certain rates while 1 Wt. % h- BN addition shows the highest tensile and flexural strength.

Design/methodology/approach

The epoxy resin was doped with h-BN nanopowder at the certain rates (0, 1, 2 and 4 Wt.%) and the epoxy: hardener ratios used in the study were selected as 80%: 20% by weight. Then, with the aid of a roller by hand lay-up method, a mixture of epoxy + hardeners containing nanoparticles and nanoparticle-free were fed onto BFs, 12 layers of each dimension 30 cm × 30 cm. The surplus epoxy resin was moved away from the composite sheets using the vacuum bagging process and left to cure at room temperature for 24 h. ASTM D3039 for tensile, D7264 for three-point bending and D256 for Izod impact test were performed for the mechanical tests. After the tensile test, the morphologies of the fracture surface were examined with a stereomicroscope and various failure mechanisms are highlighted.

Findings

In this study, a series of basalt/epoxy composites with h-BN nanopowders have been prepared to identify the effect of filler ratio on mechanical properties. It has been known from the results of mechanical experiments that the addition of h-BN improves the mechanical performance of materials at a certain rate. The tensile and flexural strengths of h-BN doped composites, increase for concentrations of 1 Wt.% h-BN, but decrease with the increasing content of it. The basalt/epoxy resin composite with higher mechanical properties could be a potential material in the automotive and aerospace industries.

Originality/value

The aim of this study is to contribute to literature within the context of this new combination of composites and their mechanical properties, failure mechanisms. It presents detailed characterization of each composite by using X-ray differaction (XRD), differential scanning calorimetry (DSC), fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy.

Details

Aircraft Engineering and Aerospace Technology, vol. 95 no. 10
Type: Research Article
ISSN: 1748-8842

Keywords

Article
Publication date: 15 April 2024

Goksel Saracoglu, Serap Kiriş, Sezer Çoban, Muharrem Karaaslan, Tolga Depci and Emin Bayraktar

The aim of this study is to determine the fracture behavior of wool felt and fabric based epoxy composites and their responses to electromagnetic waves.

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Abstract

Purpose

The aim of this study is to determine the fracture behavior of wool felt and fabric based epoxy composites and their responses to electromagnetic waves.

Design/methodology/approach

Notched and unnotched tensile tests of composites made of wool only and hybridized with a glass fiber layer were carried out, and fracture behavior and toughness at macro scale were determined. They were exposed to electromagnetic waves between 8 and 18 GHz frequencies using two horn antennas.

Findings

The keratin and lignin layer on the surface of the wool felt caused lower values to be obtained compared to the mechanical values given by pure epoxy. However, the use of wool felt in the symmetry layer of the laminated composite material provided higher mechanical values than the composite with glass fiber in the symmetry layer due to the mechanical interlocking it created. The use of wool in fabric form resulted in an increase in the modulus of elasticity, but no change in fracture toughness was observed. As a result of the electromagnetic analysis, it was also seen in the electromagnetic analysis that the transmittance of the materials was high, and the reflectance was low throughout the applied frequency range. Hence, it was concluded that all of the manufactured materials could be used as radome material over a wide band.

Practical implications

Sheep wool is an easy-to-supply and low-cost material. In this paper, it is presented that sheep wool can be evaluated as a biocomposite material and used for radome applications.

Originality/value

The combined evaluation of felt and fabric forms of a natural and inexpensive reinforcing element such as sheep wool and the combined evaluation of fracture mechanics and electromagnetic absorption properties will contribute to the evaluation of biocomposites in aviation.

Details

Aircraft Engineering and Aerospace Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1748-8842

Keywords

Article
Publication date: 12 April 2024

Ravikantha Prabhu, Sharun Mendonca, Pavana Kumara Bellairu, Rudolf D'Souza and Thirumaleshwara Bhat

This study explores how titanium oxide (TiO2) filler influences the specific wear rate (SWR) in flax fiber-reinforced epoxy composites (FFRCs) through a Taguchi approach. It aims…

Abstract

Purpose

This study explores how titanium oxide (TiO2) filler influences the specific wear rate (SWR) in flax fiber-reinforced epoxy composites (FFRCs) through a Taguchi approach. It aims to boost abrasive wear resistance by incorporating TiO2 filler, promoting sustainable and eco-friendly materials.

Design/methodology/approach

This study fabricates epoxy/flax composites with TiO2 particles (0–8 wt%) using hand layup. Composites were tested for wear following American Society for Testing and Materials (ASTM) G99-05. Statistical analysis used Taguchi design of experiments (DOE), with ANOVA identifying key factors affecting SWR in abrasive sliding conditions.

Findings

The study illuminates how integrating TiO2 filler particles into epoxy/flax composites enhances abrasive wear properties. Statistical analysis of SWR highlights abrasive grit size (grit) as the most influential factor, followed by normal load, wt% of TiO2 and sliding distance. Grit size has the highest effect at 43.78%, and wt% TiO2 filler contributes 15.61% to SWR according to ANOVA. Notably, the Taguchi predictive model closely aligns with experimental results, validating its reliability.

Originality/value

This paper integrates TiO2 filler and flax fibers to form a novel hybrid composite with enhanced tribological properties in epoxy composites. The use of Taguchi DOE and ANOVA offers valuable insights for optimizing control variables, particularly in natural fiber-reinforced composites (NFRCs).

Details

Multidiscipline Modeling in Materials and Structures, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1573-6105

Keywords

Article
Publication date: 21 June 2023

Ravikantha Prabhu, Sharun Mendonca, Pavana Kumara Bellairu, Rudolf Charles D’Souza and Thirumaleshwara Bhat

This paper aims to report the effect of titanium oxide (TiO2) particles on the specific wear rate (SWR) of alkaline treated bamboo and flax fiber-reinforced composites (FRCs…

Abstract

Purpose

This paper aims to report the effect of titanium oxide (TiO2) particles on the specific wear rate (SWR) of alkaline treated bamboo and flax fiber-reinforced composites (FRCs) under dry sliding condition by using a robust statistical method.

Design/methodology/approach

In this research, the epoxy/bamboo and epoxy/flax composites filled with 0–8 Wt.% TiO2 particles have been fabricated using simple hand layup techniques, and wear testing of the composite was done in accordance with the ASTM G99-05 standard. The Taguchi design of experiments (DOE) was used to conduct a statistical analysis of experimental wear results. An analysis of variance (ANOVA) was conducted to identify significant control factors affecting SWR under dry sliding conditions. Taguchi prediction model is also developed to verify the correlation between the test parameters and performance output.

Findings

The research study reveals that TiO2 filler particles in the epoxy/bamboo and epoxy/flax composite will improve the tribological properties of the developed composites. Statistical analysis of SWR concludes that normal load is the most influencing factor, followed by sliding distance, Wt.% TiO2 filler and sliding velocity. ANOVA concludes that normal load has the maximum effect of 31.92% and 35.77% and Wt.% of TiO2 filler has the effect of 17.33% and 16.98%, respectively, on the SWR of bamboo and flax FRCs. A fairly good agreement between the Taguchi predictive model and experimental results is obtained.

Originality/value

This research paper attempts to include both TiO2 filler and bamboo/flax fibers to develop a novel hybrid composite material. TiO2 micro and nanoparticles are promising filler materials, it helps to enhance the mechanical and tribological properties of the epoxy composites. Taguchi DOE and ANOVA used for statistical analysis serve as guidelines for academicians and practitioners on how to best optimize the control variable with particular reference to natural FRCs.

Details

World Journal of Engineering, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1708-5284

Keywords

Article
Publication date: 30 January 2024

Ravikantha Prabhu, Sharun Mendonca, Pavana Kumara Bellairu, Rudolf Charles DSouza and Thirumaleshwara Bhat

The purpose of this study is to investigate the impact of titanium oxide (TiO2) filler on the abrasive wear properties of bamboo fiber reinforced epoxy composites (BFRCs) using a…

Abstract

Purpose

The purpose of this study is to investigate the impact of titanium oxide (TiO2) filler on the abrasive wear properties of bamboo fiber reinforced epoxy composites (BFRCs) using a Taguchi approach. The study aims to enhance the abrasive wear resistance of these composites by introducing TiO2 filler as a potential reinforcement, thus contributing to the development of sustainable and environmentally friendly materials.

Design/methodology/approach

This study focuses on the fabrication of epoxy/bamboo composites infused with TiO2 particles within the Wt.% range of 0–8 Wt.% using hand layup techniques. The resulting composites were subjected to wear testing according to ASTM G99-05 standards. Statistical analysis of the wear results was carried out using the Taguchi design of experiments (DOE). Additionally, an analysis of variance (ANOVA) was used to determine the influential control factors impacting the specific wear rate (SWR) and coefficient of friction (COF).

Findings

The study illuminates how integrating TiO2 filler enhances abrasive wear in epoxy/bamboo composites. Statistical analysis of SWR highlights abrasive grit size (grit) as the most influential factor, followed by normal load, Wt.% of TiO2 and sliding distance. Analysis of the COF identifies normal load as the primary influential factor, followed by grit, Wt.% of TiO2 and sliding distance. The Taguchi predictive model closely aligns with experimental results, validating its reliability. The morphological study revealed significant differences between the unfilled and TiO2-filled composites. The inclusion of TiO2 improved wear resistance, as evidenced by reduced surface damage and wear debris.

Originality/value

This research paper aims to integrate TiO2 filler and bamboo fibers to create an innovative hybrid composite material. TiO2 micro and nanoparticles show promise as filler materials, contributing to improved tribological properties of epoxy composites. The utilization of Taguchi’s DOE and ANOVA for statistical analysis provides valuable guidance for academic researchers and practitioners in optimizing control variables, especially in the context of natural fiber reinforced composites.

Details

World Journal of Engineering, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1708-5284

Keywords

Article
Publication date: 14 March 2023

Lei Wan, Jian Xu, Yulai Li, Haiou Sun and Tao Zhang

The purpose of this paper is to improve the corrosion resistance of anodized 6063 Al alloy inertial air–water separator by means of silane technology and to investigate the effect…

219

Abstract

Purpose

The purpose of this paper is to improve the corrosion resistance of anodized 6063 Al alloy inertial air–water separator by means of silane technology and to investigate the effect of corrosion-generated surface roughness changes on aerodynamic performance.

Design/methodology/approach

The BTSE-KH560 double-layer silane film treatment technique is used to close micropores on the anodic oxide film surface. The microstructure of the coating is observed by scanning electron microscopy, the coating structure of the specimens is determined by X-ray diffraction (XPS) and the corrosion resistance is determined by electrochemical and salt-spray tests. Computational fluid dynamics is also used to calculate the effect of roughness and analyse the change in separator performance.

Findings

The silane film deposited on the surface of the anodic oxide film acts as a good seal against microporous defects on the surface of the anodic oxide film and reduces the surface roughness. Electrochemical and salt-spray tests show that the silane film improved the corrosion resistance of the anodized film. The roughness produced by the corrosion deteriorates the performance of the separator.

Originality/value

The porous structure of the anodized coating makes it easier for corrosive ions to enter the substrate and cause pitting corrosion. Therefore, in this study, the corrosion behaviour of the coating in the marine environment and its effect on aerodynamic performance are investigated using a BTSE-KH560 double-layer silane coating with a sealing effect.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 3
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 15 September 2023

Yang Liu, Qian Zhang, Jialing Wang, Yawei Shao, Zhengyi Xu, Yanqiu Wang and Junyi Wang

The purpose of this paper is to enhance the compatibility of titanium dioxide in epoxy resins and thus the corrosion resistance of the coatings.

Abstract

Purpose

The purpose of this paper is to enhance the compatibility of titanium dioxide in epoxy resins and thus the corrosion resistance of the coatings.

Design/methodology/approach

In this work, TiO2 was modified by the mechanochemistry method where mechanical energy was combined with thermal energy to complete the modification. The stability of modified TiO2 in epoxy was analyzed by sedimentation experiment. The modified TiO2-epoxy coating was prepared, and the corrosion resistance of the coating was analyzed by open circuit potential, electrochemical impedance spectroscopy and neutral salt spray test.

Findings

High-temperature mechanical modification can improve the compatibility of TiO2 in epoxy resin. At the same time, the modified TiO2-epoxy coating showed better corrosion resistance. Compared to the unmodified TiO2-epoxy coating, the coating improved the dry adhesion force by 61.7% and the adhesion drop by 33.3%. After 2,300 h of immersion in 3.5 Wt.% NaCl solution, the coating resistance of the modified TiO2 coating was enhanced by nearly two orders of magnitude compared to the unmodified coating.

Originality/value

The authors have grafted epoxy molecules onto TiO2 surfaces using a high-temperature mechanical force modification method. The compatibility of TiO2 with epoxy resin is enhanced, resulting in improved adhesion of the coating to the substrate and corrosion resistance of the coating.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 22 February 2024

Thien Vuong Nguyen, Vy Do Truc, Tuan Anh Nguyen and Dai Lam Tran

This study aims to explore the synergistic effect of oxide nanoparticles (ZnO, Fe2O3, SiO2) and cerium nitrate inhibitor on anti-corrosion performance of epoxy coating. First…

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Abstract

Purpose

This study aims to explore the synergistic effect of oxide nanoparticles (ZnO, Fe2O3, SiO2) and cerium nitrate inhibitor on anti-corrosion performance of epoxy coating. First, cerium nitrate inhibitors are absorbed on the surface of various oxide nanoparticles. Thereafter, epoxy nanocomposite coatings have been fabricated on carbon steel substrate using these oxide@Ce nanoparticles as both nano-fillers and nano-inhibitors.

Design/methodology/approach

To evaluate the impact of oxides@Ce nanoparticles on mechanical properties of epoxy coating, the abrasion resistance and impact resistance of epoxy coatings have been examined. To study the impact of oxides@Ce nanoparticles on anti-corrosion performance of epoxy coating for steel, the electrochemical impedance spectroscopy has been carried out in 3% NaCl solution.

Findings

ZnO@Ce3+ and SiO2@Ce3+ nanoparticles provide more enhancement in the epoxy pore network than modification of the epoxy/steel interface. Whereas, Fe2O3@Ce3+ nanoparticles have more to do with modification of the epoxy/steel interface than to change the epoxy pore network.

Originality/value

Incorporation of both oxide nanoparticles and inorganic inhibitor into the epoxy resin is a promising approach for enhancing the anti-corrosion performance of carbon steel.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 3
Type: Research Article
ISSN: 0003-5599

Keywords

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