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The aim of this paper was to investigate the passive corrosion control and active corrosion protective effect of the reinforced concrete structures by electrochemical chloride removal (ECR) method and inhibitors approach, respectively.

The concentration of aggressive chloride ion distributed from the reinforcing steel to the surface of the concrete cover was analyzed during the ECR processes. Besides, the half-cell potential, the concrete resistance R _c , the polarization resistance R _p and the capacitance of double layer C _dl of the steel/concrete system were used to characterize the electrochemical performance of the concrete prisms.

The effectiveness of ECR could be enhanced by increasing the amplitude of potential or prolonging the time. Inhibitor SBT-ZX(I) could successfully prevent the corrosion development of the reinforcing steel in concrete.

The research provides the scientific basis for the practical application of ECR and inhibitors in the field.

This paper aims to develop an electrochemical dechlorination method for large objects in a short time, which were for a long time in the sea. Traditionally, in conservation, chlorides are extracted from marine iron artifacts using complete immersion of those objects in alkaline solutions with or without electrolysis. However, these techniques are time-consuming and very costly, especially when applied to large marine artifacts such as cannons and anchors.

An appropriate sponge was chosen based on resistance to NaOH and the rate of exacted chlorides. Application of electrochemical dechlorination in situ and removal of chloride were measured by the scanning electron microscope (SEM)-EDAX method on the corrosion products and by titration of the electrolysis solution. X-ray diffraction (XRD) method is used for identification of corrosion products before and after application of electrochemical chloride extraction.

The electrochemical chloride extraction (ECE) method is applied against the corrosion of reinforced concrete. From the authors’ research, it is obvious that ECE can successfully extract chlorides from dried large metallic objects exported from the sea. The method of ECE removes the majority of chlorides from the metal during conservation treatment so that the application of organic coating will allow the object to remain stable over a long period.

A new methodology was developed for dechlorination of metallic objects exported from the sea in a short time and thus the consumption of chemical reagents was cut down.

This work aims to demonstrate the use of electrochemical chloride extraction (ECE) to remove chloride ions away from the steel rebar in chloride-contaminated mortar and to mitigate the corrosion of the embedded steel.

To simulate salt contamination in concrete, sodium chloride was added at 0.5 per cent by weight of cement in the fresh mortar featuring a water-to-cement ratio of 0.45. The ECE treatments were varied at two electrical current densities (1 and 5 A/m²), using two electrolytes (0.1M NaOH and 0.1M Na₃BO₃ solutions) and for two periods (2 and 4 weeks). The average free chloride concentration in cement mortars before and after ECE treatment was quantified using a customized chloride sensor, whereas the spatial distribution of relevant elements was obtained using energy-dispersive X-ray spectroscopy. The effect of ECE treatment on the electric resistivity of mortar and the corrosion resistance of steel rebar was investigated by electrochemical impedance spectroscopy and potentiodynamic polarization measurements, respectively.

The experimental results reveal that the ECE treatment was effective in removing chlorides and in improving electric resistivity and compressive strength of the mortar, when using the sodium borate solution as the electrolyte. In this case, a 4-week ECE treatment at 1 A/m² decreased the free chloride content in the mortar by 70 per cent, significantly increased the Ca/Si ratio in the mortar near rebar, led to a more refined and less permeable microstructure of the mortar and significantly improved its compressive strength. The ECE treatment was able to halt the chloride-induced corrosion of steel rebar by passivation. A 4-week ECE treatment at 1 A/m² using sodium hydroxide and sodium borate solutions decreased the corrosion rate of rebar by 36 and 34 per cent, respectively.

This electrochemical rehabilitation of steel-reinforced concrete under chloride-contaminated condition is very effective in prolonging its service life.

The purpose of this paper is to provide a modeling perspective relevant to the use of cathodic prevention (CPre) for unconventional concrete in salt‐laden environment.

Based on the experimentally obtained concrete resistivity and chloride diffusion coefficient data, numerical studies with the Nernst‐Planck equations were conducted to investigate the influence of applied voltage (magnitude, direction, and interruption), surface chloride concentration, and concrete mix design on the effectiveness of cathodic prevention and the distribution of ionic species in protected concrete.

The modeling results revealed that the direction of applied electric voltage has significant effect on the distributions of electrical potential and hydroxyl ions in the reinforced concrete, confirming the benefits of cathodic prevention in significantly increasing hydroxyl concentration near rebar and in slowing down the ingress of chloride ingress into concrete. The performance of intermittent CPre was found to be constrained by the variations in concrete resistance from the anode to the cathode. The model was also useful in illustrating the temporal and spatial evolutions on rebar surface in terms of oxygen, hydroxyl and chloride concentrations and electrical potential of top rebar, as well as such evolutions in concrete domain in terms of concrete resistivity and current density for each mix design.

The results reported herein shed light on the fundamental processes defining the performance of CPre for new unconventional concrete in salt‐laden environment.

Concrete forms a major component of the national infrastructure. Corrosion of reinforced steels embedded in concrete has recently received wide attention in R&D programmes. Different cases have been reported showing failures of concrete structures which means huge loss. An attempt has been made to identify the different factors affecting the corrosion of embedded steel. Comparative evaluation of different protective schemes use of additives in concrete admixtures and the application of the cathodic protection technique has been discussed.

Performance of the structure depends on design, construction, environment, utilization and reliability aspects. Other factors can be controlled by adopting proper design and construction techniques, but the environmental factors are difficult to control. Hence, mostly in practice, the environmental factors are not considered in the analysis and design appropriately; however, their impact on the performance of the structures is significant along with the design life. It is in this light that this paper aims to perform the time-dependent performance analysis of reinforced concrete structures majorly considering environmental factors.

To achieve the intended objective, a simply supported reinforced concrete beam was designed and detailed as per the Euro Code (EC2). The time-dependent design parameters, corrosion parameters, creep and shrinkage were identified through thorough literature review. The common empirical equations were modified to consider the identified parameters, and finally, the time-dependent performance of reinforced concrete beam was performed.

Findings indicate that attention has to be paid to appropriate consideration of the environmental effect on reinforced concrete structures. In that, the time-dependent performance of reinforced concrete beam significantly decreases with time due to corrosion of reinforcement steel, creep and shrinkage.

However, the Euro code, Ethiopian code and Indian code threat the exposure condition of reinforced concrete by providing corresponding concrete cover that retards the corrosion initiation time but does not eliminate environmental effects. The results of this study clearly indicate that the capacity of reinforced concrete structure degrades with time due to corrosion and creep, whereas the action on the structure due to shrinkage increases. Therefore, appropriate remedial measures have to be taken to control the defects of structures due to the environmental factors to overcome the early failure of the structure.

Corrosion sensors and networks are the most effective techniques to obtain the corrosion information and recognize the corrosion status of reinforced concrete structures. However, reference electrode is the key element to provide the baseline for potential control of the corrosion monitoring sensors during corrosion measurement process. Therefore, the purpose of this paper is to provide the novel solid‐state reference electrode for the corrosion sensors.

A solid‐state Ag/AgCl reference electrode has been prepared. Furthermore, the performance of the reference electrode, such as stability, temperature response, anti‐polarization and influence of the concrete admixture, has been investigated.

The results indicate that the balance potential and the temperature coefficient of the reference electrode are 3.64±1mv (vs. SCE) at 25°C and −0.51 mv/°C±0.03 mv/°C, respectively. Furthermore, the polarization curve exhibits characteristics of three stages as the polarization current is in (−10μA/cm2,+10μA/cm2). Additionally, the reference electrode is insensitive to the concrete admixtures which include Na2SO4, NaCl, NaNO3 and NaNO2.

The research provides the key element for the corrosion monitoring sensors to integrate structural health monitoring system in future.

This study aims to explore suitable anode materials used in the electrochemical system for indigo dyeing wastewater, to achieve optimal treatment performances.

The single factor experiment was used to explore the optimum process parameters for electrochemical decolorization of indigo dyeing wastewater by changing the applied voltage, electrolysis time and electrolyte concentration. At the voltage of 9 V, the morphology of flocs with different electrolytic times was observed and the effect of electrolyte concentration on decolorization rate in two electrolyte systems was also investigated. Further analysis of chemical oxygen demand (COD) removal rate, anode weight loss and sediment quantity after electrochemical treatment of indigo dyeing wastewater were carried out.

Comprehensive considering the decolorization degree and COD removal rate of the wastewater, the aluminum electrode showed the best treatment effect among several common anode materials. With aluminum electrode as an anode, under conditions of applied voltage of 9 V, electrolysis time of 40 min and sodium sulfate concentration of 6 g/L, the decolorization percentage obtained was of 94.59% and the COD removal rate reached at 84.53%.

In the electrochemical treatment of indigo dyeing wastewater, the aluminum electrode was found as an ideal anode material, which provided a reference for the choice of anodes. The electrodes used in this study were homogenous material and the composite material anode needed to be further researched.

It provided an effective and practical anode material choice for electrochemical degradation of indigo dyeing wastewater.

Combined with the influence of applied voltage, electrolysis time and electrolyte concentration and anode materials on decolorization degree and COD removal rate of indigo dyeing wastewater, providing a better electrochemical treatment system for dyehouse effluent.

The purpose of this paper is to quantitatively assess the pit growth rate on AISI 304L and AISI 316 austenitic stainless steels in natural seawater and 3.5 wt.% NaCl solutions through electrochemical measurements during the potentiostatic growth of pits.

A quantitative characterisation was carried out based on chronoamperometric measurements. The volume of dissolved metal per pit was calculated from the charge registered and Faraday's law, considering both, hemispherical and semi‐elliptical pit shapes and the density of the steels. Empirical growth laws for maximum pit depth as a function of polarisation time were obtained and compared with pits volumetric profile obtained from optical microscopy analysis and mechanical removal of material on both steels.

Electrochemical‐based calculations of localised metal dissolution per pit present acceptable fit with the real volume of dissolved metal on hemispherical pits.

The paper presents the quantitative relationship of the corrosion pit growth rate of stainless steels in chloride containing solution determined by chronoamperometry (electrochemical technique) through the Faraday law's, with the mechanical removal of material (pit profile) through the density of metal.

This study aims to evaluate the efficiency of metal electrode and electrolytes on the electroflocculation of indigo wastewater, produced by printing and dyeing factory, and to optimize the treatment system.

For effective purging, various types of metal electrodes (graphite, pure aluminum and stainless steel) and supporting electrolytes (sodium chloride and sodium sulfate) were selected for electroflocculation experiments. The decolorization rate and chemical oxygen demand (COD) removal rate were characterized.

The treatment effects of stainless steel and aluminum were similar, but the dissolution loss of aluminum and the production of flocs greatly limit its application. Electrolytes gave obvious effects to these systems. Sodium sulfate was better than sodium chloride, the decolorization rate was increased by 3.31%, the removal rate of COD in the solution was increased by 28.65% and the weight of flocculation precipitation was reduced by 0.214 g.

The electrochemical treatment system was constructed to compare and analyze the influence of experimental parameters and to provide a reference for the actual treatment of indigo wastewater.

Electrochemical flocculation can remove the insoluble indigo solids and it plays a key role in wastewater treatment.

It is novel to optimize the combination of electrode and electrolyte to improve the efficiency of electroflocculation, which can be widely used in the actual wastewater treatment process.