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This paper aims to evaluate the inhibitive action of the corrosion of mild steel in sulphuric acid solutions by ethanol extracts of Thymus vulgaris (TYV), Xylopia aethiopica (XYA) and Zingiber officinale (ZGO) as eco-friendly and non-toxic mild-steel corrosion inhibitors in H₂SO₄ solutions.

Ethanol extracts of TYV leaves, XYA fruits and ZGO roots were used as inhibitors in various corrosion tests. Gravimetric and gasometric techniques were used to characterize the mechanism of inhibition.

Results indicate that the extracts inhibit the corrosion process efficiently. Inhibition efficiency was found to increase with an increase in extract concentration and decrease with an increase in temperature. Inhibition efficiencies followed the trend TYV > ZGO > XYA. Thermodynamic considerations revealed that the energy of activation increased in the presence of the plant extracts. Adsorption of the plant extracts on mild steel surface occurred spontaneously, and E_a and ΔG_ads values confirm a physical adsorption processes. Phytochemical studies showed the presence of saponoids, flavonoids and polyphenols whose attachment to adsorption sites on the metal surface is responsible for the inhibition process. Experimental data fit the Langmuir adsorption isotherm.

The plant extracts can be used in chemical cleaning and picking processes.

The research provides information on the possible use of the ethanol extracts from TYV leaves, XYA fruits and ZGO roots as sources of cheap, eco-friendly and non-toxic corrosion inhibitors.

The purpose of this paper is to study the adsorption properties of a proven traditional medicine of West Africa origin, Alstonia boonei with an attempt to evaluate its application in the corrosion protection of mild steel in 5 M H₂SO₄ and 5 M HCl.

Phytochemical screening and Fourier transform infrared spectroscopy analysis were used to characterize the methanolic extract of the plant. Gravimetry, gasometry and electrochemical techniques were used in the corrosion inhibition studies of the extract and computational studies were used to describe the electronic and adsorption properties of eugenol, the most abundant phytochemical in Alstonia boonei.

The extract acted as a mixed-type inhibitor in both acidic solutions, with improved inhibition efficiency achieved with increasing concentration. While the efficiency increased with temperature for the HCl system, it decreased for the H₂SO₄ system. The mechanism of adsorption proposed for Alstonia boonei was chemisorption in the HCl system and physisorption in the H₂SO₄ system, and the adsorptions obeyed Langmuir isotherm at low temperatures. Computational parameters showed that eugenol, being a representative of Alstonia boonei, possesses excellent adsorption properties and has the potential to compete with other established plant-based corrosion inhibitors.

As opposed to pure compounds with distinctive corrosion effects, plant extracts are generally composed of a myriad of phytoconstituents that competitively promote or inhibit the corrosion process and their net effect is evident as inhibition efficiencies. This is, therefore, the main research limitation associated with the corrosion inhibition study of Alstonia boonei.

Being very rich in antioxidant properties by its proven curative and preventive effects for diseases, the interest was stimulated towards the attractive results that abound from its corrosion protection of metals via its anti-oxidation route.

Owing to the toxicity, biodegradability, and cost of most corrosion inhibitors, research attention is now focused on the development of environmentally benign, biodegradable, cheap, and efficient options. In consideration of these facts, chrysin, a phytocompound of Populus tomentosa (Chinese white poplar) has been isolated and investigated for its anticorrosion abilities on carbon steel in a mixed acid and chloride system. This highlights the main purpose of the study.

Chrysin was isolated from Populus tomentosa using column chromatography and characterized using Fourier Transform Infrared Spectroscopy and Nuclear Magnetic Resonance Spectroscopy. The investigations are outlined based on theory (Fukui indices, condensed density functional theory and molecular dynamic simulation) and experiments (electrochemical, gravimetry and surface morphology examinations).

Theoretical evaluations permitted the description of the adsorption characteristics, and molecular interactions and orientations of chrysin on Fe substrate. The interaction energy for protonated and neutral chrysin on Fe (110) were −149.10 kcal/mol and −143.28 kcal/mol, respectively. Moreover, experimental investigations showed that chrysin is a potent mixed-type corrosion inhibitor for steel, whose effectiveness depends on its surrounding temperature and concentration. The optimum inhibition efficiency of 78.7% after 24 h for 1 g/L chrysin at 298 K indicates that the performance of chrysin, as a pure compound, compares favorably with other phytocompounds and plant extracts investigated under similar conditions. However, the inhibition efficiency decreased to 62.5% and 51.8% at 318 K after 48 h and 72 h, respectively.

The novelty of this study relies on the usage of a pure compound in corrosion suppression investigation, thus eliminating the unknown influences obtainable by the presence of multi-phytocompounds in plant extracts, thereby advancing the commercialization of bio-based corrosion inhibitors.

Corrosion is a major concern for many industries that use metals as structural or functional materials, and the use of corrosion inhibitors is a widely accepted strategy to protect metals from deterioration in corrosive environments. Moreover, the toxic nature, non-biodegradability and price of most conventional corrosion inhibitors have encouraged the application of greener and more sustainable options, with natural and synthetic drugs being major actors. Hence, this paper aims to stress the capability of natural and synthetic drugs as manageable and sustainable, environmentally friendly solutions to the problem of metal corrosion.

In this review, the recent developments in the use of natural and synthetic drugs as corrosion inhibitors are explored in detail to highlight the key advancements and drawbacks towards the advantageous utilization of drugs as corrosion inhibitors.

Corrosion is a critical issue in numerous modern applications, and conventional strategies of corrosion inhibition include the use of toxic and environmentally harmful chemicals. As greener alternatives, natural compounds like plant extracts, essential oils and biopolymers, as well as synthetic drugs, are highlighted in this review. In addition, the advantages and disadvantages of these compounds, as well as their effectiveness in preventing corrosion, are discussed in the review.

This survey stresses on the most recent abilities of natural and synthetic drugs as viable and sustainable, environmentally friendly solutions to the problem of metal corrosion, thus expanding the general knowledge of green corrosion inhibitors.