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Article
Publication date: 6 November 2009

Lijuan Wang, Jian Li and Hao Feng

The purpose of this paper is to develop an environmentally friendly dyeing process using brown pigment from chestnut shells (BPFCS). This material is obtained from foodstuff…

Abstract

Purpose

The purpose of this paper is to develop an environmentally friendly dyeing process using brown pigment from chestnut shells (BPFCS). This material is obtained from foodstuff residues and can make a significant contribution to reusing a reproducible biomass resource, economizing petroleum, avoiding water pollution and protecting human health.

Design/methodology/approach

The brown pigment is extracted from the raw material and purified with solvents containing 30 and 100 per cent EtOH. It is then used to dye flax fabric in aqueous solution with added NaCl as a dye accelerator. The effects of dyeing conditions and fastness are investigated. The pigment, and the pristine and dyed fabrics are analysed by Fourier‐transform infrared spectroscopy (FT‐IR) and the fabric samples are observed using a scanning electron microscope (SEM). Fastness to washing, rubbing and light are also measured.

Findings

BPFCS show promising dyeability on cellulosic fibers. White flax fabric is successfully dyed with the pigment to a yellow‐brown colour. The base dyeing conditions are as follows: pigment concentration 16 g/l, NaCl concentration 10 g/l, liquor ratio 10:1, temperature 95°C, dyeing time 40 min. The dyed fabrics have lower fastness to washing and higher fastness to rubbing and light. A total of 4 per cent Al3+ or Fe2+ treatment of dyed fabric can improve fastness to washing, but decrease fastness to rubbing. The yellowish‐brown samples are transformed to brown or dark‐green after Al3+ or Fe2+ treatment, respectively. The pigment is a mixture with abundant hydroxyl groups.

Research limitations/implications

The studies of dyeing conditions and fastness are carried out in detail as BPFCS used as a dye. However, a qualitative analysis of the pigment could not be performed due to the difficulty of separating the mixture. The BPFCS used in this paper can dye cellulosic fiber and can also be used to dye other fibers such as silk, wool and PET. Dyeing conditions for these other fibers need to be investigated.

Practical implications

BPFCS may play an important role in the dyeing industries because of its good dyeability, lack of toxicity and resistance to water, rubbing and light. The present work offers an environmentally friendly dye and a simple dyeing method.

Originality/value

At present, no report exists in the literature of work on dyeing flax fabric with BPFCS. This paper represents a preliminary study to determine the relationships of dyeing conditions to fastness and the role of mordant. BPFCS appears to be a new and practically useful natural dye.

Details

Pigment & Resin Technology, vol. 38 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 22 October 2018

Monthon Nakpathom, Buppha Somboon, Nootsara Narumol and Rattanaphol Mongkholrattanasit

The purpose of this study is to investigate the possibility of dyeing polyester (PET) fabric with natural dye extracted from annatto seeds using high temperature dyeing method.

Abstract

Purpose

The purpose of this study is to investigate the possibility of dyeing polyester (PET) fabric with natural dye extracted from annatto seeds using high temperature dyeing method.

Design/methodology/approach

PET fabric was dyed with annatto extract by varying dyeing parameters (temperature, time, pH and dye concentration) to determine the optimum dyeing conditions. The influences of KAl(SO4)2, FeSO4, gallnut mordants or a commercial UV absorber on colour yield and fastness properties were further studied.

Findings

Optimum results were obtained when the fabric was dyed at 130°C for 30 min in a dyebath containing 15 per cent (owf) annatto dye at pH 6. The dyed fabric had an orange shade and exhibited good to excellent wash, crock, perspiration fastness and fair light fastness. Further dyeing with mordants or UV absorber mostly resulted in lower colour yield and similar fastness properties.

Research limitations/implications

Although the light fastness was slightly improved to moderate level for the sample with UV absorber, a noticeable colour staining on cotton portion of multi-fibre fabric occurred when subjected to standard washing test. Compared to C.I. Disperse Orange 73, the annatto dye exhibited comparable colour fastness but had inferior light fastness when dyed at approximately the same colour strength.

Originality/value

Natural colourants from annatto seeds can be used to dye PET fabric at high temperature without mordants, yielding deep orange shade and satisfactory fastness properties. This study provides a promising application to reduce the environmental impact of synthetic dyes.

Details

Pigment & Resin Technology, vol. 48 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 20 October 2023

Junling Wu, Longfei Sun and Long Lin

This study aims to dye silk with natural pigments extract of Coreopsis tinctoria, by treating the fabrics with appropriate mordant under suitable dyeing conditions, to achieve…

22

Abstract

Purpose

This study aims to dye silk with natural pigments extract of Coreopsis tinctoria, by treating the fabrics with appropriate mordant under suitable dyeing conditions, to achieve good dyeing depth, fastness and ultraviolet (UV) protection.

Design/methodology/approach

Firstly, single factor experiments were used to determine the basic dyeing conditions of Coreopsis tinctoria. The optimal process conditions for direct dyeing were determined through orthogonal experiments. After that, the dyeing with mordant was used. Based on the previously determined optimal process conditions, silk fabrics were dyed with different mordanting methods, with different mordants and mordant dosages. The dyeing results were compared, in terms of the K/S values of the dyed fabrics, to determine the most appropriate dyeing conditions with mordant.

Findings

The extract of Coreopsis tinctoria can dye silk fabrics satisfactorily. Good dyeing depth and fastness can be obtained by using suitable dyeing methods and dyeing conditions, especially when using the natural mordant pomegranate rind and the rare earth mordant neodymium oxide. The silk fabrics dyed with Coreopsis tinctoria have good UV resistance, which allows a desirable finishing effect to be achieved while dyeing, using a safe and environmentally friendly method.

Research limitations/implications

The composition of Coreopsis tinctoria is complex, and the specific composition of colouring the silk fibre has not been determined. There are many factors that affect the dyeing experiment, which have an impact on the experimental results.

Practical implications

The results of this study may help expand the application of Coreopsis tinctoria beyond medicine.

Originality/value

To the best of the authors’ knowledge, this paper is the first report on dyeing silk with the extract of Coreopsis tinctoria achieving good dyeing results. Its depth of staining and staining fastness were satisfactory. Optimum dyeing method and dyeing conditions have been identified. The fabric dyed with Coreopsis tinctoria has good UV protection effect, which is conducive to improving the application value of the dyeing fabric. The findings help offer a new direction for the application of medicinal plants in the eco-friendly dyeing of silk.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 28 March 2024

Mozhgan Hosseinnezhad, Kamaladin Gharanjig, Shahid Adeel and Alireza Mahmoudi Nahavandi

Agricultural waste and food sources are some of the pollutants of the environment. One of these wastes is the peel of fruits that cannot be consumed as food. In this regard…

Abstract

Purpose

Agricultural waste and food sources are some of the pollutants of the environment. One of these wastes is the peel of fruits that cannot be consumed as food. In this regard, walnut husk (WH) and oleaster peel (PO) are known as two important sources of tannin and are bulky wastes. Because of the high percentage of tannin, these materials can be used as a natural source for the preparation of bio-mordant in the dyeing process.

Design/methodology/approach

In this study, Reseda and Madder were used as natural dyes in the presence of a mixture of two bio-mordants. WH and PO were selected as bio-mordant. All natural resources are extracted to obtain the juice. The phenolic percentage of tannin-containing extracts was evaluated and then it was used for wool yarns by premordanting method. The results of evaluating the fastness properties using the ISO method.

Findings

The most important achievement of this research is the use of agricultural waste in the dyeing process to reduce environmental pollution and create added value. All compounds rich in tannin have some phenolic components, therefore the amount of phenolic content of these extracts was evaluated. The effect of mixing the mordant on the color characteristics of the yarns was investigated and the results showed that changing the ratio of the combination of two mordant is effective on the K/S values. The results of evaluating the fastness properties using the ISO method showed that the washing, rubbing and light fastness in the presence of mordant is good, good and moderate, respectively.

Originality/value

In this paper, to the best of the authors’ knowledge, for the first time, the combination of two natural extracts obtained from agricultural waste has been used to create a new bio-mordant on fibers and improve stability.

Details

Research Journal of Textile and Apparel, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1560-6074

Keywords

Article
Publication date: 14 August 2023

Ukanah Suleiman Pendo, Kasali Ademola Bello, Mohammed Kabir Yakubu, Abdulraheem Giwa, Umar Salami Ameuru, Ali Reza Harifi-Mood and Azim Ziyaei Halimehjani

This paper aims to synthesize a novel series of monoazo disperse dyes based on N-(1-phthalimidyl)-naphthalimides by coupling with substitute anilines, naphthylamines and naphthol…

Abstract

Purpose

This paper aims to synthesize a novel series of monoazo disperse dyes based on N-(1-phthalimidyl)-naphthalimides by coupling with substitute anilines, naphthylamines and naphthol derivatives.

Design/methodology/approach

The purification of the intermediates and the dyes was carried out by recrystallization. The structures of the synthesized intermediates and the dyes were elucidated by spectroscopic techniques. The absorption maxima, molar extinction coefficient and halochromic properties of the dyes were determined spectrophotometrically using solvents of different polarity.

Findings

The dyes were applied on polyester using a high-temperature high-pressure dyeing machine, and the dyeing performance parameters such as colour build-up on fabrics, wash fastness, perspiration fastness and light fastness were evaluated. The colour build-up was found to be very good and the wash fastness (4–5) and perspiration fastness (4–5) were excellent, whereas the light fastness was found to vary from moderate to very good (3–6).

Research limitations/implications

It is not possible to investigate the structure of the synthesized dyes by nuclear magnetic resonance spectroscopic analysis due to the low solubility of dyes in deuterated solvents.

Originality/value

A novel method for the synthesis of a new category of monoazo disperse dyes based on N-(1-phthalimidyl)-naphthalimides was developed. These dyestuffs could be used in textile printing of polyester fabrics.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 19 February 2024

Shimaa S.M. Elhadad, Hany Kafafy, Hamada Mashaly and Ahmed Ali El-Sayed

The purpose of this study is to use liposome technology in the treatment of fabrics textiles because of its efficient energy saving, reducing time and temperature.

Abstract

Purpose

The purpose of this study is to use liposome technology in the treatment of fabrics textiles because of its efficient energy saving, reducing time and temperature.

Design/methodology/approach

The newly prepared lecithin liposome was used to encapsulate dyes for the purpose of increasing dyeing affinity. Different ratios of commercially available lecithin liposomes (1%, 3%, 5% and 7%) were used simultaneously in the dyeing of cotton and wool fabrics. The treated fabrics (cotton and wool fabrics) were confirmed using different analytical procedures such as scanning electron microscope (SEM), Fourier-transition infrared spectroscopy, ultraviolet protection factor, colour strength (K|S) measurements and fastness measurements.

Findings

The results show that increasing liposome ratios in dyeing baths leads to increased dyeing affinity for cotton and wool fabrics compared with conventional dyeing without using liposomes. In addition to that, the colour strength values, infrared spectra, SEM and fastness properties of non-liposome-dyed fabrics and liposome-dyed fabrics were investigated.

Originality/value

The research paper provides broad spectrum of green encapsulation fabrics using liposome technology to perform the dye stability, dye strength and fastness.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 30 May 2019

Hanna Abomelha

This study aims to the synthesis of some novel 4-arylazo-3-hydroxythiophene analogues containing sulphapyridine and sulphathiazole dyestuffs and studying their application in…

Abstract

Purpose

This study aims to the synthesis of some novel 4-arylazo-3-hydroxythiophene analogues containing sulphapyridine and sulphathiazole dyestuffs and studying their application in dyeing polyester fabrics and rendering their antibacterial efficacy.

Design/methodology/approach

Simultaneous dyeing and antibacterial finishing for polyester fabric using a new antibacterial disperse dye having a modified chemical structure to thiophene dyes were studied. Construction of the thiophene dyes was carried out by diazo-coupling of diazotized sulphonamide-containing heterocyclic rings sulphapyridine and sulphathiazole with ethyl α-phenylthiocarbamoyl-acetoacetate followed by cyclizing the produced 2-arylazo-thioacetanilide with various α-halogenated reagents. All newly synthesized compounds were characterized by elemental analysis and extensive study of their spectral data (IR and 1H-NMR). The dyeing characteristics of these thiophene dyestuffs were evaluated at optimum conditions. Antibacterial activities of the obtained thiophene dyes were studied against some Gram-positive and Gram-negative bacteria.

Findings

The synthesized thiophene-containing sulphonamides dyes were applied on polyester fabric. The modified dyes exhibited a good fastness properties and antibacterial efficacy against some Gram-positive and Gram-negative bacteria. Synthesized dyes showed higher antibacterial potency than the reference standard drug.

Research limitations/implications

Synthesis of these disperse azo dyes for textile dyeing had never been reported previously.

Practical implications

The dyestuffs derived from thiophene are reasonable azo disperse dyestuffs giving good all-round fastness properties on polyester fabrics.

Originality/value

Thiophene dyes are used for dyeing polyester fabrics with brilliant colour and good fastness properties. The presence of sulphonamides moieties increase their fastness properties and elevate their antibacterial properties. Moreover, they can be used as antimicrobial finish due to their bactericidal properties on dyed textiles. This work afforded a new thiophene colorant that can be used in many different uses like polyester packing, thread Surgery, blends and other uses in medical textile.

Details

Pigment & Resin Technology, vol. 48 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 7 March 2023

Shahin Hossain, M. Abdul Jalil, Rois Uddin Mahmud and Abdul Kader

In recent years, natural dyes have attracted significant attention globally because of growing public awareness of the environment and health hazards associated with synthetic…

Abstract

Purpose

In recent years, natural dyes have attracted significant attention globally because of growing public awareness of the environment and health hazards associated with synthetic dyes. Natural dyes can provide special aesthetic qualities as well as the ethical significance of a product which is environmentally friendly. By keeping this burning issue in mind, this study aims to explore the dyeing properties of various unexplored environmentally friendly natural dyes.

Design/methodology/approach

In this study, the aqueous extract of coconut leaves is used for dyeing purpose. The silk and jute fabrics were dyed with the extract alone as well as in combination with metal salts as mordants by employing pre-, meta- and postmordanting techniques. The dyeing properties of the colored samples were evaluated by measuring their color strength; CIEL*a*b* values; and color fastness to washing, light and rubbing.

Findings

A yellow shade was achieved when the fabric samples were dyed solely with the extract. However, shade variations were observed when different mordants and mordanting techniques were applied. In all the cases, metallic salts improved the color fastness properties of dyed samples to washing, light and rubbing especially for the silk fabric.

Originality/value

To the best of the authors’ knowledge, this is the first report on a natural dye extracted from the leaves of coconut. Leaf as the source of dye has added an extra advantage, as it is reproducible and can be collected easily without harming the plants. The reported dye could be an attractive choice for sustainable and eco-friendly dyeing.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 7 November 2008

M.H. Helal, G.H. Elgemeie and D.M. Masoud

This paper's aim is to evaluate the dyeing performance of newly designed azo dye system based on thiazole substituted for improved dyeing when applied to synthetic fibres.

Abstract

Purpose

This paper's aim is to evaluate the dyeing performance of newly designed azo dye system based on thiazole substituted for improved dyeing when applied to synthetic fibres.

Design/methodology/approach

For improved dyeing qualities, various azo dye systems were synthesised based on polyfunctionally substituted thiazole as the coupling component. The heterocyclic moiety was coupled with diazotised aromatic amines to afford the respective azo or hydrazono systems. The structure of the novel systems was elucidated based on elemental analysis and spectral data. Dyeing performance, electronic spectra and optical properties were characterised based on UV and K/S measurements. Fastness properties were evaluated.

Findings

The novel systems were designed so that the functionalities located on the heterocyclic ring afforded structure modification that led not only to good dispersion but also to improved adherence on the fibre. The location of the sites led to constructing a resonating system with higher electron mobility and higher absorption maxima.

Research limitations/implications

The azo dyes, used in the present context were synthesised via a step‐wise pathway leading to new dyes. In addition, the variations in substituents and location of sites on the heterocyclic core could also be studied.

Practical implications

The novel azo dye systems based on polyfunctionally substituted thiazole provided a simple practical access to a series of azo dyes with improved dyeing properties. The availability of starting materials, the simplicity and efficiency to production in good yields and high purity lead to valuable achievements for commercial production.

Originality/value

The designed azo dye systems could find numerous applications as disperse dyes in the fields of dyeing, printing and surface coating. Moreover, the systems can find applications as reactive dyes for wool, silk and cellulosic fibres.

Details

Pigment & Resin Technology, vol. 37 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 3 January 2023

Nilam C. Patel, Dipen H. Desai and Paresh N. Patel

This paper aims to develop a novel protocol for the synthesis of disperse dyes derived by a triple cascade reaction with lawsone in presence of Zn acetate as a catalyst. The…

Abstract

Purpose

This paper aims to develop a novel protocol for the synthesis of disperse dyes derived by a triple cascade reaction with lawsone in presence of Zn acetate as a catalyst. The developed novel scaffolds have efficient dyeing properties on nylon and polyester fibers.

Design/methodology/approach

This report demonstrates an effectual triple cascade protocol for the synthesis of novel disperse dyes derived from various polynuclear carbaldehyde, urea and lawsone. The Zn acetate was found to be an effective catalyst for this reaction. Their dyeing performance has been studied on nylon and polyester fabrics. The wash fastness, sublimation fastness, color assessment, determination of percentage exhaustion and fixation properties were applied to both the dyed fabrics.

Findings

The obtained results indicate that the Zn acetate is an efficient catalyst for the developed triple cascade protocol. The prepared novel disperse dye greatly impacted their dyeing properties on nylon and polyester fibers. They have shown brilliant shades, higher affinity, adsorption capacity, superior tinctorial strength than the lawsone. The percentage exhaustion value, fixation value, color strength (K/s) value, washing and sublimation fastness properties have been found very well in all dyed nylon samples compared to polyester samples. These results discloses that these disperses dyes are very useful to the growing importance of nylon and polyester fibers.

Research limitations/implications

The present protocol synthesizes the racemic mixture of the prepared molecules.

Practical implications

Developed protocol can be used for various other triple cascade processes. Also these molecules can be used for dyeing of other fabrics.

Social implications

With the help of commercialization of prepared molecules, it may provide the better alternative of the current disperse dyes. This may affect the various segments of society.

Originality/value

This report represents a novel protocol for the synthesis of modified novel disperse dyes with an efficient dyeing properties on nylon and polyester fibers.

Details

Research Journal of Textile and Apparel, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1560-6074

Keywords

1 – 10 of 335