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The purpose of this paper is to provide a critical and in‐depth review of the present status and recent developments in synthetic methodologies, reaction engineering, process design and quality control aspects associated with the manufacture of mono and multifunctional acrylate monomers.

This paper reviews commercially important UV cure mono and multifunctional acrylate monomers. It covers their synthesis, catalyst, and appropriate solvents for azeotropic removal of byproducts. The detail discussion on catalysis, basis of design of reactors and commercial plant and the process engineering associated with the manufacture has been supported through citation of synthesis of various acrylate monomers. The methodologies adopted for determination of physical, chemical and compositional characterisation of acrylate monomers have been presented. In addition, the guidelines regarding the bulk storage and commercial handling of acrylates have been reviewed.

The reaction engineering of esterification reaction between acrylic acid and polyol has been worked out to provide the basis for selection of reactors. The reaction has been modeled as a series – parallel complex reaction for providing explanation for generation of various byproducts/adducts and multiple esters.

The detailed discussion on formation, characterisation and treatment of Michael adducts and purification of acrylate monomers will be relevant for new researchers for further development. A review of guidelines on selection of homogenous and heterogeneous catalysts for synthesis of acrylate monomers has been presented.

Since the related literature on acrylate monomers is scarce, scattered and proprietary, the consolidated coverage in one paper will be useful.

BP Chemicals has introduced two speciality monomers, Bisomer PPM5S and Bisomer PPM6E, designed specifically for the surface coatings industry.

The conventional curing of oxirane containing molecules such as cycloaliphatic epoxies with organic acid anhydrides, organic acids, Lewis acids and blocked Lewis acids is widely practised in the industry and the reaction mechanisms are well documented and described in epoxy resin related books

Corporate executives who sit back and take a wait‐and‐see attitude in regard to defining their internal strategy for an environmental packaging program will face a rude awakening. Today's consumer will not accept a so‐called green package that is not an improvement over previous efforts and in addition, costs more. In reality, consumers are not speaking up for the environment with their pocketbooks; instead, they are speaking out and reacting in ways that are leading to environmental legislation.