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This study aims to investigate the influence of polyepoxysuccinic acid sodium (PESA), a green antiscalant, on the nucleation, crystallization and precipitation of magnesium phosphate.

The conductivity method was used to investigate the maximum relative supersaturation of magnesium phosphate across various PESA dosages. Subsequently, a magnesium phosphate scale was prepared using the static scale inhibition method (GB/T16632-1996) and then analyzed via scanning electron microscopy.

The findings showed that PESA extends the induction period of magnesium phosphate crystallization, reduces crystal growth rate and elevates the solution’s relative supersaturation. Notably, PESA exerts a low dosage effect on inhibition of the magnesium phosphate scale, with the optimal dosage identified at 10 mL. Scanning electron microscopy revealed that PESA dispenses a dispersing effect on the magnesium phosphate scale, generating numerous concave, convex and deeper pores on the scale particles’ surface, and thereby significantly enhancing the surface area, especially when using an antiscalant with variable dosages.

This study sheds new light on the impact of PESA, a green antiscalant, on the crystallization and precipitation of magnesium phosphate, thus paving the way for the development of enhanced and eco-friendly scale inhibition strategies in future applications.

Polyethylene terephthalate (PET) as a fiber molding polymer is widely used in aerospace, electrical and electronic, clothing and other fields. The purpose of this study is to improve the thermal insulation performance of polyethylene terephthalate (PET), the SiO₂ aerogel/PET composites slices and fibers were prepared, and the effects of the SiO₂ aerogel on the morphology, structure, crystallization property and thermal conductivity of the SiO₂ aerogel/PET composites slices and their fibers were systematically investigated.

The mass ratio of purified terephthalic acid and ethylene glycol was selected as 1:1.5, which was premixed with Sb₂O₃ and the corresponding mass of SiO₂ aerogel, and SiO₂ aerogel/PET composites were prepared by direct esterification and in-situ polymerization. The SiO₂ aerogel/PET composite fibers were prepared by melt-spinning method.

The results showed that the SiO₂ aerogel was uniformly dispersed in the PET matrix. The thermal insulation coefficient of PET was significantly reduced by the addition of SiO₂ aerogel, and the thermal conductivity of the 1.0 Wt.% SiO₂ aerogel/PET composites was reduced by 75.74 mW/(m · K) compared to the pure PET. The thermal conductivity of the 0.8 Wt.% SiO₂ aerogel/PET composite fiber was reduced by 46.06% compared to the pure PET fiber. The crystallinity and flame-retardant coefficient of the SiO₂ aerogel/PET composite fibers showed an increasing trend with the addition of SiO₂ aerogel.

The SiO₂ aerogel/PET composite slices and their fibers have good thermal insulation properties and exhibit good potential for application in the field of thermal insulation, such as warm clothes. In today’s society where the energy crisis is becoming increasingly serious, improving the thermal insulation performance of PET to reduce energy loss will be of great significance to alleviate the energy crisis.

In this study, SiO₂ aerogel/PET composite slices and their fibers were prepared by an in situ polymerization process, which solved the problem of difficult dispersion of nanoparticles in the matrix and the thermal conductivity of PET significantly reduced.

Orange peel formation remains to be understood clearly because it is difficult to directly observe a laser-sintered process in a partcake. Therefore, this study aims to provide insight into the orange peel formation mechanism through the nondestructive observation of laser-sintered specimens and their surrounding powders.

This study observed polyamide 12 powder in the vicinity of a laser-sintered specimen via X-ray computed tomography (CT) scanning. The specimen for nondestructive observation was 3D modeled in a hollow box using 3D CAD software. The boxes built using a laser-sintering system contained unsintered surrounding powder and sintered specimens. The box contents were preserved even after the boxes were removed from the partcake. After X-ray CT scanning, the authors broke the boxes and evaluated the unevenness formed on the specimen surface (i.e. the orange peel evaluation).

Voids (not those in sintered parts) generated in the powder in the vicinity of the specimen triggered the orange peel formation. Voids were less likely to form in the build with a 178.5° powder bed than in the build with a 173.5° powder bed. Similarly, the increment in laser energy density effectively suppressed void formation, although there was a tradeoff with overmelting. Thin-walled parts avoided void growth and made the orange peel less noticeable.

To the best of the authors’ knowledge, this study is the first to observe and understand the relationship between voids generated in the powder in the vicinity of sintered parts and orange peel formation.

Paper aims to determinate caking paper manuscript cause through studying of the manuscript components, bio-deterioration and physio-chemical deterioration factor. It will facilitate manuscripts and paper conservators to understand paper blocking and caking phenomenon.

The manuscript condition has been diagnosed by focusing on adhesion and fossilization regions. To achieve this, some methods of analysis and examination were used, such as visual examination, digital microscopy and scanning electron microscope were used to studying surface changes. X-ray diffraction and Fourier transform infrared microscopy were used to determinate of cellulose crystallinity, ink composition and identify the binding medium.

The results revealed the use of cotton pulp, and calcium carbonate was among the fillers that were used to improve the properties of paper. The crystallization of cellulose was lower in the first and last papers than the papers located in the heart of the manuscript. The most important reasons that led to the papers caking was the presence of fungi A. niger, Cladosporium sp, Chaetomium sp, by secreting some enzymes in combination with some other factors such as difference variation in temperature and moisture.

All deterioration factors participate with each other until rule the damage circle of the papers because one factor alone cannot stick the papers. It was inferred from the examinations and analyzes that were conducted for the samples.

Titanium(IV) oxide nanoparticles (TiO₂ NP) were deposited to cotton denim fabrics using a self-crosslinking acrylate – a polymer dispersion to extend the lifetime of the products. This study aims to determine the optimum conditions to increase abrasion resistance, to provide self-cleaning properties of denim fabrics and to examine the effects of these applications on other physical properties.

The denim samples were first treated with nonionic surfactant to increase their wettability. Three different amounts of the polymer dispersion and two different pH levels were selected for the experimental design. The finishing process was applied to the fabrics with pad-dry-cure method.

The presence of the coatings and the adhesion of TiO₂ NPs to the surfaces were confirmed by scanning electron microscope and Fourier transform infrared spectroscopy analysis. It was ascertained that the most appropriate self-crosslinking acrylate amount and ambient pH level is 10 mL and “2”, respectively, for providing increased abrasion resistance (2,78%) and enhanced self-cleaning properties (363,4%) in the denim samples. The coating reduced the air permeability and softness of the denim samples. Differential scanning calorimetry and thermogravimetry analysis results showed that the treatments increased the crystallization temperatures and melting enthalpy values of the denim samples. Based on the thermal test results, it is clear that mass loss of the denim samples at 370°C decreased as the amount of self-crosslinking acrylate increased (at pH 3).

This study helped us to find out optimum amount of self-crosslinking acrylate and proper pH level for enhanced self-cleaning and abrasion strength on denim fabrics. With this finishing process, an environmentally friendly and long-life denim fabric was designed.

This paper aims to study the effects of inorganic CaCO₃ nanoadditives in the polylactic acid (PLA) matrix and fused filament fabrication (FFF) process parameters on the mechanical characteristics of 3D-printed components.

The PLA filaments containing different levels of CaCO₃ nanoparticles have been produced by mix-blending/extrusion process and were used to fabricate tensile and three-point bending test samples in FFF process under various sets of printing speed (PS), layer thickness (LT), filling ratio (FR) and printing pattern (PP) under a Taguchi L27 orthogonal array design. The quantified values of mechanical characteristics of 3D-printed samples in the uniaxial and the three-point bending experiments were modeled and optimized using a hybrid neural network/particle swarm optimization algorithm. The results of this hybrid scheme were used to specify the FFF process parameters and the concentration of nanoadditive in the matrix that result in the maximum mechanical properties of fabricated samples, individually and also in an accumulative response scheme. Diffraction scanning calorimetry (DSC) tests were conducted on a number of samples and the results were used to interpret the variations observed in the response variables of fabricated components against the FFF parameters and concentration of CaCO₃ nanoadditives.

The results of optimization in an accumulative scheme showed that the samples of linear PP, fabricated at high PS, low LT and at 100% FR, while containing 0.64% of CaCO₃ nanoadditives in the matrix, would possess the highest mechanical characteristics of 3D-printed PLA components.

FFF is a widely accepted additive manufacturing technique in production of different samples, from prototypes to the final products, in various sectors of industry. The incorporation of chopped fibers and nanoparticles has been introduced recently in a few articles to improve the mechanical characteristics of produced components in FFF technique. However, the effectiveness of such practice is strongly dependent on the extrusion parameters and composition of polymer matrix.

The purpose of this study is to develop a multifunctional coating layer based on nitrocellulose (NC)/acrylic resins containing precipitated silica and kaolin and investigate its suitability for use in packaging applications.

Different loading levels (1 and 5 Wt.%) of precipitated silica or kaolin particles were incorporated into NC/acrylic-based coating formulations and applied on low-density polyethylene (LDPE) films. The coatings and coated LDPE films were characterized in terms of structural, physical, mechanical, thermal, optical, surface, morphological and water vapor barrier properties.

The glossiness of the coating formulations decreased by increasing the precipitated silica and kaolin content. The incorporation of kaolin (1 and 5 Wt.%) and precipitated silica (1 Wt.%) had no significant effect on the melting temperature of LDPE film; however, with the addition of 5 Wt.% precipitated silica, the melting and crystallization temperatures were significantly changed. The incorporation of 5 Wt.% precipitated silica and kaolin also enhanced the water vapor barrier properties of LDPE films. The light transmittance declined with the precipitated silica and kaolin addition, especially in the ultraviolet (UV)-A/UV-B spectrum regions indicating an excellent UV light protection.

It was concluded that NC/acrylic resins coatings containing precipitated silica and kaolin exhibit improved thermal stability, UV and water vapor barrier properties and have the potential for use in packaging applications.

Material extrusion additive manufacturing processes inevitably produce bead-shaped surface patterns on the walls of parts, which create stress concentrations under load. This study aims to investigate the influence of such stress concentrations on the strength along the build direction (“Z-strength”).

This work consists of two main parts – an experimental demonstration to show the significance of stress concentrations on the Z-strength, followed by numerical modeling to evaluate the theoretical stress concentration factors (k_t) for such shapes. Meso-scale finite element analysis (FEA) was performed to evaluate k_t at the roots of the intersecting bead shapes. The critical bead shape parameters influencing k_t were identified, and parametric FEA studies were performed on different bead shapes by varying the normalized parameters.

The experimental results showed that up to a 40% reduction in the effective Z-strength could be attributed only to the presence of surface bead shapes. Bead overhang and root radius were identified as critical shape parameters influencing k_t. The results of the parametric FEA studies were used to generate a single empirical equation to determine k_t for any bead shape.

Predictive models for Z-strength often focus on crystallization kinetics and polymer chain interdiffusion to predict interlayer adhesion strength. The authors propose that the results of such studies must be combined with surface bead-shape induced stress concentration factors to obtain the combined, “effective” Z-strength.

The consolidation process and morphology evolution in ceramics-based additive manufacturing (AM) are still not well-understood. As a way to better understand the ceramic selective laser sintering (SLS), a dynamic three-dimensional computational model was developed to forecast thermal behavior of hydroxyapatite (HA) bioceramic.

AM has revolutionized automotive, biomedical and aerospace industries, among many others. AM provides design and geometric freedom, rapid product customization and manufacturing flexibility through its layer-by-layer technique. However, a very limited number of materials are printable because of rapid melting and solidification hysteresis. Melting-solidification dynamics in powder bed fusion are usually correlated with welding, often ignoring the intrinsic properties of the laser irradiation; unsurprisingly, the printable materials are mostly the well-known weldable materials.

The consolidation mechanism of HA was identified during its processing in a ceramic SLS device, then the effect of the laser energy density was studied to see how it affects the processing window. Premature sintering and sintering regimes were revealed and elaborated in detail. The full consolidation beyond sintering was also revealed along with its interaction to baseplate.

These findings provide important insight into the consolidation mechanism of HA ceramics, which will be the cornerstone for extending the range of materials in laser powder bed fusion of ceramics.

The purpose of this study is to carry out a comprehensive analysis of magneto-hydrodynamics (MHD), nanofluidic flow dynamics and heat transfer as well as thermodynamic irreversibility, within a novel butterfly-shaped cavity. Gaining a thorough understanding of these phenomena will help to facilitate the design and optimization of thermal systems with complex geometries under magnetic fields in diverse applications.

To achieve the objective, the finite element method is used to solve the governing equations of the problem. The effects of various controlling parameters such as butterfly-shaped triangle vertex angle (T), Rayleigh number (Ra), Hartmann number (Ha) and magnetic field inclination angle (γ ) on the hydrothermal performance are analyzed meticulously. By investigating the effects of these parameters, the authors contribute to the existing knowledge by shedding light on their influence on heat and fluid transport within butterfly-shaped cavities.

The major findings of this study reveal that the geometrical shape significantly alters fluid motion, heat transfer and irreversibility production. Maximum heat transfer, as well as entropy generation, occurs when the Rayleigh number reaches its maximum, the Hartmann number is minimized and the angle of the magnetic field is set to 30° or 150°, while the butterfly wings angle or vertex angle is kept at a maximum of 120°. The intensity of the magnetic field significantly controls the heat flow dynamics, with higher magnetic field strength causing a reduction in the flow strength as well as heat transfer. This configuration optimizes the heat transfer characteristics in the system.

Further research can be expanded on this study by examining thermal performance under different curvature effects, orientations, boundary conditions and additional factors. This can be accomplished through numerical simulations or experimental investigations under various multiphysical scenarios.

The geometric configurations explored in this research have practical applications in various engineering fields, including heat exchangers, crystallization processes, microelectronic devices, energy storage systems, mixing processes, food processing, air-conditioning, filtration and more.

This study brings value by exploring a novel geometric configuration comprising the nanofluidic flow, and MHD effect, providing insights and potential innovations in the field of thermal fluid dynamics. The findings contribute a lot toward maximizing thermal performance in diverse fields of applications. The comparison of different hydrothermal behavior and thermodynamic entropy production under the varying geometric configuration adds novelty to this study.