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Article
Publication date: 9 October 2023

Zhijie Yuan, Hao Wang, Rou Li, Jianxiao Mao and Hui Gao

This paper aims to investigate the equivalent relationship between accelerated corrosion tests and real environmental spectrum of suspenders in long-span suspension bridge…

Abstract

Purpose

This paper aims to investigate the equivalent relationship between accelerated corrosion tests and real environmental spectrum of suspenders in long-span suspension bridge considering multiple factors action.

Design/methodology/approach

Based on Faraday's law, corrosion current was used as a measure of metal corrosion, and the equivalent conversion relationship between laboratory environment and real service environment was established. The equivalent conversion method for bridge structural steel had been determined under different temperature, humidity, pH value and NaCl concentration conditions. The compilation of environmental spectra for large span bridges considering multiple factors and the principle of equivalent conversion have been proposed.

Findings

Environmental factors, including temperature, humidity, pH value and NaCl concentration, have significant impact on the corrosion degree of suspension steel wires, and only considering these two factors for equivalent conversion cannot accurately reflect the true service environment of the bridge. The 33.8-h salt spray accelerated corrosion test using the standard conditions can be equivalent to one year of suspenders corrosion in a real service environment.

Originality/value

The equivalent accelerated corrosion method for steel wires proposed in this study can effectively predict the corrosion degree of the suspenders, which has been verified to be correct and can provide theoretical guidance for the development of corrosion test plans for steel wires and engineering technical basis for anti-corrosion control and calendar life research of suspension bridge suspenders.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 14 June 2022

Mustafa Eken

The aim of this study is to investigate the usability of horsetail, sunflower stalk, wheat stalk and corn stalk ashes as additives in paints and their performance against…

Abstract

Purpose

The aim of this study is to investigate the usability of horsetail, sunflower stalk, wheat stalk and corn stalk ashes as additives in paints and their performance against corrosion resistance when used.

Design/methodology/approach

The ashes of horsetail, sunflower stalk, wheat stalk and corn stalk were investigated in this study in single, binary and ternary combinations with three different percentages as additives in paints. Samples of concrete with any combinations of ashes resisted against the corrosion of steel reinforcements, but horsetail ash proved to be the most effective.

Findings

It can be said that these research results show that the paint containing horsetail ash is an excellent coating material that can be used in paints for the corrosion resistance of steel in reinforced concrete. The corrosion rate decreased with the increase in the amount of reactive SiO2. There was less mass loss with the formation of resistance against corrosion in the horsetail ash added concretes. That is why horsetail ash is one of the most effective options for the aforementioned purpose.

Originality/value

Being cheap and easily obtainable, the materials used for coating in this study are perfect candidates for industrial use.

Details

Pigment & Resin Technology, vol. 52 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 6 September 2023

Donghui Hu, Shenyou Song, Zongxing Zhang and Linfeng Wang

This paper aims to figure out the conundrum that the corrosion resistance longevity of steel wires for bridge cables was arduous to meet the requirements.

Abstract

Purpose

This paper aims to figure out the conundrum that the corrosion resistance longevity of steel wires for bridge cables was arduous to meet the requirements.

Design/methodology/approach

The “two-step” hot-dip coating process for cable steel wires was developed, which involved first hot-dip galvanizing and then hot-dip galvanizing of aluminum magnesium alloy. The corrosion rate, polarization curve and impedance of Zn–6Al–1Mg and Zn–10Al–3Mg alloy-coated steel wires were compared through acetate spray test and electrochemical test, and the corrosion mechanism of Zn–Al–Mg alloy-coated steel wires was revealed.

Findings

The corrosion resistance of Zn–10Al–3Mg alloy-coated steel wires had the best corrosion resistance, which was more than seven times that of pure zinc-coated steel wires. The corrosion current of Zn–10Al–3Mg alloy-coated steel wires was lower than that of Zn–6Al–1Mg alloy-coated steel wires, whereas the capacitive arc and impedance value of the former were higher than that of the latter, making it clear that the corrosion resistance of Zn–10Al–3Mg was better than that of Zn–6Al–1Mg alloy coating. Moreover, the Zn–Al–Mg alloy-coated steel wires for bridge cables had the function of coating “self-repairing.”

Originality/value

Controlling the temperature and time of the hot dip galvanizing stage can reduce the thickness of transition layer and solve the problem of easy cracking of the transition layer in the Zn–Al–Mg alloy coating due to the Sandelin effect.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 1 April 2024

Liang Ma, Qiang Wang, Haini Yang, Da Quan Zhang and Wei Wu

The aim of this paper is to solve the toxic and harmful problems caused by traditional volatile corrosion inhibitor (VCI) and to analyze the effect of the layered structure on the…

Abstract

Purpose

The aim of this paper is to solve the toxic and harmful problems caused by traditional volatile corrosion inhibitor (VCI) and to analyze the effect of the layered structure on the enhancement of the volatile corrosion inhibition prevention performance of amino acids.

Design/methodology/approach

The carbon dots-montmorillonite (DMT) hybrid material is prepared via hydrothermal process. The effect of the DMT-modified alanine as VCI for mild steel is investigated by volatile inhibition sieve test, volatile corrosion inhibition ability test, electrochemical measurement and surface analysis technology. It demonstrates that the DMT hybrid materials can improve the ability of alanine to protect mild steel against atmospheric corrosion effectively. The presence of carbon dots enlarges the interlamellar spacing of montmorillonite and allows better dispersion of alanine. The DMT-modified alanine has higher volatilization ability and an excellent corrosion inhibition of 85.3% for mild steel.

Findings

The DMT hybrid material provides a good template for the distribution of VCI, which can effectively improve the vapor-phase antirust property of VCI.

Research limitations/implications

The increased volatilization rate also means increased VCI consumption and higher costs.

Practical implications

Provides a new way of thinking to replace the traditional toxic and harmful VCI.

Originality/value

For the first time, amino acids are combined with nano laminar structures, which are used to solve the problem of difficult volatilization of amino acids.

Details

Anti-Corrosion Methods and Materials, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 27 July 2023

Li Fan and Biao Nie

This paper aims to investigate the evolution law of surface characteristic of corroded cold-formed thin-walled steel in industrial environments.

Abstract

Purpose

This paper aims to investigate the evolution law of surface characteristic of corroded cold-formed thin-walled steel in industrial environments.

Design/methodology/approach

Five test specimens sourced from cold-formed thin-walled C-shaped steel that have been in service for three years in actual industrial environments were subjected to surface characteristic test. The surface characteristic of corroded hot-rolled steel and cold-formed steel were compared and analyzed. The relationship between the surface morphology parameters and the average corrosion depth was established.

Findings

The evolution law of the surface morphology of corroded cold-formed thin-walled steel and corroded hot-rolled steel was similar. The frequency histogram of corrosion depth was mainly single peak with high values on the middle and low values on both sides. The corrosion depth conformed to the normal distribution. The roughness average height and the root mean square of surface height gradually increased linearly with increasing the average corrosion depth.

Originality/value

The reduction in the standard deviation of corrosion depth, the maximum corrosion depth, the roughness average height and the root mean square of surface height of the cold-formed thin-walled steel was smaller than those of the hot-rolled steel.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 5
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 6 June 2023

Xuehui Hao, Changzheng Wang, Shuai Guo, Jie Ma, Hui Chen and Xingchuan Zhao

The poor corrosion resistance of the ferrite-pearlite steel limits its application in marine engineering because of the enhanced galvanic effect caused by continuously accumulated…

Abstract

Purpose

The poor corrosion resistance of the ferrite-pearlite steel limits its application in marine engineering because of the enhanced galvanic effect caused by continuously accumulated cementite. Cr as one principal alloying element is commonly used to improve the corrosion resistance of steels. This paper aims to study the effect of Cr on corrosion behaviors of ferrite-pearlite steels in an acidic environment.

Design/methodology/approach

The tested steels were immersed in a simulated solution of 10 Wt.% NaCl with pH 0.85 for 72 h to evaluate the corrosion rate. After the immersion test, the corrosion morphologies and products were tested by scanning electron microscopy, energy dispersive X-ray analysis and X-ray diffraction. Meanwhile, an electrochemical workstation was used to study the electrochemical behaviors of samples.

Findings

At the initial corrosion stage, the corrosion rate increased in the sequence of Cr0, Cr0.5 and Cr1 steels, which was because of the competitive effect between the area ratio and the driving force caused by alloyed Cr. However, Cr1 steel exhibited the best corrosion resistance after a 72-h immersion test. This was because the alloyed Cr promoted the formation of protective Fe2O3 and FeCr2O4, which suppressed the preferential dissolution of ferrite and, thus, reduced the accumulation rate of carbides, resulting in the weakened galvanic corrosion.

Originality/value

This paper reports the role that Cr plays in the galvanic corrosion of ferrite-pearlite steels, which is important for the engineering application of ferrite-pearlite steels in marine environment.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 4
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 22 April 2024

Sixian Rao, Changwei Zhang, Fei Zhao, Lei Bao and Xiaoyi Wang

This paper aims to explore the influence of corrosion-deformation interactions (CDI) on the corrosion behavior and mechanisms of 316LN under applied tensile stresses.

Abstract

Purpose

This paper aims to explore the influence of corrosion-deformation interactions (CDI) on the corrosion behavior and mechanisms of 316LN under applied tensile stresses.

Design/methodology/approach

Corrosion of metals would be aggravated by CDI under applied stress. Notably, the presence of nitrogen in 316LN austenitic stainless steel (SS) would enhance the corrosion resistance compared to the nitrogen-absent 316L SS. To clarify the CDI behaviors, electrochemical corrosion experiments were performed on 316LN specimens under different applied stress levels. Complementary analyses, including three-dimensional morphological examinations by KH-7700 digital microscope and scanning electron microscopy coupled with energy dispersive spectroscopy, were conducted to investigate the macroscopic and microscopic corrosion morphology and to characterize the composition of corrosion products within pits. Furthermore, ion chromatography was used to analyze the solution composition variations after immersion corrosion tests of 316LN in a 6 wt.% FeCl3 solution compared to original FeCl3 solution. Electrochemical experiment results revealed the linear decrease in free corrosion potential with increasing applied stress. Electrochemical impedance spectroscopy results indicated that high tensile stress level damaged the integrity of passivation film, as evidenced by the remarkable reduction in electrochemical impedance. Ion chromatography analyses proved the concentrations increase of NO3 and NH4+ ion concentrations in the corrosion media after corrosion tests.

Findings

The enhanced corrosion resistance of 316LN SS is attributable to the presence of nitrogen.

Research limitations/implications

The scope of this study is confined to the influence of tensile stress on the electrochemical corrosion of 316LN at ambient temperatures; it does not encompass the potential effects of elevated temperatures or compressive stress.

Practical implications

The resistance to stress electrochemical corrosion in SS may be enhanced through nitrogen alloying.

Originality/value

This paper presents a systematic investigation into the stress electrochemical corrosion of 316LN, marking the inaugural study of its impact on corrosion behaviors and underlying mechanisms.

Details

Anti-Corrosion Methods and Materials, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 21 February 2024

Shuliu Wang, Qianqian Liu, Jin Wang, Nana Chen, JunHang Chen, Jialiang Song, Xin Zhang and Kui Xiao

This study aims to investigate the role of aluminium (Al) in marine environment and the corrosion mechanism of galvalume coatings by conducting accelerated experiments and data…

Abstract

Purpose

This study aims to investigate the role of aluminium (Al) in marine environment and the corrosion mechanism of galvalume coatings by conducting accelerated experiments and data analysis.

Design/methodology/approach

Samples were subjected to accelerated corrosion for 136 days via salt spray tests to simulate the natural conditions of marine environment and consequently accelerate the experiments. Subsequently, the samples were examined using various test methods, such as EDS, scanning electron microscopy (SEM), X-ray diffraction (XRD) and electrochemical impedance spectroscopy (EIS), and the obtained data were analysed.

Findings

Galvalume coatings comprised interdigitated zinc (Zn)-rich and dendritic Al-rich phases. Corrosion was observed to begin with a Zn-rich phase. The primary components of the corrosion product film were Al2O3 and Zn5(OH)8Cl2·H2O. It was confirmed that the role of Al was to form a dense protective film, thereby successfully blocking the entry of corrosive media and protecting the iron substrate.

Originality/value

This study provides a clearer understanding of the corrosion mechanism and kinetics of galvalume coatings in a simulated marine environment. In addition, the role of Al, which is rarely mentioned in the literature, was investigated.

Details

Anti-Corrosion Methods and Materials, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 31 July 2023

Badegül Tunçay, Harun Çuğ, Tansel Tunçay, Dursun Özyürek and Katarzyna Cesarz-Andraczke

This study aims to investigate NiTi alloys’ characterization and corrosion behaviour produced by two different powder metallurgy (PM) methods.

Abstract

Purpose

This study aims to investigate NiTi alloys’ characterization and corrosion behaviour produced by two different powder metallurgy (PM) methods.

Design/methodology/approach

It was pre-formed under a protective atmosphere at 900 °C under a force of 45 MPa and sintered for 1 h under 10–6 Mbar in an atmosphere-controlled heat treatment furnace at 1,100 °C. The relationship between microstructural properties, SEM, XRD, density, microhardness and corrosion behaviour of pre-alloyed NiTi alloys produced by two different methods with the production method was investigated.

Findings

As a result of the studies, TiO, NiTi, NiTi2 and Ni3Ti intermetallics were determined in XRD examinations. The best surface roughness was observed in the mechanically milled (MM’ed) pre-alloyed NiTi alloy compared to the pre-alloyed NiTi alloy mixed with turbula. The corrosion tests performed in 3.5% NaCl solution determined that the MM’ed pre-alloyed NiTi alloy had better corrosion resistance than the pre-alloyed NiTi alloy mixed with turbula. Pitting corrosion was visualized in the SEM images taken from the corrosion surfaces.

Originality/value

Two different PM methods produced pre-alloyed NiTi powders, and the effects of these methods on the mechanical and corrosion resistance of NiTi alloys were systematically investigated for the first time.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 9 May 2023

Zhuangsu Kang, Zongxing Zhang, Shenyou Song, Qian Cheng, Siyu Tao and Ya Ni

This paper aims to investigate the effect of characteristic parameters of pits on the mechanical properties and fracture model of cable steel wires.

Abstract

Purpose

This paper aims to investigate the effect of characteristic parameters of pits on the mechanical properties and fracture model of cable steel wires.

Design/methodology/approach

The tensile test and finite element analysis of steel wires with corrosion damage were carried out. The stress development of corroded steel wire under corrosion morphology was studied by the 3D reverse reconstruction technology. The internal relationship between the stress triaxiality, equivalent plastic strain and pit depth, depth-width ratio of corroded steel wire was discussed.

Findings

With the increase of corrosion degree, the neck shrinkage phenomenon of steel wire was not significant, and the crack originated near the pit bottom and expanded to the section inside of specimen. The fiber area of corroded steel wire decreased while the radiation area increased, and the ductile fracture gradually changed to brittle fracture. The pit size significantly changed the triaxial degree and distribution of stress and accelerated the initiation and propagation of internal cracks at the neck shrinkage stage.

Originality/value

The proposed fracture model based on the void growth model could accurately simulate the fracture behavior of steel wires with corrosion damage.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 4
Type: Research Article
ISSN: 0003-5599

Keywords

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