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Article
Publication date: 7 February 2020

Xianping Wei and Wen Jie Zheng

This paper aims to expand the application area of Inconel 718 alloy in marine environment, the sensitivity of pitting corrosion should be analyzed and discussed, especially the…

Abstract

Purpose

This paper aims to expand the application area of Inconel 718 alloy in marine environment, the sensitivity of pitting corrosion should be analyzed and discussed, especially the effect of block carbides.

Design/methodology/approach

Effect of carbides on the sensitivity of pitting corrosion for Inconel 718 alloy was carried out at 30°C in 3.5% NaCl solution using dynamic electrochemical impedance spectroscopy and anodic polarization techniques. In addition, the initiation of pitting corrosion was investigated by immersion test in 0.05 M HCl + 6% FeCl3 solution.

Findings

As a result, the precipitation of carbides, as the initiation of pitting corrosion, increased pitting corrosion susceptibility, especially the block carbides could lead to deep-spalling. Within that process, temperature and potential acted as the main controlling factors, and the effect of the latter was more distinct.

Originality/value

The initiation of pitting corrosion was revealed by the immersion test. The mechanism of pitting corrosion was analyzed and discussed.

Details

Anti-Corrosion Methods and Materials, vol. 67 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 12 February 2024

Siquan Zhang

In eddy current nondestructive testing, ferrite-cored probes are usually used to detect and locate defects such as cracks and corrosion in conductive materials. However, the…

Abstract

Purpose

In eddy current nondestructive testing, ferrite-cored probes are usually used to detect and locate defects such as cracks and corrosion in conductive materials. However, the generic analytical model for evaluating corrosion in layered conductor using ferrite-cored probe has not yet been developed. The purpose of this paper is to propose and verify the analytical model of an E-cored probe for evaluating corrosion in layered conductive materials.

Design/methodology/approach

A cylindrical coordinate system is adopted and the solution domain is truncated in the radial direction. The magnetic vector potential of each region excited by a filamentary coil is derived first, and then the expansion coefficients of the solution are obtained by matching the boundary and interface conditions between the regions and the subregions. Finally the closed-form expression of the impedance of the multi-turn coil is derived by using the truncated region eigenfunction expansion (TREE) method, and the impedance calculation is carried out in Mathematica. In the frequency range of 100 Hz to 10 kHz, the impedance changes of the E-cored coil and air-cored coil due to the layered conductor containing corrosion are calculated, respectively, and the influences of corrosion on the coil impedance change are investigated.

Findings

An analytical model for the detection and evaluating of corrosion in layered conductive materials using E-cored probe is proposed. The model can quickly and accurately calculate the impedance change of E-cored coil due to corrosion in layered conductor. The correctness of the analytical model is verified by finite element method and experiments.

Originality/value

An accurate theoretical model of E-cored probe for evaluating corrosion of multilayer conductor is presented. The analytical model can be used to detect the inhomogeneity of layered conductor, design ferrite-cored probe or directly evaluate the corrosion defects of layered conductors.

Details

COMPEL - The international journal for computation and mathematics in electrical and electronic engineering , vol. 43 no. 1
Type: Research Article
ISSN: 0332-1649

Keywords

Article
Publication date: 31 January 2020

Hui Li, Lei Fu, Li Lin, Yu Chen, YunRong Luo, XiuLan Li, WenLing Xie and Qingyuan Wang

In summary, it can be found that the current research on the simulation of natural atmospheric dry–wet alternating accelerated corrosion mainly focused on the study of…

Abstract

Purpose

In summary, it can be found that the current research on the simulation of natural atmospheric dry–wet alternating accelerated corrosion mainly focused on the study of electrochemical corrosion process and the study of corrosion rate; the micro-pre-corrosion mechanism of materials in this environment, especially for materials. The specific effects of fatigue and fracture performance still lack detailed research. Accordingly, this study aims to more realistically simulate the effect of natural atmospheric corrosion environment on the corrosion resistance and fatigue performance of aircraft skin.

Design/methodology/approach

In this study, the uniaxial strain control method was used to test the fatigue performance of pre-corrosion samples under simulated natural atmospheric corrosion using MTS809 tensile-torque composite fatigue machine. Scanning electron microscopy, X-ray energy spectrum analysis, atomic force microscopy and X-ray diffraction analysis were used. Fatigue fracture, corrosion morphology and corrosion products were analyzed.

Findings

The results show that the deep corrosion pit caused by pre-corrosion environment leads to multi-source initiation of crack; the fatigue life of pre-corroded sample decreases by about one-half, chloride ion invades the material and promotes intergranular corrosion; life prediction results show that the natural atmospheric corrosive environment mainly affects the plastic term in the Manson–Coffin formula resulting in a decrease in fatigue life.

Originality/value

Innovative experimental schemes and materials are used and the test temperature and relative humidity are strictly controlled. The corrosion failure mechanism of 2A70-T6 aluminum alloy under alternating wet and dry accelerated corrosion environment and its influence on fatigue behavior were obtained.

Details

Anti-Corrosion Methods and Materials, vol. 67 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 15 February 2022

Zhenhuan Gao, Yongxuan Liu, Chong Wang, Huisheng Yang, Lining Xu and Lijie Qiao

This study aims to report the CO2 corrosion performance of 3Cr steel and 3Cr2Al steel and reveal the role of aluminum in mitigating corrosion of low-Cr steel.

Abstract

Purpose

This study aims to report the CO2 corrosion performance of 3Cr steel and 3Cr2Al steel and reveal the role of aluminum in mitigating corrosion of low-Cr steel.

Design/methodology/approach

Aluminum was added to 3Cr steel to prepare a new type of 3Cr2Al steel, and the effect of aluminum on the corrosion resistance of pipeline steel was studied using morphology observation and composition analysis, weight loss tests and electrochemical test.

Findings

In the CO2/O2 coexistence environment, the average corrosion rate of the 3Cr2Al steel was obviously lower than that of the 3Cr steel. The addition of aluminum expanded the range of prepassivation, and the dynamic potential polarization curve of 3Cr2Al steel showed duplex prepassivation phenomena. 3Cr steel underwent severe local corrosion, and 3Cr2Al steel underwent uniform corrosion. The addition of aluminum contributed to the formation of a dense corrosion product layer and greatly reduced the localized corrosion sensitivity.

Originality/value

The studies on CO2 corrosion of aluminum containing low-Cr steel are quite rare. This study clarifies the role of aluminum by comparing the corrosion behavior of 3Cr2Al and 3Cr steel. The effect of aluminum on the growth of corrosion product film was discussed, and the duplex prepassivation phenomena of Cr and Al were revealed.

Details

Anti-Corrosion Methods and Materials, vol. 69 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 10 February 2022

Pengxiong Zhao, Wei Wu, Zeyu Ma and Yong Dan

This paper aims to investigate the corrosion evolution process of AZ91 magnesium alloy in 3.5 wt.% NaCl solution under different stresses by using in situ methods, thereby…

Abstract

Purpose

This paper aims to investigate the corrosion evolution process of AZ91 magnesium alloy in 3.5 wt.% NaCl solution under different stresses by using in situ methods, thereby evaluate the influence of stress on the corrosion sensitivity of AZ91 magnesium alloy, and discuss the potential mechanism.

Design/methodology/approach

A four-point bending method was used to apply different loads to the magnesium alloy samples, a charge coupled device camera and electrochemical impedance spectroscopy test being used for in situ study. Scanning electron microscopy and X-ray diffraction (XRD) analysis were performed for corrosion product and morphology characteristics.

Findings

The observation results show that the corrosion of AZ91 magnesium alloy becomes more and more serious with the increase in the stress and generated many corrosion products. Originally, corrosion products prevented alloy matrix from contacting the corrosive medium. However, the increase in the stress facilitated the emergence of the corrosion holes in the corrosion products, which provided the microscopic channels for corrosive solution to attack the Mg alloy matrix, and accelerated the corrosion of the magnesium alloy, resulting in a lot of corrosion pits on the magnesium alloy surface under the corrosion product layer.

Originality/value

The evolution information of corrosion process is crucial to explore the mechanism of corrosion. Currently, most researches about corrosion of magnesium alloy used traditional testing techniques to obtain corrosion information, lacking the direct tracking and monitoring of the corrosion evolution process. Hence, this paper focuses on in situ corrosion study of AZ91 magnesium alloy. The technology with spatial resolution capability observed the changes in magnesium alloy surface at different times in the corrosion process in situ. Meanwhile, the in situ electrochemical technology was used to monitor the changes in micro-electrochemical signals during the corrosion process of magnesium alloy under different stresses.

Details

Anti-Corrosion Methods and Materials, vol. 69 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 24 November 2023

Hailong Du, Zengyao Chen, Xiyan Wang, Yongliang Li, Renshu Yang, Zhiyong Liu, Aibing Jin and Xiaogang Li

The purpose of this paper is to develop new types of anchor bolt materials by adding corrosion-resistant elements for alloying and microstructure regulation.

Abstract

Purpose

The purpose of this paper is to develop new types of anchor bolt materials by adding corrosion-resistant elements for alloying and microstructure regulation.

Design/methodology/approach

Three new anchor bolt materials were designed around the 1Ni system. The stress corrosion cracking resistance of the new materials was characterized by microstructure observation, electrochemical testing and slow strain rate tensile testing.

Findings

The strength of the new anchor bolt materials has been improved, and the stress corrosion sensitivity has been reduced. The addition of Nb makes the material exhibit excellent stress corrosion resistance under –1,200 mV conditions, but the expected results were not achieved when Nb and Sb were coupled.

Originality/value

The new anchor bolt materials designed around 1Ni have excellent stress corrosion resistance, which is the development direction of future materials. Nb allows the material to retain its ability to extend in hydrogen-evolution environments.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 1
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 6 November 2017

Ting Yuan, Min-da Zhang, Jia-hui Ni, Ya-xuan Chen and Fei Geng

The purpose of this paper is to compare corrosion behavior of a modified multilayer material with Cu before and after brazing process.

Abstract

Purpose

The purpose of this paper is to compare corrosion behavior of a modified multilayer material with Cu before and after brazing process.

Design/methodology/approach

Sea water acidified accelerated tests (SWAATs), potentiodynamic polarization tests and scanning electron microscopy were used to study the corrosion behavior and macro/micro structures. Results indicate that the corrosion mechanisms of the sheets before and after brazing process are completely different.

Findings

The un-brazed material is uniform corrosion, while the brazed material has a high sensitivity to localized corrosion and loses cathodic protection to the core. It is found that brazing process causes copper transition from the core alloy into eutectic phases in the cladding, leading to higher Ecorr and different potential distribution compared with those of un-brazed materials.

Originality/value

For the modified multilayer material after brazing, there are two stages of corrosion. First, corrosion attack takes place along eutectic phases in the cladding material, and then core alloy dissolves by forming a galvanic couple with the nobler residual cladding.

Details

Anti-Corrosion Methods and Materials, vol. 64 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 1 April 1989

Harold G Bunce

In the “in‐service” maintenance and inspection of aircraft structures, an uneasy alliance exists between corrosion detection and Non‐Destructive Testing. NDT is a widely used and…

Abstract

In the “in‐service” maintenance and inspection of aircraft structures, an uneasy alliance exists between corrosion detection and Non‐Destructive Testing. NDT is a widely used and generally successful way of inspecting for structural defects and as the service life of aircraft is extended and corrosion therefore tends to become a not uncommon structural defect, why should not NDT be as useful in this situation as it often is in detecting cracks occasioned by extended flying hours and increased flight cycles? This paper tries to answer that question by pointing out some of the advantages and disadvantages of NDT applied to corrosion detection in the aviation industry.

Details

Aircraft Engineering and Aerospace Technology, vol. 61 no. 4
Type: Research Article
ISSN: 0002-2667

Article
Publication date: 12 December 2023

Ziru Zhou, Songlin Zheng, Jiahuan Chen, Ting Zhang, Zhen He and Yuxin Wang

The high specific strength makes magnesium alloys have a wide range of applications in aerospace, military, automotive, marine and construction industries. However, its poor…

Abstract

Purpose

The high specific strength makes magnesium alloys have a wide range of applications in aerospace, military, automotive, marine and construction industries. However, its poor corrosion resistance and weldability have limited its development and application. Friction stir welding (FSW) can effectively avoid the defects of fusion welding. However, the microstructure, mechanical properties and corrosion behavior of FSW joints in magnesium alloys vary among different regions. The purpose of this paper is to review the corrosion of magnesium alloy FSW joints, and to summarize the protection technology of welded joints.

Design/methodology/approach

The corrosion of magnesium alloy FSW joints includes electrochemical corrosion and stress corrosion. This paper summarizes corrosion protection techniques for magnesium alloys FSW joints, focusing on composition, microstructure changes and surface treatment methods.

Findings

Currently, this research is mainly focused on enhancing the corrosion resistance of magnesium alloy FSW joints by changing compositions, structural modifications and surface coating technologies. Refinement of the grains can be achieved by adjusting welding process parameters, which in turn minimizes the effects of the second phase on the alloy’s corrosion resistance.

Originality/value

This paper presents a comprehensive review on the corrosion and protection of magnesium alloys FSW joints, covering the latest research advancements and practical applications. It aims to equip researchers with a better insight into the field and inspire new studies on this topic.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 1
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 4 November 2013

Madeleine Du Toit and Josias Willem Van der Merwe

– This investigation aims to find the degree of passivation required to completely inhibit the stress corrosion cracking of carbon steel exposed to CO-CO2-H2O environments.

Abstract

Purpose

This investigation aims to find the degree of passivation required to completely inhibit the stress corrosion cracking of carbon steel exposed to CO-CO2-H2O environments.

Design/methodology/approach

A516 pressure vessel steel was exposed to distilled water with 25 per cent CO and 75 per cent CO2 at an overall pressure of 800 kPa with the introduction of potassium bichromate as an additional inhibitor. Slow strain-rate tests were performed to evaluate the steel for sensitivity to cracking. Electrochemical characteristics were investigated in parallel in order to determine the extent of passivation required with the addition of the inhibitor.

Findings

Slow strain-rate tests showed that between 100 and 1,000 ppm potassium bichromate was required to completely mitigate cracking with a significant reduction in passivation current densities.

Research limitations/implications

The chosen inhibitor is not ideal for practical applications as an inhibitor, but gave an indication of the passivation required.

Practical implications

The results showed that the added inhibitor might even cause increased sensitivity to cracking in this environment, with significant passivation required for resistance to cracking.

Originality/value

The degree of passivation required for complete resistance of carbon steel in 25 per cent CO-75 per cent CO2-H2O.

Details

Anti-Corrosion Methods and Materials, vol. 60 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

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