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The purpose of this paper was to investigate the corrosion behavior of X65 steel in the CO₂/oil/water environment using mass loss method, potentiodynamic polarization technique and characterization of the corroded surface techniques.

The weight loss analysis, electrochemical study and surface investigation were carried out on X65 steel that had been immersed in the CO₂/oil/water corrosive medium to understand the corrosion behavior of gathering pipeline steel. The weight loss tests were carried out in a 3L autoclave, and effects of flow velocity, CO₂ partial pressure and water cut on the CO₂ corrosion rate of X65 steel were studied. Electrochemical studies were carried out in a three-electrode electrochemical cell with the test temperature of 60°C and CO₂ partial pressure of 1 atm by recording open circuit potential/time and potentiodynamic polarization characteristics. The surface and cross-sectional morphologies of corrosion product scales were characterized using scanning electron microscopy. The phases of corrosion product scales were investigated using X-ray diffraction.

The results showed that corrosion rates of X65 steel both increased at first and then decreased with the increase of flow velocity and CO₂ partial pressure, and there were critical velocity and critical pressure in the simulated corrosive environment, below the critical value, the corrosion products formed on the steel surface were loose, porous and unstable, higher than the critical value, the corrosion product ?lms were dense, strong adhesion, and had a certain protective effect. Meanwhile, when the flow velocity exceeded the critical value, oil film could be adsorbed on the steel surface more evenly, corrosion reaction active points were reduced and the steel matrix was protected from being corroded and crude oil played a role of inhibitor, thus it influenced the corrosion rate. Above the critical CO₂ partial pressure, the solubility of CO₂ in crude oil increased, the viscosity of crude oil decreased and its fluidity became better, so that the probability of oil film adsorption increased, these factors led to the corrosion inhibition of X65 steel reinforced. The corrosion characteristics of gathering pipeline steel in the corrosive environment containing CO₂ would change due to the presence of crude oil.

The results can be helpful in selecting the suitable corrosion inhibitors and targeted anti-corrosion measures for CO₂/oil/water corrosive environment.

This study aims to investigate the effect of changes in iron content in 70/30 copper–nickel alloy on the corrosion process.

70Copper–30Nickel-xFe-1Mn (x = 0.4,0.6,0.8,1.0 Wt.%) alloy were prepared by the high frequency induction melting furnace. The scanning electron microscope, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and electrochemical impedance spectroscopy were used to analyze the morphology and component of the corrosion product film.

The results show that the corrosion resistance of 70/30 copper–nickel alloy added with 1.0%Fe is the best, and the film is divided into inner dense Cu2O composite film and outer hydration loose layer; XRD showed that after adding 1.0% Fe, the content of Cu2(OH)3Cl in the corrosion product film was significantly reduced, while the content of Cu2O remained unchanged; XPS showed that nickel accumulates in the inner layer of corrosion product film; the stage growth mode of the film, the role of nickel in it and the enrichment mechanism of iron in the inner film were summarized and discussed.

The changes in the composition and structure of the corrosion product film caused by the iron content are revealed, and the mechanism of the difference in corrosion resistance is discussed.

In the previous two articles the emphasis was on wet and electrochemical techniques, with particular reference to the potentiostat. The physical examination of corrosion products is of equal importance, especially, for example, in the study of oxidation by dry gases at elevated temperatures where electrochemical studies are not normally feasible. In this article the application of physical techniques to corrosion studies will be discussed.

The paper aims to study the effect of liquid flow velocity on corrosion behavior of 20# steel at initial stage under (CO2/aqueous solution) gas–liquid two-phase plug flow conditions.

Weight loss, scanning electron microscopy, energy-dispersive X-ray spectroscopy and XPS methods were used in this study.

The corrosion rate increased with the increasing liquid flow velocity at any different corrosion time. The corrosion rate decreased with the extension of corrosion time at the same liquid flow velocity. There was no continuous corrosion products film on the whole pipe wall at any different corrosion time. The macroscopic brown-yellow corrosion products on the pipe wall surface decreased with the increasing liquid flow velocity and the loose floccus corrosion products decreased gradually until these products were transformed into un-continuous needle-like dense products with the increasing liquid velocity. The main elements among the products film were Fe, C and O, and the main phases of products film on the pipe wall were Fe3C, FeCO3, FeOOH and Fe3O4. When the corrosion time was 1 h under different liquid–velocity condition, the thickness of local corrosion products film was from 3.5 to 3.8 µm.

The ion mass transfer model of corrosion process in pipe was put forward under gas–liquid two-phase plug flow condition. The total thickness of diffusion sublayer and turbulence sublayer decreased as well as the turbulence propagation coefficient increased with the increasing liquid velocity, which led to the increasing velocity of ion transfer during corrosion process. This was the fundamental reason for the increase of corrosion rate with the increasing liquid velocity.

The term microbiologically induced corrosion (MIC) appears to be very closely related to the composition of the bio‐film which harbours the micro‐organism. Formation of an initial slimy layer on immersed metallic substrates is the rate‐controlling parameter of bio‐fouling, as uninterrupted undesirable growth of bio‐films occurs over this layer. To contain this bio‐film problem, formation of an adherent layer of toxic and inhibited corrosion product, that interacts with biofilm, could be exploited. Deals with the preliminary interactions of a few copper‐based alloys, with mildly toxic alkaloid class‐inhibitive compounds, in a simulated marine environment. It is assumed that the toxic and inhibited corrosion product and bio‐film interaction layer will interfere with the formation of the initial slimy cover on the immersed surface, responsible for bio‐fouling. It is seen that these alkaloid compounds exert a limited response on the inhibition of copper‐based alloys like monel. Brucine appears to be a more effective inhibitor for the monel surface. Pre‐oxidation of the uninhibited brass surface and also post‐oxidation of the inhibited surface appear to consolidate the corrosion product bio‐film‐inhibitor interaction layers, indicating the compatibility of these alkaloid compounds to the probable thermal strains to be encountered in engineering services. This indicates the possibility of using these compounds in heat transfer devices, like heat exchangers, where seawater is used as coolant.

This study aims to investigate the initial corrosion behavior in aqueous solution of 20# seamless steel under (CO₂/aqueous solution) gas–liquid two-phase stratified flow conditions.

The initial corrosion behavior was studied through the weight loss methods, scanning electron microscopy with energy-dispersive x-ray spectroscopy and x-ray diffraction.

The corrosion rate of 20# steel obviously increases with the increasing gas pressure at different corrosion time when the CO₂ pressure is less than 0.11 MPa, and the increase of corrosion rate tends to be steady when the pressure exceeds 0.11 MPa. With the increase of CO₂ pressure, the corrosion products changed from flocculent to acicular, granular and scaly. A four-stage model for the growth of the corrosion product layer was proposed, namely, the diffusion reaction stage, the local film formation stage, the complete film formation stage and the densification stage of the product film.

A four-stage model for the growth of the corrosion product layer on the pipe wall surface under this condition was proposed, namely, the diffusion reaction stage, the local film formation stage, the complete film formation stage and the densification stage of the product film. The growing process and densification mechanism of corrosion products layer were discussed.

The aim of this paper was to clarify the influence of tensile stress on the electrochemical behavior of X80 steel in a simulated acid soil solution and attempt to understand mechanistic aspects of the corrosion behaviors of X80 under these conditions.

The electrochemical behavior of X80 steel at various tensile stresses was investigated in a simulated acid soil solution using electrochemical impedance spectroscopy, potentiodynamic scan measurements and surface analysis techniques.

The results show that as tensile stress was increased, the open-circuit potential decreased, the reaction activity increase, the reaction resistance (Rct)value became smaller by degrees, the corrosion product film resistance (Rf) first decreased and then increased and polarization current densities changed conversely. The corrosion product film was compact and continuous under the low stress, whereas it was relatively loose under high-stress conditions. Tensile stress promotes the movement of dislocations, which become active points when they move to the steel surface. The increase in the number of active points enhances the anodic dissolution rate and promotes the formation of corrosion product film whose blocking effect can decrease the dissolution rate. The corrosion rate of the specimen is determined by these two effects.

This research provides an essential insight into the mechanism of the electrochemical behavior of X80 steel in acid soil environments.

This paper aims to under the laboratory environment, the corrosion behavior of X80 pipeline steel in oilfield injection water in eastern China was studied by immersion test.

First, the corrosion product film was immersed in oilfield injection water and the effect on the corrosion behavior and the corrosion reaction mechanism were constantly observed during this period. The effect was displayed by potentiodynamic polarization curve and electrochemical impedance spectrums (EIS) measurements. Second, scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction were used to observe and test the corrosion product film immersed in the oilfield water for 30 days.

The results indicate that the tendency of metal corrosion becomes weaker at an early stage, but strengthened later, which means the corrosion rate is accelerating. Besides, it is indicated by impedance spectroscopy that with the decreasing of the capacitance arc radius, the reaction resistance is reducing in this progress. Meanwhile, the character of Warburg impedance could be found in EIS, which means that the erosional components are more likely to penetrate the product film to reach the matrix. The corrosion product is mainly composed of the inner Fe₃O₄ layer and outer shell layer, which contains a large number of calcium carbonate granular deposits. It is this corrosion under fouling that produces severe localized corrosion, forming many etch pits on the metal substrate.

The experiment chose the X80 steel, the highest-grade pipeline steel used in China, to conduct the static immersion test in the injection water coming from an oilfield in eastern China. Accordingly, the corrosion mechanism and the effect of corrosion product film on the corrosion of pipeline steel were analyzed and discussed.

The purpose of this paper is to study the electrochemical behavior of 690 alloy with corrosion products in simulated pressurized water reactor (PWR) primary water environment.

This paper opted for a laboratory study using simulation of high temperature and high pressure environment immersion testing. The electrochemical behavior was studied by potentiodynamic polarization, electrochemical impedance spectroscopy, scanning Kelvin probe microscopy (SKP). Moreover, the corrosion products were analyzed by X-ray photoelectron spectroscopy.

The results demonstrated that the particle majority in the 690 alloy corrosion products subsequent to high temperature and high pressure immersion testing were mainly oxides of Fe and Ni, which protected the matrix. As the immersion testing duration increased, the corrosion potential of the 690 alloy apparently increased, and the corrosion current density de'creased, while the corrosion resistance R_f increased gradually along with the density. The SKP demonstrated that the E_KP increased by nearly 400 mV from −0.42 to −0.03 V following the immersion testing, indicating that the corrosion product film played an apparent protective role on the substrate.

This paper provides a theoretical basis for the corrosion behavior and inhibition mechanism of 690 alloy in PWR primary water environment.

Nickel-aluminum bronze (NAB) has been widely used in ship propellers. It is always subjected to local micro-plastic deformation in service environments. This paper aims to study the influence of plastic deformation on the mechanical strength and corrosion resistance of NAB in 3.5 Wt.% NaCl solution.

Scanning electron microscope and X-ray diffraction were used to analyze the microstructure of NAB alloy with different plastic deformations. Mechanical properties of the sample were measured by tensile experiment, and corrosion behavior was studied by electrochemical measurements and the long-term immersion corrosion test.

Results showed that the plastic deformation caused lattice distortion but did not change the microstructure of NAB alloy. Microhardness and yield strength of NAB were significantly improved with the increase of deformation. The lattice distortion accelerated the formation of corrosion product film, which made the deformed alloy show a more positive open-circuit potential and an increased Rp. However, during the long-term immersion corrosion, the corrosion resistance of NAB alloys deteriorated with the increase of plastic deformation. This is because larger plastic deformation brought about higher internal stress in corrosion product film, which resulted in the premature peeling of the film and the loss of its protective effect on the alloy substrate.

Tensile plastic deformations were found to cause a decline in the corrosion resistance of NAB. And the mechanism was clarified from the evolution of corrosion products during the corrosion process.