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This paper aims to research steel wire corrosion pitting distribution characteristics and evolution, the shape, number and size of corrosion pits from one tied arch bridge were tested, analyzed and researched.

The probability distribution model of corrosion pits of different shapes was established, and the law of corrosion pit growth and evolution was researched. The relationship between the steel wire local corrosion parameters and the average degree of corrosion was explored.

The results revealed that the pits of steel wires can be divided into four categories of shapes: a deep ellipsoidal shape, a shallow ellipsoidal shape, a groove shape and a saddle shape. When developing to a certain degree, the small dark narrow type corrosion pit will turn into a large open pit of either a shallow ellipsoidal shape, a groove shape or a saddle shape.

The maximum depth of the corrosion pits was close to the Weibull distribution, and the maximum width and length of the wire corrosion pits were close to the logarithmic normal distribution, causing a large error when using a uniform corrosion model of steel wire mechanics.

The relatively complex corrosion mechanism of aluminium has been studied by several authors. Corrosion of aluminium occurs only when the metal protective oxide layer is damaged and when the repair mechanism is prevented by chemical dissolution. Polarization methods have been extensively used to investigate the mechanism of localised corrosion and processes that lead to localised corrosion. The potential‐pH diagrams are shown in Fig. 1A. In using potentiostatic techniques, the potential is controlled and current is determined as the independent variable. Potentiostatic and potentiody‐namic techniques have been applied by several authors to study the corrosion of aluminium in different environment. Both anodic and cathodic polarization curves have been used to interpret the kinetics of pitting corrosion of aluminium in chloride containing environments. Both the anodic and cathodic process are complex and the interpretation of the anodic and cathodic polarization curves of aluminium is often tedious. The situation arises partly from the fact that the role of film formation on the kinetics of corrosion is not clearly understood. Previously there is not established mechanisms of initiation and propagation of pits in aluminium and its alloys. Several parameters such as pitting potential, breakdown potential, active passive transition potential, related to the pitting process of aluminium, are full of controversy. Numerous references on the above can be found in literature).

The purpose of this investigation was to develop a digital instrument for the quantitative evaluation of pitting corrosion in metals.

This investigation comprised two central parts: research, testing and monitoring of the formation of pitting by conventional methods and applying American Society for Testing and Materials (ASTM) Standards, and the development of a virtual instrument based on the LabVIEW 2010 platform.

The methodology used was suitable for the analysis of pitting on carbon steel and aluminum alloy UNS A96061, used in the aerospace industry.

This technique allows pits to be to localized, measured and quantified on metallic surfaces, for corrosion evaluation in atmospheric and industrial environments.

This combination of conventional and digital methods can assist in corrosion control of pitting in industrial equipment.

In this paper, the authors aim to study the effect of hydrogen on the pitting corrosion behavior of Incoloy 825, a commonly used material for heat exchanger tubes in hydrogenated heat exchangers.

The pitting initiation and propagation behaviors were investigated by electrochemical and chemical immersion experiments and observed and analyzed by scanning electron microscope and energy dispersive spectrometer methods.

The results show that hydrogen significantly affects the electrochemical behavior of Incoloy 825; the self-corrosion potential decreased from −197 mV before hydrogen charging to −263 mV, −270 mV and −657 mV after hydrogen charging, and the corrosion current density increased from 0.049 µA/cm² before hydrogen charging to 2.490 µA/cm², 2.560 µA/cm² and 2.780 µA/cm² after hydrogen charging. The pitting susceptibility of the material increases.

Hydrogen is enriched on the precipitate, and the pitting corrosion also initiates at that location. The synergistic effect of hydrogen and precipitate destroys the passive film on the metal surface and promotes pitting initiation.

Corrosion is one of the common damage mechanisms in many engineering structures such as marine structures, petroleum pipelines, aerospace and nuclear reactor. However, the service performance of metal materials and structures is gradually degenerating with the increase of service life due to the rapid growth of corrosion damages. Thus, the coupled effects for corrosion damage in reliability analysis should be considered urgently. Then, the purpose of this paper is to develop the corrosion damage physical model and the corresponding reliability analysis methods, which consider the coupled effect of corrosion damage.

A failure physical model, considering the coupled effect of pitting growth, crack and crack propagation, is presented in this paper. Sequentially, the corrosion reliability with respect to pitting physical damage can be investigated. The presented pitting damage physical model is formulated as time-variant performance limit state functions, which include the crack transition, crack growth and fracture failure mechanics. The first-passage failure criterion is used to construct the corrosion reliability framework, involving in the pitting damage model with the increase of service life.

Results demonstrate that the multiplicative dimensional reduction (MDR) method behaves much better than FORM no matter in accuracy or efficiency. The proposed corrosion reliability method is applicable for dealing with the damage failure model of the structural pitting corrosion.

The MDR method is used to calculate the corrosion reliability index of a given structure with fewer function calls. Finally, an aeronautical metal material is used to demonstrate the efficiency and precision of the proposed corrosion reliability method when the failure physical model considering the coupled effects of mechanical stresses and corrosion environment is adopted.

This paper aims to analyze the high temperature (200°C) corrosion behavior of 2205 duplex stainless steel in acidizing stimulation solution containing hydrochloric acid (HCl) and acetic acid.

The corrosion rate of 2205 duplex stainless steel in all kinds of acid solutions was calculated through immersion tests and electrochemical test. The corrosion product composition is analyzed by X-ray diffraction analysis. The element composition and element distribution before and after corrosion were analyzed by an X-ray energy spectrometer. The corrosion morphology of the steel surface was observed by a scanning electron microscope. Both static and dynamic corrosion experiments were carried out at 200°C.

The results show that 2205 duplex stainless steel has excellent corrosion resistance in low to high concentration acetic acid solutions, but increasing the concentration of Cl⁻ in acetic acid solution will accelerate the corrosion rate. Low concentration HCl solution can cause serious corrosion to 2205 duplex stainless steel. The system of HCl and acetic acid will produce a synergistic effect on corrosion of 2205 duplex stainless steel and accelerate the corrosion. Sb₂O₃ is a good corrosion inhibitor synergist for high-temperature acidizing stimulation solution.

The amount of HCl that is used in acidizing stimulation is usually determined by the dissolution effect of the acid on the rocks, but for ultra-high-temperature reservoirs, the amount of HCl should be based on reducing the corrosion of oil and gas wells.

The purpose of this study is to analysis the pitting corrosion on the mechanical behavior of E690 high-strength steel sandwich panel. The pitting corrosion depth and degree of pitting (DOP) damage were used to evaluate the mechanical behaviors such as peak load and specific energy absorption of E690 panel.

The mechanical behavior of quasi-static compression, low-speed impact and three-point bending of E690 panel after pitting corrosion was simulated by ABAQUS nonlinear finite element method.

The quasi-static compression and low-speed impact mechanical properties can be greatly reduced by the pitting corrosion of the panel core, the pitting corrosion of the outer panel shows no obvious effect. The mechanical properties decrease with the increase of the pitting corrosion depth and DOP, and the influence of DOP is greater than that of pitting corrosion depth. The DOP of outer panel has less effect on mechanical properties of three-point bending compared with that of the core. Therefore, the pitting corrosion in the core of panel should be strictly controlled to prevent adverse effects on the mechanical properties of the structure.

To make up for the deficiency of the research on the corrosion behavior of high-strength steel sandwich panel structure, this paper chose E690 high-strength steel panel as the research object, and nonlinear finite element method was adopted to simulate the influence of pitting corrosion coverage area and pitting depth on its mechanical property degradation. The quasi-static compression, low-speed impact and three-point bending mechanical properties of panel with various DOPs and pitting depths were systematic studied.

The purpose of this study is to elucidate the effects of electric-arc-induced ablation on the corrosion behavior of pipeline steel in neutral and high pH environments.

Electrochemical testing, an atmospheric-pressure immersion experiment and various techniques (e.g. scanning electron microscopy, energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy) were used to examine the effects of electric-arc-induced ablation on the corrosion behavior of pipeline steel in neutral and high pH environment.

Electric-arc-induced ablation occurred preferentially in areas of inclusion. The corrosion resistance of an ablation pit was lower than that of non-ablation areas. In the neutral soil solution, general corrosion was the dominant corrosion that affected pipeline steel; the effect of ablation was small but pitting corrosion could still be induced. In a high pH environment, the samples without ablation were passivated, whereas the samples with ablation pits could not be passivated; the ablation pits were likely to develop pitting corrosion.

Electric-arc-induced ablation can reduce the corrosion resistance of pipeline steel under high-voltage direct current interference.

The purpose of this study was to investigate the pitting resistance and assess the critical pitting temperature (CPT) of a super martensitic stainless steel, 00Cr13Ni5Mo2, made in China, considering especially the difference in the pitting corrosion resistance between the domestic super martensitic stainless steel and an imported one.

Potentiodynamic sweep tests were applied to investigate the effects of four NaCl concentrations (weight per cent) of 1, 3.5, 9 and 17, and four testing temperatures of 30, 50, 75 and 90°C on the pitting resistance of the domestic super martensitic stainless steel in the presence of CO₂. Potentiostatic sweep tests were utilized to determine the CPT. Furthermore, chemical immersion exposures, implemented according to the appropriate standard were used to evaluate the difference in the pitting corrosion resistance between the domestic super martensitic stainless steel and an imported one. In addition, the morphology of pits was analyzed using a scanning electron microscope.

The pitting potential of the domestic super martensitic stainless steel decreased with an increase in NaCl concentration and temperature in the presence of CO₂. The CPT of the domestic super martensitic stainless steel measured by potentiostatic polarization was 41.16°C. Two types of typical corrosion pits, closed pits formed at 35°C and open pits formed at 50°C, were observed. Furthermore, compared to the super martensitic stainless steel made in Japan, the domestic one was better in terms of pitting potential, corrosion rate and the density of the pits, but worse in terms of the depth of the pits, which may result in a risk of corrosion perforation of tubing and casings.

The paper highlights that chloride ions, temperature and the presence of CO₂ play an important role on the pitting resistance of super martensitic stainless steel.

The purpose of this study is to quantitively characterize pitting or local corrosion of steel bars. Characterization of pitting or local corrosion is important for steel bar corrosion research in concrete, which is still an unsolved problem for the reason that the pitting on corroded steel is distributed irregularly, besides the varied pitting depths. To solve this problem in a certain degree, two parameters were collectively used to find the pitting distribution and pitting depth distribution of corroded steel bar surface.

Corroded reinforcement bars were subjected to two different corrosive conditions to obtain the profile of the surface of corroded steel bar. The arithmetic mean deviation of the profile, Ra, also a roughness parameter, and the fractal dimension, D, were computed using MATLAB software from the data on corroded steel bar profiles scanned by a profile tester. Statistical analysis was performed to determine the parameters distribution of Ra.

Ra and D can assist gravimetric technique in defining the degree of pitting corrosion and make further understanding about the characterization of local or pitting corrosion.

Two parameters were collectively used to find the pitting distribution and pitting depth distribution of corroded steel bar surface, while many studies only study the fractal dimension of pitting corrosion. And, the relationship between these two parameters is studied when using them to describing the non-uniformity of pitting corrosion degree. Using these two parameters can much better describe the non-uniform degree of pitting corrosion.