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The purpose of this investigation was to study the function mechanisms of a corrosion inhibitor package used for martensitic stainless steel tubulars in acid solution at high temperatures.

The inhibition performance was evaluated by means of an acid corrosion test at high temperature and high pressure, and the functional mechanism of the inhibitor package at different temperatures was investigated using polarization curve and electrochemical impedance spectroscopy measurements.

The results showed that the corrosion inhibitor package chosen for high-temperature and high-pressure gas well applications was very suitable for use with 13Cr super martensitic stainless steel. At lower temperatures, the function mechanism of the corrosion inhibitor package was characterized as a type of negative catalytic effect. As the temperature was increased, the effect of the intensifier in the package became more significant and the function mechanism changed to be the geometric covering effect type.

This study has the important practical value for guiding the oil field to conduct reasonable screening and using the acidizing corrosion inhibitor for martensite stainless steel tubulars.

Studies on titanium implants have shown that the mechanical properties of the parts are affected by the microstructure characteristic derived from the manufacturing process. The properties of different orientations of specimens under the same process parameters will be different, which should be considered in the application of bone implants. This paper aims to understand the influence of microstructure on micro-hardness, wear and corrosion resistance in different orientations.

The authors manufactured titanium parts and carried out micro-hardness, wear tests and electrochemical corrosion of different orientations under the same process conditions. Then, finally studied the evolution mechanism of the microstructure in different orientations and its influence mechanism on wear and corrosion mechanism.

The melting method makes the grains on the surface in XY orientation finer. The wear mechanism of XY orientation is abrasive wear, that of XZ and YZ orientations are adhesive wear. During corrosion, XY orientation forms a stable passivation film earlier. Compared with XZ and YZ orientations, XY orientation has higher micro-hardness, better wear and corrosion resistance.

In this paper, the microstructure, wear and corrosion resistance of selective laser melted parts were discussed and the differences in different orientations under the same experimental conditions were discussed. The evolution mechanism of the microstructure in different orientations and its influence mechanism on wear mechanism and corrosion mechanism was studied. The mechanical anisotropy of selective laser melted components was discussed.

This paper aims to investigate the effect of alternating current (AC) on corrosion, it is not yet clear about the exact mechanism of the corrosion induced by AC. Previous reports indicated that AC corrosion was similar to the effect of continuous cathodic and anodic polarization on the corrosion process of the metals. Wan et al. studied the effect of negative half-wave AC on stress corrosion cracking behavior and mechanism of X80 pipeline steel in near-neutral solution.

This study attempted to understand the AC-induced corrosion by imposing the half-cycle AC on the X80 pipeline steel in an acid bicarbonate solution. The AC corrosion mechanism was determined by weight loss and potentiodynamic polarization curve measurements, as well as surface characterization.

The results show that the positive half-cycle AC accelerated the uniform corrosion in the NaHCO3 solution, the negative half-cycle AC would decrease the uniform corrosion and local corrosion was increased and some Ca and Mg deposited on the surface of X80 steel, so the corrosion rate decreased by negative half-cycle AC. The corrosion product was composed of α-FeOOH under the application of positive half-cycle AC. The oxygen reduction led to a local increase of pH near the electrode surface and led to the formation of α-FeOOH, which enhanced the protectability of corrosion products.

Researchers studied the effect of negative half-wave AC on stress corrosion cracking behavior and mechanism of X80 pipeline steel in near-neutral solution. However, the AC behavior and corrosion mechanism in acid solution are unknown. So to make clear about the corrosion behavior of metals in different polarization states and the mechanism involved, diode technology was used to research the AC corrosion, half-wave AC was applied on the metals after the full-wave rectified.

The purpose of this paper is to assess the serious corrosion problems of the water injection system on the offshore oil field and to study the type, and effect factors and mechanisms of corrosion on the offshore oil field in order to develop an effective corrosion inhibitor for the sea water injection system.

The corrosion of metal in a water injection system was studied by weight‐loss and electrochemical methods.The effect factors and mechanisms of corrosion on the offshore oil field were proposed from the trend of corrosion.

FeCO₃ is the main corrosion product in the water injection system of the Chengdao Offshore Oil Field. The corrosion rate of coupons in sea water injection systems reaches a maximum peak at a temperature of 50‐60°C. The corrosion rate of coupons exposed in all three water samples increased with an increase in the dissolved oxygen concentration. When the mixed ratio of sea water and produced water and well water is 1:3:1 or 1:2:2, the corrosion rate of carbon steel is lower than is the case in pure water. The electrochemical mechanism of corrosion indicates that corrosion in the well water, produced water, and sea water samples were all controlled by the oxygen absorption process, which controlled the cathodic reaction. The corrosion rate of coupons followed the ranking order: well water; produced water; sea water.

This paper provides the main corrosion product in the water injection system of the Chengdao Offshore Oil Field, and provides new information on the effect factors and mechanisms of corrosion on the offshore oil field.

The relatively complex corrosion mechanism of aluminium has been studied by several authors. Corrosion of aluminium occurs only when the metal protective oxide layer is damaged and when the repair mechanism is prevented by chemical dissolution. Polarization methods have been extensively used to investigate the mechanism of localised corrosion and processes that lead to localised corrosion. The potential‐pH diagrams are shown in Fig. 1A. In using potentiostatic techniques, the potential is controlled and current is determined as the independent variable. Potentiostatic and potentiody‐namic techniques have been applied by several authors to study the corrosion of aluminium in different environment. Both anodic and cathodic polarization curves have been used to interpret the kinetics of pitting corrosion of aluminium in chloride containing environments. Both the anodic and cathodic process are complex and the interpretation of the anodic and cathodic polarization curves of aluminium is often tedious. The situation arises partly from the fact that the role of film formation on the kinetics of corrosion is not clearly understood. Previously there is not established mechanisms of initiation and propagation of pits in aluminium and its alloys. Several parameters such as pitting potential, breakdown potential, active passive transition potential, related to the pitting process of aluminium, are full of controversy. Numerous references on the above can be found in literature).

This paper aims to describe the corrosion behavior and possibility of inhibition by corrosion inhibitor SA1-3 in acidizing solution (5 per cent hydrochloric acid [HCl] solution). The study aims to explain the mechanism of corrosion and inhibition of N80 steel in 5 per cent HCl solution to provide theoretical basis for expanding the range of application of N80 steel in acidification process.

This paper opted for a laboratory study using simulation of acidizing solution to do the experiments. The results of experiments including weight-loss method, electrochemical method and surface analysis were used to explain the mechanism of corrosion and inhibition so as to predict the dissolution progress of N80 steel in 5 per cent HCl solution with and without inhibitor SA1-3.

This paper provides theoretical insights about how to inhibit the corrosion behavior of N80 steel in 5 per cent HCl solution. It suggests that the corrosion inhibitor which can form a protective film on the steel surface should be used to expand the application of N80 steel in acidizing solution. The inhibitor SA1-3 is a kind of cathodic corrosion-controlling inhibitor which mainly inhibits cathode corrosion; it cannot change the corrosion mechanism of N80 steel.

This paper provides a theoretical basis for the corrosion behavior and inhibition mechanism of N80 steel in acidizing solution.

Most supersonic aircraft were manufactured using 2A70 aluminum alloy. The purpose of this paper is to study the corrosion mechanism and fatigue behavior of an aircraft in a semi-industrial atmospheric corrosive environment, alternating effects of corrosion and fatigue were used to simulate the aircraft’s ground parking corrosion and air flight fatigue.

For this purpose, the aluminum alloy samples were subjected to pre-corrosion and alternating corrosion-fatigue experiments. The failure mechanisms of corrosion and corrosion fatigue were analyzed using microscopic characterization methods of electrochemical testing, X-ray diffraction and scanning electron microscopy. Miner’s linear cumulative damage rule was used to predict the fatigue life of aluminum alloy and to obtain its safe fatigue life.

The results showed that the corrosion damage caused by the corrosive environment was gradually connected by pitting pits to form denudation pits along grain boundaries. The deep excavation of chloride ions and the presence of intergranular copper-rich phases result in severe intergranular corrosion morphology. During cyclic loading, alternating hardening and softening occurred. The stress concentration caused by surface pitting pits and denudation pits initiated fatigue cracks at intergranular corrosion products. At the same time, the initiation of multiple fatigue crack sources was caused by the corrosion environment and the morphology of the transient fracture zone was also changed, but the crack propagation rate was not basically affected. The polarization curve and impedance analysis results showed that the corrosion rate increases first, decreases and then increases. Fatigue failure behavior was directly related to micro characteristics such as corrosion pits and microcracks.

In this research, alternating effects of corrosion and fatigue were used to simulate the aircraft’s ground parking corrosion and air flight fatigue. To study the corrosion mechanism and fatigue behavior of an aircraft in a semi-industrial atmospheric corrosive environment, the Miner’s linear cumulative damage rule was used to predict the fatigue life of aluminum alloy and to obtain its safe fatigue life.

The purpose of this paper is to investigate the effect Ti on stress corrosion cracking (SCC) and flow accelerated stress corrosion cracking (FA-SCC) behavior and mechanisms of Monel K500 alloy.

Monel K500 alloy with different Ti contents was designed. A metallurgical microscope (XJP-3C) and scanning electron microscopy (EV0 MA15 Zeiss) with an energy dispersive spectroscopy were used to analyze the microstructure of the Monel K500 alloy. In situ electrochemical tests were carried out in static and flowing seawater to study FA-SCC behavior.

The number of TiCN particles in the alloy increased as the increase of Ti content. The static corrosion and SCC of Monel K500 alloy are reduced as the content of Ti increases. Generally, the SCC of alloys was caused by the synergistic effect of the anodic dissolution at exposed metal matrix and the pit corrosion of metal matrix adjacent to TiCN particles, which was further accelerated by flowing.

The corrosion behavior and mechanism of Monel K500 alloy with different Ti contents in a complex flowing seawater environment are still unclear, which remain systematic study to insure the safe service of the alloy.

The purpose of this paper is to investigate the mechanisms of low alloyed medium-carbon steel (LAMCS) corrosion in 0.5 M H₂SO₄ inhibited by seeds oils of rubber (SOR), Neem (SON) and Jatropha (SOJ) containing varying degree of free fatty acid (FFA).

Specific gravity, acid values and FFA compositions of oils were determined. Potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM) and X-ray diffraction (XRD) are techniques used to investigate the corrosion inhibition mechanisms with evaluated Gibbs free energy of adsorption.

Corrosion inhibition efficiencies of oils reached values >99% as obtained from PDP and EIS. Protective oxide layer was formed on LAMCS consequent on containment of carbonyl and hydroxyl groups in the FFA of SOR, SON and SOJ, respectively. The SOR and SOJ are found to be mixed inhibitors, whereas SON behaved as anodic inhibitor. Mechanism of adsorption of SOR was synergistic between physisorption and chemisorption, while SON and SOJ exhibited physisorption. SEM micrographs images showed that uninhibited sample exhibited thicker mass of corrosion products. Formation of protective oxide layer was confirmed by XRD diffractograms.

This study has shown that the need for modification of vegetable seed oils containing FFA is unnecessary as the hydroxyl and carbonyl groups of the FFA contained in the respective oil were found to be the center of adsorption of the oils on the steel surface. Hence, cost and by-products associated with modification of oils used as corrosion inhibitors are eliminated.

SOR, which has the highest percentage FFA, was found to be the most influential on the corrosion inhibition mechanism of LAMCS, specifically within 0.01–0.02 g/mL concentration. FFA contained in the respective seed oil aided formation of protective oxide layer at interface between H₂SO₄ and LAMCS, relative to amount composed.

In summary, it can be found that the current research on the simulation of natural atmospheric dry–wet alternating accelerated corrosion mainly focused on the study of electrochemical corrosion process and the study of corrosion rate; the micro-pre-corrosion mechanism of materials in this environment, especially for materials. The specific effects of fatigue and fracture performance still lack detailed research. Accordingly, this study aims to more realistically simulate the effect of natural atmospheric corrosion environment on the corrosion resistance and fatigue performance of aircraft skin.

In this study, the uniaxial strain control method was used to test the fatigue performance of pre-corrosion samples under simulated natural atmospheric corrosion using MTS809 tensile-torque composite fatigue machine. Scanning electron microscopy, X-ray energy spectrum analysis, atomic force microscopy and X-ray diffraction analysis were used. Fatigue fracture, corrosion morphology and corrosion products were analyzed.

The results show that the deep corrosion pit caused by pre-corrosion environment leads to multi-source initiation of crack; the fatigue life of pre-corroded sample decreases by about one-half, chloride ion invades the material and promotes intergranular corrosion; life prediction results show that the natural atmospheric corrosive environment mainly affects the plastic term in the Manson–Coffin formula resulting in a decrease in fatigue life.

Innovative experimental schemes and materials are used and the test temperature and relative humidity are strictly controlled. The corrosion failure mechanism of 2A70-T6 aluminum alloy under alternating wet and dry accelerated corrosion environment and its influence on fatigue behavior were obtained.