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The purpose of this paper is to investigate the effect of char on the flame retardancy of fabrics by a cone calorimeter, which is an important factor to compare the flame retardancy of different fabrics.

Cone calorimeter measurements were carried out in a Fire Testing Technology (UK) apparatus at the heat fluxes of 50 and 75 kW/m². Fabrics with one and three layers were employed, with the name of cotton1, cotton3, FR cotton1, FR cotton3, PMIA1 and PMIA3. The dimension of the fabric was 100×100 mm². A cross-steel grid was used to prevent the fabrics from curling during burning. The distance between the bottom of the cone heater and the top of the sample was 25 mm.

This work was generously supported by National Key R&D Program of China (Project No. 2017YFB0309000), Natural Science Foundation of Shandong Province of China (Project No. ZR2019BEM026), Natural Science Foundation of China (Project No. 51803101) and China postdoctoral science foundation funded project (Project No. 2018M632619).

The present research provides insight into the effect of the char formation on the flame retardancy of the fabrics, and a method to comprehensively investigate the char influence in the flame retardancy of the fabrics by a cone calorimeter is proposed.

The purpose of this study is assessment of fire and smoke hazards of some fiber reinforced polymers (FRP). The use of FRP strengthening strips has been found rapid growth in construction industry of Iran and many other countries. However, the fire and smoke hazards of these materials in both construction and use phases need to be determined and the appropriated measures against fire should be taken.

The fire hazards of two types of fibre-reinforced epoxy composites (graphite fibre-reinforced polymer and carbon fibre-reinforced polymer) were investigated in bench-scale using cone calorimeter test method. Time to ignition, heat release rate, total heat release, smoke release and carbon monoxide production were measured and analysed. Time to flashover of an assumed room lined with the tested FRP was analysed with Conetools software. Smoke production and toxicity of the considered composites were also analysed and discussed, using the fractional effective dose parameter.

The results showed that the tested FRP products had a high fire hazard and a potential high contribution to fire growth. The tests also proved that the used epoxy resin had a low glass transition temperature, around 50°C; therefore, the mechanical strength of the product could be drastically reduced at first stages of a probable fire incident. This also showed that a regular thermal barrier, typically used for protection of plastic foams against fire, could not be sufficient for the protection of strengthening FRP composites.

This research was carried out for the first time for the materials used in construction industry of Iran. The results and achievements were very useful for safe use and development of proper details of application of the system.

The purpose of this study is to review and summarise the existing available literature on lightweight cladding systems to provide detailed information on fire behaviour (ignitibility, heat release rate and smoke toxicity) and various test method protocols. Additionally, the paper discusses the challenges and provides updated knowledge and recommendation on selective-fire mechanisms such as rapid-fire spread, air cavity and fire re-entry behaviours due to dripping and melting of lightweight composite claddings.

A comprehensive literature review on fire behaviour, fire hazard and testing methods of lightweight composite claddings has been conducted in this research. In summarising all possible fire hazards, particular attention is given to the potential impact of toxicity of lightweight cladding fires. In addition, various criteria for fire performance evaluation of lightweight composite claddings are also highlighted. These evaluations are generally categorised as small-, intermediate- and large-scale test methods.

The major challenges of lightweight claddings are rapid fire spread, smoke production and toxicity and inconsistency in fire testing.

The review highlights the current challenges in cladding fire, smoke toxicity, testing system and regulation to provide some research recommendations to address the identified challenges.

In this paper the aim is that Aramid/alginate blended nonwoven fabrics were prepared, and the flame retardancy of the blended nonwoven fabrics was studied by thermogravimetric analysis, vertical flame test, limiting oxygen index (LOI) and cone calorimeter test.

The advantages of different fibers can be combined by blending, and the defects may be remedied. The study investigates whether incorporating alginate fibers into aramid fibers can enhance the flame retardancy and reduce the smoke production of prepared aramid/alginate blended nonwoven fabrics.

Thermogravimetric analysis indicated that alginate fibers could effectively inhibit the combustion performance of aramid fibers at a higher temperature zone, leaving more residual chars for heat isolation. And vertical flame test, LOI and cone calorimeter test testified that the incorporation of alginate fibers improved the flame retardancy and fire behaviors. When the ratio of alginate fibers for aramid/alginate blended nonwoven fabrics reached 80%, the incorporation of alginate fibers could notably decreased peak-heat release rate (54%), total heat release (THR) (29%), peak-smoke production rate (93%) and total smoke production (86%). What is more, the lower smoke production rate and lower THR of the blends vastly reduced the risk of secondary injury in fires.

This study proposes to inhibit the flue gas release of aramid fiber and enhance the flame retardant by mixing with alginate fiber, and proposes that alginate fiber can be used as a biological smoke inhibitor, as well as a flame retardant for aramid fiber.

This study is to investigate the fire safety of textile and clothing materials. It also assesses the flammability for textiles in general.

With the increase in big fires, accidental or non-accidental, people are worrying about the fire behaviour of combustibles. The flammability of textile and clothing materials is a great concern. Appropriate tests should be developed to assess textile and clothing materials to ensure they are safe in a fire. In fact, textile products should satisfy some fire safety criteria depending on their uses. There are specified flammability requirements on selected products, though whether these are good enough for assessing modern textile materials should be watched.

Typical textile materials with and without fire retardants protection were selected for assessing the fire behaviour with a cone calorimeter. High radiative heat flux up to 70 kWm^‒2 was applied to assess those selected textile materials. A cone calorimeter is suggested to be the minimum requirement, though some full-scale burning tests are necessary for some purposes. Heat release rate and flame spreading measures are proposed in ranking the fire safety of textile materials.

This paper aims to examine the fire retardant property potentials of cow horn ash particles (CHAp) bio-additive and aluminium trihydrate (AH), a traditional inorganic fire-retardant additive, respectively, in banana peduncle fibre (BPF) reinforced polyester composites. An attempt was made to comparatively analyse the fire retardant capacity potentials of CHAp, a bio-material waste that is readily available, at no cost, as a potential fire retardant material for composites manufacture with a conventional inorganic fire retardant additive (AH).

The fibre used in this research was derived from the banana peduncle. The matrix is unsaturated polyester. A scanning electron microscope was used to analyze the particle size of the carbonized CHAp. The composites were compounded using 0%, 2.5%, 5%, 7.5% and 10% of CHAp and AH, respectively. A cone calorimeter instrument was used in the analysis to obtain combustion information of CHAp and AH formulated polyester-BPF composites. Test samples were cut to the dimensions of 100 × 100 mm. All materials are conditioned at 23 ± 30 °C and the relative humidity of 50 ± 5% for 24 h before testing. The samples were wrapped with aluminium foil around the back and edges before placing the samples on the holder and then into the cone calorimeter. The samples were backed with a non-combustible insulating refractory material (brick). The samples were orientated horizontally and exposed to irradiances of 50 kW/m² at a temperature of approximately 6000 °C. The samples were pilot ignited and ran in triplicate; the average readings of the three runs were taken.

The results obtained from the analysis depicted similar fire retardant properties for formulations with CHAp and AH, respectively. Composites formulated with CHAp exhibited delayed ignition time of 25%, increased end of burning time of 14.24% and reduced total heat release rate of 9.07% for the developed composites. The developed BPF/CHAp/polyester composites yield composites with fire retardancy, which would find relevance in the engineering material industry.

CHAp, therefore, would suffice as an alternative to the inorganic, expensive and non-environmental friendly, conventional fire retardant additives used in composites manufacture.

The purpose of this paper is to present a complex pyrolysis computational fluid dynamics (CFD) model of timber protection exposed to fire in a medium size enclosure. An emphasis is placed on rarely used temperature-dependent thermal material properties effecting the overall simulation outputs. Using the input dataset, a fire test model with oriented strand boards (OSB) in the room corner test facility is created in Fire Dynamics Simulator (FDS).

Seven FDS models comprising different complexity approaches to modelling the burning of wood-based materials, from a simplified model of burning based on a prescribed heat release rate to complex pyrolysis models which can describe the fire spread, are presented. The models are validated by the experimental data measured during a fire test of OSB in the room corner test facility.

The use of complex pyrolysis approach is recommended in real-scale enclosure fire scenarios with timber as a supplementary heat source. However, extra attention should be paid to burning material thermal properties implementation. A commonly used constant specific heat capacity and thermal conductivity provided poor agreement with experimental data. When the fire spread is expected, simplified model results should be processed with great care and the user should be aware of possible significant errors.

This paper brings an innovative and rarely used complex pyrolysis CFD model approach to predict the behaviour of timber protection exposed to fire. A study on different temperature-dependent thermal material properties combined with multi-step pyrolysis in the room corner test scenario has not been sufficiently published and validated yet.

Alginate fiber with a breaking tenacity of up to 2.32 cN/dtex is prepared by spinning a sodium alginate solution in a coagulating solution of CaCl₂ aqueous solution followed by multi-roller drawing. Preparation parameters such as sodium alginate concentration, coagulant concentration and coagulation temperature, which affect the fiber tenacity, are investigated with an orthogonal test design, and the best spinning process is found with a coagulating 5% sodium alginate solution in 4% CaCl₂ at 40°C. The morphology, degree of crystallinity, thermal stability and the combustion performance of this alginate fiber are investigated by scanning electron microscopy (SEM), infrared (IR), X-ray diffraction (XRD), Thermo gravimetric Analysis (TGA) and Cone Calorimeter. Using the centrifugal dewatering method, the absorption capacity of this alginate fiber is determined, and has a capacity of 13.01 grams of man-made blood per gram. The test results show that fibers have an irregular cross-section without a thicker cortex and uniform longitudinal surface with grooves. The combustion property results demonstrate that the fiber has a self-flameretarding property.

In order to find an appropriate method to synthesize a new high-efficiency flame retardant for epoxy resin.

In this work, a flame retardant with heterocyclic groups, HOMP, was acquired after removing the obstacle from triazines which was not readily soluble. The molecular structure, thermal and flame retardant properties were fully characterized and analyzed. Also, the mechanism was researched through multi-methodologies. As well, the authors evaluated the effects of HOMP on mechanical properties.

The results suggested that HOMP helped extinguish the combustion of specimens and could reach an LOI value of 29.2% and the V0 level in the UL-94 test with a phosphorus content of only 0.6wt%. With respect to the mechanism, HOMP was a gas-phase flame retardant and helped generate a thicker carbon protective coating. However, for the mechanical properties, the addition of HOMP enhanced the compressibility, while the tensile strength decreased significantly.

The approach not only simplified the operations but also obtained HOMP with excellent flame retardant properties.

In this study, an eco-friendly cotton fabric (CF) treatment method was proposed to induce anti-ultraviolet and flame retardant properties, and a new application of tannic acid (TA) and phytic acid (PA) in ultraviolet protection and flame retardant fabric was put forward.

By combining diethylenetriamine, PA and TA on CF, a chemical reaction intumescent flame retardant CF with anti-ultraviolet and anti-flame retardance was developed.

The flame retardant and ultraviolet resistance of CF were characterized by LOI, vertical combustion, cone calorimetry and ultraviolet resistance testing. SEM, XPS, FTIR and other tests were used to analyze the chemical composition, surface morphology and residual carbon after combustion of the CF, and it was confirmed that the modified CF has good ultraviolet resistance and flame retardant performance.

In this study, an eco-friendly CF treatment method was proposed to induce anti-ultraviolet and flame retardant properties, and a new application of TA and PA in ultraviolet protection and flame retardant fabric was put forward.