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The purpose of this paper is to study the mechanochemical effect and self-growth mechanism of double-network (DN) gel and to provide a quasiperiodic model for rubber elasticity.

The chemical reaction kinetics is used to identify the mechanochemical transition probability of host brittle network and to explore the mechanical behavior of endosymbiont ductile network. A quasiperiodic model is proposed to characterize the cooperative coupling of host–endosymbiont networks using the Penrose tiling of a 2 × 2 matrix. Moreover, a free-energy model is formulated to explore the constitutive stress–strain relationship for the DN gel based on the rubber elasticity theory and Gent model.

In this study, a quasiperiodic graph model has been developed to describe the cooperative interaction between brittle and ductile networks, which undergo the mechanochemical coupling and mechanical stretching behaviors, respectively. The quasiperiodic Penrose tiling determines the mechanochemistry and self-growth effect of DNs.

It is expected to formulate a quasiperiodic graph model of host–guest interaction between two networks to explore the working principle of mechanical and self-growing behavior in DN hydrogels, undergoing complex mechanochemical effect. The effectiveness of the proposed model is verified using both finite element analysis and experimental results of DN gels reported in literature.

The manufacture of polymer composites with a lower environmental footprint requires incorporation of sustainably sourced components. In addition, the incorporation of novel components should not compromise the material properties. The purpose of this paper is to demonstrate the use of a synthetic amine functional toluidine acetaldehyde condensate (AFTAC) as a modifier for fiber-reinforced epoxy composites. One of the fiber components was sourced from agricultural byproducts, and glass fiber was used as the fiber component for comparison.

The AFTAC condensate was synthesized via an acid-catalyzed reaction between o-toluidine and acetaldehyde. To demonstrate its efficacy as a toughening agent for diglycidyl ether bisphenol A resin composites and for the comparison of reinforcing materials of interest, composites were fabricated using a natural fiber (mat stick) and a synthetic glass fiber as the reinforcing material. A matched metal die technique was used to fabricate the composites. Composites were prepared and their mechanical and thermal properties were evaluated.

The inclusion of AFTAC led to an improvement in the mechanical strengths of these composites without any significant deterioration of the thermal stability. It was also observed that the fracture strengths for mat stick fiber-reinforced composites were lower than that of glass fiber-reinforced composites.

To the best of the authors’ knowledge, the use of the AFTAC modifier as well as incorporation of mat stick fibers in epoxy composites has not been demonstrated previously.

This paper numerically investigates the effect of cavity radiation on the thermal response of hollow aluminium tubes and facade systems subjected to fire.

Finite element simulations were performed using ABAQUS 6.14. The accuracy of the numerical model was established through experimental and numerical results available in the literature. The proposed numerical model was utilised to study the effect of cavity radiation on the thermal response of aluminium hollow tubes and facade system. Different scenarios were considered to assess the applicability of the commonly used lumped capacitance heat transfer model.

The effects of cavity radiation were found to be significant for non-uniform fire exposure conditions. The maximum temperature of a hollow aluminium tube with 1-sided fire exposure was found to be 86% greater when cavity radiation was considered. Further, the time to attain critical temperature under non-uniform fire exposure, as calculated from the conventional lumped heat capacity heat transfer model, was non-conservative when compared to that predicted by the proposed simulation approach considering cavity radiation. A metal temperature of 550 °C was attained about 18 min earlier than what was calculated by the lumped heat capacitance model.

The present study will serve as a basis for the study of the effects of cavity radiation on the thermo-mechanical response of aluminium hollow tubes and facade systems. Such thermo-mechanical analyses will enable the study of the effects of cavity radiation on the failure mechanisms of facade systems.

Cavity radiation was found to significantly affect the thermal response of hollow aluminium tubes and façade systems. In design processes, it is essential to consider the potential consequences of non-uniform heating situations, as they can have a significant impact on the temperature of structures. It was also shown that the use of lumped heat capacity heat transfer model in cases of non-uniform fire exposure is unsuitable for the thermal analysis of such systems.

This is the first detailed investigation of the effects of cavity radiation on the thermal response of aluminium tubes and façade systems for different fire exposure conditions.

Green roofs are strategies for the ecological intensification of cities and a measure of meeting some of the sustainable development goals (SDGs). They have widely been adopted as an adaptation strategy against an urban heat island (UHI). However, they are conventionally soil-based making it difficult and expensive to adopt as a strategy for greening existing buildings (GEB). This paper, therefore, develops a novel green roof system using climbers for thermal-radiative performance. The paper explores the vitality of climbing species as a nature-based strategy for GEB, and for the ecological improvement of the predominantly used cool roofs in sub-Saharan Africa (SSA).

Simulation for the same building Kejetia Central Market (KCM) Redevelopment; the existing aluminium roof (AL), soil-based extensive green roof (GR1) and the proposed green roof using climbing plants (GR2) were performed using ENVI-met. The AL and GR1 were developed as reference models to evaluate and compare thermal-radiative performance of the conceptual model (GR2). The long wave radiation emission (Q_lw), mean radiant temperature (MRT) and outdoor air temperature (T_a) of all three roofing systems were simulated under clear sky conditions to assess the performance and plant vitality considering water access, leaf temperature (T_f) and latent heat flux (LE₀) of GR1 and GR2.

There was no short wave radiation (Q_sw) absorption at the GR2 substrate since the climbers have no underlying soil mass, recording daily mean average Q_lw emission of 435.17 Wm⁻². The soil of GR1, however, absorbed Q_sw of 390.11 Wm⁻² and a Q_lw emission of 16.20 wm⁻² higher than the GR2. The AL recorded the lowest Q_lw value of 75.43 Wm⁻². Also, the stomatal resistance (r_s) was higher in GR1 while GR2 recorded a higher average mean transpiration flux of 0.03 g/sm³. This indicates a higher chance of survival of the climbers. The T_a of GR2 recording 0.45°C lower than the GR1 could be a good UHI adaptation strategy.

No previous research on climbers for green roof systems was found for comparison, so the KCM project provided a unique confluence of dynamic events including the opportunity for block-scale impact assessment of the proposed GEB strategy. Notwithstanding, the single case study allowed a focussed exploration of the novel theory of redefining green roof systems with climbers. Moreover, the simulation was computationally expensive, and engaging multiple case studies were found to be overly exhaustive to arrive at the same meaningful conclusion. As a novelty, therefore, this research provides an alternative theory to the soil-based green roof phenomenon.

The thermal-radiative performance of green roofs could be improved with the use of climbers. The reduction of the intensity of UHI would lead to improved thermal comfort and building energy savings. Also, very little dependence on the volume of soil would require little structural load consideration thereby leading not only to cheaper green roof construction but their higher demand, adoption and implementation in SSA and other low-income economies of the global south.

The reduction of the consumption of topsoil and water for irrigation could avoid the negative environmental impacts of land degradation and pollution which have a deleterious impact on human health. This fulfils SDG 12 which seeks to ensure responsible consumption of products. This requires the need to advance the research for improvement and training of local built environment practitioners with new skills for installation to ensure social inclusiveness in the combat against the intractable forces of negative climate impacts.

Climbers are mostly known for green walls, but their innovative use for green roof systems has not been attempted and adopted; it could present a cost-effective strategy for the GEB. The proposed green roof system with climbers apart from becoming a successful strategy for UHI adaptation was also able to record an estimated 568% savings on topsoil consumption with an impact on the reduction of pollution from excavation. The research provides an initial insight into design options, potentials and limitations on the use of climbers for green roofs to guide future research and experimental verification.

The purpose of this paper is to study and analyze the effects of fly ash (FA) as a mineral admixture on compressive strength (CS), carbonation resistance and corrosion resistance of reinforced concrete (RC). In addition, the utilization of inexpensive and abundantly available FA as a cement replacement in concrete has several benefits including reduced OPC usage and elimination of the FA disposal problem.

Reinforcement corrosion and carbonation significantly affect the strength and durability of the RC structures. Also, the utilization of FA as green corrosion inhibitors, which are nontoxic and environmentally friendly alternatives. This review discusses the effects of FA on the mechanical characteristics of concrete. Also, this review analyzes the impact of FA as a partial replacement of cement in concrete and its effect on the depth of carbonation in concrete elements and the corrosion rate of embedded steel as well as the chemical composition and microstructure (X-ray diffraction analysis and scanning electron microscopy) of FA concrete were also reviewed.

This review provides a clear analysis of the available study, providing a thorough overview of the current state of knowledge on this topic. Regarding concrete CS, the findings indicate that the incorporation of FA often leads to a loss in early-age strength. However, as the curing period increased, the strength of fly ash concrete (FAC) increased with or even surpassed that of conventional concrete. Analysis of the accelerated carbonation test revealed that incorporating FA into the concrete mix led to a shallower carbonation depth and slower diffusion of carbon dioxide (CO₂) into the concrete. Furthermore, the half-cell potential test shows that the inclusion of FA increases the durability of RC by slowing the rate of steel-reinforcement corrosion.

This systematic review analyzes a wide range of existing studies on the topic, providing a comprehensive overview of the research conducted so far. This review intends to critically assess the enhancements in mechanical and durability attributes (such as CS, carbonation and corrosion resistance) of FAC and FA-RC. This systematic review has practical implications for the construction and engineering industries. This can support engineers and designers in making informed decisions regarding the use of FA in concrete mixtures, considering both its benefits and potential drawbacks.

The present work focuses on evaluating the physical and mechanical characteristics of geopolymer concrete (GPC) by replacing the sodium silicate waste (SSW) in place of traditional river sand. The aim is to create eco-friendly concrete that mitigates the depletion of conventional river sand and conserves natural resources. Additionally, the study seeks to explore how the moisture content of filler materials affects the performance of GPC.

SSW obtained from the sodium silicate industry was used as filler material in the production of GPC, which was cured at ambient temperature. Instead of the typical conventional river sand, SSW was substituted at 25 and 50% of its weight. Three distinct moisture conditions were applied to both river sand and SSW. These conditions were classified as oven dry (OD), air dry (AD) and saturated surface dry (SSD).

As the proportion of SSW increased, there was a decrease in the slump of the GPC. The setting time was significantly affected by the higher percentage of SSW. The presence of angular-shaped SSW particles notably improved the compressive strength of GPC when replacing a portion of the river sand with SSW. When exposed to elevated temperatures, the performance of the GPC with SSW exhibited similar behavior to that of the mix containing conventional river sand, but it demonstrated a lower residual strength following exposure to elevated temperatures.

Exploring the possible utilization of SSW as a substitute for river sand in GPC, and its effects on the performance of the proposed mix. Analyzing, how varying moisture conditions affect the performance of GPC containing SSW. Evaluating the response of the GPC with SSW exposed to elevated temperatures in contrast to conventional river sand.

This study aims to focus on how reactive diluents with mono- and di-functionalities affect the properties of resin formulation developed from bioderived precursors. A hydroxyethyl methacrylate (HEMA) terminated urethane acrylate oligomer was synthesized and characterized to study its application in stereolithography 3D printing with different ratios of isobornyl acrylate and hexanediol diacrylate.

Polyester polyol was synthesized from suberic acid and butanediol. Additionally, isophorone diisocyanate, polyester polyol and HEMA were used to create urethane acrylate oligomer. Fourier transform infrared spectroscopy and ¹H NMR were used to characterize the polyester polyol and oligomer. Various formulations were created by combining oligomer with reactive diluents in concentrations ranging from 0% to 30% by weight and curing with ultraviolet (UV) radiation. The cured coatings and 3D printed specimens were then evaluated for their properties.

The findings revealed an improvement in thermal stability, contact angle value, tensile strength and surface properties of the product which indicated its suitability for use as a 3D printing material.

This study discusses how oligomers that have been cured by UV radiation with mono- and difunctional reactive diluents give excellent coating characteristics and demonstrate suitability and stability for 3D printing applications.

Advancements in responsive manufacturing have been supporting companies over the last few decades. However, manufacturers now operate in a context of continuous uncertainty. This research paper explores a mechanism where companies can “elastically” provision and deprovision their production capacity, to enable them in coping with repeated disruptions. Such a mechanism is facilitated by the imitability and substitutability of production resources.

An inductive study was conducted using Gioia methodology for this theory generation research. Respondents from 20 UK manufacturing companies across multiple industrial sectors reflected on their experience during COVID-19. Resource-based view and resource dependence theory were employed to analyse the manufacturers' use of internal and external production resources.

The study identifies elastic responses at four operational levels: production-line, factory, company and supply chain. Elastic responses that imposed variable-costs were particularly well-suited for coping with unforeseen disruptions. Further, the imitability and substitutability of manufacturers helped others produce alternate goods during the crisis.

While uniqueness of production capability helps manufacturers sustain competitive advantage against competitors during stable operations, imitability and substitutability are beneficial during a crisis. Successful manufacturing companies need to combine these two approaches to respond effectively to repeated disruptions in a context of ongoing uncertainties. The theoretical contribution is in characterising responsive manufacturing in terms of resource heterogeneity and resource homogeneity, with elastic resourcing as the underlying mechanism.

This study aims to synthesize two different benzoxazines (Bz) monomers using bio-based and petroleum-based primary amines, respectively, and they have been compared to study their thermal and mechanical performances.

A bio-based bisphenol, Divanillin (DiVa), was formed by reacting two moles of vanillin with one mole of ethylenediamine (EDA) which was then reacted firstly with paraformaldehyde and EDA to form the benzoxazine DiVa-EDA-Bz, and secondly with paraformaldehyde and furfuryl amine (FFA) to form the benzoxazine DiVa-FFA-Bz. The molecular structure and thermal properties of the benzoxazines were characterized by fourier transform infrared spectroscopy and nuclear magnetic resonance (1H,13C) spectroscopies, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), respectively. The benzoxazines were further coated on mild steel panels to evaluate their mechanical properties and chemical resistance.

The DSC results of DiVa-FFA-Bz showed two exothermic peaks related to crosslinking compared to the one in DiVa-EDA-Bz. The DiVa-FFA-Bz also showed a higher heat of polymerization than DiVa-EDA-Bz. The TGA results showed that DiVa-FFA-Bz exhibited higher thermal stability with a residual char of 54.10% than 43.24% for DiVa-EDA-Bz. The chemical resistance test results showed that DiVa-FFA-Bz showed better chemical resistance and mechanical properties due to its higher crosslinking density.

This study shows the use of bio-based materials, vanillin and FFA, for synthesizing a benzoxazine resin and its application at high temperatures.