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The purpose of this paper is to prepare a spherical modifier-modified activated carbon fiber of high specific capacitance intended for electrode materials of supercapacitor.

In this study, phenolic-based microspheres are taken as modifiers to prepare PAN-based fiber composites by electrospinning, pre-oxidation and carbonization. Pearl-chain structures appear in RFC/ACF composites, and pure polyacrylonitrile fibers show a dense network. The shape and cross-linking degree are large. After the addition of the phenolic-based microspheres, the composite material exhibits a layered pearlite chain structure with a large porosity, and the RFC/ACF composite material is derived because of the existence of a large number of bead chain structures in the composite material. The density increases, the volume declines and the mass after being assembled into a supercapacitor as a positive electrode material decreases. The specific surface area of RFC/ACF composites is increased as compared to pure fibers. The increase in specific surface area could facilitate the diffusion of electrolyte ions in the material. Owing to the large number of bead chains, plenty of pore channels are provided for the diffusion of electrolyte ions, which is conducive to enhancing the electrochemical performance of the composite and improving the RFC/ACF composite and the specific capacitance of the material. The methods of electrochemical testing on symmetric supercapacitors (as positive electrodes) are three-electrode cyclic voltammetry, alternating current impedance and cycle stability.

The specific capacitance value of the composite material was found to be 389.2 F/g, and the specific capacitance of the electrode operating at a higher current density of 20 mA/cm2 was 11.87 F/g (the amount of the microsphere modifier added was 0.3 g). Using this material as a positive electrode to assemble into asymmetrical supercapacitor, after 2,000 cycles, the specific capacitance retention rate was 87.46 per cent, indicating excellent cycle stability performance. This result can be attributed to the fact that the modifier embedded in the fiber changes the porosity between the fibers, while improving the utilization of the carbon fibers and making it easier for electrolyte ions to enter the interior of the composites, thereby increasing the capacitance of the composites.

The modified PAN-based activated carbon fibers in the study had high specific surface area and significantly high specific capacitance, which makes it applicable as an efficient and environment-friendly absorbent, as well as an advanced electrode material for supercapacitor.

The main cause of aseptic inflammation after an in vivo implantation is that Poly(L-lactide) (PLLA) and Poly(D-lactide) have a slower degradation and absorption rate, while Poly(D, L-lactide) (PDLLA) has a much faster degradation rate than PLLA because of its amorphous structure. Also, the hydrolyzate of Hydroxyapatite (HA) is alkaline, which can neutralize local tissue peracid caused by hydrolysis of Polylactic acid.

In this study, the selective laser sintering (SLS) technique was chosen to prepare bone scaffolds using nano-HA/PDLLA composite microspheres, which were prepared by the solid-in-oil-in-water (S/O/W) method. First, the SLS parameters range of bulk was determined by the result of a single-layer experiment and the optimized parameters were then obtained by the orthogonal experiment. The tensile property, hydrophobicity, biocompatibility, biological toxicity and in vitro degradation of the samples with optimized SLS parameters were characterized.

As a result, the samples showed a lower tensile strength because of the many holes in their interior, which was conducive to better cell adhesion and nutrient transport. In addition, the samples retained their inherent properties after SLS and the hydrophobicity was improved after adding nano-HA because of the OH group. Furthermore, the samples showed good biocompatibility with the large number of cells adhering to the material through pseudopods and there was no significant difference between the pure PDLLA and 10% HA/PDLLA in terms of biological toxicity. Finally, the degradation rate of the composites could be tailored by the amount of nano-HA.

This study combined the S/O/W and SLS technique and provides a theoretical future basis for the preparation of drug-loaded microsphere scaffolds through SLS using HA/PDLLA composites.

The purpose of this paper is to investigate the preparation and the flexural property of hollow glass microspheres (HGMs) filled resin-matrix composites, which have been widely applied in deep-sea fields.

The composites with different contents of HGMs from 47 to 57 Wt.% were studied. The voids in syntactic foams and their flexural properties were investigated.

The results showed that the voids quantity increased because of the increment of HGM content, whereas the exural strength and the exural modulus decreased. The fracture mechanism of the composites was also investigated by scanning electron microscope, which indicated that the composites failed by the crack extending through the microspheres.

The advantages of HGMs with similar hollow spheres will be further investigated in a future research.

Results demonstrated that the properties of the composite might be tailored for specific application conditions by changing the HGM volume fraction.

The HGM filled resin-matrix composite materials have their unique properties and significant application potential. In this work, the resin-HGM composites were synthesized by mechanically mixing defined quantities of HGMs into epoxy resin, by which a kind of syntactic foams with good flexural properties could be obtained.

The purpose of this paper is to modify light hollow polymer microsphere (LHPM) with titanium dioxide nanoparticles (nano-TiO2) to improve its compatibility with latex and apply the obtained nano-TiO2/LHPM composite particles in external wall thermal insulation coatings.

The nano-TiO2/LHPM composite particles were prepared via vigorous stirring. The morphology and chemical composition of the produced nano-TiO2/LHPM composite particles were characterized using scanning electron microscopy, energy dispersion spectrum, thermo-gravimetric analyzer and Fourier transform infrared. The performance of this new composite coating was evaluated by checking its stability, density, radiation reflectivity, thermal conductivity and the resulting insulation temperature difference when forming coating film.

It was found that a 9:1 mass ratio of nano-TiO2/LHPM with total 10 weight per cent composite particles in the thermal insulation paint showed low density, good stability, low thermal conductivity (0.1687 W/m·K) and high insulation temperature difference (5.8°C).

The LHPM can be modified by other nanoparticles to improve its insulation performance in thermal insulation coatings.

This work provides a simple, robust, but effective approach to produce new thermal insulation coatings with nano-TiO2/LHPM composite particles.

This method for surface modification of LHPMs is novel and the modified hollow polymer microspheres could be applied to external wall insulation coatings.

The purpose of this paper is to report on a study of the effect of glass microsphere (GMS) and potassium bromide (KBr) powder as an additive on the reflectance and transmittance of TrueForm^TM acrylic‐styrene co‐polymer (TF) powder to CO₂ laser during selective laser sintering (SLS).

GMSs and KBr powder were chosen because glass is opaque to CO₂ laser while KBr is transparent. The GMSs were treated with silane coupling agent and hydrofluoric acid to study the surface effect on the optical properties of TF/GMS blends. KBr powder was blend with TF powder in an attempt to modify the penetration depth of the laser in the powder bed. An integrating sphere was used to measure the reflectance of the powder bed. In the measurement of transmittance, a power meter was placed below the powder layer, which was supported by a KCl disc, to register the transmitted laser energy through the powder layer.

For the TF/GMS blends, smaller GMSs gave a higher reflectance while the surface treatments had little effect. The transmittance of both the polymer and the blends were very low. Although bulk KBr is highly transparent to CO₂ laser, adding 30 vol% of KBr powder to TF hardly increased the transmittance of the powder bed.

Experiments were carried out on a modified laser engraving machine rather than a commercial SLS machine. The laser energy density used was lower than that for normal SLS processes and no significant changes of physical condition of the powder bed were inflicted. The results only indicate the optical properties in the initial state.

The effects of transparent and non‐transparent fillers on the optical properties of the powder bed are presented.

This work furthers the understanding of heat absorption behavior of the powder bed during SLS.

As a high-performance engineering plastic, polyimide (PI) is widely used in the aerospace, electronics and automotive industries. This paper aims to review the latest progress in the tribological properties of PI-based composites, especially the effects of nanofiller selection, composite structure design and material modification on the tribological and mechanical properties of PI-matrix composites.

The preparation technology of PI and its composites is introduced and the effects of carbon nanotubes (CNTs), carbon fibers (CFs), graphene and its derivatives on the mechanical and tribological properties of PI-based composites are discussed. The effects of different nanofillers on tensile strength, tensile modulus, coefficient of friction and wear rate of PI-based composites are compared.

CNTs can serve as the strengthening and lubricating phase of PI, whereas CFs can significantly enhance the mechanical properties of the matrix. Two-dimensional graphene and its derivatives have a high modulus of elasticity and self-lubricating properties, making them ideal nanofillers to improve the lubrication performance of PI. In addition, copolymerization can improve the fracture toughness and impact resistance of PI, thereby enhancing its mechanical properties.

The mechanical and tribological properties of PI matrix composites vary depending on the nanofiller. Compared with nanofibers and nanoparticles, layered reinforcements can better improve the friction properties of PI composites. The synergistic effect of different composite fillers will become an important research system in the field of tribology in the future.

Refers to how the mechanical properties of polymer‐based composite objects produced via rapid layered fabrication methods can be improved significantly using short discontinuous fibres as reinforcements. Notes in this context, that the viscosity of the uncured fibre‐photopolymer composite liquids affects the raw‐material handling, the layer formation and the draining operations. Assesses the effects of aspect ratio, surface coating and volume fraction of short glass fibres on the viscosity of the fibre‐photopolymer composite liquids. Based on extensive experimentation and analysis, concludes that the shear viscosity of the composite liquids increases with increasing fibre‐volume fraction, showing that this effect is more pronounced at low shear rates than at high shear rates. Reveals, similarly, that the aspect ratio of the dispersed fibres has a stronger effect on the increase of viscosity at low shear rates and that the surface coating of the dispersed fibres also affects the viscosity of the composite liquids.

Rapid prototyping (RP) technology is widely used in many fields in recent years. Bone tissue engineering (TE) is an interdisciplinary field involving life sciences, engineering and materials science. Hydroxyapatite (HAp) are similar to natural bone and it has been extensively studied due to its excellent biocompatibility and osteoconductivity. This paper aims to review nanoscaled HAp-based scaffolds with high porosity fabricated by various RP methods for bone regeneration.

The review focused on the fabrication methods of HAp composite scaffolds through RP techniques. The paper summarized the evaluation of these scaffolds on the basis of their biocompatibility and biodegradability through in vitro and in vivo tests. Finally, a summary and perspectives on this active area of research are provided.

HAp composite scaffold fabricated by RP methods has been widely used in bone TE and it has been deeply studied by researchers during the past two decades. However, its brittleness and difficulty in processing have largely limited its wide application in TE. Therefore, the formability of HAp combined with biocompatible organic materials and fabrication techniques could be effectively enhanced, and it can be used in bone TE applications finally.

This review paper presented a comprehensive study of the various types of HAp composite scaffold fabricated by RP technologies and introduced their potential application in bone TE, as well as future roadmap and perspective.

The purpose of this paper is to develop a potential nanoparticles lubricant additive for solving the problem of the insolubility and stable dispersity; the complex nanoparticles with core-shell structures are less studied in the field. Therefore, this paper determines novel complex nanoparticles and their tribological properties.

According to the conventional preparation method, the complex nanoparticle styrene/calcium borate (PS/O-CaB) was synthesized. The microstructures of the as-obtained samples were characterized by X-ray diffraction infrared spectroscopy and thermogravimetric analysis. Tribological properties of PS/O-CaB used as lubricating oil additive were evaluated on four-ball tribometer. The worn surface of the steel ball was investigated by a three-dimensional non-contact surface profilometer and X-ray photoelectron spectroscopy (XPS).

The results of the structure characteristic indicate two different crystalline forms, namely, Ca₂B₆O₁₁ and Ca₂B₂O₅, and the average size of calcium borate nanoparticles in PS/O-CaB is about 20-40 nm. Moreover, the good tribological properties are due to a wear resistance film containing both depositions and the tribochemical reaction products which comprise B2O3, FeB and Fe2O3.

Novel complex nanoparticles with core-shell structure (PS/O-CaB) were successfully prepared. Moreover, the PS/O-CaB shows excellent tribological capacity such as load-carrying, friction-reducing and antiwear property.

The purpose of this study is to establish a finite element (FE) model with the random distribution of the Nylon12/hydroxyapatite (PA12/HA) composite material in selective laser sintering (SLS) process for considering the material anisotropy, which aims to obtain the law of temperature and stress changes in PA12/HA sintering.

By using python script in Abaqus, the FE model is established in which the two materials are randomly distributed and are assigned to their intrinsic temperature-dependent physical parameters. Molten pool sizes at various process parameters were evaluated in terms of numerical simulation and scanning electron microscope analysis, identifying a good agreement between them. Evaluation of temperature and stress distribution under the condition of different HA contents was also conducted.

It shows that the uneven distribution and quantity of HA powder play a vital role in stress concentration and temperature increase. Additionally, the influence of HA addition on the mechanical performance of SLS-fabricated parts shows that it is conducive to improve compressive strength when the HA ratio is less than 5% because an excess of HA powder tends to bring about a certain amount of microspores resulting in a decrease in part density.

The FE model of the PA12/HA composite material with parameterized random distribution in SLS can be applied in other similar additive manufacturing technologies. It provides a feasible guideline for the numerical analysis of properties of composite materials.