Search results

The purpose of this paper is to report the investigation of a low temperature application process for three‐layer polyethylene coating (3LPE) at 185‐195°C to meet the requirement of the coating temperature for X80 longitudinally welded pipe.

Plant coating and laboratory tests were performed to determine the properties of 3LPE coating coated at 185‐195°C.

The properties of the 3LPE coating, which was applied by using a suitable low temperature cured epoxy powder at temperature of 185‐195°C, were nearly the same as those of a 3LPE coating that had been applied at the normal coating temperature (200‐230°C).

Recommended acceptance criteria for 3LPE coatings applied at 185‐195°C are proposed. The research results met the requirements for external anti‐corrosion properties for X80 longitudinally welded pipe.

Demands for coatings with superior technical characteristics have induced the use of composite coatings, which usually represent an extremely strong product. The resin blend technique is a simple and useful method for improving paint properties. Coal tar resins are the most economical coating extensively used in the industry; short oil‐length alkyd resins are usually used for air and force‐dry industrial coatings for metal surfaces. The purpose of this paper is to evaluate coating blends composed of these resins, in particular, the effects of short oil‐length alkyd additive on the properties of coal tar binder.

One way to achieve new types of binders is to make combinations of the existing ones, in an ideal case retaining the desirable properties of both. The alkyd has important properties over the original drying oil. To achieve the goal of improving coal tar resin properties, short oil‐length alkyd was blended with it. The prepared short oil‐length alkyd was characterised using IR and ¹HNMR spectroscopy. The mixing ratio of short oil‐length alkyd with coal tar was up to 25 per cent. The compatibility of coating blend was characterised by scanning electron microscope. The physical, mechanical and chemical properties of the coating blend in addition to the corrosion resistance were determined according to ASTM methods.

In spite of a large number of synthetic resins being available for use in paint formulations, the alkyd resins surpassed all of them in versatility and low cost. The blend of short oil‐length alkyd resin with coal tar has yielded better coating blend properties. The coating blend showed significant enhancement of physical, mechanical and chemical properties such as gloss, drying time, adhesion, scratch hardness, acid and solvent resistance because the coating blend combines the properties of thermosetting and thermoplastic resins.

Alkyd resins are the most extensively used synthetic polymers in the coating industry. Modification of coal tar blend based on other type of polyester resins could also be studied in order to assess the applicability of the coal tar blend system found for other applications.

These types of alkyd resins can be applied in other bitumen composites as additives and reinforce agent.

The paper shows how the low‐cost modified coal tar binder can be used for air and force‐dry industrial coatings for metal surfaces.

The purpose of this paper is to examine the effects of coating process parameters (base fabric, coating material, coating technique and production parameters) on mechanical properties of coated fabrics.

In this research, 24 coated fabrics were produced under controlled production conditions by using two cotton base fabrics and two coating materials as polyurethane (PU), PU/silicone in order to study how coating affects some of the base fabric's mechanical properties such as breaking strength, breaking elongation, tear strength, bursting strength, bending rigidity and abrasion resistance. The measured data were evaluated with variance analysis to determine the effects of the coating parameters at 95 per cent confidence level.

Breaking strength shows increments for almost all fabrics, whereas breaking elongation values decreased by coating application. Coating has a very clear influence on tear strength of coated fabrics due to the penetration of coating material into the fabric structure. Changes in bursting strength are not similar for two base fabrics with systematically changed production parameters. Coating improves all measured parameters of bending rigidity. Coating application enhances abrasion resistance though some broken fibers are observed on the fabric surface in scanning electron microscopy investigation.

In the past few years, the researches on this area focused on investigating the effects of coating materials and layers on tensile properties. This study comprehensively examines the effects of several coating parameters on mechanical properties such as breaking strength, breaking elongation, tear strength, bursting strength, bending rigidity and abrasion resistance.

The purpose of this paper is to investigate the effects of carbon nanotubes (CNTs) on the mechanical, thermal and colour properties of solvent-containing two-component polyurethane (PU) coating.

Fourier transform infrared spectroscopy and observation of dispersion stability were used to assess the effects of acid treatment on CNTs. The CNTs and PU composite coating was synthesised by in situ polymerisation and bending polymerisation, and the mechanical, thermal and colour appearance properties of coating were characterised.

It was found that desirable modifications to CNTs occurred after acid treatment; thus, mainly carboxylic acid groups were introduced onto the surface of CNTs. And the acid-treated CNTs could improve the mechanical and thermal properties of PU coating, and the properties of composite coating was improved more successfully by in situ polymerisation than by blending polymerisation.

The investigation established a method to synthesise CNTs and PU composite coating. The mechanical and thermal properties of PU coating could be improved by the inclusion of CNTs.

This study established a method to synthesise CNTs and PU composite coating by in situ polymerisation and blending polymerisation; the effects of CNTs on modifying mechanical, thermal and colour properties of PU coating were investigated and compared in detail.

The performance of epoxy coating on metal substrate at low temperature and high humidity application has adverse effect on cure rate, film properties and adhesion. In recent years, several advanced amine cross-linking agents having superior curing ability at low temperature application environment have been introduced. The aim of this paper is to study the properties of epoxy-based coating cured with different cross-linking agents designed for low temperature application at different environmental conditions.

Series of cross linking agents such as modified cycloaliphatic amine (H1), polyamine adduct (H2), modified aliphatic ketamine (H3), phenalkamine (H4) and phenalkamide (H5) have been studied to evaluate their performance in epoxy compositions when cured at four environmental conditions, i.e. at ambient and sub-ambient temperatures with 60 and 90 per cent relative humidity, respectively. The effect of curing conditions was investigated by evaluating different physico-mechanical properties. Dynamic mechanical analyser technique was used to determine glass transition temperature (T_g) and cross-link density (ρ) of coatings. Anticorrosive properties of coatings also have been studied by electrochemical impedance spectroscopy.

The outcome of this study is expected to generate new insight into the curing behaviour of epoxy coating using different cross-linking agents which are recommended for low temperature application. Optimum physico-mechanical and corrosion resistance properties have been obtained by phenalkamine curing agent at low temperature and high humidity condition.

This study is an experimental approach to select the better cross-linking agent for low temperature application. Different test conditions were measured for understanding the performance of epoxy coating cured at different environmental condition.

The understanding reaction mechanism of the epoxy resin with cross-linking agent at different environmental condition is the great challenge and is hardly investigated in the literature. Therefore, in this research, the influence of climatic conditions and type of cross-linking agents on curing behaviour of epoxy-based coating was investigated.

Intumescent coatings are nowadays a dominant passive system used to protect structural materials in case of fire. Due to their reactive swelling behaviour, intumescent coatings are particularly complex materials to be modelled and predicted, which can be extremely useful especially for performance-based fire safety designs. In addition, many parameters influence their performance, and this challenges the definition and quantification of their material properties. Several approaches and models of various complexities are proposed in the literature, and they are reviewed and analysed in a critical literature review.

Analytical, finite-difference and finite-element methods for modelling intumescent coatings are compared, followed by the definition and quantification of the main physical, thermal, and optical properties of intumescent coatings: swelled thickness, thermal conductivity and resistance, density, specific heat capacity, and emissivity/absorptivity.

The study highlights the scarce consideration of key influencing factors on the material properties, and the tendency to simplify the problem into effective thermo-physical properties, such as effective thermal conductivity. As a conclusion, the literature review underlines the lack of homogenisation of modelling approaches and material properties, as well as the need for a universal modelling method that can generally simulate the performance of intumescent coatings, combine the large amount of published experimental data, and reliably produce fire-safe performance-based designs.

Due to their limited applicability, high complexity and little comparability, the presented literature review does not focus on analysing and comparing different multi-component models, constituted of many model-specific input parameters. On the contrary, the presented literature review compares various approaches, models and thermo-physical properties which primarily focusses on solving the heat transfer problem through swelling intumescent systems.

The presented literature review analyses and discusses the various modelling approaches to describe and predict the behaviour of swelling intumescent coatings as fire protection for structural materials. Due to the vast variety of available commercial products and potential testing conditions, these data are rarely compared and combined to achieve an overall understanding on the response of intumescent coatings as fire protection measure. The study highlights the lack of information and homogenisation of various modelling approaches, and it underlines the research needs about several aspects related to the intumescent coating behaviour modelling, also providing some useful suggestions for future studies.

The purpose of this work was to study the effect of different wood surface preparations on the wetting and adhesion of coating.

In this research, six different chemical preparations to evaluate the photostability and properties of wood coating. Also, the effect of the same wood treatments on the properties of the coating, i.e. wetting, adhesion and the permeability of two types of coatings, was investigated.

As a result, benzoyl chloride and chromic acid were found to be the most effective photostabilizing preparations. Solvent-based polyurethane was more compatible with the prepared wood surfaces compared with water-based alkyd coatings.

Chemical modifications of wood surfaces affected the wetting of various coatings.

Various surface properties could be changed using preparation that affects important coating properties.

Unfortunately, the properties of transparent wood coatings used outdoors disappear through the early years of use, essentially due to the wood substrate’s photodegradation.

Wood is a widespread substrate because of its comfortable handling, availability, proper cost of preparation and its good mechanical strength because of its density. Architects and designers tend to use wood in the construction of green buildings. However, this material is disposed to weathering while using outdoors and it should be solved.

This paper aims to address the coating and compound analysis of diamond-like carbon (DLC) on steel, to understand the frictional behavior in tribological gear systems presented in paper Part I. Here, the Ti and Zr modified DLC coating architectures are analyzed regarding their chemical, mechanical and thermophysical properties. The results represent a systematic analysis of the thermal insulating effect in tribological contact of DLC coated gears.

The approach was to evaluate the effect of the substitution of Zr through Ti at the reference coating ZrCg to TiCg and the effect on thermophysical properties. Furthermore, the influence of different carbon and hydrogen contents on the coating and compound properties was analyzed. Therefore, different discrete Ti or Zr containing DLC coatings were deposited on an industrial coating machine. Thereby the understanding of the microstructure and chemical composition of the reference coatings is increased.

Results prove comparable mechanical properties of metal modified DLC independent of differences in chemical compositions. Moreover, the compound adhesion between TiC_g/16MnCr5E was improved compared to ZrC_g/16MnCr5E. The effect of hydrogen content Ψ and carbon content x_c on the thermophysical properties is limited by Ψ = 18 at.% and x_c = 90 at.%.

The findings of the combined papers Part I and II show a high potential for industrial application of DLC on gears. Based on the results DLC coatings and gears can be tailored to each other.

Systematic analysis of DLC coatings were conducted to evaluate the effect of titanium, carbon and hydrogen on thermophysical properties.

To examine the mechanical properties of TiN PVD coated Ti‐6Al‐4V alloy through three‐point bending tests.

Ti‐6Al‐4V alloy is cut in size and polished and cleaned chemically before TiN PVD coating process. INSTRON three‐point bending equipment is used to conduct the bending tests for TiN coated and uncoated workpieces. During the tests, the load and displacement characteristics were recorded. The tests were terminated when the coating failed. Micrographs of surface and crack sites were obtained by SEM.

Coating failure occurs due to shearing effect on the tensile surface. The spalling and buckling of the coating on the compressive surface are observed. The compressive stress generated on the top surface (where the indent is in contact) did not cause adhesive failure of the coating. Moreover, cohesive cracks occur on the tensile surface of the coating. The crack ledge under the action of shear stress appears on the tensile surface of TiN coating and multi cracking of coating is resulted. The crack spacing is small indicating sliding and splitting separation between the adjacent columns in the coating.

The tests can be extended to include the duplex treated workpieces such as the heat treatment of surface prior to TiN coating. This enhances the interface properties of the coating and base alloy.

The results can be used to assess the TiN coating applications in cutting tools, particularly drill bits and punches.

This paper provides information on mechanical behavior of TiN coating when subjected to bending force and offers practical help for the researchers and scientists working in the coating area.

The purpose of this paper is to present an overview of functional properties of the polysaccharide-based component and their application in developing edible film and coating for the food processing sector.

In this review study, approximately 271 research and review articles focusing on studies related to polysaccharide-based components and their film-forming properties. This article also focused on the application of polysaccharide-based edible film in the food sector.

From the literature reviewed, polysaccharide components and components-based edible film/coating is the biodegradable and eco-friendly packaging of the materials and directly consumed by the consumer with food. It has been reported that the polysaccharide components have excellent properties such as being nontoxic, antioxidant, antimicrobial, antifungal and with good nutrients. The polysaccharide-based edible film has lipid and gas barrier properties with excellent transparency and mechanical strength. In various studies, researchers worked on the development of polysaccharide-based edible film and coating by incorporating plant based natural antioxidants. This was primarily done for obtaining improved physical and chemical properties of the edible film and coating. In future, the technology of developing polysaccharide-based edible film and coating could be used for extending the shelf life and preserving the quality of fruits and vegetables at a commercial level. There is more need to understand the role of edible packaging and sustainability in the food and environment sector.

Through this review paper, possible applications of polysaccharide-based components and their function property in the formation of the edible film and their effect on fruits, vegetables and other food products are discussed after detailed studies of literature from thesis and journal article.