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Article
Publication date: 1 September 2023

Dinçer Aydın and Şule Yılmaz Erten

The buildings should be designed by respecting the environmental and climatic conditions they are in and their orientation. Then, the characteristics of the building envelope (BE…

159

Abstract

Purpose

The buildings should be designed by respecting the environmental and climatic conditions they are in and their orientation. Then, the characteristics of the building envelope (BE) play an important role in building energy consumption and user comfort. In fact, the type and material of glazing is one of the crucial parameters for BE. The transparency ratio of BE also determines the façade performance. The aim of this study is to analyze the different renovation scenarios for BE with high transparency of an educational building (EB) in hot summer weather to obtain indoor thermal comfort (ITC) for users.

Design/methodology/approach

The methodology includes thorough measurement of existing ITC using TESTO-440 and simulation of each retrofit scenario using DesignBuilder building energy modeling (BEM) simulation software with Energyplus to determine optimal thermal comfort. Since the study focuses on the impact of the transparent BE on summer ITC, four main scenarios, naturally ventilated (NV) façade, film-coated glass façade, replacement of glazing with opaque units, sun-controlled façade with overhang and solar shading, were simulated. The results were analyzed comparatively on both performance and cost to find the best renovation solutions.

Findings

A total of 7 different renovation scenarios were tested. Simulation results show that passive systems such as NV have limited contribution to indoor air temperature (IAT) improvement, achieving only a 4 °C reduction while offering the lowest cost. A film coating resulted in a reduction of 3–6 °C, but these applications have the highest cost and least impact on ITC. It was found that exterior coating leads to better results in film coating. Preventing and limiting the increase in IAT was achieved by reducing the transparency ratio of BE. The best results were obtained in these scenarios, and it was possible to reduce IAT by more than 10 °C. The best performance/cost value were also obtained by decreasing transparency ratio of roof and sun control.

Research limitations/implications

Since the high transparency ratio has a negative impact on summer comfort, especially in hot climate zones, summer ITC was prioritized in the renovation solutions for the case building.

Originality/value

The study’s findings present a range of solutions for improving the ITC of highly transparent buildings. The solutions can help building managers see the differences in renovation costs and their impacts on ITC to decrease the cooling load of the existing buildings.

Details

Open House International, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0168-2601

Keywords

Article
Publication date: 19 February 2024

Bassem Assfour, Bassam Abdallah, Hour Krajian, Mahmoud Kakhia, Karam Masloub and Walaa Zetoune

The purpose of this study is to investigate the structural, surface roughness and corrosion properties of the zirconium oxide thin films deposited onto SS304 substrates using the…

Abstract

Purpose

The purpose of this study is to investigate the structural, surface roughness and corrosion properties of the zirconium oxide thin films deposited onto SS304 substrates using the direct current (DC) magnetron sputtering technique.

Design/methodology/approach

DC sputtering at different powers – 80, 100 and 120 W – was used to deposit ZrO2 thin films onto different substrates (Si/SS304) without annealing of the substrate. Atomic force microscope (AFM), energy-dispersive X-ray spectroscopy (EDS), Tafel extrapolation and contact angle techniques were applied to investigate the surface roughness, chemical compositions, corrosion behavior and hydrophobicity of these films.

Findings

Results showed that the thickness of the deposited film increased with power increase, while the corrosion current decreased with power increase. AFM images indicated that the surface roughness decreased with an increase in DC power. EDS analysis showed that the thin film has a stoichiometric ZrO2 (Zr:O 1:2) composition with basic uniformity. Water contact angle measurements indicated that the hydrophobicity of the synthesized films decreased with an increase in surface roughness.

Originality/value

DC magnetron sputtering technique is infrequently used to deposition thin films. The obtained thin films showed good hydrophobic and anticorrosion properties. Finally, results are compared with other deposition techniques.

Details

World Journal of Engineering, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1708-5284

Keywords

Article
Publication date: 18 May 2023

Bassam Abdallah, Mahmoud Kakhia, Karam Masloub and Walaa Zetoune

Niobium Nitride (NbN) was interesting material for its applications in the medicinal tools or tools field (corresponding to saline serum media) as well as in mechanical…

41

Abstract

Purpose

Niobium Nitride (NbN) was interesting material for its applications in the medicinal tools or tools field (corresponding to saline serum media) as well as in mechanical properties. The aim of this work was depositing NbN thin films on two types of substrates (stainless steel (SS304) and silicon (100)) using plasma technique at varied powers (100–150 W).

Design/methodology/approach

DC magnetron sputtering technique at different powers were used to synthesis NbN films. Film structure was studied using X-ray diffraction (XRD) pattern. Rutherford elastic backscattering and energy dispersive X-ray were used to examine the deposited film composition. The films morphology was studied via atomic force microscopy and scanning electron microscopy images. Corrosion resistance of the three NbN/SS304 films was studied in 0.9% NaCl environment (physiological standard saline).

Findings

All properties could be controlled by the modification of DC power, where the crystallinity of samples was changed and consequently the corrosion and microhardness were modified, which correlated with the power. NbN film deposited at higher power (150 W) has shown better corrosion resistance (0.9% NaCl), which had smaller grain size (smoother) and was thicker.

Originality/value

The NbN films have a preferred orientation (111) matching to cubic structure phase. Corrosion resistance was enhanced for the NbN films compared to SS304 substrates (noncoating). Therefore, NbN films deposited on SS304 substrate could be applied as medicinal tools as well as in mechanical fields.

Details

World Journal of Engineering, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1708-5284

Keywords

Article
Publication date: 2 March 2023

Walid E. Elgammal, Essam M. Eliwa, Hosni A. Goomaa, Medhat E. Owda and H. Abd El-Wahab

This paper aims to focus on the synthesis of the macrocyclic complexes (Cu and Zn) and their applications as anticorrosive materials in epoxy paint formulation for surface coating…

Abstract

Purpose

This paper aims to focus on the synthesis of the macrocyclic complexes (Cu and Zn) and their applications as anticorrosive materials in epoxy paint formulation for surface coating application.

Design/methodology/approach

A selected macrocyclic Cu(II) and Zn(II) complexes were prepared via template synthesis and characterized using Fourier transform infrared, thermal gravimetric analysis, scanning electron microscope, flexibility, hardness and adhesion of coating films prepared using epoxy paint.

Findings

The corrosion resistance of the epoxy-painted films was improved due to the incorporation of the Zn and Cu complexes into the formulation.

Originality/value

It was found that the metal complex-based formulation with Cu(II) and Zn(II) had outperformed the sample blank.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 13 September 2023

Amirul Syafiq, Lilik Jamilatul Awalin, Syukri Ali and Mohd Arif

The paper aims to design the optimum formulation of the nano-titanium dioxide (TiO2) hydrophilic coating system using the synthetic polypropylene glycol (PPG), which can create…

Abstract

Purpose

The paper aims to design the optimum formulation of the nano-titanium dioxide (TiO2) hydrophilic coating system using the synthetic polypropylene glycol (PPG), which can create the reflection and absorption property.

Design/methodology/approach

TiO2 nanoparticles are used as fillers, and PPG has been blended at the proper ratio of 1PPG: 0.2TiO2. The prepared resin has been applied onto the glass substrate at different numbers of glass immersions during the dip-coating fabrication process. One-time glass immersion is labeled as T1 coating, two-time glass immersion is labeled as T2 coating and three-time glass immersion is labeled as T3 coating. All the prepared coating systems were left dry at ambient temperature.

Findings

T3 coating showed the lowest reading of WCA value at 40.50°, due to higher surface energy at 61.73 mN/m. The T3 coating also shows the greatest absorbance property among the prepared coating systems among the prepared coating. In terms of reflectance property, the T2 coating system has great reflectance in UV region and near-infrared region, which is 16.47% and 2.77 and 2.73%, respectively. The T2 coating also has great optical transmission about 75.00% at the visible region.

Research limitations/implications

The development of thermal insulation coating by studying the relationship between convection heat and reflectance at different wavelengths of incident light.

Practical implications

The developed coating shows high potential for glass window application.

Originality/value

The application of the hydrophilic coating on light absorption, reflectance and transmission at different wavelengths.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 13 February 2023

Iling Aema Wonnie Ma, Gerard Ong, Ammar Shafaamri, Julie Nabilah Jamalludin, Nina Nazirah Ishun, Ramesh Kasi and Ramesh Subramaniam

This study aims to fabricate the acrylic-based polymeric composite coating with a hydrophobic surface associated with natural oil polyol (NOP) and polydimethylsiloxane with the…

Abstract

Purpose

This study aims to fabricate the acrylic-based polymeric composite coating with a hydrophobic surface associated with natural oil polyol (NOP) and polydimethylsiloxane with the incorporation of 3 Wt.% SiO2 nanoparticle (SiO2np) against the corrosive NaCl media.

Design/methodology/approach

The structural properties of the formulated polymeric composite coatings were investigated by using Fourier transform infrared spectroscopy, ultraviolet-visible spectroscopy, water contact angle (WCA) and cross-hatch (X-Hatch) tests. The WCA measurement was used to study the surface wettability of the formulated polymeric composite coatings. The corrosion protection performance of the nanocomposite coated on the mild steel substrate was studied by immersing the samples in 3.5 Wt.% NaCl solution for 30 days using electrochemical impedance spectroscopy.

Findings

The enhanced polymeric composite coating system performed with an excellent increase in the WCA up to 111.1° which is good hydrophobic nature and very high coating resistance in the range of 1010 Ω attributed to the superiority of SiO2np.

Originality/value

The incorporation of SiO2np into the polymeric coating could enhance the surface roughness and hydrophobic properties that could increase corrosion protection. This approach is a novel attempt of using NOP along with the addition of SiO2np.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 28 November 2022

Dhananjay A. Patil, Vidhukrishnan Ekambaram Naiker, Ganesh A. Phalak, Karan W. Chugh and S.T. Mhaske

This study aims to synthesize two different benzoxazines (Bz) monomers using bio-based and petroleum-based primary amines, respectively, and they have been compared to study their…

194

Abstract

Purpose

This study aims to synthesize two different benzoxazines (Bz) monomers using bio-based and petroleum-based primary amines, respectively, and they have been compared to study their thermal and mechanical performances.

Design/methodology/approach

A bio-based bisphenol, Divanillin (DiVa), was formed by reacting two moles of vanillin with one mole of ethylenediamine (EDA) which was then reacted firstly with paraformaldehyde and EDA to form the benzoxazine DiVa-EDA-Bz, and secondly with paraformaldehyde and furfuryl amine (FFA) to form the benzoxazine DiVa-FFA-Bz. The molecular structure and thermal properties of the benzoxazines were characterized by fourier transform infrared spectroscopy and nuclear magnetic resonance (1H,13C) spectroscopies, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), respectively. The benzoxazines were further coated on mild steel panels to evaluate their mechanical properties and chemical resistance.

Findings

The DSC results of DiVa-FFA-Bz showed two exothermic peaks related to crosslinking compared to the one in DiVa-EDA-Bz. The DiVa-FFA-Bz also showed a higher heat of polymerization than DiVa-EDA-Bz. The TGA results showed that DiVa-FFA-Bz exhibited higher thermal stability with a residual char of 54.10% than 43.24% for DiVa-EDA-Bz. The chemical resistance test results showed that DiVa-FFA-Bz showed better chemical resistance and mechanical properties due to its higher crosslinking density.

Originality/value

This study shows the use of bio-based materials, vanillin and FFA, for synthesizing a benzoxazine resin and its application at high temperatures.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 16 October 2023

Monapriya Naidu Kerinasamy Naidu, Iling Aema Wonnie Ma, Sachin Sharma Ashok Kumar, Vengadaesvaran Balakrishnan, Ramesh Subramaniam and Ramesh Kasi

The purpose of this study is to develop a protective coating system on mild steel panel incorporating epoxidized natural rubber with acrylic polyol resin.

Abstract

Purpose

The purpose of this study is to develop a protective coating system on mild steel panel incorporating epoxidized natural rubber with acrylic polyol resin.

Design/methodology/approach

In this work, a novel attempt is made to develop binder coatings using epoxidized natural rubber-based material and an organic resin (acrylic resin) for corrosion protection on metal substrate. Seven different samples of multifunctional coatings are developed by varying the compositions of epoxidized natural rubber (ENR) and acrylic resin. The properties of the developed coatings have been characterized using analytical methods such as Fourier transform infrared spectroscopy (FTIR) and electrochemical impedance spectroscopy (EIS). EIS has been carried out for 30 days to evaluate the corrosion resistance after immersing into 3.5 wt.% of sodium chloride. Cross hatch cut tester (CHT) has been used to study the adhesive properties. UV–Visible Spectroscopy (UV–Vis) was also used to assess changes in the coating-film transparency of the natural rubber-based coating systems in this study.

Findings

The developed coatings have formed uniform layer on the substrate. CHT results show excellent adhesion of the coatings. Higher concentrations of ENR have higher transparency level, which reduces when the acrylic concentration increases. FTIR analysis confirms the crosslinking that occurred between the components of the coatings. Based on the impedance data from EIS, the incorporation of natural rubber can be an additive for the corrosion protection, which has the coating resistance values well above 108Ω even after 30 days of immersion.

Practical implications

The blending method provides a simple and practical solution to improve the strength and adhesion properties of acrylic polyol resin with epoxidized natural rubber. There is still improvement needed for long-term applications.

Originality/value

The work has been conducted in our laboratory. The combination of natural rubber-based materials and organic resins is a new approach in coating research.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 28 March 2024

Monica Puri Sikka, Jameer Aslam Bargir and Samridhi Garg

Intense interest has been shown in creating new and effective biocide agents as a result of changes in bacterial isolates, bacterial susceptibility to antibiotics, an increase in…

Abstract

Purpose

Intense interest has been shown in creating new and effective biocide agents as a result of changes in bacterial isolates, bacterial susceptibility to antibiotics, an increase in patients with burns and wounds and the difficulty of treating infections and antimicrobial resistance. Woven, nonwoven and knitted materials are used to make dressings; however, nonwoven dressings are becoming more popular because of their softness and high absorption capacity. Additionally, textiles have excellent geometrical, physical and mechanical features including three-dimensional structure availability, air, vapor and liquid permeability, strength, extensibility, flexibility and diversity of fiber length, fineness and cross-sectional shapes. It is necessary to treat every burn according to international protocol and along with it has to focus on particular problems of patients and the best possible results.

Design/methodology/approach

The objective of this paper is to conduct a thorough examination of research pertaining to the utilization of textiles, as well as alternative materials and innovative techniques, in the context of burn wound dressings. Through a critical analysis of the findings, this study intends to provide valuable insights that can inform and guide future research endeavors in this field.

Findings

In the past years, there have been several dressings such as xeroform petrolatum gauze, silver-impregnated dressings, biological dressings, hydrocolloid dressings, polyurethane film dressings, silicon-coated nylon dressings, dressings for biosynthetic skin substitutes, hydrogel dressings, newly developed dressings, scaffold bandages, Sorbalgon wound dressing, negative pressure therapy, enzymatic debridement and high-pressure water irrigation developed for the fast healing of burn wounds.

Originality/value

This research conducts a thorough analysis of the role of textiles in modern burn wound dressings.

Details

Research Journal of Textile and Apparel, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1560-6074

Keywords

Article
Publication date: 13 June 2023

Roma G. Elfadel, Hala M. Refat, H. Abdelwahab, Salem S. Salem, Mohamed A. Awad and M.A.M. Abdel Reheim

This paper aims to investigate the prepared modified alkyd and poly(ester-amide) (PEA) resins as antimicrobial and insecticide binders for surface coating applications.

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Abstract

Purpose

This paper aims to investigate the prepared modified alkyd and poly(ester-amide) (PEA) resins as antimicrobial and insecticide binders for surface coating applications.

Design/methodology/approach

Salicylic diethanolamine and 4-(N, N-dimethylamino) benzylidene glutamic acid were prepared and used as new sources of polyol and dibasic acid for PEA and alkyd resins, then confirmed by: acid value, FT-IR and 1H-NMR. The coating performance of the resins was determined using measurements of physico-mechanical properties. The biological and insecticide activities of the prepared resins were investigated.

Findings

The tests carried out revealed that the modified PEA and alkyd enhanced both phyisco-mechanical and chemical properties in addition to the biological and insecticide activities. The results of this paper illustrate that the introduction of salicylic diethanolamine and 4-(N, N-dimethylamino) benzylidene glutamic acid within the resin structure improved the film performance and enhanced the antimicrobial activity performance of PEA and alkyd resins.

Research limitations/implications

The modified alkyd and PEA organic resins can be used as biocidal binders when incorporated into paint formulations for multiple surface applications, especially those that are exposed to several organisms.

Originality/value

Modified alkyd and PEA resins based on newly synthesized modifiers have a significant potential to be promising in the production and development of antimicrobial and insecticide paints, allowing them to function to restrict the spread of insects and microbial infection.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

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