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A major drawback of current copper thick‐film technology is the inefficient removal of the organic binder associated with the dielectric material in the low‐oxygen inert gas (N2) atmosphere of the furnace. In processing large area and/or multilayer substrates, the incomplete binder removal causes deleterious effects which have been well documented. Therefore, it is necessary to remove hydrocarbons and residual carbon from the films in the burn‐out section of the furnace before the films begin developing their characteristic microstructures. However, the atmosphere currently employed is not capable of removing all the carbon and hydrogen in the form of gaseous oxides. In literature, in addition to furnace modifications, several atmosphere modifications and manipulations have been proposed to achieve optimum properties for the fired films. With few exceptions, the scientific basis for such atmosphere modifications and manipulations has been left either unaddressed or obscure. With this background, this paper examines the feasibility of using a reactive gas mixture in the furnace to achieve efficient organic binder removal. Phase stability diagrams are presented to illustrate the stability of (i) carbon, (ii) thick film copper ingredients, (iii) active phases of resistors, and (iv) components of glassy and crystalline phases of dielectrics in selected reactive atmospheres. The stability of certain furnace belt constituents is also addressed. Mass balance calculations are shown to demonstrate the extent of carbon removal and copper oxidation in typical nitrogen atmospheres. Based on the interpretation of thermodynamic data and reaction mechanisms involved, a specific H2‐H2O mixture with nitrogen as the carrier gas is recommended. The approach presented here constitutes a general analytical scheme to understand materials‐atmosphere interactions occurring across a temperature range. Several issues in furnace design are also discussed from the standpoint of gas‐solid reaction kinetics. These deal with the design of gas‐flow systems that facilitate removal of organic binders.

THE partial pressure of the oxygen content in the atmosphere decreases directly with the atmospheric pressure, i.e., with the altitude, the proportion of oxygen in the atmosphere (about 20·9 per cent) remaining practically constant in the substratosphere.

This paper aims to study flow‐induced corrosion mechanisms for carbon steel in high‐velocity flowing seawater and to explain corrosive phenomena.

An overall mathematical model for flow‐induced corrosion of carbon steel in high‐velocity flow seawater was established in a rotating disk apparatus using both numerical simulation and test methods. By studying the impact of turbulent flow using the kinetic energy of a turbulent approach and the effects of the computational near‐wall hydrodynamic parameters on corrosion rates, corrosion behavior and mechanism are discussed here. It is applicable in order to understand in depth the synergistic effect mechanism of flow‐induced corrosion.

It was found that it is scientific and reasonable to investigate carbon steel corrosion through correlation of the near‐wall hydrodynamic parameters, which can accurately describe the influence of fluid flow on corrosion. The computational corrosion rates obtained by this model are in good agreement with measured corrosion data. It is shown that serious flow‐induced corrosion is caused by the synergistic effect between the corrosion electrochemical factor and the hydrodynamic factor, while the corrosion electrochemical factor plays a dominant role in flow‐induced corrosion.

The corrosion kinetics and mechanism of metals in a high‐velocity flowing medium is discussed here. These results will help those interested in flow‐induced corrosion to understand in depth the type of issue.

A method extensively used in the production of optically flat and finely finished surfaces is that of lapping the surface upon a plate using a loose abrasive mixed into a slurry form with a carrying fluid. If the surfaces finished in this way are in continuous or intermittent sliding contact, it is the author's opinion that any abrasives retained in their surfaces will affect surface wear. This paper reported on some exploratory work to indicate the degree of embedment of abrasive in certain materials lapped by hand.

The purpose of this paper is to provide a critical and in‐depth review of the present status and recent developments in synthetic methodologies, reaction engineering, process design and quality control aspects associated with the manufacture of mono and multifunctional acrylate monomers.

This paper reviews commercially important UV cure mono and multifunctional acrylate monomers. It covers their synthesis, catalyst, and appropriate solvents for azeotropic removal of byproducts. The detail discussion on catalysis, basis of design of reactors and commercial plant and the process engineering associated with the manufacture has been supported through citation of synthesis of various acrylate monomers. The methodologies adopted for determination of physical, chemical and compositional characterisation of acrylate monomers have been presented. In addition, the guidelines regarding the bulk storage and commercial handling of acrylates have been reviewed.

The reaction engineering of esterification reaction between acrylic acid and polyol has been worked out to provide the basis for selection of reactors. The reaction has been modeled as a series – parallel complex reaction for providing explanation for generation of various byproducts/adducts and multiple esters.

The detailed discussion on formation, characterisation and treatment of Michael adducts and purification of acrylate monomers will be relevant for new researchers for further development. A review of guidelines on selection of homogenous and heterogeneous catalysts for synthesis of acrylate monomers has been presented.

Since the related literature on acrylate monomers is scarce, scattered and proprietary, the consolidated coverage in one paper will be useful.

The reported mathematical models of gas–liquid flow in single snorkel Rheinstahl–Heraeus (SSRH) are based on the assumption of steady Ar-molten steel flow. The purpose of this paper is to develop a mathematical model to describe the unsteady turbulent flow (CO-Ar-molten steel) with nonequilibrium decarburization reaction.

On the base of the finite volume method, the computational fluid dynamics software CFX is used to predict the unsteady fluid flow, the spatial distributions of CO/argon gas and carbon element. The water model experiment and the industrial experiment are carried out to verify the mathematical models.

A two-way coupling model (T-WCM) based on algebraic slip model is developed to investigate the coupling phenomena. The related results show that T-WCM is more rigorous and accurate than one-way coupling model in predicting carbon content of molten steel. The amount of CO gas, which can enhance turbulent flow and mass transfer, is about three times the argon gas blown into SSRH.

CO gas is the key factor in investigating the transport phenomena. This study fully reveals the truth about the unsteady gas-liquid flow in SSRH. It is necessary to adopt T-WCM based on algebraic slip model to describe the CO-Ar-molten steel flow phenomenon.

The chemical structure of paper is simply explained, commencing with subatomic particles, atoms and molecules. The forces which bond atoms into molecules, molecules into chains, chains into sheets, and sheets into layers are described. Acid is defined, and the deleterious role of acid in breaking the forces which bond atoms into molecules is detailed.

Describes the various sensing techniques that can be employed to monitor hydrocarbons in water, which can be applied to continuous organic monitoring as well as the detection of major chemical spills. Outlines the methods of analysing water to measure for total carbons, total organic carbons, volatile chemicals and total oxygen demand and the problems of making effective measurements. Concludes that successful monitoring of hydrocarbons in water often requires a tailored approach depending on the characteristics of the sample and the site of the instruments, and therefore close consultation with the monitoring authorities and the instrument manufacturer are essential.

This paper aims to demonstrate the synthesis of polyesterification reaction of non-edible jatropha seed oil (JO) and acrylic acid, which leads to the production of acrylated epoxidised-based resin. To understand the physico-chemical characteristics when synthesis the JO-based epoxy acrylate, the effect of temperature on the reaction, concentration of acrylic acid and role of catalyst on reaction time and acid value were studied.

First, the double bond in JO was functionalised by epoxidation using the solvent-free performic method. The subsequent process was acrylation with acrylic acid using the base catalyst triethylamine and 4-methoxyphenol as an inhibitor respectively. The physico-chemical characteristics during the synthesis of the epoxy acrylate such as acid value was monitored and analysed. The formation of the epoxy and acrylate group was confirmed by a Fourier transform infrared spectroscopy spectra analysis and nuclear magnetic resonance analysis.

The optimum reaction condition was achieved at a ratio of epoxidised JO to acrylic acid of 1:1.5 and the reaction temperature of 110°C. This was indicated by the acid value reduction from 86 to 15 mg KOH/g sample at 6 hours.

The JO-based epoxy acrylate synthesised has a potential to be used in formulations the prepolymer resin for UV curable coating applications. The JO which is from natural resources and is sustainable raw materials that possible reduce the dependency on petroleum-based coating.

The epoxidised jatropha seed oil epoxy acrylate was synthesised, as a new type of oligomer resin that contains a reactive acrylate group, which can be alternative to petroleum-based coating and can used further in the formulation of the radiation curable coating.

The model of a shaft furnace operation is presented in this paper. Aim of this model is to predict concentrations of carbon monoxide and dioxide, the temperature of the lava and the heat losses.

The mathematical model is based on 1D mass and heat balance laws for flue gas, coke and four materials used in a mineral wool production. Process parameters should be optimized for the minimal heat loss and the carbon monoxide concentration while keeping the prescribed lava temperature. The model consists of heterogeneous and homogeneous reactions for coke combustion, dolomite decomposition, rock and coke heating and a rock-melting model. The resulting system of partial differential equations is discretized by the finite volume method and solved with the explicit Euler scheme together with the point-implicit preconditioning of sources in species balance equations.

Numerical results are compared with the measured data on the pilot-scale device and show good agreement. It is found that in the lower region of the furnace, the large amount of carbon monoxide is present despite high oxygen levels.

Based on the numerical model, the parameters of the secondary air stream could be studied (position, volume flux, oxygen enrichment and temperature) to decrease levels of carbon monoxide emissions while keeping lava temperature at needed levels.

The paper includes mathematical and numerical model needed for simulation of shaft furnaces in mineral wool industry. It can be used as a valuable tool for design engineers and furnace operators during research or redesign of existing devices.