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Linseed oil was employed to modify polyesteramide resin via the condensation of hydroxyethylamide derivatives of fatty acids of linseed oil, i.e. {N, N′‐bis(2 hydroxylethyl) linseed amide} and phthalic anhydride and dicarboxylic acids such as adipic acid, succinic acid and sebacic acid. The polyesteramide resins obtained were tested for their application as a vehicle/binder in the preparation of surface coatings. The resins obtained were also characterised for their physico‐chemical properties, film forming properties and chemical resistance.

The composition and properties of milk are considerably important for dairy farmers, manufacturers and consumers. Despite the significant role of bovine milk in Iranian dairy products, there is little information about the effect of production season and location on the physicochemical properties of pasteurized milk as a final product. The purpose of this study was to investigate the effects of seasonal, geographical and product brand variations on the chemical components and physical properties of Iranian pasteurized bovine milk.

A total of 400 samples of pasteurized milk were obtained during a 12-month period, from April 2014 to March 2015, using random sampling. Chemical components (protein, fat, lactose, dry matter and solids-not-fat) and physical properties (freezing point, extraneous water content, titratable acidity, density and pH) of the collected samples were analyzed. A one-way ANOVA was used to perform the statistical analysis of data, and results were presented as the mean ± standard deviation.

It was found that the biochemical constituents and physical properties of pasteurized milk samples were linked to seasonal and geographical variation parameters. The milk sampled during spring and summer contained significantly less fat, protein and solids-not-fat (p < 0.05) than samples in autumn and winter. Also, samples in spring had a significantly higher (p < 0.05) extraneous water (0.8 per cent) compared to milk sampled in winter (−0.4 per cent). Samples in Maragheh and Mianeh contained the highest level of fat (2.82 per cent) and protein (3.09 per cent) content in the province. The sampled milk from the south (Mianeh and Hashtrud) and the northwest (Marand) had also significantly higher (p < 0.01) freezing points than the other areas. No significant differences (p > 0.01) were found in physicochemical properties in different product brands of the milk samples.

Seasonal and geographical parameters are crucial factors in the diversity of physicochemical parameters of commercial pasteurized milk. In this study, unlike the other studies, differences in milk product brand were not significant. Further research will be needed to assess other factors such as the effect of management practices and feeding strategies on farms.

Presents a hyperbranched polymer, a hydroxyl functional aliphatic polyester which consists of a polyalcohol core from which branches extend, forming a core‐shell structure with a large number of hydroxyl groups at its peripheral surface. It is polydisperse and consists, apart from the main core/shell fraction, of a minor fraction with tree‐like branches. Hyperbranched polyesters of this type have been found to contribute to improved physical, as well as chemical and mechanical, properties. Due to the unique molecular architecture, it is possible to design the hyper‐branched polyester in numerous ways to acquire the desired properties in different applications. Focuses on and illuminates how molecular design might affect properties in not only one, but many applications. Illustrates this by way of examples in the field of alkyds, where presented hyperbranched polymer contributes to low viscosities combined with excellent drying; in amine cured epoxies, where a hyperbranched epoxy demonstrates dramatically increased toughening; and in polyurethanes and radcure, where rapid curing can be obtained by proper molecular design.

The present study aims to demonstrate the use of renewable source in the preparation of polyurethane (PU) coatings and mitigation of corrosion of mild steel using nano zinc phosphate. Results indicated improvement in the properties of the PU coatings, especially anticorrosive properties by the addition of nano zinc phosphate.

Renewable-source-based polyestermyristamide polyol was synthesized using myristic acid as a starting material. The synthesis of polyol was carried by amidation as well as by esterification by a one-pot route. The structure of the prepared polyestermyristamide was confirmed with the support of end-group analysis and spectral study. PU coatings were prepared from synthesized polyestermyristamide polyol and used to protect metal substrate against corrosion. Corrosion properties of the prepared PU were found to be lower; hence, to improve the performance of these coatings, nano zinc phosphate was added to the coatings. The nano zinc phosphate was synthesized in the laboratory by reported sonication method and analyzed for morphology by scanning electron microscopy. Performance of coatings was studied with respect to effect of percentage nano zinc phosphate on thermal stability, mechanical properties and chemical resistances of PU coatings.

The combination of zinc phosphate nano rods and particles in myristic acid-based PU coatings provided substantial corrosion barrier properties to the coatings. Different per cent of the synthesized zinc phosphate nano rods and particles were loaded into the matrix, and corresponding coatings were estimated for corrosion resistance, thermal and chemical properties. Immersion study of the coated panels in 3.5 per cent NaCl solution showed good corrosion resistance for both PU coatings containing 2 and 3 per cent nano zinc phosphate.

This paper has provided the solution to replace existing petroleum-based raw materials with myristic acid as a renewable source in preparing PU coatings. Conventional coatings act as physical barriers against aggressive species but do not have ability to perform as permanent impassable to corrosive species. Hence, nano-sized zinc phosphate is used as corrosion inhibitor in to the synthesized PU coatings for enhancing anticorrosive performance.

In the paper, polyesteramide polyol is synthesized using renewable-source-based material, i.e. myristic acid to replace existing petroleum-based acid as a greener approach. Normally, vegetable oils are preferred as they have such kinds of polyols. The polyesteramide reaction is one pot that avoids the extra steps required in the synthesis. Further, it has been found that the pristine renewable coatings are unable to fully protect subtract from corrosion, whereas an addition of the nano-size zinc phosphate has enhanced the corrosion properties of the coatings.

Polymeric systems based on polyesteramides (PEA) are high performance materials, which combine the useful properties of polyester and polyamide resins, and find many applications, most importantly as protective surface coatings. The purpose of this paper is to characterise and evaluate new modified anti‐corrosive PEA resins for use in protective coating formulations.

In the study report here, new modified PEA compositions were prepared and evaluated as vehicles for surface coating. The PEA resins were obtained by means of a condensation polymerisation reaction between phthalic anhydride (PA) and N,N‐bis‐(2‐hydroxyethyl) linseed oil fatty acid amide (HELA) as the ingredient source of the polyol used. The phthalic anhydride was partially replaced with N‐phthaloylglutamic acid NPGA as the ingredient source of the dibasic acid. The structure of the resin was confirmed by FT‐IR spectral studies. Coatings of 50±5 μm thickness were applied to the surface of glass panels and mild steel strips by means of a brush. The coating performance of the resins was evaluated using international standard test methods and involved the measurement of phyisco‐mechanical properties and chemical resistance.

The tests carried out revealed that the modified PEA based on N‐phthaloylglutamic acid (NPGA) enhanced both phyisco‐mechanical and chemical properties. Also, the resins were incorporated within primer formulations and evaluated as anti‐corrosive single coatings. The results illustrate that the introduction of N‐phthaloylglutamic acid, within the resin structure, improved the film performance and enhances the corrosion resistance performance of PEA resins.

The modified PEA compounds can be used as binder in paint formulations to improve chemical, physical and corrosion resistance properties.

Modified PEA resins are cheaper and can be used to replace other more expensive binders. These modified PEA resins can compensate successfully for the presence of many the anticorrosive paint formulations and thus lower the costs. The main advantage of these binders is that they combine the properties of both polyester and polyamide resins based on nitrogenous compound, are of lower cost, and they also overcome the disadvantages of both its counterparts. Also, they can be applied in other industrial applications.

The purpose of this paper is to describe the synthesizing of polyesteramide (PEA) resins using an acid functional acrylic copolymer (ACR) and hydroxy ethyl fatty amide (HEFA) of dehydrated castor oil (DCO) and to study the effect of HEFA on the performance properties of the coating films of PEA resins.

The PEA resins are synthesised by using ACR (synthesised by using butyl methacrylate (BMA) and maleic anhydride (MA)), and HEFA. Different formulations are developed by using ACR and HEFA. The coatings are made using xylene/acetone as a solvent. These coatings are applied on mild steel panels and are cured at 110°C. Various mechanical, optical and chemical properties of the coating films are evaluated.

The study reveals that, HEFA of DCO is used successfully as a cross‐linking agent for the ACR to form the PEA resins. Incorporation of long chain fatty acid (C₁₈) moieties of the fatty amide in the PEA resins backbone is thought to serve as flexibliser, which lead to improved mechanical and chemical properties of the films. The optimum results are obtained from composition three of copolymer A having (3:1) (ACR:HEFA) molar ratio.

The PEA resins synthesised here are made up of ACR (synthesised by using BMA and MA), and HEFA of DCO. Besides, this ACRs can be synthesised from acrylic acid. In addition to this, one can also use HEFA synthesised from other oils.

This method provides a simple solution for the synthesis of PEA resins and resulting to their improved mechanical properties. The developed product is also an environment friendly product.

The method developed here for the synthesis of PEA resins form ACRs and HEFA is unique and can be used as an effective surface coating material. These studies will help to develop low volatile organic compounds product which could find numerous industrial applications in surface coatings for metal surfaces.

To prepare modified epoxy resins from resorcinol, cresol and phenol for improved adhesion and chemical resistance. To evaluate the properties of such modified epoxy resins.

Epoxy novolac resins (ENRs) were synthesised by condensing epichlorohydrin with novolacs based on different types of substituted phenols for improving adhesion and chemical resistance. Various compositions were made by incorporating different proportions of polyamide resin. The chemical and adhesive strengths of the conventional epoxy and the modified epoxy resins were characterised.

The modified ENR using substituted phenols showed significant enhancement of chemical and adhesive strengths over the conventional DGEBA resin. The modified ENR had an increased number of glycidyl groups (thus increased functionality) of resin, which was responsible for improved chemical and adhesive strengths over the conventional DGEBA resin.

The EPN resins used in the present context was synthesised from phenol, resorcinol and cresol and cured by polyamide resin of different amine values. Besides, it could be synthesised from phenolphthalein p‐aminophenol and p‐ter‐butylcatachol, etc.

The method developed provided a simple and practical solution to improving the adhesive and chemical resistance of cured epoxy phenol novolac resins.

The method for enhanced adhesive and chemical resistance of cured epoxy was novel and could find numerous applications in surface coating and adhesive.

To provide information about technical data; wear behaviour of worn rotor parts in mining industry and for the other application of ferrous alloys.

Wear behaviour of the various filler wires were tested (tensile, hardness, and wear) and compared with each other in the light of microstructure, chemical, and mechanical properties.

The results showed that the wear rates were significantly increased with the increasing load, welding current, wear distance and poor mechanical properties. A larger amount of C, Cr, and Mn specimen showed the best wear resistance since it contained a number of hard MC‐type carbides and coarse grains. Furthermore, for all materials the weight loss increases linearly with the increasing of welding arc current, load and wear distance.

It would be interesting to search about the toughness values and fatigue behaviour of these materials. It could be the good idea for future work could be concentrated fracture surface analysis of these materials.

For these materials choosing the right chemical composition of the filler material, certain arc current and ideal microstructure is crutial for the wear response.

The main value of this paper is to contribute and fulfil the mechanical properties of welding wires that is being studied so far in the literature such as the effects of chemical composition, applied road range, and arc current on the tensile, hardness and wear behaviours of the welding wires.

Compilation of numeric data has been of interest to mankind since ancient times. Collections of astronomic observations permitted the production of systematic calendars for great nations like the Mayans, Egyptians, Babylonians and Jews. Extensive sets of data were available to early navigators and pioneer physicists of medieval times. A well known example of data compilation was the celebrated Alfonsine Tables. The tables were completed in 1252 under the direction of Isaac ben Said and Yehuda ben Moshe Cohen during the rule of Alfonso X. of Castile. For three hundred years this was considered to be the best planetary data collection. Another famous astronomical data compilation was Caroline Herschel's Catalogue of Stars published in 1798. In the last decade there has been an increased need for precise information by government agencies, private industries, the business world and academic institutions. The continuing acknowledgement of the need for quantitative data contributed to the quick development and marketing of many databases that contain numerical and other factual information.

The aim of this paper is to synthesise polyester/silica hybrid resins and their hybrid polyurethanes via in situ (IS) and blending (BL) methods and to evaluate the effect of preparation method, interaction type and silica content on the physico‐chemical and thermal properties of polyurethane/silica (PU/Silica) hybrid coatings.

Silica particle‐containing silica sol was prepared according to Stöber method using tetraethylorthosilicate as the precursor and then introduced into polyester matrix by in situ and direct blending method. The modified polyester/silica resin was further crosslinked with TMP‐TDI adduct to synthesise PU/Silica hybrid coatings and studied for thermo‐mechanical, physico‐chemical properties.

It was found IS polymerisation caused more polyester segments to chemically bond onto the surface of silica particles than BL process. Results also reveal that due to stronger interaction between silica particles and PU matrix, hybrid resins prepared by IS method confers better properties than BL method and exhibit optimal properties at the critical concentration of 8 wt% silica.

In the present study, silica particles are used to modify properties of polyurethane resins. Many other countless combinations in terms of inorganic filler or organic matrices can be explored to obtain a wide range of interesting properties and applications.

The results obtained in this study will be extremely useful to enhance the understanding of this class of hybrid materials.

Hybrid organic‐inorganic networks offer a new area of material science that has extraordinary implications for developing novel materials that exhibit a diverse range of multi‐functional properties.