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1 – 10 of 175Xing Juan Chen, Cheng Luo, Zheng Han Zhang and Min Zhao
The purpose of this investigation was to synthesize a doped polyaniline‐containing coating and investigate the anti‐corrosion properties of the coating on Mg‐Li alloy.
Abstract
Purpose
The purpose of this investigation was to synthesize a doped polyaniline‐containing coating and investigate the anti‐corrosion properties of the coating on Mg‐Li alloy.
Design/methodology/approach
The doped polyaniline pigments were prepared by two different methods using ammonium persulphate as oxidant and hydrochloric acid, phosphoric acid, p‐toluene sulfonic acid and sulfosalicylic acid as doping agents. The doped polyaniline was characterized by Fourier transform infrared (FT‐IR) analysis, X‐ray diffraction (XRD) and scanning electron microscopy (SEM). The coatings consisted of polyaniline, epoxy resin and other additives that were formed on Mg‐Li alloy. The anti‐corrosion properties of the polyaniline‐containing coating on the Mg‐Li alloy were investigated in 3.5 wt.% NaCl solution using open circuit potential logging and electrochemical impedance spectroscopy.
Findings
The results of the electrochemical tests indicated that the polyaniline‐containing coatings showed better anti‐corrosion properties, as compared to conventional epoxy coatings on Mg‐Li alloy when exposed in 3.5 wt.% NaCl solution. The coating containing 2 wt.% polyaniline (relative to the mass of epoxy resin) doped with hydrochloric acid had the best anti‐corrosion properties on the Mg‐Li alloy.
Originality/value
Previous reports on the anti‐corrosion properties of polyaniline‐containing coatings focused mainly on the surface of iron, steel, aluminum and magnesium, and there have been few studies on the anti‐corrosion properties as protective coatings for Mg‐Li alloy.
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Belkis Ustamehmetoğlu, Ahmet Akar, Nilgun Kizilcan and Eda Kelleboz
The purpose of this paper is to develop the soluble and processable conducting copolymers of carbazole (Cz), ethylcarbazole (ECz), N‐vinylcarbazole (NVCz) by oxidatively…
Abstract
Purpose
The purpose of this paper is to develop the soluble and processable conducting copolymers of carbazole (Cz), ethylcarbazole (ECz), N‐vinylcarbazole (NVCz) by oxidatively polymerising carbazoles by ceric ammonium nitrate (CAN) in the presence of methyl ethyl ketone formaldehyde resin (MEKF‐R); and to report the advantages of obtaining copolymer structure.
Design/methodology/approach
A new class of soluble and conductive P(Cz/MEKF‐R), P(NVCz/MEKF‐R) and P(ECz/MEKF‐R) copolymers were synthesised by the method of oxidative polymerisation with ceric ammonium nitrate. MEKF‐R, CAN and carbazole monomers (Cz, NVCz and ECz) were dissolved in acetonitrile separately. Then, the CAN solution was added dropwise into the mixture of MEKF‐R and Cz, NVCz or ECz solutions while stirring and a green powder was formed almost instantaneously. After one hour stirring at 25°C, the powder was filtered, washed with acetonitrile and dried at room temperature. A green coloured product was obtained. The colourless insulator copolymer present in this product was separated by selectively dissolving with toluene. The insoluble green copolymer was filtered off and dried at room temperature under vacuum. The products were characterised by FTIR, DSC thermograms, 1H‐NMR, four‐point probe conductivity and atomic absorption measurements.
Findings
The solubility and conductivity of the Cz/MEKF‐R copolymer P(Cz/MEKF‐R), the NVCz/MEKF‐R copolymer P(NVCz/MEKF‐R) and the ECz/MEKF‐R copolymer P(ECz/MEKF‐R) were regulated by the ratios of (Cz, NVCz, ECz)/CAN/MEKF‐R. By inclusion of the ketonic resin segments to the polycarbazole chains, thermally processable copolymers have been obtained with a melting point of about 80°C. FT‐IR results in different reaction time and the presence of metal in copolymers show together a complex between monomer‐metal and resin.
Research limitations/implications
This study focuses on obtaining conductive, soluble and processable copolymers. Since the ketonic resin is an insulator, in order to obtain both conductive and totally soluble polymer, successively regulating the ratios of (Cz, NVCz, ECz)/CAN/MEKF‐R is necessary.
Practical implications
This work provides technical information for the synthesis of conducting and totally soluble copolymer.
Originality/value
The conductive P(Cz/MEKF‐R), P(NVCz/MEKF‐R) and P(ECz/MEKF‐R) copolymers obtained by the method of oxidative polymerisation with ceric ammonium nitrate, which are totally soluble in DMF, could only be produced with this method and may increase the area of application of the carbazole polymers.
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S. Abhijit, Prakash A. Mahanwar and V.A. Bambole
The aim of this paper is to conduct a real time evaluation of polypyrrole as an anti‐corrosive pigment in epoxy polyamide coating.
Abstract
Purpose
The aim of this paper is to conduct a real time evaluation of polypyrrole as an anti‐corrosive pigment in epoxy polyamide coating.
Design/methodology/approach
This study deals with synthesis of polypyrrole (PPy) by chemical oxidative polymerisation in laboratory conditions. The synthesised PPy was characterised by employing FT‐IR, XRD, SEM and EDX analysis. Epoxy film of bisphenol type hardened with polyamide based curing agent was used as the binder. PPy was used as anti‐corrosive pigment in concentrations varying from 0 to 5 wt% in the coating. In addition to anti‐corrosive property, mechanical, chemical and weathering properties of the coating containing PPy were studied and compared with epoxy polyamide coating without PPy.
Findings
The result obtained through various tests showed that the coating with 1 and 2% PPy exhibited excellent weathering resistance, mechanical properties and improved chemical resistance.
Research limitations/implications
The anti‐corrosion property of the coating can be tested by means of atmospheric exposure such as Florida test or by means of electrochemical impedance spectroscopy.
Practical implications
The results find application in anti‐corrosive paints for industrial application.
Originality/value
This research paper presents the results of anti‐corrosion behaviour of PPy in epoxy‐polyamide coating. Based on this result, a highly effective anti‐corrosive coating can be formulated by addition of small percentage of PPy in combination with other conventional pigments, thereby enhancing corrosion protection.
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Prakash Mahanwar, Abhijit Sathyanarayana, Vaishali Bambole and Sunil Sabharwal
– The paper aims to discuss the evaluation of anti-corrosive efficiency of conducting polymer, polypyrrole in water borne epoxy-polyamine coatings.
Abstract
Purpose
The paper aims to discuss the evaluation of anti-corrosive efficiency of conducting polymer, polypyrrole in water borne epoxy-polyamine coatings.
Design/methodology/approach
Polypyrrole (PPy) is synthesised by chemical oxidative polymerisation. The synthesised PPy is characterised by employing FT-IR, XRD, SEM and EDX analysis. The coatings are formulated using water borne epoxy cross-linked with aliphatic polyamine adduct and the effect of PPy on corrosion prevention is studied. PPy was used as anti-corrosive pigment in concentration varying from 1 to 5 wt.%. In addition to anti-corrosive property; mechanical properties, chemical resistance and weathering properties of the coatings containing PPy are studied, thereby obtaining a wholesome data about the quality and performance of these coatings.
Findings
The result obtained through various tests showed that the coating with 1 and 2% PPy exhibited excellent weathering resistance, mechanical properties and improved chemical resistance. Higher percentage loading of PPy (beyond 3 per cent) proves to be disastrous, as extended percolation networks are formed which results in rapid intense corrosion leading to fast coating breakdown.
Research limitations/implications
The anti-corrosion property of the coating can be tested by means of atmospheric exposure such as Florida test which produces a real time evaluation of the anti-corrosive nature of the coating at natural condition rather than accelerated weathering, thereby providing more reliable performance data for intended application purpose.
Practical implications
The results find application in anti-corrosive/performance paints for industrial application.
Originality/value
This research paper presents the results of anti-corrosion behaviour of PPy in water borne epoxy-polyamide coating. Based on this result, a highly effective anti-corrosive coating can be formulated by the addition of small percentage of PPy in combination with other conventional pigments, thereby enhancing corrosion protection. But care must be taken so as to avoid formation of extended percolation network of PPy which leads to rapid coating breakdown.
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Examines the fourteenth published year of the ITCRR. Runs the whole gamut of textile innovation, research and testing, some of which investigates hitherto untouched aspects…
Abstract
Examines the fourteenth published year of the ITCRR. Runs the whole gamut of textile innovation, research and testing, some of which investigates hitherto untouched aspects. Subjects discussed include cotton fabric processing, asbestos substitutes, textile adjuncts to cardiovascular surgery, wet textile processes, hand evaluation, nanotechnology, thermoplastic composites, robotic ironing, protective clothing (agricultural and industrial), ecological aspects of fibre properties – to name but a few! There would appear to be no limit to the future potential for textile applications.
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N. Köken, M.E. Çamoglu and E.A. Güvel
This paper aims to synthesise block copolymers (PPy-b-ENP) of pyrrole (Py) and ethoxylated nonyl phenols (ENP) via redox systems in presence of ceric ammonium nitrate (CAN) at…
Abstract
Purpose
This paper aims to synthesise block copolymers (PPy-b-ENP) of pyrrole (Py) and ethoxylated nonyl phenols (ENP) via redox systems in presence of ceric ammonium nitrate (CAN) at room temperature. The initiating radical was formed on reducing organic compound which in turn initiated polymerisation to give diblock copolymers containing chain ends of ENPs and polypyrrole (Ppy). The effects of the concentration of Ce+4 salt, ENPs and Py on both the yield and electrical conductivities of corresponding polymers were studied.
Design/methodology/approach
In total, 0.1 M stock solution of CAN:100 ml 1 M HNO3 was prepared freshly (7 ml HNO3 dissolved in 100 ml water) and used in 50 ml of 0.1 M CAN solution (2.7438 g CAN dissolved in 50 ml nitric acid solution). The reducing compound (Py) was dissolved in water. Py and ENP were added slowly to the flask with vigorous stirring. The content of the flask was flushed with oxygen-free nitrogen. The resulting copolymers were characterised with spectroscopic methods like Fourier transform infrared spectroscopy and scanning electron microscope.
Findings
In this study, DMSO-slightly soluble Py copolymers were produced with ENPs. The conductivities of copolymers were found to be in the range of 10-1 to 10-4 S/cm. Soluble and processable conductive polymers were developed.
Research limitations/implications
In this study, the water solubility of ENPs diminishes the conductivity of copolymer because of its surfactant structure. When the CAN/Py ratio was increased, PPys and copolymers with both higher yield and lower conductivity values were obtained. The results indicated that solubilities and the yield of the polymers synthesised in the presence of ENP have increased considerably. ENP caused degradative chain transfer reaction to become significant compared with bimolecular termination, so the yield decreased with increasing ENP concentration about 20 g/l. Results showed that yield of the copolymers strongly depends on Ce+4 concentrations while of copolymers were measured to be 10-3 S/cm.
Practical implications
PPy-b-ENP diblock copolymers were prepared with Ce+4 as an oxidation agent in a single step.
Social implications
These slightly soluble and conductive copolymers may overcome difficulties in the applications of PPy homopolymers and open new application areas.
Originality/value
PPy-b-ENPs of lightly soluble (in DMSO) and conductive (10-2 S/cm) copolymers have been synthesised in one step. The results indicate that the surface of the copolymer is composed of well-distributed nanospheres with an average particle diameter of 35-400 nm.
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Examines the fifthteenth published year of the ITCRR. Runs the whole gamut of textile innovation, research and testing, some of which investigates hitherto untouched aspects…
Abstract
Examines the fifthteenth published year of the ITCRR. Runs the whole gamut of textile innovation, research and testing, some of which investigates hitherto untouched aspects. Subjects discussed include cotton fabric processing, asbestos substitutes, textile adjuncts to cardiovascular surgery, wet textile processes, hand evaluation, nanotechnology, thermoplastic composites, robotic ironing, protective clothing (agricultural and industrial), ecological aspects of fibre properties – to name but a few! There would appear to be no limit to the future potential for textile applications.
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Abstract
Purpose
The aim of the paper is to develop a method of synthesising polyaniline (PANI) with excellent electrical conductivity.
Design/methodology/approach
The preparation of PANI was carried out by vibration of emulsifier (SDBS), oxidant (APS) and hydrochloric acid (HCl) solution concentration. The changes of temperature and time of reaction had also been observed and researched.
Findings
Changing of reaction conditions was found to have a great influence on polyaniline's conductivity. The optimum condition for preparing polyaniline salt is as follows: the molar ratio of n(An)/n(SDBS)/n(APS) is 10/10/9, the concentration of HCl is 0.9 M, stirred constantly at 0°C for a period of 3 h. By using this emulsion polymerisation pathway the maximum of conductivity of polyaniline is 4.35 s/cm.
Practical implications
The method can be widely applicable to coatings, preparation of exfoliated clay composites and solution blending with other commodity polymers.
Originality/value
The method could be adapted for use on an industrial scale.
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The purpose of this paper is to synthesise polyaniline‐SiO2 (PANI‐SiO2) composites and investigate the anticorrosion properties of polyaniline‐SiO2‐containing coating on Mg‐Li…
Abstract
Purpose
The purpose of this paper is to synthesise polyaniline‐SiO2 (PANI‐SiO2) composites and investigate the anticorrosion properties of polyaniline‐SiO2‐containing coating on Mg‐Li alloy.
Design/methodology/approach
The PANI‐SiO2 composites were prepared by in situ chemical oxidative polymerisation in phosphoric acid medium. The PANI‐SiO2 composites were characterised by Fourier transform infrared, X‐ray diffraction and scanning electron microscopy techniques. The coating consisted of PANI‐SiO2 composites and epoxy resin was formed on Mg‐Li alloy. The anticorrosion properties were investigated by open circuit potentials (OCP), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarisation curves.
Findings
The results indicated that the PANI‐SiO2‐containing coating on Mg‐Li alloy demonstrated good anticorrosion properties in 3.0 wt% NaCl solution. It has been found that the OCP of PANI‐SiO2‐containing coating were able to maintain more noble potential values in comparison to pure epoxy coatings in 3.0 wt% NaCl solution. EIS analysis indicated that the resistance of PANI‐SiO2‐containing coating was more than 106 Ω cm2 in 3.0 wt% NaCl solution in immersion process. Furthermore, the corrosion current of PANI‐SiO2‐containing coating on Mg‐Li alloy showed a significant reduction.
Originality/value
Previous reports on PANI‐SiO2 composites were mostly focused on their conductivity and optical properties and there are few studies so far on their anticorrosion properties as protective coatings for Mg‐Li alloy.
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R. Rajkumar and C. Vedhi
Polypyrrole (PPy) and PPy/metal oxide nanocomposites were synthesized by oxidative polymerization process, and its corrosion protection ability was studied by immersion test and…
Abstract
Purpose
Polypyrrole (PPy) and PPy/metal oxide nanocomposites were synthesized by oxidative polymerization process, and its corrosion protection ability was studied by immersion test and electrochemical corrosion studies in 1 per cent HCl and 3.5 per cent NaCl solution.
Design/methodology/approach
The prepared composites were loaded in acrylic resin and subsequently coated on a mild steel surface. The characterization of the polymer composites using FT-IR, UV-vis, XRD and FE-SEM with EDS analysis confirmed the interaction between PPy and metal oxide nanoparticles. The PPy nanoparticles were less protected on the mild steel, but the nanocomposite coating with metal oxide nanoparticles dramatically increased the corrosion resistance.
Findings
According to the corrosion protection ability of the coating, it was demonstrated that the acrylic resin coating composed of PPy/metal oxide nanocomposites was highly efficient in protecting the mild steel compared to the PPy nanoparticles. The highest protection efficiency was obtained by PPy/TiO2 nanocomposites with acrylic resin coating.
Originality/value
To the best of the authors’ knowledge, this paper consists of original, unpublished work which is not under consideration for publication elsewhere and that all the co-authors have approved the contents of this manuscript and submission.
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