Search results

1 – 10 of 90
Article
Publication date: 29 August 2023

Chigoziri N. Njoku, Temple Uzoma Maduoma, Wilfred Emori, Rita Emmanuel Odey, Beshel M. Unimke, Emmanuel Yakubu, Cyril C. Anorondu, Daniel I. Udunwa, Onyinyechi C. Njoku and Kechinyere B. Oyoh

Corrosion is a major concern for many industries that use metals as structural or functional materials, and the use of corrosion inhibitors is a widely accepted strategy to…

Abstract

Purpose

Corrosion is a major concern for many industries that use metals as structural or functional materials, and the use of corrosion inhibitors is a widely accepted strategy to protect metals from deterioration in corrosive environments. Moreover, the toxic nature, non-biodegradability and price of most conventional corrosion inhibitors have encouraged the application of greener and more sustainable options, with natural and synthetic drugs being major actors. Hence, this paper aims to stress the capability of natural and synthetic drugs as manageable and sustainable, environmentally friendly solutions to the problem of metal corrosion.

Design/methodology/approach

In this review, the recent developments in the use of natural and synthetic drugs as corrosion inhibitors are explored in detail to highlight the key advancements and drawbacks towards the advantageous utilization of drugs as corrosion inhibitors.

Findings

Corrosion is a critical issue in numerous modern applications, and conventional strategies of corrosion inhibition include the use of toxic and environmentally harmful chemicals. As greener alternatives, natural compounds like plant extracts, essential oils and biopolymers, as well as synthetic drugs, are highlighted in this review. In addition, the advantages and disadvantages of these compounds, as well as their effectiveness in preventing corrosion, are discussed in the review.

Originality/value

This survey stresses on the most recent abilities of natural and synthetic drugs as viable and sustainable, environmentally friendly solutions to the problem of metal corrosion, thus expanding the general knowledge of green corrosion inhibitors.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 17 April 2023

Kawaljit Singh Randhawa

The purpose of this study is to prepare a state-of-the-art review on advanced ceramic materials including their fabrication techniques, characteristics, applications and…

Abstract

Purpose

The purpose of this study is to prepare a state-of-the-art review on advanced ceramic materials including their fabrication techniques, characteristics, applications and wettability.

Design/methodology/approach

This review paper presents the various types of advanced ceramic materials according to their compounding elements, fabrication techniques of advanced ceramic powders as well as their consolidation, their characteristics, applications and wetting properties. Hydrophobic/hydrophilic properties of advanced ceramic materials are described in the paper with their state-of-the-art application areas. Optical properties of fine ceramics with their intrinsic characteristics are also presented within. Special focus is given to the brief description of application-based manipulation of wetting properties of advanced ceramics in the paper.

Findings

The study of wetting/hydrophobicity/hydrophilicity of ceramic materials is important by which it can be further modified to achieve the required applications. It also makes some sense that the material should be tested for its wetting properties when it is going to be used in some important applications like biomedical and dental. Also, these advanced ceramics are now often used in the fabrication of filters and membranes to purify liquid/water so the study of wetting characteristics of these materials becomes essential. The optical properties of advanced ceramics are equally making them suitable for many state-of-the-art applications. Dental, medical, imaging and electronics are the few sectors that use advanced ceramics for their optical properties.

Originality/value

This review paper includes various advanced ceramic materials according to their compounding elements, different fabrication techniques of powders and their consolidation, their characteristics, various application area and hydrophobic/hydrophilic properties.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 26 August 2022

Satanu Ghosh and Kun Lu

The purpose of this paper is to present a preliminary work on extracting band gap information of materials from academic papers. With increasing demand for renewable energy, band…

Abstract

Purpose

The purpose of this paper is to present a preliminary work on extracting band gap information of materials from academic papers. With increasing demand for renewable energy, band gap information will help material scientists design and implement novel photovoltaic (PV) cells.

Design/methodology/approach

The authors collected 1.44 million titles and abstracts of scholarly articles related to materials science, and then filtered the collection to 11,939 articles that potentially contain relevant information about materials and their band gap values. ChemDataExtractor was extended to extract information about PV materials and their band gap information. Evaluation was performed on randomly sampled information records of 415 papers.

Findings

The findings of this study show that the current system is able to correctly extract information for 51.32% articles, with partially correct extraction for 36.62% articles and incorrect for 12.04%. The authors have also identified the errors belonging to three main categories pertaining to chemical entity identification, band gap information and interdependency resolution. Future work will focus on addressing these errors to improve the performance of the system.

Originality/value

The authors did not find any literature to date on band gap information extraction from academic text using automated methods. This work is unique and original. Band gap information is of importance to materials scientists in applications such as solar cells, light emitting diodes and laser diodes.

Details

Aslib Journal of Information Management, vol. 75 no. 3
Type: Research Article
ISSN: 2050-3806

Keywords

Article
Publication date: 3 November 2021

Onukwuli O.D. and Ernest Mbamalu Ezeh

This paper aims to examine the fire retardant property potentials of cow horn ash particles (CHAp) bio-additive and aluminium trihydrate (AH), a traditional inorganic…

37

Abstract

Purpose

This paper aims to examine the fire retardant property potentials of cow horn ash particles (CHAp) bio-additive and aluminium trihydrate (AH), a traditional inorganic fire-retardant additive, respectively, in banana peduncle fibre (BPF) reinforced polyester composites. An attempt was made to comparatively analyse the fire retardant capacity potentials of CHAp, a bio-material waste that is readily available, at no cost, as a potential fire retardant material for composites manufacture with a conventional inorganic fire retardant additive (AH).

Design/methodology/approach

The fibre used in this research was derived from the banana peduncle. The matrix is unsaturated polyester. A scanning electron microscope was used to analyze the particle size of the carbonized CHAp. The composites were compounded using 0%, 2.5%, 5%, 7.5% and 10% of CHAp and AH, respectively. A cone calorimeter instrument was used in the analysis to obtain combustion information of CHAp and AH formulated polyester-BPF composites. Test samples were cut to the dimensions of 100 × 100 mm. All materials are conditioned at 23 ± 30 °C and the relative humidity of 50 ± 5% for 24 h before testing. The samples were wrapped with aluminium foil around the back and edges before placing the samples on the holder and then into the cone calorimeter. The samples were backed with a non-combustible insulating refractory material (brick). The samples were orientated horizontally and exposed to irradiances of 50 kW/m2 at a temperature of approximately 6000 °C. The samples were pilot ignited and ran in triplicate; the average readings of the three runs were taken.

Findings

The results obtained from the analysis depicted similar fire retardant properties for formulations with CHAp and AH, respectively. Composites formulated with CHAp exhibited delayed ignition time of 25%, increased end of burning time of 14.24% and reduced total heat release rate of 9.07% for the developed composites. The developed BPF/CHAp/polyester composites yield composites with fire retardancy, which would find relevance in the engineering material industry.

Originality/value

CHAp, therefore, would suffice as an alternative to the inorganic, expensive and non-environmental friendly, conventional fire retardant additives used in composites manufacture.

Details

World Journal of Engineering, vol. 20 no. 3
Type: Research Article
ISSN: 1708-5284

Keywords

Article
Publication date: 30 September 2022

Amirul Syafiq, Vengadaesvaran Balakrishnan and Nasrudin Abd. Rahim

This paper aims to design the nano-titanium dioxide (TiO2) coating system which has superhydrophilic property, self-cleaning mechanism and antifog property as well as strong…

Abstract

Purpose

This paper aims to design the nano-titanium dioxide (TiO2) coating system which has superhydrophilic property, self-cleaning mechanism and antifog property as well as strong adhesion on glass substrate.

Design/methodology/approach

Two hydrophilic materials have been used such as TiO2 nanoparticles as fillers and hydrophilic copolymer, Pluronic F-127 by using simple sol–gel approach. The prepared solution was applied onto glass through dip- and spray-coating techniques and then left for drying at ambient temperature.

Findings

The nano-TiO2 superhydrophilic coating has achieved the water contact angle of 4.9° ± 0.5°. The superhydrophilic coating showed great self-cleaning effect against concentrated syrup and methylene blue where thin layer of water washes the dirt contaminants away. The nano-TiO2 coating exhibits great antifog performance that maintains high transparency of around 89% when the coated glass is placed above hot-fog vapor for 10 min. The fog droplets were condensed into water film which allowed the transmission of light through the glass. The strong adhesion of coated glass shows no total failure at scratch profile when impacted with scratch load of 500, 800 and 1,200 mN.

Research limitations/implications

Findings will be useful in the development of self-cleaning superhydrophilic coating that is applicable on building glass and photovoltaic panel.

Practical implications

The developed nano-TiO2 coating is developed by the combination of hydrophilic organic copolymer–inorganic TiO2 network to achieve great superhydrophilic property, optimum self-cleaning ability and supreme antifog performance.

Social implications

The findings will be useful for residents in building glass window where the application will reduce dust accumulation and keep the glass clean for longer period.

Originality/value

The synthesis of nano-TiO2 superhydrophilic coating which can be sprayed on large glass panel and cured at ambient temperature.

Article
Publication date: 1 March 2024

Asif Ur Rehman, Pedro Navarrete-Segado, Metin U. Salamci, Christine Frances, Mallorie Tourbin and David Grossin

The consolidation process and morphology evolution in ceramics-based additive manufacturing (AM) are still not well-understood. As a way to better understand the ceramic selective…

Abstract

Purpose

The consolidation process and morphology evolution in ceramics-based additive manufacturing (AM) are still not well-understood. As a way to better understand the ceramic selective laser sintering (SLS), a dynamic three-dimensional computational model was developed to forecast thermal behavior of hydroxyapatite (HA) bioceramic.

Design/methodology/approach

AM has revolutionized automotive, biomedical and aerospace industries, among many others. AM provides design and geometric freedom, rapid product customization and manufacturing flexibility through its layer-by-layer technique. However, a very limited number of materials are printable because of rapid melting and solidification hysteresis. Melting-solidification dynamics in powder bed fusion are usually correlated with welding, often ignoring the intrinsic properties of the laser irradiation; unsurprisingly, the printable materials are mostly the well-known weldable materials.

Findings

The consolidation mechanism of HA was identified during its processing in a ceramic SLS device, then the effect of the laser energy density was studied to see how it affects the processing window. Premature sintering and sintering regimes were revealed and elaborated in detail. The full consolidation beyond sintering was also revealed along with its interaction to baseplate.

Originality/value

These findings provide important insight into the consolidation mechanism of HA ceramics, which will be the cornerstone for extending the range of materials in laser powder bed fusion of ceramics.

Details

Rapid Prototyping Journal, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1355-2546

Keywords

Article
Publication date: 20 December 2023

Halime Morovati, Mohammad Reza Noorbala, Mansoor Namazian, Hamid R. Zare and Ahmad Ali Dehghani-Firouzabadi

The main purpose of the present work is to introduce two new Schiff bases as corrosion inhibitors (CIs) for carbon steel (CS). The anti-corrosion performance of these Schiff bases…

Abstract

Purpose

The main purpose of the present work is to introduce two new Schiff bases as corrosion inhibitors (CIs) for carbon steel (CS). The anti-corrosion performance of these Schiff bases having N and S heteroatoms in their structures was investigated and compared in 2 M HCl electrolyte. The inhibitory activity of these Schiff bases was also assessed.

Design/methodology/approach

Common electrochemical assays like potentiodynamic polarization and electrochemical impedance measurements were used to evaluate the ability of compounds in reduction of the rate of corrosion. Quantum chemical calculations (QCCs) were also used to examine the corrosion inhibitive and the process related to the electrical and structural characteristics of the molecules acting as CIs.

Findings

The electrochemical measurements indicate that both Schiff bases acted as the efficient CIs of CS in 2 M HCl electrolyte. The adsorption of the Schiff base on the surface of the CS caused the corrosion to be inhibited. The change of Gibbs energies indicated that both physical and chemical interactions are involved in the adsorption of NNS and SNS on CS surfaces. The predicted QCCs of the CIs neutral and positively charged versions were well-aligned with those obtained by electrochemical experiments.

Originality/value

Using electrochemical experiments and quantum chemical modelings, two new Schiff bases, N-2-((2-nitrophenyl)thio)phenyl)-1-(pyrrole-2-yl)methanimine (NNS) and N-2-((2-nitrophenyl)thio)phenyl)-1-(thiophen-2-yl)methanimine (SNS), were evaluated as anti-corrosion agents for CS in 2 M HCl electrolyte. The DFT calculations were considered to compute the quantum chemical parameters of the inhibitors.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 1
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 9 May 2023

Dheeraj Choppara, Alysia Garmulewicz and Joshua M. Pearce

This study aims to apply an open-source approach to protect the 3D printing industry from innovation stagnation due to broad patenting of obvious materials.

Abstract

Purpose

This study aims to apply an open-source approach to protect the 3D printing industry from innovation stagnation due to broad patenting of obvious materials.

Design/methodology/approach

To do this, first an open-source implementation of the first five conditions of an open-source algorithm developed to identify all obvious 3-D printing materials was implemented in Python, and the compound combinations of two and three constituents were tested on ten natural and synthetic compounds. The time complexity for combinations composed of two constituents and three constituents is determined to be O(n2) and O(n3), respectively.

Findings

Generating all combinations of materials available on the Chemical Abstracts Services (CAS) registry on the fastest processor on the market will require at least 73.9 h for the latter, but as the number of constituents increases the time needed becomes prohibitive (e.g. 3 constituents is 1.65 million years). To demonstrate how machine learning (ML) could help prioritize both theoretical as well as experimental efforts a three-part biomaterial consisting of water, agar and glycerin was used as a case study. A decision tree model is trained with the experimental data and is used to fill in missing physical properties, including Young's modulus and yield strength, with 84.9 and 85.1% accuracy, respectively.

Originality/value

The results are promising for an open-source system that can theoretically generate all possible combinations of materials for 3-D printing that can then be used to identify suitable printing material for specific business cases based on desired material properties.

Details

Journal of Manufacturing Technology Management, vol. 34 no. 6
Type: Research Article
ISSN: 1741-038X

Keywords

Article
Publication date: 28 February 2023

Goksel Saracoglu, Ferhat Ceritbinmez, Vildan Özkan and Ahmet Yapici

This study aims to systematically compare the effect of increasing fiber–matrix interface adhesion and matrix toughness in layered composite materials.

Abstract

Purpose

This study aims to systematically compare the effect of increasing fiber–matrix interface adhesion and matrix toughness in layered composite materials.

Design/methodology/approach

Silane ((3-glycidyloxypropyl) trimethoxysilane) was applied to strengthen the fiber–matrix interface connection in e-glass/epoxy laminated composite material. Using a cationic surfactant, 0.1% multi-walled carbon nanotubes (CNTs) were added to the matrix in two different ways, by with and without chemical functionalization using the vacuum infusion method.

Findings

In the results obtained from the three-point bending test specimens, it was determined that the synergistic effect of silane application and non-functionalized CNT in the matrix was higher in terms of flexural modulus and strength values.

Practical implications

The functionalization of multi-walled CNT did not give the expected results because of reasons such as viscosity increase and agglomeration in the matrix.

Originality/value

In this study, a simple model for normalization and prediction purposes was developed, which allows the determination of the flexural modulus and un-notched flexural strength values from one test result of the notched specimen. A systematic comparison was performed by varying each parameter in the composite material.

Details

Aircraft Engineering and Aerospace Technology, vol. 95 no. 7
Type: Research Article
ISSN: 1748-8842

Keywords

Book part
Publication date: 14 December 2023

Nausheen Bibi Jaffur, Pratima Jeetah and Gopalakrishnan Kumar

The increasing accumulation of synthetic plastic waste in oceans and landfills, along with the depletion of non-renewable fossil-based resources, has sparked environmental…

Abstract

The increasing accumulation of synthetic plastic waste in oceans and landfills, along with the depletion of non-renewable fossil-based resources, has sparked environmental concerns and prompted the search for environmentally friendly alternatives. Biodegradable plastics derived from lignocellulosic materials are emerging as substitutes for synthetic plastics, offering significant potential to reduce landfill stress and minimise environmental impacts. This study highlights a sustainable and cost-effective solution by utilising agricultural residues and invasive plant materials as carbon substrates for the production of biopolymers, particularly polyhydroxybutyrate (PHB), through microbiological processes. Locally sourced residual materials were preferred to reduce transportation costs and ensure accessibility. The selection of suitable residue streams was based on various criteria, including strength properties, cellulose content, low ash and lignin content, affordability, non-toxicity, biocompatibility, shelf-life, mechanical and physical properties, short maturation period, antibacterial properties and compatibility with global food security. Life cycle assessments confirm that PHB dramatically lowers CO2 emissions compared to traditional plastics, while the growing use of lignocellulosic biomass in biopolymeric applications offers renewable and readily available resources. Governments worldwide are increasingly inclined to develop comprehensive bioeconomy policies and specialised bioplastics initiatives, driven by customer acceptability and the rising demand for environmentally friendly solutions. The implications of climate change, price volatility in fossil materials, and the imperative to reduce dependence on fossil resources further contribute to the desirability of biopolymers. The study involves fermentation, turbidity measurements, extraction and purification of PHB, and the manufacturing and testing of composite biopolymers using various physical, mechanical and chemical tests.

Details

Innovation, Social Responsibility and Sustainability
Type: Book
ISBN: 978-1-83797-462-7

Keywords

1 – 10 of 90