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This paper aims to study a new halogen-free fame-retardant curing agent 1-aminoethylidenediphosphonate (AAEDP).

The AAEDP was synthesized by phosphoric acid, acetonitrile and ammonia. The chemical structures of AAEDP were characterized by proton nuclear magnetic resonance, mass spectrometry and Fourier transform infrared spectrometer. Thermal gravimetric analysis (TGA) and scanning electron microscope (SEM) would study the thermal properties and the char residues of AAEDP/EP. The thermal stability, mechanical and flame properties and morphology for the char layer of composite materials were separately investigated using TGA, tensile and charpy impact tests, limiting oxygen index (LOI), UL-94 HB flammability standard (UL-94) and SEM.

The results showed that the AAEDP had been prepared successfully. When the intumescent flame retardant was added into the EP, the LOI of composite material was improved.

The AAEDP can be prepared successfully and can improve the flame resistance of composite material.

The AAEDP has excellent flame-retardant properties and produce no toxic fumes when burnt in case of fire.

The results showed that the phosphorus content of AAEDP was 2.958 Wt.%; the impact and tensile strength of the composite material were 6.417 kJ m⁻² and 38.0 MPa, respectively; and the LOI and UL-94 were 29.7% and V-0 ranking, respectively. The TGA results indicated that the carbon residue ratio can be increased by 1000°C in air. The denser and more uniform structure of residual carbon prevents heat transfer and diffusion, restricts the production of combustible gas and reduces the rate of heat release.

In fire condition, the time to failure of a timber connection is mainly reliant on the wood charring rate, the strength of the residual wood section, and the limiting temperature of the steel connectors involved in the connection. The purpose of this study is to experimentally investigate the effects of loaded bolt end distance, number of bolt rows, and the existence of perpendicular-to-wood grain reinforcement on the structural fire behavior of semi-rigid glued-laminated timber (glulam) beam-to-column connections that used steel bolts and concealed steel plate connectors.

In total, 16 beam-to-column connections, which were fabricated in wood-steel-wood bolted connection configurations, in eight large-scale sub-frame test assemblies were exposed to elevated temperatures that followed CAN/ULC-S101 standard time-temperature curve, while being subjected to monotonic loading. The beam-to-column connections of four of the eight test assemblies were reinforced perpendicular to the wood grain using self-tapping screws (STS). Fire tests were terminated upon achieving the failure criterion, which predominantly was dependent on the connection’s maximum allowed rotation.

Experimental results revealed that increasing the number of bolt rows from two to three, each of two bolts, increased the connection’s time to failure by a greater time increment than that achieved by increasing the bolt end distance from four- to five-times the bolt diameter. Also, the use of STS reinforcement increased the connection’s time to failure by greater time increments than those achieved by increasing the number of bolt rows or the bolt end distance.

The invaluable experimental data obtained from this study can be effectively used to provide insight and better understanding on how mass-timber glulam bolted connections can behave in fire condition. This can also help in further improving the existing design guidelines for mass-timber structures. Currently, beam-to-column wood connections are designed mainly as axially loaded connections with no guidelines available for determining the fire resistance of timber connections exerting any degree of moment-resisting capability.

Intumescent coatings are nowadays a dominant passive system used to protect structural materials in case of fire. Due to their reactive swelling behaviour, intumescent coatings are particularly complex materials to be modelled and predicted, which can be extremely useful especially for performance-based fire safety designs. In addition, many parameters influence their performance, and this challenges the definition and quantification of their material properties. Several approaches and models of various complexities are proposed in the literature, and they are reviewed and analysed in a critical literature review.

Analytical, finite-difference and finite-element methods for modelling intumescent coatings are compared, followed by the definition and quantification of the main physical, thermal, and optical properties of intumescent coatings: swelled thickness, thermal conductivity and resistance, density, specific heat capacity, and emissivity/absorptivity.

The study highlights the scarce consideration of key influencing factors on the material properties, and the tendency to simplify the problem into effective thermo-physical properties, such as effective thermal conductivity. As a conclusion, the literature review underlines the lack of homogenisation of modelling approaches and material properties, as well as the need for a universal modelling method that can generally simulate the performance of intumescent coatings, combine the large amount of published experimental data, and reliably produce fire-safe performance-based designs.

Due to their limited applicability, high complexity and little comparability, the presented literature review does not focus on analysing and comparing different multi-component models, constituted of many model-specific input parameters. On the contrary, the presented literature review compares various approaches, models and thermo-physical properties which primarily focusses on solving the heat transfer problem through swelling intumescent systems.

The presented literature review analyses and discusses the various modelling approaches to describe and predict the behaviour of swelling intumescent coatings as fire protection for structural materials. Due to the vast variety of available commercial products and potential testing conditions, these data are rarely compared and combined to achieve an overall understanding on the response of intumescent coatings as fire protection measure. The study highlights the lack of information and homogenisation of various modelling approaches, and it underlines the research needs about several aspects related to the intumescent coating behaviour modelling, also providing some useful suggestions for future studies.

In this paper the aim is that Aramid/alginate blended nonwoven fabrics were prepared, and the flame retardancy of the blended nonwoven fabrics was studied by thermogravimetric analysis, vertical flame test, limiting oxygen index (LOI) and cone calorimeter test.

The advantages of different fibers can be combined by blending, and the defects may be remedied. The study investigates whether incorporating alginate fibers into aramid fibers can enhance the flame retardancy and reduce the smoke production of prepared aramid/alginate blended nonwoven fabrics.

Thermogravimetric analysis indicated that alginate fibers could effectively inhibit the combustion performance of aramid fibers at a higher temperature zone, leaving more residual chars for heat isolation. And vertical flame test, LOI and cone calorimeter test testified that the incorporation of alginate fibers improved the flame retardancy and fire behaviors. When the ratio of alginate fibers for aramid/alginate blended nonwoven fabrics reached 80%, the incorporation of alginate fibers could notably decreased peak-heat release rate (54%), total heat release (THR) (29%), peak-smoke production rate (93%) and total smoke production (86%). What is more, the lower smoke production rate and lower THR of the blends vastly reduced the risk of secondary injury in fires.

This study proposes to inhibit the flue gas release of aramid fiber and enhance the flame retardant by mixing with alginate fiber, and proposes that alginate fiber can be used as a biological smoke inhibitor, as well as a flame retardant for aramid fiber.

Nowadays people are connected by social media like Facebook, Instagram, Twitter, YouTube and much more. Bullies take advantage of these social networks to share their comments. Cyberbullying is one typical kind of harassment by making aggressive comments, abuses to hurt the netizens. Social media is one of the areas where bullying happens extensively. Hence, it is necessary to develop an efficient and autonomous cyberbullying detection technique.

In this paper, the authors proposed a transformer network-based word embeddings approach for cyberbullying detection. RoBERTa is used to generate word embeddings and Light Gradient Boosting Machine is used as a classifier.

The proposed approach outperforms machine learning algorithms such as logistic regression, support vector machine and deep learning models such as word-level convolutional neural networks (word CNN) and character convolutional neural networks with short cuts (char CNNS) in terms of precision, recall, F1-score.

One of the limitations of traditional word embeddings methods is context-independent. In this work, only text data are utilized to identify cyberbullying. This work can be extended to predict cyberbullying activities in multimedia environment like image, audio and video.

The purpose of this study is to reduce the application of petroleum in automobile paint industry by replacing it with bio-based castor oil along with nano fillers to synthesize automobile base coat (BC).

Bio-based polyurethane (PU) coating applicable in automobile BC was synthesized by using modified castor oil incorporated with nano silica (NS) and titanium-based pigment particles. The influential characteristics of the coating was studied by carrying out cross-cut tape test, abrasion resistance, pencil hardness, lap-shear, thermo gravimetric analysis, differential scanning calorimetry, dynamic mechanical analysis and acid, alkali and oil resistance tests.

Incorporation of NS particles, along with titanium-based pigment particles in optimized ratio into the paint matrix, increases the mechanical, chemical and oil resistance properties and hydrophobicity of the BC, and the findings are compared with the petro-based commercial BC.

There is no significant improvement in thermal properties of the paint matrix, and it is less thermally stable than the commercial BC.

The paint developed through this study provides a simple and practical solution to reduce the petro-based feed-stock in automobile paint industry.

The current work which reports the use of ecofriendly PU BC for automobile paint applications is novel and findings of this study are original.

This chapter investigates the cost of public debt for firms using a comprehensive sample consisting of 17,368 industrial bond issues from 1970 to 2011. The empirical evidence shows that yield spreads for seasoned bond issues are significantly lower than those for initial bond issues. This seasoning effect is robust across different sample periods, subsamples, and model specifications. On average, the yield spreads for seasoned bond issues are around 50 bps lower than those for initial bond issues. This difference cannot be explained by other bond and firm characteristics. The seasoning effect is more pronounced for firms with higher levels of uncertainty, lower information disclosure quality, and longer time intervals between the first and subsequent issues. Our empirical findings provide supportive evidence for the extant theories that aim to rationalize the information role in determining the cost of capital.

This chapter focuses on the intricacies of marginalized communities in Bangladesh. It provides an in-depth understanding of these communities, considering their sociocultural backgrounds and the challenges they face. This chapter introduces the empowerment paradigm, highlighting the importance of empowering marginalized groups as a catalyst for positive change. It further explores various strategies and initiatives designed to uplift these communities, emphasizing the pivotal role of family planning in this process. By examining the transformative impact of family planning on marginalized communities, this chapter underscores how it can lead to improved health, education, economic opportunities, gender equality, and overall community development in the Bangladeshi context.

This paper aims to reveal the interdisciplinarity of information science (IS) from the perspective of the evolution of theory application.

Select eight representative IS journals as data sources, extract the theories mentioned in the full texts of the research papers and then measure annual interdisciplinarity of IS by conducting theory co-occurrence network analysis, diversity measure and evolution analysis.

As a young and vibrant discipline, IS has been continuously absorbing and internalizing external theoretical knowledge and thus formed a high degree of interdisciplinarity. With the continuous application of some kernel theories, the interdisciplinarity of IS appears to be decreasing and gradually converging into a few neighboring disciplines. Influenced by big data and artificial intelligence, the research paradigm of IS is shifting from a theory centered one to a technology centered one.

This study helps to understand the evolution of the interdisciplinarity of IS in the past 21 years. The main limitation is that the data were collected from eight journals indexed by the Social Sciences Citation Index and a small amount of theories might have been omitted.

This study identifies the kernel theories in IS research, measures the interdisciplinarity of IS based on the evolution of the co-occurrence network of theory source disciplines and reveals the paradigm shift being happening in IS.

This paper aims to analyse COVID-19’s effects on job loss and job finding rate in Serbia, focusing on groups with already low employment before the pandemic, such as youth, women, low-educated and rural areas.

The authors exploit the panel structure of the Labour Force Survey (LFS) data for Serbia to analyse if the impact of the pandemic on transition probabilities was different for vulnerable groups and their counterparts during the first year of the pandemic.

The results indicate that stagnation in overall employment growth in Serbia during the first year of the COVID-19 crisis resulted from decreases in new hiring rather than increases in job losses. However, trends differed for vulnerable groups. Young workers faced the highest increase in job losses, partly due to their higher shares in informal wage employment. In contrast, decreases in job finding rates were particularly high among low-educated and in rural areas.

After the first year of the COVID-19 pandemic, employment opportunities of vulnerable groups further deteriorated, and already existing labour market inequalities were exacerbated. These effects are partially due to policies implemented to mitigate the crisis, which focused on preserving permanent employment while leaving vulnerable workers and groups unprotected.

The authors investigate the annual effects of the first year of the pandemic in a country with a large informal sector and explore the role of vulnerable groups’ job characteristics in transition changes.