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Article
Publication date: 2 June 2020

Quratulain Mohtashim, Muriel Rigout and Sheraz Hussain Siddique

Sulphur dyes are the most highly consumed colourants for cellulosic substrates owing to their reasonable cost and acceptable fastness. However, the use of noxious conventional…

Abstract

Purpose

Sulphur dyes are the most highly consumed colourants for cellulosic substrates owing to their reasonable cost and acceptable fastness. However, the use of noxious conventional reducing agent, sodium sulphide and impaired wash fastness against oxidative bleaching is gradually decreasing the market of these dyes. As the need for “Green” goods and services is raising public awareness, this paper aims to use a glucose-based biodegradable reducing agent in place of sodium sulphide to dye cotton fabrics with a range of commercial sulphur dyes. The study also proposes an aftertreatment method to improve the fastness properties of the dyeing.

Design/methodology/approach

The paper investigated the impact of a newly developed aftertreatment method on the fastness properties of dyeing. This involved the sequential application of a cationic fixing agent (Tinofix ECO) and tannin (Bayprotect CL) on the coloured fabrics and subsequent evaluation of colour strength, washing, light and rubbing fastness.

Findings

The effect of aftertreating the dyed cotton was found to significantly improve the light and wet rub fastness. The surface morphology of the dyeing remained unaffected as depicted by the absence of any finish residues.

Research limitations/implications

The protective effect of the cation–tannin aftertreatments was examined with a view to providing the necessary commercial performance; however, it was established that the dry rub fastness was either reduced or remained unaffected and the wash fastness to International Organization for Standardization 105 C09 was also marginal.

Originality/value

This finishing technique is novel and can be found useful for manufacturing sulphur-dyed products with the improved light and wet rub fastness.

Details

Pigment & Resin Technology, vol. 49 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 28 May 2021

Quratulain Mohtashim, Muriel Rigout and Sheraz Hussain Siddique Hussain Yousfani

Sulphur dyes provide an inexpensive medium to dye cellulosic fibres with heavy shade depths. They offer moderate to good fastness to light and wet treatments. However, owing to…

Abstract

Purpose

Sulphur dyes provide an inexpensive medium to dye cellulosic fibres with heavy shade depths. They offer moderate to good fastness to light and wet treatments. However, owing to the environmental hazard produced by the use of sodium sulphide, the practical implication of these dyes is steadily decreasing. Moreover, these dyes are prone to oxidation causing pronounced fading on exposure to laundering. This paper aims to present the green processing of sulphur dyes by using a biodegradable reducing agent in place of sodium sulphide to dye cotton fabrics. The study also proposes after-treatments with tannin to improve the fastness properties of the dyeings.

Design/methodology/approach

In this study, dyeings were produced on cotton fabric with a range of C.I. Leuco Sulphur dyes, which were reduced with sodium sulphide and glucose. Sulphur dyeings were after-treated with an environment-friendly tannin-based product (Bayprotect CL (BP)); subsequently, the after-treated samples were evaluated for colour strength, wash, light and rubbing fastness.

Findings

A novel after-treatment method was developed, which substantially improved the wash fastness of C.I. Leuco Sulphur Black 1 dyeing to ISO 105 C06/C09 washing. However, the degree of this improvement varied for the other sulphur dyes used. The surface morphology and the possible mechanisms for the improved fastness properties were also discussed.

Research limitations/implications

The effect of after-treatment was significant for improving the wash fastness of sulphur black dyeings in particular, while the effect on other colours was minor. Significant improvements were observed for light and wet rub fastness for most of the dyeings, which signifies the importance of tannins as a finishing agent.

Practical implications

It is observed that the tannin-based product, BP, is found to provide the photoprotective effect by improving the lightfastness of the dyeings. Future research may involve the exploration of various tannins as a finishing agent to sulphur dyeings.

Originality/value

This novel finishing technique is found significant for improving the wash fastness of sulphur black 1 dyeings for both the reducing systems. Improvements were also observed for light and wet rub fastnesses for most of the dyeings.

Details

Pigment & Resin Technology, vol. 51 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 21 October 2019

Khaled Mostafa and Azza El-Sanabary

This study aims to explore the incorporation of the authors previously prepared chitosan nanoparticles (CNPs) of size around 60-100 nm in the cross-linking formulation of viscose…

Abstract

Purpose

This study aims to explore the incorporation of the authors previously prepared chitosan nanoparticles (CNPs) of size around 60-100 nm in the cross-linking formulation of viscose fabrics to see CNPs impact in terms of imparting multi-functional characteristics such as tensile strength, dry wrinkle recovery angles and antibacterial properties.

Design/methodology/approach

CNPs of size around 60-100 nm were incorporated in cross-linking formulations for viscose fabrics, including different concentrations of glutaraldehyde as a non-formaldehyde cross-linking agent and magnesium chloride hexahydrate as a catalyst. The formulations were applied at different curing times and temperatures in 100 mL distilled water, giving rise to a wet pickup of ca. 85 per cent. The fabrics were dried for 3 min at 85°C and cured at specified temperatures for fixed time intervals in thermo fixing oven according to the traditional pad-dry-cure method.

Findings

The above eco-friendly method for finished viscose fabrics was found to obtain high dry wrinkle recovery angle and maintain the tensile strength of the finished fabric within the acceptable range, as well as antibacterial properties against Escherichia coli and Staphylococcus aureus as a gram-negative and gram-positive bacteria, respectively. Both, scanning electron microscope and nitrogen percent on the finished fabric confirm the penetration of CNPs inside the fabric structure. Finally, viscose fabrics pageant antibacterial activity against gram-positive and gram-negative bacteria assessed even after 20 washing cycle.

Research limitations/implications

CNPs with its flourishing effect with respect to cationic nature, biodegradability, reactivity, higher surface area and antimicrobial activity; in addition to glutaraldehyde as non-formaldehyde finishing agent can be used as multi-functional agents for viscose fabrics instead of DMDHEU, polyacrylate and monomeric composites as hazardous materials.

Practical implications

CNPs as cationic biopolymers were expected to impart multi-functional properties to viscose fabrics especially with obtaining reasonable dry wrinkle recovery angle and tensile strength in addition to antibacterial properties.

Originality/value

The novelty addressed here is undertaken with a view to impart easy care characteristics and antibacterial activities onto viscose fabrics using CNPs as antimicrobial agent and glutaraldehyde as non-formaldehyde durable press finishes to-replace the traditional formaldehyde-based resins. Besides, to the authors’ knowledge, there is no published work so far using the above cross-linking formulation written above.

Details

Pigment & Resin Technology, vol. 49 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 December 2004

George K. Stylios

Examines the tenth published year of the ITCRR. Runs the whole gamut of textile innovation, research and testing, some of which investigates hitherto untouched aspects. Subjects…

3545

Abstract

Examines the tenth published year of the ITCRR. Runs the whole gamut of textile innovation, research and testing, some of which investigates hitherto untouched aspects. Subjects discussed include cotton fabric processing, asbestos substitutes, textile adjuncts to cardiovascular surgery, wet textile processes, hand evaluation, nanotechnology, thermoplastic composites, robotic ironing, protective clothing (agricultural and industrial), ecological aspects of fibre properties – to name but a few! There would appear to be no limit to the future potential for textile applications.

Details

International Journal of Clothing Science and Technology, vol. 16 no. 6
Type: Research Article
ISSN: 0955-6222

Keywords

Article
Publication date: 20 October 2021

Osama A. Hakeim, Samah A. Rashed and Hanan Diab

The present research aims to manage the formulations of pigment-based inks containing aminopropyl/vinyl/silsesquioxane (APSV) as a pigment binding agent for inkjet printing of…

Abstract

Purpose

The present research aims to manage the formulations of pigment-based inks containing aminopropyl/vinyl/silsesquioxane (APSV) as a pigment binding agent for inkjet printing of polyester as a commercial trial for the printing of polyester as a single-step process.

Design/methodology/approach

The proposed formulations incorporated APSV by using the mini-emulsion technique at a low relieving temperature under the thermal initiation or UV radiation of vinyl-terminated groups in APSV. In this study, the storage stability of inks with regard to physical properties was broadly examined. Moreover, the color performance, including colorimetric data, color fixation and fastness properties of printed fabrics was evaluated.

Findings

The results indicated that the inks containing APSV were formulated and were stable in terms of particle size, dispersion stability, surface tension and viscosity over a period of one month and for four freeze/thaw cycles. APSV successfully fixed the pigment-based inkjet inks on polyester fabric and could achieve a significantly higher color performance and degree of fixation than the formulated inks without APSV.

Research limitations/implications

It could also fulfill all the physical properties of ink prerequisites over storing and eliminating all challenges in improving the performance and utilization of inkjet printing.

Practical implications

APSV can also be used as a pigment binding agent to formulate inks for inkjet printing of polyester fabrics as the authors’ past examination for inkjet printing of polyester fabrics post-treated with APSV.

Social implications

This study eliminates the noteworthy challenges in formulating the pigment-based inks for textile applications by incorporation of a binder while keeping up the necessary viscosity profile for a specific print head.

Originality/value

This study addressed all the issues arising from the complex nature and very challenging requirements of inkjet inks.

Details

Pigment & Resin Technology, vol. 51 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 5 July 2023

Khaled Mostafa, Nader Abdelaziz and Azza El-Sanabary

The purpose of this study is to undertake surface graft copolymerization of viscose fabric via altering its fibrous properties by using acrylic acid (AA) as a carboxyl-containing…

Abstract

Purpose

The purpose of this study is to undertake surface graft copolymerization of viscose fabric via altering its fibrous properties by using acrylic acid (AA) as a carboxyl-containing monomer and peroxydisulfate (PDS) in presence of ferrous sulfate as a novel redox pair for initiating grafting. The latter process acted as an energy-saving process with respect to the reduction in polymerization temperature and maximizing the graft yield %, in addition to rendering the grafted viscose fabrics dye-able with cationic dye (crystal violet), which has frequently no direct affinity to fix on fabric.

Design/methodology/approach

To make graft copolymerization more efficient and economic, the optimum conditions for graft copolymerization were established. The graft yield % was determined as a function of initiator, catalyst and monomer concentrations and the material to liquor ratio, in addition to polymerization time and temperatures. Metrological characterizations via Fourier transform infrared spectroscopy and scanning electron microscopy of topographic morphological surface change have also been established in comparison with the ungrafted samples.

Findings

The maximum graft yield of 70.6% is obtained at the following optimum conditions: monomer (150 % based on the weight of fabric), PDS (50 m mole), ferrous sulfate (80 m mole) and sulfuric acid (30 m mole) at 40° C for 1.5 h using a liquor ratio of 30. Remarkably, grafting with AA enabled a multifold upsurge in color strength, with improvements in the fastness properties of cationically dyed grafted viscose fabric measured on the blue scale in comparison with untreated viscose fabric.

Originality/value

The novelty addressed here is undertaken with studying the effect of altering the extent of grafting of poly (AA)-viscose graft copolymers expressed as graft yield % in addition to carboxyl contents on cationic dyeing of viscose fabric for the first time in the literature. Moreover, rendering the viscose fabrics after grafting is dye-able with cationic dye with high brilliance of shades, which has regularly no direct affinity to fix on this type of fabrics.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 September 1999

Michael Carano

While the interest in alternative metalization processes for the manufacturing of printed wiring boards is extremely keen, the long‐term reliability of plated through holes…

366

Abstract

While the interest in alternative metalization processes for the manufacturing of printed wiring boards is extremely keen, the long‐term reliability of plated through holes fabricated with these electroless copper alternatives remains in question. However, during the last three years, significant process improvements have been made in the direct metalization process based on a patented dispersion of graphite. This paper will describe the technology in detail and present data on the reliability and versatility of the graphite based direct metalization process.

Details

Circuit World, vol. 25 no. 3
Type: Research Article
ISSN: 0305-6120

Keywords

Article
Publication date: 1 January 1981

Americus

If the paint chemist is to meet the challenges of ecology, toxicity, and government regulations generally, he must rely on two things. One of these is formulating skill, the…

Abstract

If the paint chemist is to meet the challenges of ecology, toxicity, and government regulations generally, he must rely on two things. One of these is formulating skill, the other, new raw materials. In fact, however, there have been very few truly new raw materials in the past decade. Most of the advances have involved variations of known products and these variations have related to the needs of the paint chemist. For example there has been a strong desire to convert materials which are normally solvent‐based to forms useful in water‐borne compositions.

Details

Pigment & Resin Technology, vol. 10 no. 1
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 27 July 2012

Roqaya Sadek

The purpose of this research is to study the effect of softener treatment on plain jersey fabrics with properties made of cotton and spandex yarn.

Abstract

Purpose

The purpose of this research is to study the effect of softener treatment on plain jersey fabrics with properties made of cotton and spandex yarn.

Design/methodology/approach

Samples with 100 percent cotton yarns, spandex yarns in alternating courses (half plating) and spandex yarns in every courses (full plating) were produced on a circular knitting machine where the two latter cases were produced at five different levels of spandex extension. After the dyeing process, fabrics were treated with fabric softener using two softener types (cationic and silicon) and all type two concentrations (3 percent, 6 percent) to evaluate the most appropriate softener type and concentration on fabric friction force, sewing needle penetration force and weight loss percent under different levels of spandex extension.

Findings

Results showed that silicon softener treatment results in high decreases in fabric sewing needle penetrating force, friction force and while treatment with cationic softener results in high decreases in weight loss percent for 100 percent cotton, half and full plating fabrics.

Originality/value

There is a growing need to study the effect of softeners when spandex yarns are used in the production of knitted fabric which results in high increase of stitch density. This research compares the effects of two different softener types at different concentrations on the properties of both plain jersey fabric produced from 100 percent cotton yarns and from cotton/spandex yarns with different stitch density.

Details

International Journal of Clothing Science and Technology, vol. 24 no. 4
Type: Research Article
ISSN: 0955-6222

Keywords

Article
Publication date: 3 August 2022

Nargess Yousefi-Limaee, Behzad Shirkavand Hadavand and Zahra Rahmani

Methylene blue (MB) is classified as a cationic dye which is widely used as chemical indicator, coloring agent and biological stain. The discharge of this dye to the water streams…

Abstract

Purpose

Methylene blue (MB) is classified as a cationic dye which is widely used as chemical indicator, coloring agent and biological stain. The discharge of this dye to the water streams is harmful to the human beings. For this reason, this study investigated the removal of MB from aqueous solution by hydrogel nanocomposite.

Design/methodology/approach

In experimental part, at first, ultraviolet (UV)-curable hydrogel/chitosan nanocomposite, which improves its elasticity by urethane acrylate, was synthesized and characterized by FTIR and SEM analysis. Afterward, the synthesized hydrogel nanocomposite was applied for the removal of MB and the influence of operational condition including nanocomposite loading, dye concentration, contact time and pH of solution was specified. Moreover, isotherm studies as well as kinetics survey were performed.

Findings

Langmuir, Freundlich, Brunauer, Emmett and Teller and Tempkin adsorption isotherms were assessed for the analysis of experimental data indicating the Freundlich isotherm was the best fitted one. The adsorption kinetics data was examined indicating the adsorption kinetics appropriate to pseudo-second-order kinetics model.

Originality/value

The predominant water absorption property of the UV-curable hydrogel/chitosan nanocomposite to 8.5 steps and outstanding adsorption capacity for the elimination of MB on hydrogel nanocomposite subscribed that the synthesized hydrogel could be a favorable adsorbent for simultaneous absorption of water and removal of cationic dyes.

Details

Pigment & Resin Technology, vol. 52 no. 3
Type: Research Article
ISSN: 0369-9420

Keywords

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