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Article
Publication date: 11 September 2023

Yang Liu, Jialing Wang, Huayang Cai, Yawei Shao, Zhengyi Xu, Yanqiu Wang and Junyi Wang

Epoxy zinc-rich coatings are widely used in harsh environments because of the long-lasting cathodic protection of steel surfaces. The purpose of this paper is to use flake zinc…

Abstract

Purpose

Epoxy zinc-rich coatings are widely used in harsh environments because of the long-lasting cathodic protection of steel surfaces. The purpose of this paper is to use flake zinc powder instead of the commonly used spherical zinc powder to reduce the zinc powder content.

Design/methodology/approach

In this paper, the authors have prepared an anticorrosive zinc-rich coating using a flake zinc powder instead of the conventional spherical zinc powder. The optimal dispersion of scaly zinc powder in zinc-rich coatings has been explored by looking at the surface and cross-sectional morphology and studying the cathodic protection time of the coating.

Findings

The final epoxy zinc-rich coating with 35 Wt.% flake zinc powder content was prepared using sand-milling dispersions. It has a similar cathodic protection time and salt spray resistance as the 60 Wt.% spherical zinc-rich coating, with a higher low-frequency impedance modulus value.

Originality/value

This study uses flake zinc powder instead of the traditional spherical zinc powder. This reduces the amount of zinc powder in the coating and improves the corrosion resistance of the coating.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 10 August 2023

Clément Génin, Marc Jeannin, Anne-Marie Grolleau and Philippe Refait

The purpose of this study is to investigate cathodic protection (CP) efficiency in the tidal zone and its associated processes.

Abstract

Purpose

The purpose of this study is to investigate cathodic protection (CP) efficiency in the tidal zone and its associated processes.

Design/methodology/approach

Specific features of CP in the tidal zone, that is, persistence of a thin seawater film and insufficient cathodic potential due to ohmic drop, were addressed. In this preliminary study, carbon steel electrodes were polarized at two cathodic potentials (correct or insufficient protection) while immersed in 1 mm or 5 mm thick natural seawater layers. After CP interruption, the protective ability of the layers covering the steel electrodes was studied using various electrochemical methods, including electrochemical impedance spectroscopy. The layers were characterized by XRD.

Findings

The protective ability of calcareous deposits was increased in thin seawater films. Insufficient CP could promote protective aragonite/corrosion products layer.

Originality/value

The combined effects of thin seawater film and applied potential were never addressed, and the conclusions drawn from this preliminary study give new insight on the efficiency of CP in the tidal zone.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 3 May 2023

Xiao Wang, Xuan Liang, Bo Wang, Chang-qing Guo, Shan-gui Zhang, Kai Yang, Shi-ya Shao, Yan Sun, Zheng Guo, Xue-yan Yu, Donghai Zhang, Tai-jiang Gui, Wei Lu, Ming-liang Sun and Rui Ding

The purpose of this study is to evaluate the effect of graphene, basalt flakes and their synergy on the corrosion resistance of zinc-rich coatings. As the important heavy-duty…

Abstract

Purpose

The purpose of this study is to evaluate the effect of graphene, basalt flakes and their synergy on the corrosion resistance of zinc-rich coatings. As the important heavy-duty anticorrosion coatings, zinc-rich coatings provided cathodic protection for the substrate. However, to ensure cathodic protection, a large number of zinc powder made the penetration resistance known as the weakness of zinc-rich coatings. Therefore, graphene and basalt flakes were introduced into zinc-rich coatings to coordinate its cathodic protection and shielding performance.

Design/methodology/approach

Three kinds of coatings were prepared; they were graphene modified zinc-rich coatings, basalt flakes modified zinc-rich coatings and graphene-basalt flakes modified zinc-rich coatings. The anticorrosion behavior of painted steel was studied by using the electrochemical impedance spectroscopy (EIS) technique in chloride solutions. The equivalent circuit methods were used for EIS analysis to obtain the electrode process structure of the coated steel system. Simultaneously, the corrosion resistance of the three coatings was evaluated by water resistance test, salt water resistance test and salt spray test.

Findings

The study found that the addition of a small amount of graphene and basalt flakes significantly improved the anticorrosion performance of coatings by enhancing their shielding ability against corrosive media and increasing the resistance of the electrochemical reaction. The modified coatings exhibited higher water resistance, salt water resistance and salt spray resistance. The graphene-basalt flakes modified zinc-rich coatings demonstrated the best anticorrosion effect. The presence of basalt scales and graphene oxide in the coatings significantly reduced the water content and slowed down the water penetration rate in the coatings, thus prolonging the coating life and improving anticorrosion effects. The modification of zinc-rich coatings with graphene and basalt flakes improved the utilization rate of zinc powder and the shielding property of coatings against corrosive media, thus strengthening the protective effect on steel structures and prolonging the service life of anticorrosion coatings.

Originality/value

The significance of developing graphene-basalt flakes modified zinc-rich coatings lies in their potential to offer superior performance in corrosive environments, leading to prolonged service life of metallic structures, reduced maintenance costs and a safer working environment. Furthermore, such coatings can be used in various industrial applications, including bridges, pipelines and offshore structures, among others.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 21 February 2024

Nehal Elshaboury, Tarek Zayed and Eslam Mohammed Abdelkader

Water pipes degrade over time for a variety of pipe-related, soil-related, operational, and environmental factors. Hence, municipalities are necessitated to implement effective…

Abstract

Purpose

Water pipes degrade over time for a variety of pipe-related, soil-related, operational, and environmental factors. Hence, municipalities are necessitated to implement effective maintenance and rehabilitation strategies for water pipes based on reliable deterioration models and cost-effective inspection programs. In the light of foregoing, the paramount objective of this research study is to develop condition assessment and deterioration prediction models for saltwater pipes in Hong Kong.

Design/methodology/approach

As a perquisite to the development of condition assessment models, spherical fuzzy analytic hierarchy process (SFAHP) is harnessed to analyze the relative importance weights of deterioration factors. Afterward, the relative importance weights of deterioration factors coupled with their effective values are leveraged using the measurement of alternatives and ranking according to the compromise solution (MARCOS) algorithm to analyze the performance condition of water pipes. A condition rating system is then designed counting on the generalized entropy-based probabilistic fuzzy C means (GEPFCM) algorithm. A set of fourth order multiple regression functions are constructed to capture the degradation trends in condition of pipelines overtime covering their disparate characteristics.

Findings

Analytical results demonstrated that the top five influential deterioration factors comprise age, material, traffic, soil corrosivity and material. In addition, it was derived that developed deterioration models accomplished correlation coefficient, mean absolute error and root mean squared error of 0.8, 1.33 and 1.39, respectively.

Originality/value

It can be argued that generated deterioration models can assist municipalities in formulating accurate and cost-effective maintenance, repair and rehabilitation programs.

Details

Engineering, Construction and Architectural Management, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0969-9988

Keywords

Article
Publication date: 15 August 2023

Yongtao Zhao, Weili Li, Xiaoyang Xuan, Jianbang Gao, Jue Wang, Liang Dong, Dawei Zang, Mingjian Wang and Xiankang Zhong

This study aims to evaluate the protection performance of zinc as sacrificial anode for ABS A steel in the presence of H2S under different temperatures, pH and salinities.

Abstract

Purpose

This study aims to evaluate the protection performance of zinc as sacrificial anode for ABS A steel in the presence of H2S under different temperatures, pH and salinities.

Design/methodology/approach

In this paper, weight loss measurements and electrochemical measurements are used to evaluate the corrosion degree of zinc and ABS A steel.

Findings

Under the conditions involved in this work, it is shown that zinc is a nice sacrificial anode with the reason of its stable potential and excellent anode current efficiency according to the relevant standard. And it is also found that the hydrogen evolution does not occur on ABS A steel specimens. The potential difference between cathode and anode is suitable; thus, it can be concluded that each steel is well protected.

Originality/value

To the best of the authors’ knowledge, no other study has analyzed the protection mechanism and effect of zinc as sacrificial anode in H2S-containing environments under high temperature at present.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 7 June 2022

James Geisbush and Samuel T. Ariaratnam

Reliability centered maintenance (RCM) is a process used to determine activities to be taken to ensure an asset continues to perform asset's function in asset's present operating…

1421

Abstract

Purpose

Reliability centered maintenance (RCM) is a process used to determine activities to be taken to ensure an asset continues to perform asset's function in asset's present operating context by identifying asset's function, failure modes that could preclude performing asset's intended function, prioritizing failure modes and determining effective preventative maintenance tasks that can be cost effectively and efficiently implemented to reduce the likelihood of a failure.

Design/methodology/approach

A comprehensive survey of literature was undertaken to examine the current industry state of practice. Various industries were examined to better understand applications of RCM within the various industry sectors and determine those industries that RCM has not historically been readily adopted. A case study example of RCM applied to radial gates for water control in open channel canals for water conveyance is presented to demonstrate a civil infrastructure application.

Findings

The results found that RCM has been used since RCM's inception in the airline industry during the 1960s to reduce the cost of maintaining aircrafts. Over the past 40 years, an assortment of industries has begun implementing cost effective preventative maintenance tasks identified during RCM analysis. However, there is a noticeable lack of civil assets being analyzed by RCM, such as water conveyance systems and other civil infrastructure systems vital to the health and well-being of today's societies.

Originality/value

The comprehensive literature review of the current state of practice will provide a better understanding of the various applications of RCM to facilitate RCM's application to other industries, thereby reducing failure due to early identification of maintenance tasks. An example RCM demonstrates the application to a radial gate, used in water conveyance for the drinking water and irrigation sectors, which have not historically used RCM for developing maintenance strategies.

Details

Journal of Quality in Maintenance Engineering, vol. 29 no. 2
Type: Research Article
ISSN: 1355-2511

Keywords

Article
Publication date: 5 October 2023

Minakshi Koundal, Ajay Kumar Singh and Chhaya Sharma

This paper aims to investigate the eco-friendly neodymium tartrate (NdTar) inhibitor for mild steel in sodium chloride (NaCl) solution.

Abstract

Purpose

This paper aims to investigate the eco-friendly neodymium tartrate (NdTar) inhibitor for mild steel in sodium chloride (NaCl) solution.

Design/methodology/approach

The mild steel 1010 coupon was considered for the current study. Weight loss and the electrochemical methods were used to evaluate the inhibitory effects of neodymium chloride (NdCl3) and NdTar on mild steel in NaCl solution. Scanning electron microscopy, energy-dispersive X-ray analysis and attenuated total reflectance-Fourier transform infrared spectroscopy measurements were carried out to study the morphology and composition of the film, nature of deposits and corrosion products formed in test media on the corroded steel, with the objective of further analyzing the observed behavior of the two inhibitors.

Findings

Of the two, NdTar performs better than NdCl3 because it shields mild steel surfaces for longer. According to the results, when NdCl3 is present in a corrosive solution, the protective film only comprises Nd/Fe oxide/hydroxide/carbonate. However, when neodymium is coupled with the tartrate group (an organic group) and then added to the NaCl solution, the inhibitor film comprises both bimetallic complexes (Fe-Tar-Nd) and metal oxide/hydroxide/carbonate, which results in a more compact film and has higher inhibition efficiency.

Originality/value

This study evaluated the combined effects of inorganic and organic inhibitors with those of an inorganic inhibitor used alone for mild steel in NaCl solution.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 6 February 2024

Shuangjiu Deng, Chang Li, Xing Han, Menghui Yu and Han Sun

The restoration and strengthening of QT600 is an industry bottleneck challenge. The Co-12 cladding layer has great wear and corrosion resistance. The purpose of this paper is to…

Abstract

Purpose

The restoration and strengthening of QT600 is an industry bottleneck challenge. The Co-12 cladding layer has great wear and corrosion resistance. The purpose of this paper is to quantitatively reveal the transient evolution law of the corrosion process of Co-12 cladding layer on QT600 surface.

Design/methodology/approach

In this paper, a three-dimensional numerical model of the corrosion process of Co-12 cladding layer by QT600 laser cladding is established. The interaction between pitting pits and corrosion medium is considered to reveal the transient evolution of ion concentration, electrode potential, pH and corrosion rate at different locations.

Findings

The calculation shows that the ion concentration in pitting pit changes Cl>Co2+>Na+, pH value decreases from top to bottom and corrosion rate at bottom is greater than that at top. The electrochemical corrosion test of Co-12 cladding layer was carried out. It is shown that the current density of QT600 increases by an order of magnitude compared to the Co-12 cladding layer, and the corrosion rate is 4.862 times higher than that of the cladding layer.

Originality/value

The results show that Co-12 cladding layer has great corrosion resistance, which provides an effective way for QT600 protection.

Details

Anti-Corrosion Methods and Materials, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 18 December 2023

Yingying Li, Lanlan Liu, Jun Wang, Song Xu, Hui Su, Yi Xie and Tangqing Wu

The purpose of this paper is to study the corrosion behavior of Q235 steel in saturated acidic red and yellow soils.

Abstract

Purpose

The purpose of this paper is to study the corrosion behavior of Q235 steel in saturated acidic red and yellow soils.

Design/methodology/approach

The corrosion behavior of Q235 steel in saturated red and yellow soils was compared by weight-loss, SEM/EDS, 3D ultra-depth microscopy and electrochemical measurements.

Findings

Rp of the steel gradually increases and icorr gradually decreases in both the red and yellow soils with time. The Rp of the steel in the red soil is lower, but its icorr is higher than that in the yellow soil. The uniform corrosion rate, diameter and density of the corrosion pit on the steel surface in the red soil are greater than those in the yellow soil. Lower pH, higher contents of corrosive anions and high-valence Fe oxides in the red soil are responsible for its higher corrosion rates and local corrosion susceptibility.

Originality/value

This paper investigates the difference in corrosion behavior of carbon steel in saturated acidic red and yellow soils, which can help to understand the mechanism of soil corrosion.

Details

Anti-Corrosion Methods and Materials, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 6 April 2023

Yongxiong Li, Junying Hu and Xiankang Zhong

This study aims to shed light on the corrosion behavior of X80 steel when sulfate-reducing bacteria (SRB) and permeating hydrogen interact.

Abstract

Purpose

This study aims to shed light on the corrosion behavior of X80 steel when sulfate-reducing bacteria (SRB) and permeating hydrogen interact.

Design/methodology/approach

In this study, electrochemical tests were conducted between 25 and 55 °C, and the surface morphology of the specimen was observed using scanning electron microscopy and three-dimensional photos. The composition of the oxide film was characterized by X-ray photoelectron spectroscopy (XPS).

Findings

Under the condition of 6 MPa simulated natural gas (15% H2), the content of S-containing compounds (FeS and FeSO4) in the corrosion products on the surface of the specimen decreases from 60.8% to 54.4%. This finding indicates that hydrogen permeation inhibits the metabolic processes of SRB in this environment. By comparing the hydrogen-uncharged specimen, it was found that under the condition of 6 MPa simulated natural gas (15% H2) hydrogen charging, the uniform corrosion on the X80 surface was weakened, and the protection of the oxide film on the specimen surface in this environment was better than that without hydrogen charging.

Originality/value

To the best of the authors’ knowledge, most of these existing studies have focused on the effect of hydrogen on the mechanical properties of materials and very little is known about corrosion behavior in the hydrogen environment. In this study, a self-designed small gas phase hydrogen charging device was used to study the X80 surface corrosion behavior in the environment of the H2-doped natural gas pipeline.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 3
Type: Research Article
ISSN: 0003-5599

Keywords

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