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Ti-Si-N coating with nanocomposite structure is a promising protective coating for cutting tools which will be subject to high temperature oxidation during service. This study aims to investigate the thermal stability of Ti-Si-N coatings and lays the foundation for its application in high speed dry cutting.

Nanocomposite Ti-Si-N coating was deposited on stainless substrate and silicon wafer (100) by Ti90Si10 alloy target by using cathodic arc ion plating. The microstructure of Ti-Si-N coating had been detected by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS).

The results suggested that the coating was TiN nanocrystals with a diameter of 6.3 nm surrounded by amorphous Si3N4. The oxidation test was conducted under 550, 650, 750, 800, 850, 900 and 950°C for 2 h. The structure evolution was observed by Scanning electron microscope (SEM), energy dispersive spectrum (EDS), XRD and XPS. The results indicated that rutile has been formed at 650°C, while Si3N4 began to oxidized at 800°C. The grain size of TiN increased from 6.3 to 13 nm as the samples oxidized from 550 to 800. Micro-crack also formed in samples oxidized over 900°C.

Ti-Si-N coating, in this study, was deposited by cathodic arc ion plating using alloy target at high-bias voltage. The oxidation temperature ranged from 500 to 950°C with TiN coating as reference.

The purpose of this study was to develop a TiAlSiCN coating with high bonding and hardness, ultra-low friction and good lubrication characteristics, which provided an experimental basis for the surface modification of YT14 cemented carbide cutting tools.

In this work, a TiAlSiCN coating was deposited on YT14 cemented carbide cutting tool through cathodic arc ion plating. The surface-interface morphologies, distributions of chemical elements, phases, bonding energy and surface roughness were analyzed using field emission scanning electron microscopy, energy-dispersive spectroscopy (EDS), X-ray diffraction, X-ray photoelectron spectroscopy and atomic force microscopy, respectively, and the coating the bonding strength were quantitatively characterized with a scratch.

The average COFs of the TiAlSiCN coating at 700°C, 800°C and 900°C were 0.68, 0.57 and 0.38, respectively, showing that the TiAlSiCN coating was an effective lubricant at a high temperature, and the wear rate of the coating increases with wear temperature. After wearing at 700°C, 800°C and 900°C, the Ti, Si and N elements form atom-poor regions, while Al forms an atom-rich region, showing that the oxides of Ti, Al and Si are formed to improve the wear resistance of the coating. The wear mechanism of TiAlSiCN coating at high temperatures was composed of abrasive wear and oxidation wear.

The friction-wear behaviors of TiAlSiN coating were investigated using an HT-1000-type high-temperature friction wear tester, and the worn tracks on the coatings were analyzed using an EDS plane scan, thus obtaining the wear mechanism of TiAlSiN coating.

The purpose of this paper is to evaluate the salt spray corrosion (SSC) and electrochemical corrosion performances of CrNi, TiAlN/NiCr and CrNi–Al₂O₃–TiO₂ coatings on H13 steel, which improved the corrosion resistance of H13 hot work mold.

CrNi, TiAlN/NiCr and CrNi–Al₂O₃–TiO₂ coatings were fabricated on H13 hot work mold steel using a laser cladding and cathodic arc ion plating. The SSC and electrochemical performances of obtained coatings were investigated using a corrosion test chamber and electrochemical workstation, respectively. The corrosion morphologies, microstructure and phases were analyzed using an electron scanning microscope, optical microscope and X-ray diffraction, respectively, and the mechanisms of corrosion resistance were also discussed.

The CrNi coating is penetrated by corrosion media, producing the oxide of Fe₃O₄ on the coating surface; and the TiAlN coating is corroded to enter into the CrNi coating, forming the oxides of TiO and NiO, the mechanism is pitting corrosion, whereas the CrNi–Al₂O₃–TiO₂ coating is not penetrated, with no oxides, showing the highest SSC resistance among the three kinds of coatings. The corrosion potential of CrNi coating, TiAlN/CrNi and CrNi–Al₂O₃–TiO₂ coatings was –0.444, –0.481 and –0.334 V, respectively, and the corresponding polarization resistances were 3,074, 2,425 and 86,648 cm², respectively. The electrochemical corrosion resistance of CrNi–Al₂O₃–TiO₂ coating is the highest, which is enhanced by the additions of Al₂O₃ and TiO₂.

The CrNi, TiAlN/CrNi and CrNi–Al₂O₃–TiO₂ coatings on H13 hot work mold were firstly evaluated by the SSC and electrochemical performances.

This study aims to investigate the surface modification on 20CrMnTi gear steel individually treated by diamond-like carbon films and nitride coatings.

For this purpose, the mechanical properties of a-C:H, ta-C and AlCrSiN coatings are characterized by nano-indentation and scratch tests. The friction and wear behaviors of these three coatings are evaluated by ball-on-disc tribological experiments under dry contact conditions.

The results show that the a-C:H coating has the highest coating-substrate adhesion strength (495 mN) and the smoothest surface (Ra is about 0.045 µm) compared with the other two coatings. The AlCrSiN coating shows the highest mean coefficient of friction (COF), whereas the ta-C coating exhibits the lowest one (steady at about 0.16). The carbon-based coatings possess excellent self-lubricating properties compared with nitride ceramic ones, which effectively reduce the COF by about 64%. The major failure mode of carbon-based coatings in dry contact is slight abrasive wear. The damage of AlCrSiN coating is mainly adhesive wear and abrasive wear.

It is suggested that the carbon-based film can effectively improve the friction-reducing and wear resistance performance of the gear steel surface, which has a promising application prospect in the mechanical transmission field.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-05-2023-0129/

Copper matrix composites are widely used in high-voltage switches, electrified railways and other electric friction fields. The purpose of this study is to improve its wear resistance and investigate the effect of hybrid carbon nanotubes (CNTs) and titanium diboride (TiB₂) particles reinforced copper matrix composites on electrical wear performance.

CNTs and TiB₂ particles were introduced into copper matrix simultaneously by powder metallurgy combined with electroless copper plating. Electrical wear performance of the composites was studied on self-made pin on disk electrical wear tester.

The results show that the friction coefficient and wear rate of (1CNTs–4TiB₂)/Cu composite are respectively reduced by 40% and 25.3%, compared with single TiB₂/Cu composites. The micron-sized TiB₂ particles can hinder the plastic deformation of composites, and bear part of the load to weaken the wear rate of composites. CNTs with the self-lubricating property can form lubricating layer to reduce the friction coefficient of composites.

This work can provide a design method for further improving the wear properties of TiB₂/Cu composites.

This study aims to review the recent advancements in high entropy alloys (HEAs) called high entropy materials, including high entropy superalloys which are current potential alternatives to nickel superalloys for gas turbine applications. Understandings of the laser surface modification techniques of the HEA are discussed whilst future recommendations and remedies to manufacturing challenges via laser are outlined.

Materials used for high-pressure gas turbine engine applications must be able to withstand severe environmentally induced degradation, mechanical, thermal loads and general extreme conditions caused by hot corrosive gases, high-temperature oxidation and stress. Over the years, Nickel-based superalloys with elevated temperature rupture and creep resistance, excellent lifetime expectancy and solution strengthening L12 and γ´ precipitate used for turbine engine applications. However, the superalloy’s density, low creep strength, poor thermal conductivity, difficulty in machining and low fatigue resistance demands the innovation of new advanced materials.

HEAs is one of the most frequently investigated advanced materials, attributed to their configurational complexity and properties reported to exceed conventional materials. Thus, owing to their characteristic feature of the high entropy effect, several other materials have emerged to become potential solutions for several functional and structural applications in the aerospace industry. In a previous study, research contributions show that defects are associated with conventional manufacturing processes of HEAs; therefore, this study investigates new advances in the laser-based manufacturing and surface modification techniques of HEA.

The AlxCoCrCuFeNi HEA system, particularly the Al0.5CoCrCuFeNi HEA has been extensively studied, attributed to its mechanical and physical properties exceeding that of pure metals for aerospace turbine engine applications and the advances in the fabrication and surface modification processes of the alloy was outlined to show the latest developments focusing only on laser-based manufacturing processing due to its many advantages.

It is evident that high entropy materials are a potential innovative alternative to conventional superalloys for turbine engine applications via laser additive manufacturing.

The purpose of this paper is to examine mechanical and metallurgical properties of AlTiN coating HSS materials in detail.

In this study, high-speed steel (HSS) parts were processed by the way of machining and were coated with AlTiN on physical vapour deposition (PVD) workbench at approximately 650°C for 4 h. Tensile strength, fatigue strength and hardness tests for AlTiN coated HSS samples were performed. Samples were also analyzed by energy dispersive X-ray analysis (EDS), X-ray diffraction (XRD) and scanning electron microscope (SEM). The results were compared with uncoated HSS components.

It was found that an amorphous aluminium-oxide layer emerges on surface of parts by AlTiN coating. This layer prevents further oxide formations. The coating thickness of AlTiN-coated sample is between 1,530 and 1,558 μm. Compared to uncoated HSS, AlTiN coated HSS gives higher performance.

It would be interesting to search different coatings for cutting tools. It could be the good idea for future work concentrated wear properties on tool materials using different coatings.

This paper provides information on mechanical and metallurgical behaviour of AlTiN coated HSS materials and offers practical help for the researchers and scientists working in the coating area.

The purpose of this paper is to examine mechanical and metallurgical properties of AlTiN- and TiN-coates high-speed steel (HSS) materials in detail.

In this study, HSS steel parts have been processed through machining and have been coated with AlTiN and TiN on physical vapour deposition workbench at approximately 6,500°C for 4 hours. Tensile strength, fatigue strength, hardness tests for AlTiN- and TiN-coated HSS samples have been performed; moreover, energy dispersive X-ray spectroscopy and X-ray diffraction analysis and microstructure analysis have been made by scanning electron microscopy. The obtained results have been compared with uncoated HSS components.

It was found that tensile strength of TiAlN- and TiN-coated HSS parts is higher than that of uncoated HSS parts. Highest tensile strength has been obtained from TiN-coated HSS parts. Number of cycles for failure of TiAlN- and TiN-coated HSS parts is higher than that for HSS parts. Particularly TiN-coated HSS parts have the most valuable fatigue results. However, surface roughness of fatigue samples may cause notch effect. For this reason, surface roughness of coated HSS parts is compared with that of uncoated ones. While the average surface roughness (Ra) of the uncoated samples was in the range of 0.40 μm, that of the AlTiN- and TiN-coated samples was in the range of 0.60 and 0.80 μm, respectively.

It would be interesting to search different coatings for cutting tools. It could be the good idea for future work to concentrate on wear properties of tool materials.

The detailed mechanical and metallurgical results can be used to assess the AlTiN and TiN coating applications in HSS materials.

This paper provides information on mechanical and metallurgical behaviour of AlTiN- and TiN-coated HSS materials and offers practical help for researchers and scientists working in the coating area.

The purpose of this study is to reveal the effect of nano-Al₂O₃ particle addition on the nucleation/growth kinetics, microhardness, wear resistance and corrosion resistance of Co–P–xAl₂O₃ nanocomposite plating.

The kinetics and properties of Co–P–xAl₂O₃ nanocomposite plating prepared by electroplating were investigated by electrochemical measurements, scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Vickers microhardness measurement, SRV5 friction and wear tester and atomic force microscopy.

A 12 g/L nano-Al₂O₃ addition in the plating solution can transform the nucleation/growth kinetics of the plating from the 3D progressive model to the 3D instantaneous model. The microhardness of the plating increased with the increase of nano-Al₂O₃ content in plating. The wear resistance of the plating did not adhere strictly to Archard’s law. An even and denser corrosion product film was generated due to the finer grains, with a high corrosion resistance.

The effect of different nano-Al₂O₃ addition on the nucleation/growth kinetics and properties of Co–P–xAl₂O₃ nanocomposite plating was investigated, and an anticorrosion mechanism of Co–P–xAl₂O₃ nanocomposite plating was proposed.

This paper aims to investigate the effects of deposition time on the structure and anti-corrosion properties of a micro-arc oxidation (MAO)/Al coating on AZ31B Mg alloy.

The study describes the fabrication of the coating via a combined process of MAO with multi-arc ion plating. The structure, composition and corrosion resistance of the coatings were evaluated using scanning electron microscopy, energy dispersive spectroscopy, X-ray diffraction and electrochemical methods.

The Al-layer is tightly deposited with a good mechanical interlock along the rough interface due to the Al diffusion. However, the Al layer reduces the anti-corrosion of MAO-coated Mg alloy because of structural defects such as droplets and cavities, which act as channels for corrosive media infiltration towards the substrate. Fortunately, the Al layer improves the substrate corrosion resistance owing to its passive behaviour, and the corrosion resistance can be enhanced with increasing deposition time. All results indicate that a buffer layer fabricated through the duplex process improves the interfacial compatibility between the hard coating and soft Mg alloys.

An MAO/Al duplex coating was fabricated via a combined process of MAO and physical vapour deposition. MAO/Al duplex coatings exhibit obviously passive behaviours on AZ31 Mg alloy. The structure and corrosion resistance of MAO/Al coatings were investigated.