Search results

The purpose of this paper is to study the manufacturing of SAC 305 solder paste with multiwall carbon nanotubes (MWCNT) before and after structure modification and also to investigate the added carbon nanotubes' influence on the technological properties and the microstructure of “nano” solder pastes. This work is a continuation of similar previous studies of SAC solder pastes with silver nanopowder additions.

The authors applied functionalization and esterification methods for the structural modification of the carbon nanotubes. The “nano” solder paste preparation was performed with the use of a two‐stage method of carbon nanotube dispersion in “own‐manufactured” SAC 305 solder paste. To determine the technological properties of the “nano” solder paste, slump, solder ball, wetting and spreading tests were applied according to the existing standards. Standard metallographic procedures were applied for microstructural analysis.

As expected on the basis of the previous studies of SAC solder pastes with silver nanopowders, positive results were obtained for the own‐manufactured SAC 305 solder paste with carbon nanotubes by applying the dispersion method. Also applied were functionalization and esterification methods, whose results showed microstructural changes in the carbon nanotubes. The “nano” SAC solder pastes showed a positive influence on the slump properties, compared to the basic SAC solder paste. The authors proved a negative influence of the carbon nanotubes' addition (dependent on their concentration) on the spreading and wetting of the SAC solder paste on a copper substrate, which provoked the non‐wetting and dewetting phenomena. A slight improvement was observed for the “nano” SAC solder pastes with modified carbon nanotubes. The carbon nanotubes' presence in the solder paste showed a positive effect on the growth reduction of the IMCs' thickness, which depended on the type.

The authors intend to verify the reinforcement effect of the alloys with carbon nanotubes suggested in the literature (the aim of Part II). For this purpose, an assembly process with RC electronic elements on PCBs with Ni/Au and SAC (HASL) finishes will be performed, with the use of the SAC 305 solder paste with modified carbon nanotubes, for the purpose of reflow soldering. Next, measurements of the mechanical strength of the solder joints and their microstructures will be conducted.

It is suggested that further studies of the mechanical properties and the reliability of solder joints are necessary for the practical implementation of the “nano” SAC solder pastes, but taking into account the wetting data, the investigation should be performed only for “nano” pastes with the lowest additions of modified carbon nanotubes.

The paper demonstrates a method of “nano” solder paste preparation by means of a two‐stage dispersion of carbon nanotubes in the own‐manufactured SAC 305 solder paste and a comparison study of the properties of “nano” pastes with the basic SAC solder paste.

The purpose of this paper is to explore the use of chiral single‐walled carbon nanotubes (SWCNTs) as mass sensors. Analysis of SWCNT with chiralities is performed using an atomistic finite element model based on a molecular structural mechanics approach.

The cantilever carbon nanotube (CNT) is modeled by considering it as a space frame structure similar to three‐dimensional beams and point masses. The elastic properties of the beam element are calculated by considering mechanical characteristics of covalent bonds between the carbon atoms in the hexagonal lattice. The mass of each beam element is assumed as point mass at nodes coinciding with carbon atoms. An atomistic simulation approach is used to find the natural frequencies and to study the effects of defect like atomic vacancies in CNTs on the resonant frequency. The migration of the atomic vacancies along the length is observed for different chiralities.

A reduction in the simulated natural frequency is observed with the maximum value occurring, when the vacancy is found nearer to the fixed end. It is quite evident from the simulation results that the effect of vacancies is significant, and the effect diminishes at 10⁻² femtograms mass. Using the higher modes of vibration of SWCNT‐based mass sensors, the amount and the position of the mass on the nanotube can be identified.

CNT have been used as mass sensors extensively. The present approach is focused to explore the use of chiral SWCNT as sensing device with vacancy defect in it. The variation of the atomic vacancies in CNT along the length has been taken and is analyzed for different chiralities. The effects of defect like atomic vacancies in CNTs on the resonant frequency have been analyzed and observed that the maximum reduction in natural frequency occurs when the vacancy is found nearer to the fixed end due to large stiffness variation.

The purpose of this paper is to explore and evaluate the performance comparison of carbon nanotubes (CNT) and nickel silicide (NiSi) nanowires interconnects as prospective alternatives to copper wire interconnects.

The increasing resistivity of the copper wire with scaling and rising demands on current density drives the need for identifying new wiring solutions. This paper explores the various alternatives to copper. The metallic bundle CNTs and NiSi nanowires are promising candidates that can potentially address the challenges faced by copper. This paper analyzes various electrical models of carbon nanotube and recently introduced novel interconnect solution using NiSi nanowires.

The theoretical studies proves CNTs and NiSi nanowires to be better alternatives against copper on the ground of performance parameters, such as effective current density, delay and power consumption. NiSi nanowire provides highest propagation speed for short wire length, and copper is the best for intermediate wire length, while bundle CNTs is faster for long wire length. NiSi nanowire has lowest power consumption than copper and CNTs.

This paper investigates, assess and compares the performance of carbon nanotubes (CNT) and NiSi nanowires interconnects as prospective alternatives to copper wire interconnects in future VLSI chips.

The purpose of this paper is concerned with the study of nonlinear ultrasonic waves in a magneto-flexo-thermo (MFT) elastic armchair single-walled carbon nanotube (ASWCNT) resting on polymer matrix.

A mathematical model is developed for the analytical study of nonlinear ultrasonic waves in a MFT elastic armchair single walled carbon nanotube rested on polymer matrix using Euler beam theory. The analytical formulation is developed based on Eringen’s nonlocal elasticity theory to account small scale effect. After developing the formal solution of the mathematical model consisting of partial differential equations, the frequency equations have been analysed numerically by using the nonlinear foundations supported by Winkler-Pasternak model. The solution is obtained by ultrasonic wave dispersion relations.

From the literature survey, it is evident that the analytical formulation of nonlinear ultrasonic waves in an MFT elastic ASWCNT embedded on polymer matrix is not discussed by any researchers. So, in this paper the analytical solutions of nonlinear ultrasonic waves in an MFT elastic ASWCNT embedded on polymer matrix are studied. Parametric studies is carried out to scrutinize the influence of the nonlocal scaling, magneto-electro-mechanical loadings, foundation parameters, various boundary condition and length on the dimensionless frequency of nanotube. It is noticed that the boundary conditions, nonlocal parameter and tube geometrical parameters have significant effects on dimensionless frequency of nanotubes.

This paper contributes the analytical model to find the solution of nonlinear ultrasonic waves in an MFT elastic ASWCNT embedded on polymer matrix. It is observed that the increase in the foundation constants raises the stiffness of the medium and the structure is able to attain higher frequency once the edge condition is C-C followed by S-S. Further, it is noticed that the natural frequency is arrived below 1% in both local and nonlocal boundary conditions in the presence of temperature coefficients. Also, it is found that the density and Poisson ratio variation affects the natural frequency with below 2%. The results presented in this study can provide mechanism for the study and design of the nano devices such as component of nano oscillators, micro wave absorbing, nano-electron technology and nano-electro--magneto-mechanical systems that make use of the wave propagation properties of ASWCNTs embedded on polymer matrix.

The purpose of this paper is to focus on the influence of electromagnetic field during the arc discharge carbon nanotubes synthesis. It proposes modeling of electromagnetic field distribution to calculate forces in the area of arcing. The paper presents the influence of this field on the final product of the synthesis.

A short literature review of the arc discharge systems supported by electromagnetic field is presented. The technical solution of the coil placement is discussed. An experimental research is described. The research system constructed preceded by a series of measurements and modeling is analyzed.

The paper describes the significant meaning of the electromagnetic field during the synthesis. The electromagnetic field forces the slow rotation of the carbon plasma column where carbon nanotubes are formed. It leads to the improvement in yield.

Because the research is limited to one type of geometry of the reactor, the results may vary in different reactors. However, the influence of the electromagnetic field is confirmed. Therefore, researchers are encouraged to investigate the influence of the electromagnetic coil in the applied systems.

The systems with a coil inside the reactor require the application of complex cooling systems or/and additional screens. The work proposes a technical solution based on the coil placed outside the reactor. Therefore, it simplifies the construction and increases the yield.

The high yield of the high-quality nanotubes opens new technical possibilities for electronics and electrical engineering.

The paper identifies a connection between the electromagnetic field, the arc discharge movement, plasma jet, carbon nanotubes containing deposit and the yield.

The purpose of this paper is to consider the static analysis of nanocomposite plates. Nanocomposites consist of a small amount of nanoscale reinforcements which can have an observable effect on the macroscale properties of the composites.

In the present study the reinforcements considered are non‐spherical, high aspect ratio fillers, in particular nanometer‐thin platelets (clays) and nanometer‐diameter cylinders (carbon nanotubes, CNTs). These plates are considered simply supported with a bi‐sinusoidal pressure applied at the top. These conditions allow the solving of the governing equations in a closed form. Four cases are investigated: a single layered plate with CNT reinforcements in elastomeric or thermoplastic polymers, a single layered plate with CNT reinforcements in a polymeric matrix embedding carbon fibers, a sandwich plate with external skins in aluminium alloy and an internal core in silicon foam filled with CNTs and a single layered plate with clay reinforcements in a polymeric matrix. A short review of the most important results in the literature is given to determine the elastic properties of the suggested nanocomposites which will be used in the proposed static analysis. The static response of the plates is obtained by using classical two‐dimensional models such as classical lamination theory (CLT) and first order shear deformation theory (FSDT), and an advanced mixed model based on the Carrera Unified Formulation (CUF) which makes use of a layer‐wise description for both displacement and transverse stress components.

The paper has two aims: to demonstrate that the use of classical theories, originally developed for traditional plates, is inappropriate to investigate the static response of nanocomposite plates and to quantify the beneficial effect of the nanoreinforcements in terms of static response (displacements and stresses).

In the literature these effects are usually given only in terms of elastic properties such as Young moduli, shear moduli and Poisson ratios, and not in terms of displacements and stresses.

Carbon nanotube-based architectures have increased the scientific interest owning to their exceptional performance rendering them promising candidates for advanced industrial applications in the nanotechnology field. Despite individual CNTs being considered as one of the most known strong materials, much less is known about other CNT forms, such as CNT arrays, in terms of their mechanical performance. The paper aims to discuss these issues.

In this work, thermal CVD method is employed to produce VA-MWCNT carpets. Their structural properties were studied by means of SEM, XRD and Raman spectroscopy, while their hydrophobic behavior was investigated via contact angle measurements. The resistance to indentation deformation of VA-MWCNT carpets was investigated through nanoindentation technique.

The synthesized VA-MWCNTs carpets consisted of well-aligned MWCNTs. Static contact angle measurements were performed with water and glycerol, revealing a rather super-hydrophobic behavior.

The structural analysis, hydrophobic behavior and indentation response of VA-MWCNTs carpets synthesized via CVD method are clearly demonstrated.

The purpose of the study is to explore the potential possibility of using the conductive and piezoresistive nanocomposites that consist of insulating poly(dimethylsiloxane), a very popular silicone polymer, and the amazing properties of carbon nanotubes (CNT) in sensing applications. This nanocomposite is prepared by an optimized process to achieve a high-quality nanocomposite with uniform properties.

The optimized process achieved in this study to provide PDMS/CNT nanocomposite includes the appropriate use of ultrasonic bath, magnetic stirrer, molding and curing in certain circumstances that results in obtaining high-quality nanocomposite with uniform properties. Experiments to characterize the influence of some factors such as pressure, temperature and the impact of CNT’s concentration on the electrical properties of the prepared nanocomposite have been designed and carried out.

The obtained preparing method of this nanocomposite is found to have better homogeneity in comparison to other methods for CNT/PDMS nanocomposite. This nanocomposite has both desirable properties of the PDMS elastomer and the additional conductive CNT, and it can be used to create all-polymer systems. Furthermore, the conductivity values of these nanocomposites can be changed by varying some factors such as temperature and pressure, so that those can be used in temperature- and pressure-sensoring applications.

In the present research, a convenient, inexpensive and reproducible method for preparing CNT/PDMS nanocomposite was investigated. These nanocomposites with the unique properties of both PDMS elastomer and CNTs and also with high electrical conductivity, piezoresistive properties and temperature dependent resistivity can be used in different sensoring applications.

The purpose of this paper is to fabricate cellular Ti6Al4V with carbon nanotube (CNT)-like structures by selective electron beam melting and study the resultant mechanical properties based on each respective geometry to provide fundamental information for optimizing molecular architectures and predicting the mechanical properties of cellular solids.

Cellular Ti6Al4V with CNT-like zigzag and armchair structures are fabricated by selected electron beam melting. The microstructures and mechanical properties of these samples are evaluated utilizing scanning electron microscopy, synchrotron radiation X-ray and compressive tests.

The mechanical properties of the cellular solids depend on the geometry of strut architectures. The armchair-structured Ti6Al4V samples exhibit Young’s modulus from 501.10 to 707.60 MPa and compressive strength from 8.73 to 13.45 MPa. The zigzag structured samples demonstrate Young’s modulus from 548.19 to 829.58 MPa and compressive strength from 9.32 to 16.21 MPa. The results suggest that the zigzag structure of the Ti6Al4V cellular solids can achieve improved mechanical properties and the mechanism for the enhanced mechanical properties in the zigzag structures was revealed.

The results provide an innovative example for modulating the mechanical properties of cellular titanium by adjusting the unit cell geometry. The Ti6Al4V cellular solids with single-walled CNT-like structures could be used as light-weight construction components or filters in industries. The Ti6Al4V with multiwalled CNT-like structures could be used as new scaffolds for biomedical applications.

New types of substrates were used for fabrication of printed electroluminescent structures. Polymer foils mainly used as substrates for such optoelectronic elements were replaced with paper and textiles. Printing on non-transparent substrate requires elaboration of printed transparent electrode, while usually polyester foils with sputtered ITO transparent electrodes are used. The paper aims to discuss these issues.

Electroluminescent structures were fabricated with elaborated polymer compositions filled with nanomaterials, such as carbon nanotubes and graphene platelets, dielectric and luminophore nanopowders. Structures were printed as “reverse stack”, where transparent electrode is printed on top of the last luminophore layer. For that carbon nanotubes and graphene platelets filled composition was used, deposited with spray-coating technique.

Main issue with new substrates is proper wetting with the use of screen-printing pastes, and much higher roughness especially for textiles.

Fully functional structures were obtained, but several disadvantages were observed that needs to be eliminated in further studies.