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Article
Publication date: 1 April 1983

Tony Smith

This classification covers a wide range of very useful pigments in the paint and printing industry. They consist largely of elementary carbon which differ mainly in colour and…

Abstract

This classification covers a wide range of very useful pigments in the paint and printing industry. They consist largely of elementary carbon which differ mainly in colour and particle size. Carbon black, although consisting essentially of elementary carbon is usually grouped with the inorganic pigments, and is the generic name for a wide variety of finely divided carbonaceous pigments produced by the partial combustion or thermal decomposition of liquid or gaseous hydrocarbon feedstocks under controlled conditions. The most important are derived from natural gases and are classified as channel or furnace blacks according to the method of production.

Details

Pigment & Resin Technology, vol. 12 no. 4
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 1 January 1988

Y. Sorimachi, I. Tsubata and S. Miyauchi

A thick film overcurrent protector with self‐recovery has been developed using carbon black graft polymer. Carbon black graft polymer, henceforth called CG, is a thick film PTC…

Abstract

A thick film overcurrent protector with self‐recovery has been developed using carbon black graft polymer. Carbon black graft polymer, henceforth called CG, is a thick film PTC thermistor material in which a polymer forms a three‐dimensional network structure around carbon blacks by graft‐copolymerising vinyl monomers. Since the CG material gives a large and stable positive temperature coefficient of resistance depending on the copolymer material, due to the difference of thermal expansion coefficient between carbon blacks and polymer, the stable thick film overcurrent protector with self‐recovery can be realised by using the CG material. The overcurrent protector utilises the dynamic current‐time characteristics of the CG element. When a very large current flows through the CG element, the temperature rises by self‐heating, and the resistance of the element increases dramatically; as a result it restrains the current at a lower level. Since this element is not destroyed after excess current flow, it can be used repeatedly, unlike a metal fuse. In this paper, the manufacturing process and thermal and electrical characteristics of the CG overcurrent protector are investigated, including an analysis of these characteristics.

Details

Microelectronics International, vol. 5 no. 1
Type: Research Article
ISSN: 1356-5362

Article
Publication date: 8 August 2016

X.A. Cao, G.Q. Shao and K.H. Hu

The purpose of this paper is to explore the tribological properties of high-density polyethylene (HDPE) modified by carbon soot from the combustion of No. 0 diesel.

Abstract

Purpose

The purpose of this paper is to explore the tribological properties of high-density polyethylene (HDPE) modified by carbon soot from the combustion of No. 0 diesel.

Design/methodology/approach

Carbon soot is characterized using X-ray diffraction, transmission electron microscopy and scanning electronic microscopy. The tribological properties of HDPE samples with carbon soot are investigated on a materials surface tester with a ball-on-disk friction pair.

Findings

The collected carbon soot mainly comprises amorphous carbon nanoparticles of 50-100 nm in diameter. The main wear behaviours of pure HDPE include abrasive wear and plastic deformation. After adding carbon soot nanoparticles to HDPE, HDPE wear decreases. The appropriate carbon soot content is 8 per cent in HDPE under the selected testing conditions. Compared with other HDPE samples, HDPE with 8 per cent carbon soot has higher melting temperature, lower abrasive wear and better wear resistance. The lubrication of HDPE with carbon soot is due to the formation of a transferring film composed of HDPE, amorphous carbon and graphite carbon.

Originality/value

The paper reveals the HDPE modification and lubrication mechanisms by using carbon soot from the combustion of diesel. Related research can perhaps provide a potential approach for the treatment of carbon soot exhaust emission.

Details

Industrial Lubrication and Tribology, vol. 68 no. 5
Type: Research Article
ISSN: 0036-8792

Keywords

Article
Publication date: 3 July 2017

Behnam Seyyedi

The purpose of this paper is to introduce bio-inspired FeN4-S-C black nano-electrocatalyst for the oxygen reduction reaction (ORR) in an alkaline medium. The FeN4-S-C derived…

Abstract

Purpose

The purpose of this paper is to introduce bio-inspired FeN4-S-C black nano-electrocatalyst for the oxygen reduction reaction (ORR) in an alkaline medium. The FeN4-S-C derived without pyrolysis of precursors in high temperature is recognized as a new electrocatalyst for the ORR in an alkaline electrolyte. For the proper design of bio-inspired nano-electrocatalyst for the ORR performance, chlorinated iron (II) phthalocyanine nanoparticles were used as templates for achieving the active sites in aqueous KOH by rotating disk electrode methods. The most active FeN4-S-C catalyst exhibited a remarkable ORR activity in the alkaline medium. The objectives of this paper are to investigate the possibility of nanoscale particles size (˜5nm) of electrocatalyst, to achieve four-electron transfer mechanism and to exhibit much superior catalytic stability in measurements. This paper will shed light on bio-inspired FeN4-S-C materials for the ORR catalysis in alkaline fuel cells.

Design/methodology/approach

The paper presents a new bio-inspired nano-electrocatalyst for the ORR, which has activity nearby platinum/carbon electrocatalyst. Chlorinated iron phthalocyanine nanoparticles have been used as FeN4 template, which is the key point for the ORR. Bio-inspired nano-electrocatalyst has been fabricated using chlorinated iron phthalocyanine, sodium sulphide and carbon black.

Findings

The particles’ size was 5 nm and electron transfer number was 4.

Research limitations/implications

The catalyst that is used in this method should be weighed carefully. In addition, the solvent should be a saturated solution of NaCl in water.

Practical implications

The method provides a simple and practical solution to improving the synthesis of iron-based catalyst for ORR.

Originality/value

The method for the synthesis of bio-inspired electrocatalyst was novel and can find numerous applications in industries, especially as ORR non-precious metal catalyst.

Details

Pigment & Resin Technology, vol. 46 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 30 August 2019

Muhammad Ali, Long Lin, Saira Faisal, Syed Rizwan Ali and Syed Imran Ali

This paper aims to analyse the let-down stability of the binder-free dispersion of non-printing ink grades of carbon black and to assess the screen-printability of the finished…

Abstract

Purpose

This paper aims to analyse the let-down stability of the binder-free dispersion of non-printing ink grades of carbon black and to assess the screen-printability of the finished inks formulated thereof from these pigment dispersions.

Design/methodology/approach

Binder-free pigment dispersions that were prepared and optimised following a ladder series of experiments (reported in a separate study by the authors) were let-down with three different binders such that inks containing various amounts of a binder were prepared followed by a rheological characterisation immediately after formulation and after four weeks of storage. The screen printability of the inks that displayed considerable stability was assessed, so was the ink film integrity.

Findings

The pigment dispersions that were considered in the present study were generally found to be stable after let-down with different binders. This was indicated by the fact that the finished inks possessed a shear thinning viscosity profiles, after formulation and after storage, in most of the cases. Furthermore, the screen printability of the inks was also found to be good in terms of registration quality of a selected design. The structure of the ink film deposits on uncoated and binder-coated textile fabrics was also highly integrated and free from discontinuities.

Originality/value

Carbon blacks with very low volatile matter content and/or high surface area are generally not considered suitable for use in the formulation of printing inks. This is because of their generally poor dispersability and inability to form dispersions that remain stable over extended periods. This work, which is a part of a larger study by the authors, concerns with the stability of inks formulated from binder-free dispersions of such non-printing ink grades of carbon black. The major advantage of using such pigments in inks is that the required functionality is achieved at considerably low pigment loadings.

Details

Pigment & Resin Technology, vol. 48 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 23 March 2020

Majid Mazhar, Majid Abdouss, Farhad Zarifi and Mojdeh Zargaran

The purpose of this study is to investigate the performance of eight perylene diimide pigments as a hypothetical building facades using EnergyPlus.

Abstract

Purpose

The purpose of this study is to investigate the performance of eight perylene diimide pigments as a hypothetical building facades using EnergyPlus.

Design/methodology/approach

A hypothetical building located in Tehran is modeled using EnergyPlus, and the effectiveness of the pigments was examined. Furthermore, the performance of the pigments was compared with those of common commercial black (carbon black) and red (iron oxide) pigments.

Findings

The results show that the studied black pigments reduce the cooling energy demand up to 37 per cent in comparison with carbon black paint and the red ones, which reduce the value by as much as 32 per cent in comparison to iron oxide.

Originality/value

This study demonstrates that the application of cool paints rather than common paints will significantly reduce the cooling energy demand and subsequent costs.

Details

Pigment & Resin Technology, vol. 49 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 January 1995

Water‐borne coatings Increasing use of water‐borne emulsion coatings for original equipment manufacturers (OEM) and product finishes is requiring greater efficiency in…

Abstract

Water‐borne coatings Increasing use of water‐borne emulsion coatings for original equipment manufacturers (OEM) and product finishes is requiring greater efficiency in coalescing‐aid solvents, an Eastman Chemical Co. representative said at a recent Chicago Society for Coatings Technology meeting. Eastman's Ronald K. Litton said emulsions designed for OEM and industrial applications have higher glass transition temperatures than emulsions used in architectural paints. That requires higher levels of coalescing aid to achieve good film formation. As a result, coalescing‐aid efficiency with a given emulsion system is a key factor, both from environmental (lower‐volatile organic compound (VOC)) and economic standpoints. Several properties should be examined when a coalescing aid is selected for water‐borne emulsion industrial coatings. The formulator should consider the evaporation rate and solubility parameter of the coalescing aid, along with its distribution pattern in a specific emulsion system. Those properties are important in defining the efficiency of a coalescing aid in terms of its ability to lower the minimum film‐forming temperature (MFFT) of an emulsion system. The coalescing aids also must be hydrolytically stable to provide minimum loss of efficiency due to ageing, Litton said. He showed several charts designed to assist formulators in the selection of optimum coalescing aids for emulsion systems. At the same conference, James T.K. Woo of The Glidden Co. discussed the grafting of high‐molecular‐weight epoxy resins with styrene‐methacrylic acid monomers, producing a water‐reducible copolymer. Grafting takes place at the aliphatic carbons of the epoxy resin, according to carbon‐13 NMR spectroscopy. The study was a follow‐up to a paper presented 14 years ago. Woo said recent research indicates that five grafting “peaks” were identified on a 400 megacycle carbon‐13 nuclear magnetic resonance spectroscopy instrument. The paper provided several theoretical calculation on grafting. Three of the graft peaks resulted from grafting at the secondary methylene carbons ‐CH2‐ and two resulted from grafting at the tertiary carbon ‐CH‐. The ratio of grafting at ‐CH2‐ to ‐CH‐appears to be 2.7:1 — lower than the 4:1 ratio of protons present on the aliphatic carbons that are susceptible to hydrogen abstraction leading to grafting. That indicates that the tertiary hydrogen is somwhat more susceptible to grafting than the methylene hydrogens, he said.

Details

Pigment & Resin Technology, vol. 24 no. 1
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 1 January 2014

Haibao Lu, Yongtao Yao and Long Lin

This article aims to present a systematic and up-to-date account of carbon-based reinforcements, including carbon nanotube (CNT), carbon nanofibre (CNF), carbon black (CB), carbon

1633

Abstract

Purpose

This article aims to present a systematic and up-to-date account of carbon-based reinforcements, including carbon nanotube (CNT), carbon nanofibre (CNF), carbon black (CB), carbon fibre (CF) and grapheme, in shape-memory polymer (SMP) for electrical actuation.

Design/methodology/approach

Studies exploring carbon-based reinforcement in SMP composites for electrically conductive performance and Joule heating triggered shape recovery have been included, especially for the principle design, characterisation and shape recovery behaviour, making the article a comprehensive account of the systemic progress in SMP composite incorporating conductive carbon reinforcement.

Findings

SMPs are fascinating materials and have attracted great academic and industrial attention owing to their significant macroscopic shape deformation in the presence of an appropriate stimulus. The working mechanisms, the physico requirements and the theoretical origins of the different types of carbon-based reinforcement SMP composites have been discussed. Current research and development on the fabrication strategies of carbon-based reinforcement SMP composites have been summarised.

Research limitations/implications

A systematic review is to evaluate carbon-based reinforcements in SMPs for electrical actuation and discuss recent developments and future applications.

Practical implications

Carbon-based reinforcements in SMPs can be used as smart deployable space structure in the broad field of aerospace technologies.

Originality/value

To reveal the research and development of utilising CNT, CNF, CB, CF and grapheme to achieve shape recovery of SMP composites through electrically resistive heating, which will significantly benefit the research and development of smart materials and systems.

Details

Pigment & Resin Technology, vol. 43 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Content available
Article
Publication date: 30 August 2013

73

Abstract

Details

Pigment & Resin Technology, vol. 42 no. 5
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 1 August 1990

The International Chemical Company, Columbian Chemicals Company based in Atlanta, Georgia, recently opened its European Central Laboratory at Avonmouth, England. A £1.25 million…

Abstract

The International Chemical Company, Columbian Chemicals Company based in Atlanta, Georgia, recently opened its European Central Laboratory at Avonmouth, England. A £1.25 million investment, it is believed to be the most up‐to‐date facility of its kind servicing the interests of all users of carbon black throughout Europe.

Details

Pigment & Resin Technology, vol. 19 no. 8
Type: Research Article
ISSN: 0369-9420

1 – 10 of over 5000