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1 – 10 of 91Zheng Jin, Yuxi Liu, Xuduo Bai, Xiaomin Ren, Chuanli Qin and Yunhua Wang
The purpose of this paper is to develop a facile method to synthesise nitrogen‐doped carbon aerogels to increase the capacity of supercapacitors.
Abstract
Purpose
The purpose of this paper is to develop a facile method to synthesise nitrogen‐doped carbon aerogels to increase the capacity of supercapacitors.
Design/methodology/approach
Nitrogen‐doped carbon aerogels are prepared as electrode materials through sol‐gel method, using resorcinol, formaldehyde and aniline as raw materials. A series of symmetric supercapacitors are assembled by putting Ni‐MH battery separator between two carbon aerogels electrodes. The electrochemical performances of carbon aerogels and supercapacitors are studied.
Findings
The results show that the optimal molar percentage of aniline in the total molar ratio of resorcinol and aniline is 15 per cent, the mass specific capacitance of which is supposed to be about three times that of RF carbon aerogels. This result could be attributed to the pseudocapacitive effect of nitrogen heteroatoms. Moreover, the nitrogen‐doped carbon aerogels are found to exhibit lower charge transfer resistance at the electrolyte/carbon aerogels interface and lower Warburg impedance.
Practical implications
The supercapacitors can be used in the field of automobile and can solve the problems of energy shortage and environmental pollutions.
Originality/value
For the first time, nitrogen‐doped carbon aerogels are prepared through sol‐gel method, using resorcinol, formaldehyde and aniline as raw materials.
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Jing Yang, Jie Zhong, Fang Xie, Xiaoyang He, Liwen Du, Yaqian Yan, Meiyu Li, Wuqian Ma, Wenxin Wang and Ning Wang
The purpose of this work is to controllably synthesize a carbon aerogel with programmable functionally graded performance via a simple and effective strategy.
Abstract
Purpose
The purpose of this work is to controllably synthesize a carbon aerogel with programmable functionally graded performance via a simple and effective strategy.
Design/methodology/approach
This work uses polyvinyl alcohol (PVA) via the controllable sol-gel, lyophilization, and carbonization approach to achieve a programmable carbon aerogel. This design has the advantages of low raw material and preparation cost, simple and controllable synthetic process and low carbonization temperature.
Findings
The thermal stability and microstructure of PVA aerogel can be controlled by the crosslinking agent content within a certain range. The crosslinking agent content and the carbonization temperature are the key factors for functionally graded programming of carbon aerogels, including microstructure, oxygen-containing functional groups and adsorption performance. The adsorption ratio and adsorption rate of uranium can be controlled by adjusting initial concentration and pH value of the uranium solution. The 2.5%25 carbon aerogel with carbonization temperature of 350 °C has excellent adsorption performance when the initial concentration of uranium solution is 32 ppm at pH 7.5.
Research limitations/implications
As a new type of lightweight nano-porous amorphous carbon material, this carbon aerogel has many excellent properties.
Originality/value
This work presents a simple, low cost and controllable strategy for functionally graded programming of novel carbon aerogel. This carbon aerogel has great potential for application in various fields such as uranium recovery, wastewater treatment, sound absorption and shock absorption.
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Chuanli Qin, Xuduo Bai, Geping Yin, Yuxi Liu, Zheng Jin and Haijun Niu
The purpose of this paper is to show how to obtain a supercapacitor with high specific power (P) and high specific energy (Ep) simultaneously.
Abstract
Purpose
The purpose of this paper is to show how to obtain a supercapacitor with high specific power (P) and high specific energy (Ep) simultaneously.
Design/methodology/approach
The carbon aerogels are obtained by ambient pressure drying method instead of supercritical drying method and carbon aerogels/Ni(OH)2 composites are prepared by in situ polymerisation. A series of asymmetric supercapacitors based on carbon aerogels/Ni(OH)2 composites as positive electrode and activated carbon as negative electrode, respectively, are assembled. The electrochemical performances of carbon aerogels/Ni(OH)2 composites and supercapacitors are studied.
Findings
The results show that the specific capacitance (CP) of carbon aerogels/Ni(OH)2 composites is 584 F/m2. The working potential of supercapacitors could be increased to 1.6V. When the mass ratio of carbon aerogels and Ni(OH)2 is 3:7, the mass ratio of positive electrode and negative electrode is 1:1, the EP and P of the supercapacitor is higher than 10.5 Wh/kg and 578 W/kg, respectively, when the current varies from 50 mA to 100 mA and the attenuation ratio of CP is only 8.3 per cent after 10,000 cycles at 100 mA.
Practical implications
The supercapacitors can be used in the field of automobile engineering and can solve the problems of energy shortage and environmental pollutions.
Originality/value
The supercapacitor based on carbon aerogels/Ni(OH)2 composites as positive electrode and activated carbon as negative electrode is novel and the synthetic properties of the supercapacitor are excellent.
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Pengyang Li, Qiang Chen, Qingyu Peng and Xiaodong He
This paper aims to study the synergistic effect of graphene sponge on the thermal properties and shape stability of composite phase change material (PCM).
Abstract
Purpose
This paper aims to study the synergistic effect of graphene sponge on the thermal properties and shape stability of composite phase change material (PCM).
Design/methodology/approach
Graphene oxide sponge is first prepared from an aqueous solution of graphene oxide by freeze-drying method. The oxidized graphene sponge is reduced by hydrazine hydrate. Finally, use vacuum impregnation method to introduce paraffin into graphene sponge to prepare composite PCM.
Findings
Graphene sponge is used to improve the shape stability of paraffin wax and improves the thermal conductivity and latent heat of the composite PCM. The thermal conductivity increases by 200 per cent and the composite PCM has excellent reliability in 100 melt-freezing cycles.
Research limitations/implications
A simple way for fabricating composite PCM with high thermal conductivity and latent heat which has the potential to be used as thermal storage materials without container encapsulation has been developed by using graphene sponge and paraffin.
Originality/value
The materials and preparation methods with special structure and properties in this paper provide a new idea for the research of PCM, which can be widely used in the fields of energy conversion and storage.
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Viju Subramoniapillai and Govindharajan Thilagavathi
In recent years, oil spill pollution has become one of the main problems of environmental pollution. Recovering oil by means of sorbent materials is a very promising approach and…
Abstract
Purpose
In recent years, oil spill pollution has become one of the main problems of environmental pollution. Recovering oil by means of sorbent materials is a very promising approach and has acquired more attention due to its high cleanup efficiency. Compared to synthetic fibrous sorbents, the use of natural fibers in oil spill cleanups offers several advantages including environmental friendliness, degradable features and cost-effectiveness. Therefore, studies on developing sorbents using natural fibers for oil spill cleanup applications have become a research hotspot.
Design/methodology/approach
This paper reviews the work conducted by several researchers in developing oil sorbents from fibers such as cattail, nettle, cotton, milkweed, kapok, populous seed fiber and Metaplexis japonica fiber. Some featured critical parameters influencing the oil sorption capacity of fibrous substrates are discussed. Oil sorption capacity and reusability performance of various fibers are also discussed. Recent developments in oil spill cleanups and test methods for oil sorbents are briefly covered.
Findings
The main parameters influencing the oil sorption capacity of sorbents are fiber morphological structure, fiber density (g/cc), wax (%), hollowness (%) and water contact angle. An extensive literature review showed that oil sorption capacity is highest for Metaplexis japonica fiber followed by populous seed fiber, kapok, milkweed, cotton, nettle and cattail fiber. After use, the sorbents can be buried under soil or they can also be burned so that they can be vanished from the surface without causing environmental-related issues.
Originality/value
This review paper aims to summarize research studies conducted related to various natural fibers for oil spill cleanups, fiber structural characteristics influencing oil sorption and recent developments in oil spill cleanups. This work will inspire future researchers with various knowledge backgrounds, particularly, from a sustainability perspective.
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Yuming Guan, Jingbo Mu, Hongwei Che, Xiaoliang Zhang and Zhixiao Zhang
The purpose of this study is to design carbon electrode materials for high performance electric double-layer capacitors (EDLCs) with pores that are large enough and have suitable…
Abstract
Purpose
The purpose of this study is to design carbon electrode materials for high performance electric double-layer capacitors (EDLCs) with pores that are large enough and have suitable pore size distribution for the electrolyte to access completely to improve EDLCs’ electrochemical performance.
Design/methodology/approach
This study develop an improved traditional KOH activation method, and a series of micro-meso hierarchical porous carbons have been successfully prepared from phenol formaldehyde resin by combining polyethylene glycol (PEG) and conventional KOH activation.
Findings
As evidenced by N2 adsorption/desorption tests, the obtained samples present Types IV and I-IV hybrid shape isotherms compared with KOH-activated resin (typical of Type I). The sample AC2-7-1, which the addition quantity of PEG is 25 per cent PF (weight ration) activated at 700? For 1 h is considered as the optimum preparation condition. It exhibits the highest specific capacitance value of 240 F/g in 30 wt% KOH aqueous electrolytes because of its higher specific surface area (2085 m2/g), greater pore volume (1.08 cm3/g) and the maximum mesoporosity (43 per cent). In addition, the capacity decay of this material is only 3.1 per cent after 1000 cycles.
Originality/value
The materials that are rich in micropores and mesopores show great potential in EDLC capacitors, particularly for applications where high power output and good high-frequency capacitive performances are required.
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Abstract
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Qiang Li, Jiahuan Du, Xugang Zhang, Chuanli Qin, Zheng Jin and Xuduo Bai
The purpose of this paper is to develop porous nitrogen-enriched carbon (NC-U) with high nitrogen concentration and high specific capacitance (Cpe) as the electrode material for…
Abstract
Purpose
The purpose of this paper is to develop porous nitrogen-enriched carbon (NC-U) with high nitrogen concentration and high specific capacitance (Cpe) as the electrode material for supercapacitors.
Design/methodology/approach
NC-U was obtained by carbonization of polyvinylpyrrolidone/melamine formaldehyde resin (PVP/MF) with different contents of urea. In comparison, NC-K was also prepared by the KOH activation method. A series of asymmetric supercapacitors with NC as a negative electrode was assembled. The composition, microstructure and electrochemical properties of NC and their supercapacitors were studied.
Findings
The results show that NC-U shows irregular particles with a porous honeycomb structure. High Cpe was obtained for urea-treated NC-U because of the improvement of nitrogen, conductivity and specific surface area (S BET ). NC-U50 with 13.15 per cent at nitrogen has the highest Cpe of 148.53 F/g because of the highest concentration of N-6 and N-5. NC-K with higher S BET has lower Cpe than NC-U50 because of its lower nitrogen concentration. When the specific power of the supercapacitor with NC-U50 as a negative electrode is 1,565.56 W/kg, its specific energy is still 4.35 Wh/kg. There is only 5.9 per cent decay in Cpe over 1,000 cycles.
Research limitations/implications
NC-U is a suitable electrode material for supercapacitors, which can be used in the field of electric vehicles to solve the problems of energy shortage and environmental pollutions.
Originality/value
Porous NC-U based on PVP/MF/urea composites with high nitrogen concentration and Cpe is novel, and it owns good electrochemical properties.
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The purpose of this paper is to describe a range of artificial muscle and soft gripping technologies for robotic applications.
Abstract
Purpose
The purpose of this paper is to describe a range of artificial muscle and soft gripping technologies for robotic applications.
Design/methodology/approach
Following a short introduction, this paper first discusses the role of air muscles and other pneumatic actuation technologies. It then considers electroactive polymer and shape‐memory alloys and finally discusses the prospects for various classes of electrohydrodynamic fluids.
Findings
This paper shows that a technologically diverse range of novel actuation techniques exist, or are under development, which can act as artificial muscles and soft grippers. They are based on pneumatics, shape changing materials and electrohydrodynamic fluids and have prospects to impart robots with improved or unique capabilities.
Originality/value
The paper provides an insight into developments in artificial muscle and soft gripping technologies. These are expected to play a vital role in future robot generations.
Details
Keywords
Jiahuan Du, Qiang Li, Chuanli Qin, Xugang Zhang, Zheng Jin and Xuduo Bai
– The purpose of this paper is to develop nitrogen-enriched carbon (NC) with high conductivity and specific capacitance as electrode materials for supercapacitors.
Abstract
Purpose
The purpose of this paper is to develop nitrogen-enriched carbon (NC) with high conductivity and specific capacitance as electrode materials for supercapacitors.
Design/methodology/approach
Graphene oxide (GO) was synthesized by the modified Hummers–Offeman method. NC was synthesized by carbonization of melamine formaldehyde resin/graphene oxide (MF/GO) composites. Supercapacitors based on Ni(OH)2/Co(OH)2 composites as the positive electrode and NC as the negative electrode were assembled. The electrochemical performances of NC and supercapacitors are studied.
Findings
The results show that obtained NC has high nitrogen content. Compared to NC-GO0 without GO, high conductivity and specific capacitance were obtained for NC with GO due to the introduction of layered GO. The presence of pseudocapacitive interactions between potassium cations and the nitrogen atoms of NC was also proposed. When the weight ratio of GO to MF is 0.013:1, the obtained NC-GO3 has the highest specific capacitance of 154.07 F/g due to GO and its highest content of N-6. When the P of the asymmetric supercapacitor with NC-GO3 as the negative electrode is 1,326.70 W/kg, its Cps and Ep are still 23.84 F/g and 8.48 Wh/Kg, respectively. There is only 4.4 per cent decay in Cps of the supercapacitor over 1,000 cycles.
Research limitations/implications
NC is a suitable electrode material for supercapacitors. The supercapacitors can be used in the field of automobiles and can solve the problems of energy shortage and environmental pollutions.
Originality/value
NC based on MF/GO composites with high nitrogen content and conductivity was novel and its electrochemical properties were excellent.
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