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This study aims to report the CO₂ corrosion performance of 3Cr steel and 3Cr2Al steel and reveal the role of aluminum in mitigating corrosion of low-Cr steel.

Aluminum was added to 3Cr steel to prepare a new type of 3Cr2Al steel, and the effect of aluminum on the corrosion resistance of pipeline steel was studied using morphology observation and composition analysis, weight loss tests and electrochemical test.

In the CO₂/O₂ coexistence environment, the average corrosion rate of the 3Cr2Al steel was obviously lower than that of the 3Cr steel. The addition of aluminum expanded the range of prepassivation, and the dynamic potential polarization curve of 3Cr2Al steel showed duplex prepassivation phenomena. 3Cr steel underwent severe local corrosion, and 3Cr2Al steel underwent uniform corrosion. The addition of aluminum contributed to the formation of a dense corrosion product layer and greatly reduced the localized corrosion sensitivity.

The studies on CO₂ corrosion of aluminum containing low-Cr steel are quite rare. This study clarifies the role of aluminum by comparing the corrosion behavior of 3Cr2Al and 3Cr steel. The effect of aluminum on the growth of corrosion product film was discussed, and the duplex prepassivation phenomena of Cr and Al were revealed.

The salinity of the oilfield produced water has a significant effect on steel corrosion. The purpose of this paper is to study the influence of salinity on corrosion behavior of X60 steel and it also provides basic for material selection of gas wells with high salinity.

The weight loss experiment was carried out on steel with high temperature and high pressure autoclave. The surface morphology and composition of corrosion scales were studied by means of scanning electron microscopy, energy dispersive spectroscopy and X-ray diffractometry.

The results show that as salinity increases, the corrosion rate of X60 steel will gradually experience a rapid decline stage and then a slow decline stage. X60 steel is mainly exhibiting uniform corrosion in the first rapid decline stage and pitting corrosion in the second slow decline stage. The increase in salinity reduces gas solubility, which, in turn, changes the morphology and density of the corrosion scales of X60 steel. At low salinity, loose iron oxides generated on the surface of the steel, which poorly protects the substrate. At high salinity, surface of the steel gradually forms protective films. Chloride ions in the saline solution mainly affect the structure of the corrosion scales and initiate pitting corrosion. The increased chloride ions lead to more pitting pits on the surface of steel. The recrystallization of FeCO₃ in pitting pits causes the corrosion scales to bulge.

The investigation determined the critical concentration of pitting corrosion and uniform corrosion of X60 steel, and the new corrosion mechanism model was presented.