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1 – 10 of 32Mohsen Sajadnia, Sajjad Dehghani, Zahra Noraeepoor and Mohammad Hossein Sheikhi
The purpose of this study is to design and optimize copper indium gallium selenide (CIGS) thin film solar cells.
Abstract
Purpose
The purpose of this study is to design and optimize copper indium gallium selenide (CIGS) thin film solar cells.
Design/methodology/approach
A novel bi-layer CIGS thin film solar cell based on SnS is designed. To improve the performance of the CIGS based thin film solar cell a tin sulfide (SnS) layer is added to the structure, as back surface field and second absorbing layer. Defect recombination centers have a significant effect on the performance of CIGS solar cells by changing recombination rate and charge density. Therefore, performance of the proposed structure is investigated in two stages successively, considering typical and maximum reported trap density for both CIGS and SnS. To achieve valid results, the authors use previously reported experimental parameters in the simulations.
Findings
First by considering the typical reported trap density for both SnS and CIGS, high efficiency of 36%, was obtained. Afterward maximum reported trap densities of 1 × 1019 and 5.6 × 1015 cm−3 were considered for SnS and CIGS, respectively. The efficiency of the optimized cell is 27.17% which is achieved in CIGS and SnS thicknesses of cell are 0.3 and 0.1 µm, respectively. Therefore, even in this case, the obtained efficiency is well greater than previous structures while the absorbing layer thickness is low.
Originality/value
Having results similar to practical CIGS solar cells, the impact of the defects of SnS and CIGS layers was investigated. It was found that affixing SnS between CIGS and Mo layers causes a significant improvement in the efficiency of CIGS thin-film solar cell.
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Alexandra Waluszewski, Enrico Baraldi and Andrea Perna
Contemporary innovation policy investments rests on the assumption that the main problematic interface is the one between the non-business developing setting and a rather…
Abstract
Purpose
Contemporary innovation policy investments rests on the assumption that the main problematic interface is the one between the non-business developing setting and a rather friction-free producer and user setting. Given a business landscape characterized by interdependencies, any innovation attempt will be faced with complex interfaces also within and among all these settings. The purpose of this paper is to shed light over this issue through the investigation of the interface between policy and a specific innovation journey. The attention is directed to the creation and distribution of social-material values; and the translation of these values into a monetary dimension.
Design/methodology/approach
To fulfill this aim the authors utilize an empirical study on the commercialization of university research results in the field of solar power technology, based on the ARA model as a conceptual and methodological foundation, with a focus on the establishment of resource combinations, activity links and actor bonds in the involved developing, producing and using settings. In order to pin-point the creation of social-material values and the establishment of a monetary dimension the authors used a model adapted from Håkansson and Olsen (2015).
Findings
From a national policy perspective, the transnational nature of innovation processes and the connectedness of resources across different, often far-away places, entail a loss of control on the social-material and monetary benefits of innovation; even more so if the policy of one country stands against that of another country. Still, not only policy but also representatives for academic research and business seem to consider the transnational aspect as an exception.
Research limitations/implications
Due to that the embedding in the user setting did not occur as expected; with the Swedish focal firm as main interface, but from a Chinese firm that the authors did not have access to, the main focus is on the developing and the producing setting, while the embedding in the user setting is covered through indirect information.
Practical implications
The role that established production structures have for the embedding of innovations into producing and using settings seems to be neglected in policy circles – although these have a strong impact on the creation of social-material value and a monetary flow.
Social implications
See practical implication.
Originality/value
The paper underlines the impact of interfaces with established production structures for the creation of social-material value and monetary flow – and for transnational dimension of the innovation journey.
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Ark Ifeanyi, Patrick Isherwood and Aminat Olawumi Abdul-Lateef
Even though copper–tungsten has shown signs of potentials, relatively little is currently known about its appropriateness for photovoltaic application. This paper aims to evaluate…
Abstract
Purpose
Even though copper–tungsten has shown signs of potentials, relatively little is currently known about its appropriateness for photovoltaic application. This paper aims to evaluate the suitability of copper-tungs oxides as photovoltaic absorbers while investigating the consequences of oxygen content variation.
Design/methodology/approach
Using profilometry, Hall measurements, Seebeck test and spectrophotometry, grown samples were defined. Samples of 5 standard cubic centimeters per minute (sccm) and 7 sccm exhibited appropriate characteristics and were further tested using personal computer one dimension (PC1D) computational simulation at the system stage. To grow materials with an average thickness below 0.45 µm, magnetron co-sputtering was used. Three sample sets, varied by oxygen flow rate, were made with flow rates of 5sccm, 7sccm and 9sccm, respectively.
Findings
Some samples proved to be effective absorbers, using a cadmium telluride device as the criterion of output calculation, with one sample chosen as ideal for each type of flow rate. For the chosen samples, an optimum thickness was also obtained, i. It was discovered that thinner cells, optimal for both groups with 0.6 µm, performed better to than other thicknesses.
Research limitations/implications
The material also demonstrated prospects for applications in window layers, but more needs to be known.
Practical implications
Thin film material properties and their operating processes are relatively complex, so it is important to find simple and cost-effective ways to forecast performance. While relatively new, numerical modeling has proven to be very useful in defining the critical properties of thin film devices, thereby helpful for predictions of performance. Solar cell capacitance simulator one dimension, amorphous semiconductor analysis, personal computer one dimension (PC1D), analysis of micro-electronic and photonic structures and automat for simulation for heterostructures (33) are several common models in the thin film industry. Due to its availability and relative ease of use, PC1D was used in this project.
Social implications
As the search for the balance among performance, cost, reliability and availability continue, more absorber components continue to evolve, notably from the chalcogenides. Because of their ability to absorb light, ternary transition metal chalcogenides are useful in the production of hydrogen and in the energy storage sector, as well as in the production of light-emitting diodes and solar photovoltaic (PV).
Originality/value
There are several methods for the manufacture of copper–tungsten alloys, but the process of combinatorial sputtering of magnetrons provides satisfactory results even for the manufacture of various other materials. Cu2WSe4, an excellent alternative to sputtering, is one of the very few copper–tungsten selenide materials tested, synthesized by hot simple injection to have strong crystallinity and lacks impurity. The optical properties of colloidal Cu2WSe4 show that Schottky diode–like behaviors are present in the material, suggesting its potential for use in solar cells. Cu-W alloys could have a lot more to give the PV industry, by all indications. Further exploration of the oxides by this work is thus justified. Transparent conducting oxides, interfacial layers or charge-transporting compounds are commonly used as transition metal oxides. Nevertheless, as absorbers, metal oxides such as BiFeO3 and the traditionally highly studied Cu2O have been tested, with Cu2O showing a conversion efficiency of up to 10% under particular conditions. This displays strong electronic and optical properties, so there might be some possibility of studying other PV absorption metal oxides. The optical properties of colloidal Cu2WSe4 show that Schottky diode–like behaviors are present in the material, suggesting its potential for use in solar cells.
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Aleksandra Drygała, Marek Szindler, Magdalena Szindler and Ewa Jonda
The purpose of this paper is to improve the efficiency of dye-sensitized solar cells (DSSCs) which present promising low-cost alternative to the conventional silicon solar cells…
Abstract
Purpose
The purpose of this paper is to improve the efficiency of dye-sensitized solar cells (DSSCs) which present promising low-cost alternative to the conventional silicon solar cells mainly due to comparatively low manufacturing cost, ease of fabrication and relatively good efficiency. One of the undesirable factor in DSSCs is the electron recombination process that takes place at the transparent conductive oxide/electrolyte interface, on the side of photoelectrode. To reduce this effect in the structure of the solar cell, a TiO2 blocking layer (BL) by atomic layer deposition (ALD) was deposited.
Design/methodology/approach
Scanning electron microscope, Raman and UV-Vis spectroscopy were used to evaluate the influence of BL on the photovoltaic properties. Electrical parameters of manufactured DSSCs with and without BL were characterized by measurements of current-voltage characteristics under standard AM 1.5 radiation.
Findings
The TiO2 BL prevents the physical contact of fluorine-doped tin oxide (FTO) and the electrolyte and leads to increase in the cell’s overall efficiency, from 5.15 to 6.18%. Higher density of the BL, together with larger contact area and improved adherence between the TiO2 layer and FTO surface provide more electron pathways from TiO2 to FTO which facilitates electron transfer.
Originality/value
This paper demonstrates that the introduction of a BL into the photovoltaic device structure is an important step in technology of DSSCs to improve its efficiency. Moreover, the ALD is a powerful technique which allows for the highly reproducible growth of pinhole-free thin films with excellent thickness accuracy and conformality at low temperature.
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In this paper, it can be seen from AFM images of the as-deposited ZnO and CZO films, and the particle size and shape are not clear, while by increasing annealing temperature, they…
Abstract
Purpose
In this paper, it can be seen from AFM images of the as-deposited ZnO and CZO films, and the particle size and shape are not clear, while by increasing annealing temperature, they become distinguishable. By increasing temperature to 600°C, ZnO and CZO, CAZO and aluminum-doped zinc oxide (AZO) films particles became almost spherical. Due to high content of Cu in CZO target, and of Al in AZO target which was 5% weight ratio, doping plays a great role in the subject. Therefore, the annealing processing strongly affect the size and the shape of nanoparticles.
Design/methodology/approach
In this paper, the authors tried to study, in detail, nobel optical characterizations of ZnO films doped by transition metals in different annealing temperature. The authors found that the values of skin depth, optical density, electron–phonon interaction, steepness parameter, band tail width, direct and indirect carriers transitions and the dissipation factor, free carriers density and roughness of films affect the optical properties, especially the optical absorptions of ZnO films doped by transition metals. Also these properties were affected by annealing temperatures. The authors also found that topography characterizations strongly were affected by these parameters.
Findings
The CZO films have maximum value of coordination number ß, with considering NC = 4, Za = 2, Ne = 8. The CZO films annealed at 500 °C have maximum value of optical density. The as-deposited CAZO films have maximum value of steepness parameters in about of 0.13 eV. The as-deposited AZO films have maximum value of dispersion energy Ed in about of 5.75 eV. Optical gap and disordering energy plots of films can be fitted by linear relationships Eg = 0.49 + 0.2 EU and Eg = 0.52 + 0.5 EU, respectively.
Originality/value
With considering Nc = 4, Za = 2, Ne = 8 for ZnO films, coordination number ß has maximum value of 0.198. CZO nanocomposites films annealed at 500°C have maximum value of optical density. Different linear fitting of ln (α) for films were obtained as y = Ax + B where 5<A < 17 and 5<B < 12. As-deposited CAZO nanocomposites films have minimum value of electron phonon interaction in about of 4.91 eV. Optical gap and disordering energy plots can be fitted by linear relationships Eg = 0.49 + 0.2 EU and Eg = 0.52 + 0.5 EU for as-deposited films and films annealed at 500°C, respectively. Steepness parameters of as-deposited CAZO nanocomposites films have maximum value of 0.13 eV. Dispersion energy Ed for as-deposited AZO nanocomposites films has maximum value of 5.75 eV.
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The aim of this paper is to provide a review of the present‐day and anticipated future uses of lasers in the production of solar cells.
Abstract
Purpose
The aim of this paper is to provide a review of the present‐day and anticipated future uses of lasers in the production of solar cells.
Design/methodology/approach
Following a brief introduction to photovoltaics (PV), this paper first describes the two main types of solar cell, crystalline silicon and thin film and then discusses the use of lasers in their manufacture. Finally, future developments are considered.
Findings
The paper shows that lasers are used in the manufacture of both crystalline silicon and thin film PV. Applications are many and varied, e.g. edge isolation, hole drilling, border deletion and selective doping but few are yet adopted universally across the industry. Significant future prospects exist for laser‐based processes, as solar cell manufacturers seek to improve conversion efficiency and reduce production costs.
Originality/value
The paper shows that lasers play a vital role in solar cell manufacture and many additional applications will arise as photovoltaic technology is further developed.
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Assiya Haddout, Abderrahim Raidou and Mounir Fahoume
The purpose of this paper is to study the effect of individual layers of cadmium telluride (CdTe) solar cell to improve the efficiency of the photovoltaic cell.
Abstract
Purpose
The purpose of this paper is to study the effect of individual layers of cadmium telluride (CdTe) solar cell to improve the efficiency of the photovoltaic cell.
Design/methodology/approach
To improve the performances of CdTe thin-film solar cells, the thickness of CdTe and cadmium sulfide (CdS) have been modified separately. High-efficiency ultra-thin CdTe solar cell with ZnTe layer as back surface field (BSF) was achieved. The CdTe solar cell is under AM1.5 g illumination using a one-dimensional (1-D) model, i.e. personal computer one dimensional (PC1D).
Findings
The highest conversion efficiency of about 15.3 per cent was achieved for ultrathin CdTe solar cell with a ZnTe BSF layer. The results of simulation were compared with experimental and analytical results by other researchers.
Originality/value
In this paper, according to the authors’ knowledge ZnO:Al/CdS/CdTe/ZnTe is simulated by PC1D model for the first time and is compared with experimental result (ZnO:Al/CdS/CdTe). The results show a suitable performance.
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Kuei-Kuei Lai, Hsueh-Chen Chen, Yu-Hsin Chang, Vimal Kumar and Priyanka C. Bhatt
This study aims to propose a methodology by integrating three approaches, namely, internal core technology, external knowledge flow and industrial technology development to help…
Abstract
Purpose
This study aims to propose a methodology by integrating three approaches, namely, internal core technology, external knowledge flow and industrial technology development to help companies improve their decision-making quality for technology planning and enhance their research and development (R&D) portfolio efficiency.
Design/methodology/approach
The primary focus of this study is thin-film solar technology and patent data is retrieved from the United States Patent and Trademark Office (USPTO) database. This study presents a methodology based on the proposed integrated analysis method, constructed with patent indicators, centrality analysis of social networks and main path analysis.
Findings
The results of this study can be itemized as – the core technological competency: companies involved in two specific technology fields have lower strength in R&D portfolio than leading companies with single-core technology. Knowledge flow: most companies in a network are knowledge producers/absorbers and technological development: diverse source and sink nodes were identified in the global main path during 1997-2003, 2004-2010 and 2011-2017.
Research limitations/implications
Latecomer companies can emulate leaders’ innovation and enhance their technological competence to seek niche technology. Using the global main path, companies monitor outdated technologies that can be replaced by new technologies and aid to plan R&D strategy and implement appropriate strategic decisions avoiding path dependency.
Originality/value
The knowledge accumulation process helps in identifying the change of position and the role of companies; understanding the trend of industrial technology knowledge helps companies to develop new technology and direct strategic decisions. The novelty of this research lies in the integrated approach of three methods aiding industries to find their internal core technical competencies and identify the external position in the competitive market.
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Susan Liscouet-Hanke, Arash Shafiei, Luiz Lopes and Sheldon Williamson
This paper aims to analyze the viability of a solar power system as a supplemental power source for commercial and business aircraft.
Abstract
Purpose
This paper aims to analyze the viability of a solar power system as a supplemental power source for commercial and business aircraft.
Design/methodology/approach
First, a model is established to estimate the potential available power from suitable aircraft surfaces for various meteorological conditions, ground and flight mission characteristics. A proposed aircraft system architecture and an associated parametric conceptual sizing model are presented. This supplemental solar power system sizing model is integrated into an aircraft multidisciplinary design optimization environment to evaluate the aircraft-level impact on mission fuel burn. A parametric study for a business jet aircraft is performed to analyze various solar cell types and power densities for converters. Trade-off studies are performed between efficiency and weight.
Findings
Considering today’s efficiency and power-to-weight ratio of the system components, overall fuel burn reduction can be achieved. Therefore, the technology development work can start now to target short to mid-term applications. In addition, promising system integration scenarios are identified, such as the use of solar power for autonomous operation of the air conditioning system on ground, which yield potential further benefit. In conclusion, a supplemental solar power system seems a promising candidate for more efficient aircraft operation.
Originality/value
The presented novel supplemental solar power system architecture concept and its foreseen aircraft integration show potential benefits for near term applications. The results show that the break even for this technology is already reached and therefore build the foundation to further investigate the technology integration challenges. Clear directions for future research and development are outlined enabling the advancement of the technology readiness level.
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