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The purpose of this paper is to investigate three Arylfuranylnicotinamidine derivatives against corrosion of carbon steel (C-steel) in 1.0 M HCl by chemical and electrochemical means. The inhibition efficiency (%IE) increases with increasing the dose of inhibitors. The tested compounds exhibited improved performance at elevated temperature, with %IE reaching 93 percent at 21 µM. Tafel polarization method revealed that the tested compounds act as mixed-type inhibitors. The inhibition action was rationalized due to chemical adsorption of inhibition molecules on C-steel surface following Temkin’s isotherm. Surface examination was carried out by AFM and FTIR techniques. Further, theoretical chemical approaches were used to corroborate the experimental findings.

Experimental and computational methods were applied to investigate the efficiency of these new compounds. These studies are complemented with spectral studies and surface morphological scan by AFM. The theoretical results indicate good correlation with experimental findings.

The tested derivatives are promising corrosion inhibitors for C-steel in the acid environment. The molecular scaffold of this class of compounds can be used to design new highly efficient inhibitors by screening its activity by modeling studies.

The studied compounds are safe inhibitors and greatly adsorbed on Fe surface. The action of compounds is enhanced with temperature, which means these compounds can be used in higher temperature systems. The new compounds are effective at very low concentration.

The aim of this work was to investigate how Andrographis paniculata (Burm.f.) Wall.ex Nees extract affected the corrosion of low-carbon (C) steel in 0.1M HCl.

The Andrographis paniculata (Burm.f.) Wall.ex Nees was extracted into distilled water at 70°C for 1 h. The corrosion inhibition efficiency of the extract was determined in 0.1M HCl using weight loss measurements, potentiodynamic polarization and electrochemical impedance spectroscopy. The effects of extract concentrations and of temperature were investigated.

The Andrographis paniculata (Burm.f.) Wall.ex Nees extract could inhibit the corrosion process of low-C steel in 0.1M HCl. With the extract concentration of 1 g/l, an inhibition efficiency of 96.3 per cent was obtained. The extract acted as an anodic inhibitor. The adsorption process of the extract was physisorption and it followed the Langmuir adsorption isotherm.

This paper revealed that Andrographis paniculata (Burm.f.) Wall.ex Nees cultivated in Thailand, which was extracted using a simple and environmentally friendly method, could act as a very good green corrosion inhibitor for low-C steel in 0.1M HCl solution.

An experimental investigation for developing structure-property correlations of hot-rolled E410 steels with different carbon contents, i.e. 0.04wt.%C and 0.17wt.%C metal active gas (MAG) and cold metal transfer (CMT)-MAG weldments was undertaken.

Mechanical properties and microstructure of MAG and CMT-MAG weldments of two E410 steels with varying content of carbon were compared using standardized mechanical testing procedures, and conventional microscopy.

0.04wt.%C steel had strained ferritic and cementite sub-structures in blocky shape and large dislocation density, while 0.17wt.%C steel consisted of pearlite and polygonal ductile ferrite. This effected yield strength (YS), and microhardness being larger in 0.04wt.%C steel, %elongation being larger in 0.17wt.%C steel. Weldments of both E410 steels obtained with CMT-MAG performed better than MAG in terms of YS, ultimate tensile strength (UTS), %elongation, and toughness. It was due to low heat input of CMT-MAG that resulted in refinement of weld metal, and subzones of heat affected zone (HAZ).

A substantial improvement in YS (∼9%), %elongation (∼38%), and room temperature impact toughness (∼29%) of 0.04wt.%C E410 steel is achieved with CMT-MAG over MAG welding. Almost ∼10, ∼12.5, and ∼16% increment in YS, %elongation, and toughness of 0.17wt.%C E410 steel is observed with CMT-MAG. Relatively low heat input of CMT-MAG leads to development of fine Widmanstätten and acicular ferrite in weld metal and microstructural refinement in HAZ subzones with nearly similar characteristics of base metal.

To make clear that C‐steel can differ very much in corrosion resistance under practical conditions only because of differences in chemical composition of the steels.

In the electricity generating industry, “mild” (i.e. “plain carbon”) and low‐alloyed steels are used in huge quantities, for instance, in boilers, steam generators, heat recovery boilers and waste incineration boilers. The resistance to strain induced corrosion cracking (SICC) was determined by measuring the “repassivation” behaviour of the steels at freshly ground surfaces with an electrochemical technique. The corrosion current measured with time was used to calculate the cracking rates of a compact tension specimen.

A correlation was found between chemical composition, corrosion resistance to SICC and experiences under practical conditions. The results of early‐published papers on boiler corrosion (testing in FeCl₂ solutions), erosion corrosion (testing in wet steam at 20 bar), nitrate stress corrosion cracking (testing in NH₄NO₃ solutions) and SICC together with those originating from in‐service failures, were compiled into a reference database. This paper is a compilation of this work too.

The database and formulas presented make clear there is often a direct correlation between chemical composition of ordinary C‐steel and mentioned types of corrosion failures. The paper is of importance to designers, failure analysts and researchers.

The purpose of this study is to inspect the corrosion inhibition of API N80 steel pipelines in uninhibited solution and inhibited with a synthesized surfactant compound [N-(3-(dimethyl octyl ammonio) propyl) palmitamide bromide] (DMDPP), which is prepared through a simple and applicable method.

Weight loss was inspected at five different temperatures of 25°C, 30°C, 40°C, 50°C and 60°C Potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation were used at room temperature. Density functional theory was used to study the relation between the molecular structure and inhibition theoretically.

Adsorption of the prepared DMDPP fits the Langmuir isotherm model. The inhibition efficiency of the prepared DMDPP amphipathic inhibitor is directly proportional to temperature increase. Polarization results reveal that the investigated DMDPP amphipathic compound behaves as a mixed-type inhibitor. EIS spectra produced one individual capacitive loop.

The originality is the preparation of cationic surfactants through a simple method, which can be used as corrosion inhibitors in oil production. The synthesized inhibitors were prepared from low-price materials. The work studied the behavior of the synthesized surfactants in inhibiting the corrosion of the steel in an acidic medium. Electrochemical and theoretical studies were presented, besides gravimetric and surface examination.

Introduction Plastic deformation of steel causes crystalline imperfections such as increased dislocation density, vacancies, cracks and microvoids which, in turn, influence dissolution and transport of hydrogen in traps. The increased dislocation density and dislocation pile‐ups against cementile lamella or non‐metallic inclusions lead to microcrack formation. The dislocation pile‐ups are mobile under stress. Transport of hydrogen by dislocation under stress can be expected but the temperature should be neither so high as to force the hydrogen to leave the dislocation sites nor so low that the hydrogen cannot diffuse into the dislocation sites.

THE rules for the 1935 Deutsch de la Meurthe Cup Race remained almost identical with those of 1933 and 1934. Briefly, the contest was open to all types of land “aerodynes”; the only limitation being that the total capacity of the engine (or engines) remained under 8 litres (488·20 cu. in.). In other directions, designers were left with an absolutely free hand—the usual Certificate of Airworthiness even being dispensed with. To avoid the participation of machines of doubtful characteristics, each competitor had to qualify between April 2 and May 2 by passing successfully the following tests: a flight of 500 km. (311 miles) in a closed circuit at a speed exceeding 300 k.p.h. (186·5 m.p.h.)—against 250 k.p.h. (155·5 m.p.h.) last year. In addition, take‐off and landing had to be performed in less than 500 metres (1,640 ft.) over a “screen” 1 metre (3·28 ft.) high—against 550 metres (1,801 ft.) last year. Actually, the “screen” took the form of two parallel ropes set at the required height and separated by an interval of 50 metres (164 ft.), so as to ensure correct execution of the test. The wind velocity had to be under 6 metres per second (19·7 f.p.s.) during the take‐off and landing tests.

In the present work, the authors carried out siliconizing, chromizing, aluminizing and chrome‐aluminizing of mild steel in a pack cementation process with a view to evaluate the optimum experimental conditions to obtain satisfactory coatings which possess high resistance to oxidation. It is visualised to adopt some of the experimental conditions in later experiments where diffusion coating treatments are carried out using pastes containing the various diffusion elements. Some of the findings of the authors in siliconizing, chromizing, aluminizing and chrome‐aluminizing of mild steel in pack process are reported. It was observed that there is excess grain growth during siliconizing by the pack process and the coatings are porous and lack good oxidation resistance compared to coatings in the gas phase carried out by other workers. Chromized, aluminized and chrome‐aluminized samples are superior to 18/8 stainless steel and even Inconel in their oxidation resistance. Chromizing followed by aluminizing makes the coating layer less brittle as observed by the micro hardness measurements across the layer and hence chrome‐aluminizing will improve the spoiling resistance of the coatings.

The purpose of this study is to critically analyze the properties of quenched and tempered steel samples. Austenite to martensite transformation of steel is a common process in any steel industry. Water quenching is the best suited technique to convert the steel into martensitic structure. Although quenched products are very hard, yet they possess brittleness. Due to which, their industrial applications become very limited. To avoid this problem, tempering of the martensite is usually done to achieve the required combination of hardness and toughness.

The present work deals with comparative analysis of mechanical properties and microstructural behavior of quenched and tempered steel samples. For the purpose, a low carbon steel (0.2%-C) was taken under study. Quenching was done in water, and tempering was done in atmospheric air. Four different mechanical properties such as tensile strength, toughness, hardness and shear strength were analyzed on steel samples that underwent through two different above-mentioned heat treatment processes.

An improvement in all the four mechanical properties was reported after tempering the quenched products. Also, the microstructural images of quenched and tempered specimens showed a good corroboration with mechanical properties.

A significant improvement in mechanical properties was reported in tempered specimens. Also, there was a strong corroboration between mechanical properties and microstructural attributes. A clear view of needle-shaped martensite and lamellar-shaped pearlite was observed in water-quenched and tempered specimens, respectively.

Corrosion cracking A metal fails due to corrosion fatigue if it cracks while being subjected to repeated or alternating tensile stresses in a corrosive environment. If the corrosive environment is removed, the metal will not fail through fatigue, even after a very high number of cycles, providing the tensile stress is below the fatigue limit.