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Water-based graphite lubricants have good lubricity in the process of metal forming, especially for hot-rolling seamless pipe. Although the use of water as a working fluid system instead of conventional mineral oil has many advantages for the fuel consumption, post cleaning and a new type of lubricant, the graphite contaminated the machine and workers for its physical properties. From the global environmental protection viewpoint, it is urgent to develop a kind of benign material.

Magnesium hydroxide which has the average particle size of 10 μm was chosen as a base material without further modification and pretreatments. On the HT-1000 high-temperature tribometer, the influence of temperature and lubricant materials on the friction coefficient was studied. The tribological performance at 900^°C provided evidence under high temperature for exploring a new lubricant material.

Tap water-based brucite lubricant will open a new chapter in the industrial lubrication, effectively avoiding many unfavorable factors caused by graphite lubrication, such as conductivity, pollution and energy loss. Meanwhile, it expanded the application of brucite as flame-retardant agent, catalyst, water treatment agent and so on.

It is a new and environmental lubricant to tap water-based brucite lubricant. And specially, the preparation process of lubricant is simple and economical.

In spite of the high interest in thermally sprayed aluminium (TSA) to protect offshore structures, pipelines, risers, etc., data correlating the exposure of TSA-coated steel in hot seawater to its performance are lacking. No information is available on the performance of TSA in hot seawater, especially when damaged. This paper aims to address this knowledge gap and report the corrosion performance of damaged TSA on carbon steel exposed to boiling synthetic seawater for different periods (up to 5,000 h). It also attempts to understand the mechanism of formation of calcareous deposits in boiling synthetic seawater by using various characterisation tools.

Twin wire arc spray was used to coat carbon steel specimens with commercially pure aluminium. Holiday was drilled on the coated surface to expose the underlying steel, amounting to 4 per cent of the specimen surface area. These specimens were then exposed to boiling synthetic seawater for different periods: 2, 68, 188, 335 and 5,000 h. During exposure, the potential was monitored (vs standard calomel electrode [SCE]) and linear polarisation resistance (LPR) method was used to calculate the corrosion rate (CR). After exposure, these specimens were analysed by using characterisation tools such as X-ray diffraction (XRD) and scanning electron microscope (SEM)/energy-dispersive X-ray spectroscopy (EDX).

The TSA-coated steel samples with 4 per cent holiday showed a CR of approximately 0.008-0.015 mm y⁻¹ and a stable potential (E_corr) around −800 mV (SCE), when exposed to boiling synthetic seawater for approximately 5,000 h. Microstructural characterisation established that the deposits comprised brucite [Mg(OH)₂] only (this is very different to what has been reported at ambient temperatures). The stable potentials obtained after 5,000 h suggest that the brucite layers provided effective corrosion mitigation. Thus, TSA seems to show the potential to protection hot carbon steel risers, even when damage exposing the external steel surface to the seawater is present.

The mechanism of calcareous deposit formation has been studied for many years, but most of the previously reported studies concentrate on low or ambient temperature behaviour. The reported studies mainly concentrate on the application of cathodic protection, rather than the effect of TSA. This is the first journal paper where the behaviour of damaged TSA in boiling synthetic seawater has been reported. The formation of brucite-only layer in the damaged area adjacent to the steel surface in boiling synthetic seawater is novel. And the mechanism of formation of this layer has been explained in the paper.

This study aims to evaluate the influence of pulsed cathodic protection on calcareous deposit formation on structures submerged in the synthetic sea water.

Chronoamperometric and C_HF methods have been used to evaluate the influence of pulsed cathodic protection on decreasing the required cathodic current for protection and also decreasing the surface coverage. The morphology of the formed deposits was evaluated using scanning electron microscopy. Chemical analyses of the formed deposits were performed using energy dispersive X‐ray spectrometer and X‐ray diffraction.

It was observed that pulse frequency influenced both the structure and the composition of the deposits. The most compact aragonite layer was obtained at high frequencies and at a high off‐time. It was clearly shown that by applying currents with less than 100 Hz frequency, the deposits formed on the sample involved CaCO₃ (aragonite) and Mg(OH)₂ (brucite). However, the kinetics of deposits formed when applying pulse current have been improved, compared to deposits formed by conventional cathodic protection. The reason is that large electrode overpotential favors nucleation through a decrease in the energy of nucleus formation. On the other hand, by intensive decrease of surface potential, repulsion of aggressive anions such as SO₄²⁻ and Cl⁻ occurs. These anions inhibit the formation of aragonite deposits.

In order to have a better investigation of electrodeposition processes in the shorter time, the use of more advanced techniques and analysis methods such as XPS is recommended. Furthermore, EHD techniques could be used for measurements of thickness of the layers.

The pulsed cathodic protection method is a relatively new method for the protection of buried and submerged structures. Recently, many researches have investigated that the influence of this technique on increasing the throwing power, decreasing interference effects on neighboring structures and increasing the uniformity of current distribution under cathodic protection.

Very little attention has been paid in the past to the effect of pulsed CP on deposit formation. The present paper, therefore, contributes useful understanding of the mechanism and advantages of such deposits in improving the effectiveness and lowering the operational cost of cathodic protection in use on offshore structures.

Besides with a large amount of Na⁺ and Cl⁻ ions in seawater, the presence of Mg⁺² and SO₄⁻² ions builds more complex corrosion mechanism. This paper aims to investigate the corrosion of embedded reinforcement in concrete with the environment of both Cl⁻ and SO₄⁻² anions associated Mg⁺² cation.

The concrete specimens were prepared by using ordinary Portland cement (OPC), and OPC blended with metakaolin (MK) for water to cementitious material ratio (w/cm) 0.48 and 0.51. The concrete mixes were contaminated with the addition of MgCl₂ alone and combined MgCl₂ and MgSO₄ in mix water. Reinforcement corrosion was evaluated by half-cell potential and corrosion current densities (I_corr) at regular intervals. Moreover, the influence of cementitious material type, salt type and w/cm ratio on electrical resistivity of concrete was also investigated. The statistical models were developed for electrical resistivity as a function of calcium to aluminium content ratio, compressive strength, w/cm ratio and age of concrete.

Although the corrosion initiation time increases in the concomitant presence of MgSO₄ and MgCl₂ as internal source compared to MgCl₂, I_corr values are higher in both OPC and MK blended concrete. However, electrical resistivity decreased with addition of MgSO₄. MK blended concrete performed better with increased resistivity, corrosion initiation time and decreased I_corr values.

This study reports statistical distributions for scattered I_corr of rebar in different concrete mixtures. Stepwise regression models were developed for resistivity by considering the interactions among different variables, which would help to estimate the resistivity through basic information.

Magnesium-aluminum layered double hydroxides (LDH) with a platelet-like morphology were synthesized through a modified co-precipitation method. The purpose of this paper is to investigate calcined Mg-Al-CO₃ LDH (CLDH) as chloride ion traps.

The morphology and chemical composition of the synthesized materials were studied through UHR-SEM, EDS, FT-IR and XRD. The chloride ion adsorption was confirmed by XRD; the characteristic diffraction peaks of the reconstructed LDH structure were revealed, similar to the one before the thermal treatment process. The effect of varying the experimental conditions on the chloride ion adsorption, such as the initial target-ion concentration, the adsorbent material dosage, the solution temperature and the solution pH was also investigated.

The experimental data fitting revealed that the Langmuir equation is a better model on the basis of correlation coefficients (R²) and that the pseudo-second kinetic model can satisfactorily describe the chloride ion uptake.

The ability of Mg-Al CLDH to recover their layered structure upon exposure to aqueous sodium chloride solutions with concentrations up to 0.3 M (10,636 mg/L) through the chloride adsorption and the simultaneous rehydration process is clearly demonstrated.

The purpose of this study is to investigate cathodic protection (CP) efficiency in the tidal zone and its associated processes.

Specific features of CP in the tidal zone, that is, persistence of a thin seawater film and insufficient cathodic potential due to ohmic drop, were addressed. In this preliminary study, carbon steel electrodes were polarized at two cathodic potentials (correct or insufficient protection) while immersed in 1 mm or 5 mm thick natural seawater layers. After CP interruption, the protective ability of the layers covering the steel electrodes was studied using various electrochemical methods, including electrochemical impedance spectroscopy. The layers were characterized by XRD.

The protective ability of calcareous deposits was increased in thin seawater films. Insufficient CP could promote protective aragonite/corrosion products layer.

The combined effects of thin seawater film and applied potential were never addressed, and the conclusions drawn from this preliminary study give new insight on the efficiency of CP in the tidal zone.

A new type of realisation of the hydrotalcite‐type lamellar compound Zn2AI(OH)6Cl.nH2O is described, using an original ink composed of a concentrated aqueous suspension of Zn2AI(OH)6Cl.nH2O powder, which, when applied by the screen‐printing technique, in particular environmental conditions—in a high relative humidity atmosphere—permits one to obtain very satisfactory deposits. Optical characterisation shows good resolution and levelling of the screen‐printed layer. X‐ray patterns show a high orientation of the (hkO) reticular planes of the screen‐printed material in a direction parallel to the substrate; this is a very interesting characteristic related to experiment on the electrical properties of this type of compound. Tests show the good adherence of the deposited layer on alumina or glass. Future applications are envisaged.

The purpose of this paper is to investigate whether the sedimentation of calcareous deposits occurs on cathodically protected steel in Baltic sea water.

Steel electrodes were cathodically polarized in natural Baltic sea water at potential +0.150 V vs Zn electrode in potentiostatic mode. During exposure chronoamperometric measurements were carried out. After the exposure, the electrode's surface was examined by scanning atomic force microscope (AFM) and by scanning electron microscope (SEM). Deposit composition was examined by energy‐dispersive X‐ray spectroscopy (EDX). Comparative investigation was carried out in 1 percent NaCl solution (comparable to the salinity of Baltic sea water).

During cathodic polarization in Baltic sea water, non‐conducting calcareous deposits developed on steel surface. These deposits significantly lowered the cathodic current demand. Morphology and EDX spectroscopy of the deposit indicated that it was built mainly of aragonite (polymorph of CaCO3). No non‐conducting deposits on cathodically protected steel electrodes developed in 1 percent NaCl solution.

Composition of Baltic sea water favours the formation of calcareous deposits on cathodically protected steel. Sedimentation is a beneficial and desired phenomenon from the point of view of cathodic protection system of maritime construction as it facilitates polarization. Evolution of calcareous deposits should be taken into account as one of the environmental factors when designing a cathodic protection system.

The purpose of the paper is to assess the influence of the volume fraction solid lubricants like talc lead and graphite in oil separately and in combination towards controlling the sliding wear behaviour of a grey cast iron and understand the factors controlling the response of the material in a given set of experimental conditions.

The composition of the lubricating medium (oil) has been changed by dispersing 5 per cent graphite, talc and lead particles separately and in combination. Sliding wear tests were conducted on grey cast iron samples over a range of applied pressures. Parameters determined were wear rate and frictional heating. The wear behaviour of the samples was further substantiated through the features of wear surfaces, subsurface regions and debris particles. Material removal mechanisms and factors responsible for a specific response of the samples have also been analysed.

The wear rate increased with increasing applied pressure. Addition of graphite and lead to the oil separately or in combination brought about a reduction in the wear rate of the samples; talc and talc + lead produced a reverse trend. Temperature near the specimen surface increased with test duration and applied pressure. The test environment influenced the frictional heating in a manner similar to that of the wear rate. Adhesion and abrasion were observed to be the operating material removal mechanisms. Smearing of the solid lubricating phase and delamination resulting from cracking tendency also controlled the wear response.

Oil is a very popular lubricant used in engineering applications involving friction and wear. Solid lubricants are used along with the oil. The nature, characteristics and content of the solid lubricants very much control the performance. Limited information is available pertaining to assessing the influence of the type and fraction of solid lubricants in the oil towards controlling the wear behaviour of cast irons (popularly known tribomaterials). The present study enables to understand the effectiveness of talc, lead and graphite in oil towards governing the wear characteristics of cast iron and analyse wear mechanisms and controlling parameters.

Graphite and talc are available in nature in abundance. Graphite is a popularly known solid lubricant, while talc is less explored. Lead is also well-known as a solid lubricant but poses health hazard in practice due to its toxic nature. The present study explores the lubricating capability of talc when mixed with oil separately or in combination with lead and graphite towards controlling the wear response of a grey cast iron. It enables to understand the factors responsible for the specific response of talc.

Assessment of the lubricating potential of talc as a possible substitute to lead is important in view of the toxic nature of the latter. If successful, the exercise could enable to replace lead with talc.

The present manuscript is an original piece of the author's research work.

Around the world, many structures are affected by pathological reactions between the concrete and the surrounding environment in which these structures are designed, these pathologies lead to compromise their serviceability. In this context, this paper aims to study the durability of concrete in different environments with non-destructive techniques, by studying its contamination by the aggressive agents’ penetration. And this, by evaluation of the influence of the durability indicator that is the absorption by immersion, on the mechanical properties (compressive strength, modulus of elasticity and damage), of specimens having undergone immersion/drying cycles, in different aggressive media (water, seawater and acids: sulfuric and acetic with a concentration of 5%).

Concrete specimens were manufactured in the laboratory, and then underwent immersion/drying cycles, in parallel, the weight gain of the specimens was carried out in the wet state after immersion and in the dry state after drying, and the ultrasonic speeds were also taken in a dry state. The results showed a decrease in the mechanical properties studied, namely, the compressive strength as well as the elastic properties (modulus of elasticity, damage) as a function of the increase in absorption, and that the weakest properties are those of test specimens submerged in water.

Non-destructive tests have shown that the parameters examined increase with the immersion/drying cycles, up to the fourth cycle. Beyond that, they drop gradually, and this is valid for four environments. This decline is due to the degradation of cement pastes exposed to water, seawater and acid attacks. This is explained by the greater or lesser dissolution of all the major elements making up the cementitious matrix (CSH, Ca(OH)2, CaO, SiO2, C3S, C2S, C3A, C2S) depending on the nature and concentration of the chemical substances evacuated. The results showed that the highest absorption rate and damage are those recorded for the specimen immersed in water, followed by that of the specimens immersed in acids, followed by that of the specimen immersed in sea water. The highest compressive strength and stiffness are those of the specimen immersed in sea water, followed by that immersed in acids, then in water.

The work developed aimed to study the durability of concrete, by addressing the study of the coupling absorption – mechanical characteristics of concrete, in different aggressive media (water, seawater and acids), to seek a relationship between these parameters. The tests provided are non-destructive tests, which consist of taking measures that do not damage the concrete. They allow indirect measurements of the mechanical properties of concrete as well as the monitoring of their evolution over time. They also allow having certain accuracy, because the measurements are taken at the same place.