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1 – 10 of 951Syahrir Ridha, Afif Izwan Abd Hamid and Che Ku Afiza Hanim Che Ku Mazuan
The purpose of this paper is to investigate the mechanical properties changing of geopolymer cement under different brine salinity.
Abstract
Purpose
The purpose of this paper is to investigate the mechanical properties changing of geopolymer cement under different brine salinity.
Design/methodology/approach
Geopolymer Cement of Class F Fly Ash and Class G Cement slurries were prepared according to API RP 10B. The optimum alkaline activator/cement and water/cement ratio of 0.44 was used for geopolymer and Class G cement samples, respectively. The alkaline activator was prepared by mixing the proportion of Sodium Hydroxide (NaOH) solutions of 8 M and Sodium Silicate (Na2SiO3) using ratio of 1:2.5 by weight. The slurries were cured for 24 hours at 130oC and 3,000 psi in HPHT Curing Chamber followed by coring process. Both cement sample were immersed in brine water salinity up to 28 days with different brine salinity up to 30 per cent of NaCl. The mechanical properties were investigated using OYO Sonic Viewer-SX and Uniaxial Compressive Strength. The surfaces of the cement samples were extracted for Scanning Electron Microscope (SEM) and EDS tests to evaluate the morphology and chemical compositions of the cured samples.
Findings
The paper shows that geopolymer samples experiences strength reduction in brine water but the reduction rate of geopolymer is about half of the Ordinary Portland cement based oil well cement. The finding was also verified by SEM and EDS result.
Originality/value
This paper investigates the mechanical property changes of emerging geopolymer cement due to different water salinity. The results provide potential application of geopolymer cement for oil well cementing.
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David C. Finnoff and Arthur J. Caplan
We present a computable general equilibrium model of the interface between the Great Salt Lake (GSL) ecosystem and both the international and regional economy that impacts the…
Abstract
We present a computable general equilibrium model of the interface between the Great Salt Lake (GSL) ecosystem and both the international and regional economy that impacts the ecosystem. International trade is accounted for in the simplest of terms, involving the export of each of the ecosystem's main commodities and importation of a composite good, as well as equilibrium balances in the savings-investment and current accounts. With respect to the ecosystem, the model treats the various representative species as net energy maximizers and bases population dynamics on the period-by-period sizes of surplus net energy. Energy markets – where predators and prey exchange biomass – determine equilibrium energy prices. With respect to the regional economy, we model five production sectors (at the aggregate industry level) – brine cyst harvesters, the mineral-extraction industry, agriculture, recreation, and a composite-good industry – as well as the household sector. By performing dynamic simulations of the joint ecosystem–regional economy model, we isolate the effects of period-by-period stochastic changes in salinity levels and an initial shock to species-population levels on the ecological and economic variables of the model.
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Dupe Temilade Otolowo, Abiodun Adekunle Olapade, Samouel Olugbenga Oladele and Felix Egbuna
Fresh catfish (Clarias gariepinus) is highly perishable. This paper aims to investigate the drying characteristics and quality of body-mass dehydrated catfish to determine the…
Abstract
Purpose
Fresh catfish (Clarias gariepinus) is highly perishable. This paper aims to investigate the drying characteristics and quality of body-mass dehydrated catfish to determine the effective dehydration parameters for preservation.
Design/methodology/approach
Brine concentration (3-9 per cent), brining time (30-90 min) and drying temperature (90-130°C) interacted using the response surface methodology. Preliminary experiments were conducted to select treatments. Moisture content and ratio and drying rate were determined and fitted into five thin-layer drying models; the goodness of fit was evaluated by average grade ranking of the regression parameters. Proximate compositions and microbial load of dehydrated catfish were determined using standard methods.
Findings
Treatments with 110°C gave initial higher drying rate (0.034-0.043 kg H2O/kg solid/h) and shorter drying time (20-21 h). Drying occurred at two falling rate periods. Midilli model ranked first in fitting the drying data. It explained up to 99.6-99.7 per cent of the total variations in the independent variables with low values of error terms; RMSE was 0.02131-0.01794 and χ2 was 0.00037-0.00043, indicating good predictive quality. Processing parameters positively and significantly (p < 0.05) influenced the proximate compositions of dehydrated catfish. Treatment: 6 per cent brine, 90 min and 110°C presented the most effective dehydration parameters for quality preservation of body-mass catfish.
Practical implications
The dehydration technique used in this study could enhance nutritive quality and storage stability of body-mass dehydrated catfish that could serve as a useful and convenient tool for commercial application.
Social implications
Hygienically processed dehydrated catfish of good quality could be used as a source of nutrients to ameliorate malnutrition and reduce post-harvest losses of catfish.
Originality/value
The effective processing parameters established is an important step to harness the high nutrients and economic values embedded in catfish.
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Benjamin Valdez, Michael Schorr, Margarito Quintero, Monica Carrillo, Roumen Zlatev, Margarita Stoytcheva and Juan de Dios Ocampo
The aim of this work is to study the corrosion and scaling factors, mechanisms and processes affecting the materials, equipment and installations of the Cerro Prieto geothermal…
Abstract
Purpose
The aim of this work is to study the corrosion and scaling factors, mechanisms and processes affecting the materials, equipment and installations of the Cerro Prieto geothermal field (GTF).
Design/methodology/approach
The physicochemical characteristics of the geothermal well and fluids were analysed, recorded and related to the corrosion and scaling phenomena.
Findings
The high temperature and salinity of the steam‐brine mixture and the presence of hydrogen sulphide and carbon dioxide impart a severe level of corrosivity.
Originality/value
Corrosion and scaling control assure an efficient production regime, provide for the durability of the GTF engineering materials and equipment and contribute to environmental quality.
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Lu Zhaoling, Fu Chaoyang and Guo Xingpeng
This paper seeks to investigate the different inhibition performance and adsorption behaviour of dodecylamine in acidic and neutral environments and to understand further the…
Abstract
Purpose
This paper seeks to investigate the different inhibition performance and adsorption behaviour of dodecylamine in acidic and neutral environments and to understand further the inhibition mechanism of dodecylamine in CO2‐saturated brine solution.
Design/methodology/approach
The inhibition performance and adsorption behaviour of dodecylamine on N80 steel in CO2‐saturated brine solution in acidic and neutral environments were investigated by potentiodynamic polarization, electrochemical impedance spectroscopy and the attenuated total reflection‐Fourier transform infrared spectroscopy.
Findings
Corrosion potentials exhibited a pronounced shift in the positive direction at higher concentrations of dodecylamine. The inhibition efficiency of dodecylamine was shown to be pH‐dependent. The effective inhibition concentration of dodecylamine decreased from pH 4.9 to 7.4. In a neutral environment, the inhibitor was shown to affect the deposition of the corrosion products and provide more active sites to bond with the inhibitor. More alkaline environments made the electron cloud density of dodecylamine much higher, which was more favourable to the interaction of dodecylamine and the naked metal base, and hence dodecylamine had a much better inhibition performance in a neutral environment than in acidic environments.
Originality/value
This paper provides information regarding the inhibition performance and adsorption behaviour of dodecylamine on N80 steel and probes the inhibition mechanism of dodecylamine in acidic and neutral environments. The results of the work contribute to an understanding of the inhibition mechanism of the inhibitor in different environments, which will be useful for effective design and choice of inhibitors in CO2 corrosion.
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At a recent inquest upon the body of a woman who was alleged to have died as the result of taking certain drugs for an improper purpose, one of the witnesses described himself as…
Abstract
At a recent inquest upon the body of a woman who was alleged to have died as the result of taking certain drugs for an improper purpose, one of the witnesses described himself as “an analyst and manufacturing chemist,” but when asked by the coroner what qualifications he had, he replied : “I have no qualifications whatever. What I know I learned from my father, who was a well‐known ‘F.C.S.’” Comment on the “F.C.S.” is needless.
Jion Sean Pau, William Pao and Suet Peng Yong
The purpose of this paper is to introduce the solution to two-phase flow in CO2/brine system with salt precipitation by applying mixed hybrid finite element (MHFE) method to…
Abstract
Purpose
The purpose of this paper is to introduce the solution to two-phase flow in CO2/brine system with salt precipitation by applying mixed hybrid finite element (MHFE) method to pressure equation and finite volume (FV) method to saturation equation. Mixed finite element method solves pressure and velocity in two subspaces while hybrid method is an extension of mixed method, where the Lagrange multiplier is added to the former in order to ensure the continuity from one element to the adjacent elements. The authors propose the modeling of salt precipitation using core flood experimental result and adapt to be applicable for numerical modeling.
Design/methodology/approach
The governing equations are discretized using Mixed Hybrid Finite Element-Finite Volume (MHFE-FV) method. This method has the feature of localized conservation which is attractive for application on heterogeneous porous media. In addition to this, the salt precipitation effect is modeled using the data from core flood experiment (Ott et al., 2011). The random data are linearized to obtain the relationship between salt precipitate and CO2 saturation and implemented to the algorithm for two-phase flow in CO2 and brine system.
Findings
The solution of MHFE-FV scheme has good agreement with the solution using implicit pressure and explicit saturation (IMPES) reported by Negara et al. (2011), with average error of 4.20 percent. Localized conservation is demonstrated in the case of randomized heterogeneous porous media where fingering effects are explicitly observed. Salt precipitation prediction using the proposed method is able to predict the decrement of porosity by 16.71 percent and permeability by 22.19 percent. This results in the decreased amount of CO2 injected by 64.70 percent.
Research limitations/implications
This paper presents the solution of two-phase flow in CO2 brine system during CO2 injection in saline aquifer using MHFE-FV method with the additional salt precipitation model obtained based on core flood experiment result.
Practical implications
A methodology to predict the salt precipitation based on CO2 saturation.
Social implications
Contribution to green house gas reduction.
Originality/value
The authors use MHFE-FV to solve hyperbolic PDE to obtain accurate results of CO2 saturation, and subsequently use this to compute the salt precipitation.
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S. Olivella, A. Gens, J. Carrera and E.E. Alonso
Presents numerical aspects of the program CODE_BRIGHT, which is a simulator for COupled DEformation, BRIne, Gas and Heat transport problems. It solves the equations of mass and…
Abstract
Presents numerical aspects of the program CODE_BRIGHT, which is a simulator for COupled DEformation, BRIne, Gas and Heat transport problems. It solves the equations of mass and energy balance and stress equilibrium and, originally, it was developed for saline media. The governing equations also include a set of constitutive laws and equilibrium conditions. The main peculiarities of saline media are in the dissolution/precipitation phenomena, presence of brine inclusions in the solid salt and creep deformation of the solid matrix.
Details
Keywords
Outlook for the lithium market.
Details
DOI: 10.1108/OXAN-DB214868
ISSN: 2633-304X
Keywords
Geographic
Topical
C. Miranda‐Herrera, I. Sauceda, J. González‐Sánchez and N. Acuña
The purpose of this paper is to evaluate the electrochemical behaviour of two carbon steels exposed to acidic geothermal solutions and their resistance to hydrogen induced…
Abstract
Purpose
The purpose of this paper is to evaluate the electrochemical behaviour of two carbon steels exposed to acidic geothermal solutions and their resistance to hydrogen induced cracking (HIC), in order to determine the effect of hydrogen damage on the failure process of the steels used for line pipe and casings at a geothermal plant.
Design/methodology/approach
Samples of two different steels: ASTM A‐53 Grade B (line pipe) and API L‐80 (casing) were immersed for a duration of 96 h in the electrolyte proposed by NACE to evaluate susceptibility to HIC. Samples of the two steels embedded in non‐conducting Bakelite were subjected to potentiodynamic polarisation scans at room temperature using as the electrolyte brines obtained from different wells at the Cerro Prieto geothermal plant. Hardness tests were performed on the samples before and after the HIC tests in order to determine hardness changes induced by hydrogen penetration as field results indicated embrittlement of the steels after four months of service.
Findings
The steels, ASTM A‐53 Grade B and API L‐80 did not exhibit crack sensitivity as no cracks are observed in the tests specimens, though they showed an increase in hardness. The steels exhibited high‐corrosion rates in the brine media at room temperature (3.3 mm/yr), which is expected to increase at higher temperatures.
Originality/value
The work revealed that carbon steels used for line pipes and casings at geothermal plants can exhibit high resistance to HIC, however they corrode at high rates and may show embrittlement. It is suggested that due to the high‐operation temperature, the damage induced by hydrogen resulted in hardness increase but was not sufficient to develop cracks.
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