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The authors have prepared the triazole film on copper surface by click reaction and explored its inhibition mechanism.

The protective film is assembled by immersing bronze in solution containing p-toluenesulfonyl azide (TA) and propiolic acid (PA).

Fourier transform infrared spectroscopy (FT-IR) indicates that triazole (TTP) film was formed on bronze surface via click chemistry reaction between TA and PA. It shows TTP film has a good protection for bronze in the atmospheric environment simulation solution. Quantum chemical calculation (QC) and molecule dynamics simulation suggests TTP molecule adsorbs on bronze surface via N and O.

This is beneficial to develop the corrosion inhibitors for the corroded copper alloys.

The composition and corrosion behaviors of recycled and virgin Pb anode were investigated in industrial zinc electrowinning solution with different methods. The purpose of this study is the illustration of good anticorrosion activity of virgin Pb anodes compared to recycled one in industrial operation, while the compositions of both of them are the same which obtained from quantmetry method.

Its corrosion properties and electrocatalytic activity toward oxygen evolution reaction were appraised using potentiodynamic polarization, electrochemical impedance spectroscopy, galvanostatic polarization and ionic equilibrium methods. In addition, composition of anodes investigated with X-ray photoelectron spectroscopy (XPS) method. The surface composition of samples was studied via X-ray diffractogram (XRD).

The results indicate that the anodes display different anodic behaviors during the galvanostatic polarization. Virgin Pb anode shows a “potential reduction” about 320 mV lower than recycled Pb anode after 6 h of polarization; also, the stable potential after 72 h for virgin Pb anode is 100 mV lower than recycled Pb anode. Also, The XPS results show a trace amount of Cl in recycled anodes which cause the more corrosion activity. XRD results indicate that virgin Pb anodes have been covered by more oxides than recycled anodes after 72 h of electrowinning.

The treatment of corrosion behavior by virginity has not been detected by any researchers yet. Therefore, it is imperative to study the corrosion behavior and exact composition analysis of virgin and recycled Pb anodes to comprehension of them. This paper fulfills this need.

Clothing comfort has been one important and complex area which is the result of a balanced process of heat and moisture/liquid exchange between the human body, the clothing system and the environment. And the clothes will represent different properties when they are in different conditions, which have great influence on human comfort. Therefore, the purpose of this paper is to investigate the hygroscopicity-exothermicity property of plain cotton fabric.

A real-time testing device for monitoring the temperature change of cotton fabrics after adsorbing liquids was constructed, and serveral liuqids such as water, NaCl solution with different concentrations, NaOH solution with different concentrations, and urea solution with different concentrations were used in this work.

It was found out that absorption of liquids by cotton fabric was followed by the liberation of heat, which increased the temperature of cotton fabric as well as the temperature of surrounding environment, and the process of temperature increase was much shorter than the process of temperature decrease. In addition, the released heat energy were different according to different liquids as well as the concentrations of liquid solutions.

There have some studies in the heat of water/vapor sorption of textiles. Here the temperature changes of surrounding environment and fabric after absorbing different liquids were real-time observed and recorded.

The purpose of this paper is to investigate the effect of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) on improvement of physical and electrical properties of vanadyl phthalocyanine derivative. The correlation between the physical characteristics of the active layers, comprising vanadyl 2,9,16, 23-tetraphenoxy-29H,31H-phthalocyanine (VOPcPhO) and PCBM, and the electrical properties of metal/organic/metal devices have been studied. The use of soluble vanadyl phthalocyanine derivative makes it very attractive for a variety of applications due to its tunable properties and high solubility.

The sandwich type structures Al/VOPcPhO/Al and Al/VOPcPhO:PCBM/Al were fabricated by spin casting the active organic layers between the top and bottom (aluminum) electrodes. The stand-alone (VOPcPhO) and composite (VOPcPhO:PCBM) thin films were characterized by X-ray diffraction, atomic force microscopy, UV/Vis and Raman spectroscopy. The electronic properties of the metal/organic/metal devices were studied using current-voltage (I-V) characteristics in dark at room temperature.

The values of barrier height for Al/VOPcPhO/Al and Al/VOPcPhO:PCBM/Al devices were obtained from the forward bias I-V curves and were found to be 0.7 eV and 0.62 eV, respectively. The present study indicates that the device employing VOPcPhO:PCBM composite film as the active layer, with better structural and morphological characteristics, results in reduced barrier height at the metal-organic film interface as compared to the one fabricated with the stand-alone film.

It is shown that doping VOPcPhO with PCBM improves the crystallinity, morphology and junction properties.

The spin coating technique provides a simple, less expensive and effective approach for preparing thin films. The soluble VOPcPhO is conveniently dissolved in a number of organic solvents.

The physical properties of the VOPcPhO:PCBM composite thin film and the electrical properties of the composite thin-film-based metal/organic/metal devices have not been reported in the literature, as far as our knowledge is concerned.

Considers that when efficiency and effectiveness of systems are measured by the quantity and quality of their output they may be inadequate for the purpose of comparing one system with another. Seeks new criteria and defines entropy, wastivity and quality concepts in relation to system performance. Establishes the interdependence of the three concepts. Proposes that system wastivity should be used as a measure of system performance.

Explains the fused deposition process and examines the rationale behind the cooling process model. Outlines the complexity of the problems and characteristics of fused deposition. Presents a general formulation for road cooling followed by results and their implications. Concludes with proposed directions for future work.

MS / MBA / Executive Education

Leadership

In 2019, French multinational electric utility company, ENGIE SA (ENGIE) was on the verge of zero carbon transition. Under the leadership of Isabelle Kocher (Kocher) who became the CEO in 2016, ENGIE embarked on an arduous journey toward re-profiling ENGIE toward renewable, low-carbon energies, such as solar, green gases and digital. Kocher inherited a loss-making company and took in on a path of transformation toward a company with business lines for future. This meant ENGIE would slowly move out of energy generation through non-renewable sources, toward renewables along with storage and digital technologies. This case chronicles Kocher’s turnaround plans and investments, and explains how she went about making ENGIE a forerunner in energy revolution. While the turnaround was on track, ENGIE was unable to give returns as expected. With mounting pressure Kocher announced a strategic plan in 2019, which reemphasized ENGIE’s focus on renewables and technology. But several major shareholders including the Government of France were not impressed with the plan. It is time Kocher proves that transformation of ENGIE into a clean power company also means returns for the shareholders.

The outcomes are as follows: First, to illustrate how leaders bring in change and innovation in large well-established companies. It shows the role of leaders in leading the innovation process and in molding the companies according to the opportunities and threats presented by the macro environment. Second, to analyze the role of a leader in bringing changes in the organization. Third, to understand the strategies used by energy companies as they position their businesses in the context of a changing energy landscape.

Teaching Note

Renewable Energy – Growing cocnern about the impact of climate change on the world at large, has brought to the fore the importance of renewable energy.

CSS 4: Environmental management

Switzerland boasts arguably the highest density of green properties in the world. In 2008, more than 15 percent of total new construction received the Swiss energy building label Minergie. The spatial distribution of these green buildings, however, is highly heterogeneous. In some regions, more than half of the new dwellings are built according to the Swiss green building standard. In others, this share is still negligible. The purpose of this paper is to identify the determinants of the distribution of green housing.

For 2,571 Swiss municipalities, the author computes the green building share of new residential buildings. Data are collected for several variables measuring demographic, geographic, social, cultural, and political aspects that – according to the authors' hypothesis – may influence green building activity. Count regression is used to estimate the impact of these variables on the demand for green buildings.

It is found that differences in income levels and cultural affiliation between Swiss municipalities account for the largest part of the variation in green building activity. The impact of homeowners' stance on environmentalism is highly significant but less important. Government subsidies do not seem to trigger additional green housing activity.

The paper presents one of the first empirical analyses regarding the determinants of green building activity. Thanks to a comprehensive dataset, the authors are able to investigate the impact of potential drivers of “green housing” construction activity. The regional variation in governmental incentives is analysed and delivers valuable insight for policymakers interested in spurring the development of green buildings.

This paper aims to investigate the influence of stearate types on the thickening ability, dropping point and fiber structure of greases.

Several greases were prepared from polyolefins and various stearates. The melting point of the stearates and the dropping point of the resultant greases were measured, and the intermolecular binding energies of the thickener and the radial distribution function of the metal–oxygen in the thickener were determined with the aid of molecular simulation. The microstructures of the greases were also analyzed via scanning electron microscopy.

A higher stearate binding energy was found to correlate to a higher dropping point of the resultant greases. The thickening ability of the stearate is related to the group and period of the constituent metal ion. Within a group, greater atomic numbers of the metal were correlated to lower thickening ability. In a period, as the atomic number of the metal increased, the thickening ability was enhanced. The radial distribution functions of metal and oxygen can explain the aggregation of the stearate thickeners in the grease.

This work compared the thickening capacity of several stearates. Guidelines for preparing stearates to tailor the resultant grease are presented.

In the last decade, XML has become the de facto standard for data exchange in the world wide web (WWW). The positive benefits of data exchangeability to support system and software heterogeneity on application level and easy WWW integration make XML an ideal data format for many other application and network scenarios like wireless sensor networks (WSNs). Moreover, the usage of XML encourages using standardized techniques like SOAP to adapt the service‐oriented paradigm to sensor network engineering. Nevertheless, integrating XML usage in WSN data management is limited by the low hardware resources that require efficient XML data management strategies suitable to bridge the general resource gap. The purpose of this paper is to present two separate strategies on integrating XML data management in WSNs.

The paper presents two separate strategies on integrating XML data management in WSNs that have been implemented and are running on today's sensor node platforms. The paper shows how XML data can be processed and how XPath queries can be evaluated dynamically. In an extended evaluation, the performance of both strategies concerning the memory and energy efficiency are compared and both solutions are shown to have application domains fully applicable on today's sensor node products.

This work shows that dynamic XML data management and query evaluation is possible on sensor nodes with strict limitations in terms of memory, processing power and energy supply.

The paper presents an optimized stream‐based XML compression technique and shows how XML queries can be evaluated on compressed XML bit streams using generic pushdown automata. To the best of the authors' knowledge, this is the first complete approach on integrating dynamic XML data management into WSNs.