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This study aims to dye silk with natural pigments extract of Coreopsis tinctoria, by treating the fabrics with appropriate mordant under suitable dyeing conditions, to achieve good dyeing depth, fastness and ultraviolet (UV) protection.

Firstly, single factor experiments were used to determine the basic dyeing conditions of Coreopsis tinctoria. The optimal process conditions for direct dyeing were determined through orthogonal experiments. After that, the dyeing with mordant was used. Based on the previously determined optimal process conditions, silk fabrics were dyed with different mordanting methods, with different mordants and mordant dosages. The dyeing results were compared, in terms of the K/S values of the dyed fabrics, to determine the most appropriate dyeing conditions with mordant.

The extract of Coreopsis tinctoria can dye silk fabrics satisfactorily. Good dyeing depth and fastness can be obtained by using suitable dyeing methods and dyeing conditions, especially when using the natural mordant pomegranate rind and the rare earth mordant neodymium oxide. The silk fabrics dyed with Coreopsis tinctoria have good UV resistance, which allows a desirable finishing effect to be achieved while dyeing, using a safe and environmentally friendly method.

The composition of Coreopsis tinctoria is complex, and the specific composition of colouring the silk fibre has not been determined. There are many factors that affect the dyeing experiment, which have an impact on the experimental results.

The results of this study may help expand the application of Coreopsis tinctoria beyond medicine.

To the best of the authors’ knowledge, this paper is the first report on dyeing silk with the extract of Coreopsis tinctoria achieving good dyeing results. Its depth of staining and staining fastness were satisfactory. Optimum dyeing method and dyeing conditions have been identified. The fabric dyed with Coreopsis tinctoria has good UV protection effect, which is conducive to improving the application value of the dyeing fabric. The findings help offer a new direction for the application of medicinal plants in the eco-friendly dyeing of silk.

This paper aims to investigate the responses of single piles and pile groups due to tunneling-induced ground movements in a two-layered soil system. The analyses mainly focus on the additional single pile responses in terms of bending moment, lateral deflection, axial force, shaft resistance and pile settlement. Subsequently, a series of parametric studies were carried out to better understand the responses of single piles induced by tunneling. To give further understanding regarding the pile groups, a 2 × 2 pile group with two different pile head conditions, namely, free and capped, was considered.

Using the PLAXIS three-dimensional (3D) software, a full 3D numerical modeling is performed to investigate the effects of ground movements caused by tunneling on adjacent pile foundations. The numerical model was validated using centrifuge test data found in the literature. The relevance of the 3D model is also judged by comparison with the 2D plane strain model using the PLAXIS 2D code.

The numerical test results reveal that tunneling induces significant displacements and internal forces in nearby piles. The magnitude and distribution of internal forces depend mainly on the position of the pile toe relative to the tunnel depth and the distance between the pile and the vertical axis of the tunnel. As the volume loss increases from 1% to 3%, the apparent loss of pile capacity increases from 11% to 20%. By increasing the pile length from 0.5 to 1.5 times, the tunnel depth, the maximum pile settlement and lateral deflection decrease by about 63% and 18%, respectively. On the other hand, the maximum bending moment and axial load increase by about 7 and 13 times, respectively. When the pile is located at a distance of 2.5 times the tunnel diameter (Dt), the additional pile responses become insignificant. It was found that an increase in tunnel depth from 1.5Dt to 2.5Dt (with a pile length of 3Dt) increases the maximum lateral deflection by about 420%. Regarding the interaction between tunneling and group of piles, a positive group effect was observed with a significant reduction of the internal forces in rear piles. The maximum bending moment of the front piles was found to be higher than that of the rear piles by about 47%.

Soil is a complex material that shows differently in primary loading, unloading and reloading with stress-dependent stiffness. This general behavior was not possibly being accounted for in simple elastic perfectly plastic Mohr–Coulomb model which is often used to predict the behavior of soils. Thus, in the present study, the more advanced hardening soil model with small-strain stiffness (HSsmall) is used to model the non-linear stress–strain soil behavior. Moreover, unlike previous studies THAT are usually based on the assumption that the soil is homogeneous and using numerical methods by decoupled loadings under plane strain conditions; in this study, the pile responses have been exhaustively investigated in a two-layered soil system using a fully coupled 3D numerical analysis that takes into account the real interactions between tunneling and pile foundations. The paper presents a distinctive set of findings and insights that provide valuable guidance for the design and construction of shield tunnels passing through pile foundations.

From a technological determinist perspective, machine learning (ML) may significantly contribute towards sustainable development. The purpose of this study is to synthesize prior literature on the role of ML in promoting sustainability and to encourage future inquiries.

This study conducts a systematic review of 110 papers that demonstrate the utilization of ML in the context of sustainable development.

ML techniques may play a vital role in enabling sustainable development by leveraging data to uncover patterns and facilitate the prediction of various variables, thereby aiding in decision-making processes. Through the synthesis of findings from prior research, it is evident that ML may help in achieving many of the United Nations’ sustainable development goals.

This study represents one of the initial investigations that conducted a comprehensive examination of the literature concerning ML’s contribution to sustainability. The analysis revealed that the research domain is still in its early stages, indicating a need for further exploration.

The compressive strength of concrete depends on many interdependent parameters; its exact prediction is not that simple because of complex processes involved in strength development. This study aims to predict the compressive strength of normal concrete and high-performance concrete using four datasets.

In this paper, five established individual Machine Learning (ML) regression models have been compared: Decision Regression Tree, Random Forest Regression, Lasso Regression, Ridge Regression and Multiple-Linear regression. Four datasets were studied, two of which are previous research datasets, and two datasets are from the sophisticated lab using five established individual ML regression models.

The five statistical indicators like coefficient of determination (R²), mean absolute error, root mean squared error, Nash–Sutcliffe efficiency and mean absolute percentage error have been used to compare the performance of the models. The models are further compared using statistical indicators with previous studies. Lastly, to understand the variable effect of the predictor, the sensitivity and parametric analysis were carried out to find the performance of the variable.

The findings of this paper will allow readers to understand the factors involved in identifying the machine learning models and concrete datasets. In so doing, we hope that this research advances the toolset needed to predict compressive strength.

This paper aims to develop a stable gel-type lubricant emulating commercial conditions. This encompassed rheological and tribological assessments, alongside field trials on the Medellín tram system.

The gel-type lubricant with graphite and aluminum powder is synthesized. Rheological tests, viscosity measurements and linear viscoelastic regime assessments are conducted. Subsequently, tribological analyses encompassing four-ball and twin disc methods are executed. Finally, real-world testing is performed on the Medellín tram system.

An achieved lubricant met the stipulated criteria, yielding innovative insights into the interaction of graphite and aluminum powder additives under varying tests.

Novel findings are unveiled regarding the interaction of graphite and aluminum powder additives in tribological, rheological and real-world trials. In addition, the wear behavior of polymers is observed, along with the potential utilization of such additives in tramway systems.

The purpose of this study is to investigate the authors' previously prepared and fully characterized poly (methacrylamide)-chitosan nanoparticles (CNPs) graft copolymer having 50.2% graft yield with respect to flocculation efficiency for ferric laurate aqueous dispersions. This was done to compare the ability of the latter cheap, biodegradable and ecofriendly hybrid natural-synthetic polymeric substrate as a flocculant in comparison with higher cost, nonbiodegradable and harmful polyacrylamide as a well-known synthetic flocculant counterpart.

The graft copolymerization process was carried out at 450°Cfor 120 min using (1.0 g) CNPs, methacrylamide (1.5 g), 100 mmol/l potassium chromate and 80 mmol/l mandelic acid. Fourier transform infrared spectroscopy, thermogravimetric analysis, elemental analysis and specific viscosity were used to characterize and analyze the resultant copolymer. The flocculation efficiency was conferred in terms of transmittance % and weight removal %. The main factors influencing the flocculation process, such as flocculent dose, flocculation medium pH, stirring speed, flocculation temperature and grafting extent, were comprehensively discussed.

The flocculation efficiency of the prepared copolymers revealed the following findings: increased by increasing the flocculant dose, pH, temperature and stirring speed to a maximum values denoted at 30 ppm, 6.0, 30°C and 50 r/min, respectively, then decreased thereafter; increased by increasing the extent of grafting within the range studied; showed a comparable flocculation efficiency in comparison with polyacrylamide as a synthetic polymeric flocculent; and, finally, a preliminary bridging mechanism representing the attraction between the anionic suspended particles ferric laurate and cationic poly (MAam)-CNPs graft copolymer has been projected.

The advancement addressed here is undertaken with using the authors’ poly (MAam)-CNPs graft copolymers having different extent of grafting (a point which is not cited in the literature especially for the authors’ prepared copolymer) as a hybrid natural-synthetic polymeric substrate as a flocculant for ferric laurate aqueous dispersions in comparison with the high cost and nondegradable polyacrylamide synthetic flocculant.

This paper aims to explore the intellectual structure shaping the circular economy (CE) discourse within the built environment in Africa.

The study adopted a bibliometric analysis approach to explore the intellectual structure of CE in the built environment in Africa. The authors collected 31 papers published between 2005 and 2021 from the Scopus database and used VOSviewer for data analysis.

The findings show that there are six clusters shaping the intellectual structure: demolition, material recovery and reuse; waste as a resource; cellulose and agro-based materials; resilience and low-carbon footprint; recycling materials; and the fourth industrial revolution. The two most cited scholars had three publications each, while the top journal was Resources, Conservation and Recycling. The dominant concepts included CE, sustainability, alternative materials, waste management, lifecycle, demolition and climate change. The study concludes that there is low CE research output in Africa, which implies that the concept is either novel or facing resistance.

The data were drawn from one database, Scopus; hence, adoption of alternative databases such as Web of Science, Google Scholar and Dimensions could potentially have yielded a higher number of articles for analysis which potentially would result in different conclusions on the subject understudy.

This study made a significant contribution by articulating the CE intellectual structure in the built environment, identified prominent scholars and academic platforms responsible for promoting circularity in Africa.

The purpose of this study is to prepare Polystyrene grafted with Zeolite Y (Zeosty) for Uranyl ion [U(VI)] adsorption from aqueous solution. The adsorption mechanism has been explained by studying kinetic, isothermal and thermodynamic models.

Polystyrene was grafted with Zeosty by a simple hydrothermal technique. Zeosty was characterized by different techniques such as X-ray diffraction, scanning electron microscope, energy dispersive X-ray and Infrared spectroscopy to confirm its structure and its molecular composition. Zeosty was used for U(VI) adsorption from an aqueous solution in a series of batch experiments. The effects of pH, contact time, initial U(VI) concentration and temperature on the adsorption process were investigated.

The results showed that the adsorption of U(VI) on the prepared reached equilibrium at pH 6 with a removal efficiency of 98.9%. Adsorption kinetics and isotherms models are studied on the experimental data to estimate the mechanism of the adsorption reaction was chemisorption and homogenous reaction. The activity of Zeosty increased at high temperatures, resulting in the adsorption capacity increase. Thermodynamic parameters ΔGo, ΔHo and ΔSo indicate that the adsorption processes are spontaneous and endothermic. Zeosty has an effective surface and could be considered a valuable adsorbent for U(VI) removal from aqueous waste. A comparison study proves that the new adsorbent has high effective behavior in the adsorption process, and it is considered a new reliable adsorbent for U(VI) removal from wastewater.

This study is complementary to the previous study using the same technique to prove that the effective fine particle adsorbents need solid support to enhance their absorption capacities.

The purpose of this study is to adapt the incompressible smoothed particle hydrodynamics (ISPH) method with artificial intelligence to manage the physical problem of double diffusion inside a porous L-shaped cavity including two fins.

The ISPH method solves the nondimensional governing equations of a physical model. The ISPH simulations are attained at different Frank–Kamenetskii number, Darcy number, coupled Soret/Dufour numbers, coupled Cattaneo–Christov heat/mass fluxes, thermal radiation parameter and nanoparticle parameter. An artificial neural network (ANN) is developed using a total of 243 data sets. The data set is optimized as 171 of the data sets were used for training the model, 36 for validation and 36 for the testing phase. The network model was trained using the Levenberg–Marquardt training algorithm.

The resulting simulations show how thermal radiation declines the temperature distribution and changes the contour of a heat capacity ratio. The temperature distribution is improved, and the velocity field is decreased by 36.77% when the coupled heat Cattaneo–Christov heat/mass fluxes are increased from 0 to 0.8. The temperature distribution is supported, and the concentration distribution is declined by an increase in Soret–Dufour numbers. A rise in Soret–Dufour numbers corresponds to a decreasing velocity field. The Frank–Kamenetskii number is useful for enhancing the velocity field and temperature distribution. A reduction in Darcy number causes a high porous struggle, which reduces nanofluid velocity and improves temperature and concentration distribution. An increase in nanoparticle concentration causes a high fluid suspension viscosity, which reduces the suspension’s velocity. With the help of the ANN, the obtained model accurately predicts the values of the Nusselt and Sherwood numbers.

A novel integration between the ISPH method and the ANN is adapted to handle the heat and mass transfer within a new L-shaped geometry with fins in the presence of several physical effects.

Current evidence indicates that humans and animals are at increased risk of multiple health challenges due to microplastic (MP) profusion. However, mitigation is constrained by inadequate scientific data, further aggravated by the lack of evidence in many African countries. This review therefore synthesized evidence on the current extent of MP pollution in Africa and the analytical techniques for reporting.

A literature search was undertaken in research databases. Medical subject headings (MeSH) terms and keywords were used in the literature search. The authors found 38 studies from 10 countries that met the inclusion criteria.

Marine organisms had MPs prevalence ranging from 19% to 100%, whereas sediments and water samples had between 77 and 100%. The most common and dominant polymers included polypropylene and polyethylene.

This review shows that most studies still use methods that are prone to human errors. Therefore, the concentration of MPs is likely underestimated, even though the authors’ prevalence evaluations show MPs are still largely pervasive across multiple environmental matrices. Also, the study reveals significant spatial disparity in MP research across the African continent, showing the need for further research in other African countries.

Even though some reviews have assessed MPs pollution in Africa, they have not evaluated sample prevalence, which is necessary to understand not only concentration but pervasiveness across the continent. Secondly, this study delves deeper into various methods of sampling, extraction and analysis of MPs, as well as limitations and relevant recommendations.