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Article
Publication date: 2 October 2007

Baomin Hu, Lili Wang and Xinkai Yu

This paper aims to explore the research and development (R&D) structure and the effect which R&D may have on economic growth in Hebei Province, PRC. Through the comparison of R&D…

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Abstract

Purpose

This paper aims to explore the research and development (R&D) structure and the effect which R&D may have on economic growth in Hebei Province, PRC. Through the comparison of R&D efficiency in Hebei and that of seven other regions (with top economic performance in China), it tries to find out the right ways of improving R&D performance, in order to increase its contribution to economic growth. It concludes with practical suggestions for future R&D management in Hebei, and it also offers a useful evaluation framework for other regions.

Design/methodology/approach

Based on the analysis of R&D census in 2000 in China and an investigation of 532 large and medium enterprises in Hebei Province, this paper presents a data envelopment analysis (DEA) framework to measure the effects of R&D on economic growth in China. Regional comparisons of R&D efficiencies are also carried out.

Findings

Applying the DEA model, this paper finds out the shortcomings of R&D structure in Hebei Province as well as problems in R&D efficiency compared to some other regions. The R&D scale of Hebei is still at the stage of increasing returns to scale, and its ratio of basic research: applied research: development should be adjusted to 2.9:10.4:86.7 instead of 5.7:2.6:67.6. Through the investigation of 532 large and medium enterprises between 1998 and 2000 in Hebei, it was also found that the indigenous innovation is currently the main pattern of Hebei's enterprises.

Originality/value

With the DEA model, this paper presents a useful evaluation model on R&D structure and contribution to economic growth in Hebei Province, PRC. A comparison of regional R&D efficiencies provides an important guideline for local governments with respect to future policy making. The framework used in Hebei Province in this paper offers a good reference for some other regions as well.

Details

Journal of Technology Management in China, vol. 2 no. 3
Type: Research Article
ISSN: 1746-8779

Keywords

Article
Publication date: 25 February 2014

Baomin Fan, Gang Wei, Zhan Zhang and Ning Qiao

This work was focused upon the main factors that influence the formation of a hydroxypropyl-β-cyclodextrin (HP-β-CD) supramolecular complex with octadecylamine (ODA) and their…

Abstract

Purpose

This work was focused upon the main factors that influence the formation of a hydroxypropyl-β-cyclodextrin (HP-β-CD) supramolecular complex with octadecylamine (ODA) and their optimal processing conditions. The anti-corrosion properties of the products in the simulated boiler water condensate of power plants also needed to be tested. The paper aims to discuss these issues.

Design/methodology/approach

A grinding method was applied to synthesize the supramolecular structures. Using Fourier transform infrared, X-ray diffraction and proton nuclear magnetic resonance spectroscopy (1H NMR), the specific structures of the complex were clarified. The anti-corrosion properties were obtained from gravimetric results, potentiodynamic polarization tests and electrochemical impedance spectroscopy measurements.

Findings

The results reveal the highly soluble supramolecular complex could be formed between two HP-β-CD molecules and one ODA molecule at 85°C with a processing period of 15 minutes. In the condensate, the corrosion inhibition efficiency of the complex was over 95 percent, much higher than the inhibition efficiency of the hydrophobic ODA compound.

Practical implications

The supramolecular corrosion inhibitor could be used as an anti-corrosion method for industrial boiler condensate to reduce the content of corrosive ions. In this way, it is easier to reuse the condensate without re-polishing.

Originality/value

The research introduces supramolecular chemistry into corrosion science for the first time. The results provide a new option to modify the traditional corrosion inhibitors.

Details

Anti-Corrosion Methods and Materials, vol. 61 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 2 January 2023

Yinxia Dong, Mingtian Li, Yingjun Zhang, Chun Xie and Zhongwen Pan

The purpose of this study is to modify cerium dioxide with fumaric acid (CeO2-f) to improve its compatibility and dispersibility in epoxy resin and to investigate the effect of…

Abstract

Purpose

The purpose of this study is to modify cerium dioxide with fumaric acid (CeO2-f) to improve its compatibility and dispersibility in epoxy resin and to investigate the effect of the content on the coating performance.

Design/methodology/approach

To investigate whether CeO2-f reacts with epoxy resin by ring opening, CeO2-f and epoxy resin-treated CeO2-f (Ce CeO2-f/EP) were analyzed by infrared radiation (IR), X-ray diffraction (XRD) and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis). To reveal the effect of different content on coatings properties, neutral salt spray test (NSST) and electrochemical test were performed.

Findings

The results of IR, XRD, X-ray photoelectron spectroscopy and UV-Vis indicated that fumaric acid attached to the CeO2 surface by chemical bonding and underwent a ring-opening reaction with epoxy resin, thus, improving the compatibility of CeO2 in epoxy resin. NSST and electrochemical impedance spectroscopy results showed that the coatings containing 5% CeO2-f exhibited the optimal corrosion resistance. The reason is that a dense conversion film was established on the substrate surface.

Originality/value

The epoxy coatings using CeO2-f as fillers with synergistic inhibition ability are promising for the protection of carbon steel.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 25 August 2023

Xin Zhou, Wenbin Zhou, Yang Zheng Zhang, Meng-Ran Li, Haijing Sun and Jie Sun

This paper aims to study the corrosion inhibition behavior of imidazopyridine and its three derivatives on brass.

Abstract

Purpose

This paper aims to study the corrosion inhibition behavior of imidazopyridine and its three derivatives on brass.

Design/methodology/approach

The authors performed weight loss experiments, electrochemical experiments including the polarization curve and electrochemical impedance spectrum, corrosion morphology observation using scanning electron microscope (SEM) and atomic force microscope (AFM) and surface composition analysis via X-ray photoelectron spectroscopy (XPS) to analyze the corrosion inhibition behavior of imidazopyridine and its three derivatives on brass by using quantum chemical calculation (Gaussian 09), molecular dynamics simulation (M-S) and Langmuir adsorption isotherm.

Findings

According to the results, imidazole-pyridine and its derivatives were found to be modest or moderately mixed corrosion inhibitors; moreover, they were spontaneously adsorbed on the metal surface in a single-layer, mixed adsorption mode.

Originality/value

The corrosion inhibition properties of pyrazolo-[1,2-a]pyridine and its derivatives on brass in sulfuric acid solution were analyzed through weight loss and electrochemical experiments. Moreover, SEM and AFM were simultaneously used to observe the corrosion appearance. Furthermore, XPS was used to analyze the surface. Then, Gaussian 09 and M-S were combined along with the Langmuir adsorption isotherm to investigate the corrosion inhibition mechanism of imidazole-[1,2-a]pyridine and its derivatives.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

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