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To decrease wear and friction, zinc dialkyldithiophosphate (ZDDP) has been used in engine oil for several decades, but the mechanism of the tribofilm formation is still unclear. The purpose of this study is to characterize the chemical details of the tribofilm by using high-resolution approaching.

An ISO VG 100 mineral oil mixed with ZDDP was used in sliding tests on cylindrical roller bearings. Tribofilm formation was observed after 2 h of the sliding test. X-ray photoelectron spectroscopy (XPS) and atom probe tomography (APT) were used for chemical analysis of the tribofilm.

The results show that the ZDDP tribofilm consists of the common ZDDP elements along with iron oxides. A considerable amount of zinc and a small amount of sulfur were observed. In particular, an oxide interlayer with sulfur enrichment was revealed by APT between the tribofilm and the steel substrate. The depth profile of the chemical composition was obtained, and a tribofilm of approximately 40 nm thickness was identified by XPS.

A sulfur enrichment at the interface is observed by APT, which is beneath an oxygen enrichment. The clear evidence of the S interlayer confirms the hard and soft acids and bases principle.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-01-2020-0035/

The purpose of this study is to investigate the effect of ferrite on hydrogen embrittlement (HE) of the 17-4PH stainless steels.

The effects of ferrite on HE of the 17-4PH stainless steels were investigated by observing microstructure and conducting slow-strain-rate tensile tests and hydrogen permeability tests.

The microstructure of the ferrite-bearing sample is lath martensite and banded ferrite, and the ferrite-free sample is lath martensite. After hydrogen charging, the plasticity of the two steels is significantly reduced, along with the tensile strength of the ferrite-free sample. The HE susceptibility of the ferrite-bearing sample is significantly lower than the ferrite-free steel, and the primary fracture modes gradually evolved from typical dimple to quasi-cleavage and intergranular cracking. After aging at 480°C for 4 h and hydrogen charging for 12 h, the 40.9% HE susceptibility of ferrite-bearing samples was the lowest. In addition, the hydrogen permeation tests show that ferrite is a fast diffusion channel for hydrogen, and the ferrite-bearing samples have higher effective hydrogen diffusivity and lower hydrogen concentration.

There are a few studies of the ferrite effect on the HE properties of martensitic precipitation hardening stainless steel.

High-strength martensitic steels having strong hydrogen embrittlement (HE) susceptibility and the metal carbide (MC) nanoprecipitates of microalloying elements such as Nb, V, Ti and Mo in the steel matrix can effectively improve the HE resistance of steels. This paper aims to review the effect of MC nanoprecipitates on the HE resistance of high-strength martensitic steels.

In this paper, the effects of MC nanoprecipitates on the HE resistance of high-strength martensitic steels are systematically described in terms of the types of MC nanoprecipitates, the influencing factors, along with numerical simulations.

The MC nanoprecipitates, which are fine and semicoherent with the matrix, effectively improve the HE resistance of steel through the hydrogen trapping effects and microstructure optimization, but its effect on the HE resistance of steel is controlled by its size, number and distribution state.

This paper summarizes the effects and mechanisms of MC nanoprecipitates on HE performance of high-strength martensitic steel and provides the theoretical basis for corrosion engineers to design high-strength martensitic steels with excellent HE resistance and improve production processes.

The purpose of this paper is to investigate the driving mechanisms for crack propagation regarding the related microstructures. Cracks in white etching layers have been found at the surface of submerged steel blades subjected to frictional sliding conditions.

In-situ monitoring revealed a fluctuation between mixed lubrication and hydrodynamic lubrication conditions. One lamella including a crack tip was prepared for transmission electron microscopy (TEM) using focused ion beam milling. Transmission electron microscope analysis was performed with the aim to understand the characteristics of the crack propagation, especially considering the influence of the microstructural configuration (grain refinement, carbides, martensite and ferrite grains).

The investigations have shown a grain-refined plastically deformed layer (friction martensite with grain sizes of < 100 nm) which influences the propagation direction of cracks introduced at the frictionally stressed surface. Thereby, the crack propagation is dominantly parallel to the margin of the grain-refined martensitic layer at the surface and the base material. Cracks were split into side cracks what mostly appears at present carbides. In this case, the crack propagation might strike through the carbide or separate it from the matrix due to the mechanical misfit.

For obtaining the results of this paper, a very special preparation of tribologically stressed samples was performed. Accordingly, specific findings of the crack propagation behavior under such conditions were achieved and are documented in the presented work. Moreover, the described crack propagation process is a combination of several mechanisms which occur in very limited region underneath the surface and are investigated by high-resolution TEM.

Additive manufacturing is a fabrication technology with flexibility and economy. 18Ni300 is one of maraging steels with ultra-high strength, superior toughness, so it is an excellent candidate of structural material. This paper aims to explore the feasibility of using direct laser metal deposition method to fabricate18Ni300, and the evolution of its microstructure and defects is studied.

The experiments were conceived from single-trace-single-layer (STSL) test to multi-trace-multi-layers (MTML) test via single-trace-multi-layers (STML) test. The microstructure, defects and mechanical properties were analyzed.

The STML results showed that the columnar/equiaxed transformation occurred at the top part and the grain size increased with the layer number increasing, and it was explained by an innovative attempt combining columnar/equiaxed transformation model and the change of grain size. The MTML test with the interlayer orthogonal parallel reciprocating scanning pattern resulted in the grain growing along orthogonal directions; with the increase of overlap rate, the length and the area of the columnar grain decreased. What is more, the later deposition layer had lower micro-hardness value because of heat history.

Direct laser metal deposition method was a novel additive manufacturing method to manufacture 18Ni300 components, as 18Ni300 maraging steel was mainly manufactured by selective laser melting (SLM) method nowadays. It was useful to manufacture maraging steel parts using direct laser deposition method because it could manufacture larger parts than SLM method. Influence of processing parameters on forming quality and microstructure evolution was studied. The findings will be helpful to understand the forming mechanism of laser additive manufacturing of 18Ni300 components.

To find out the optimum heat treatments to recover the microstructural changes of stainless steel alloys.

A total of four alloys were used in this study: two duplex stainless steel (DSS) alloys type 2304 and 2205, super DSS (SDSS) type 2507 and austenitic stainless steel alloy type 316 L. The alloys were heated to different temperatures, 750, 850, 950 and 1,050°C, for three different times, 10 min, 1 and 4 h.

The microstructural investigations showed that 2205 and 2507 behaved similarly in recovering their microstructures, especially in terms of the ferrite:austenite ratio within specific heat treatments and changing the hardness values. The results indicated that the microstructure of both alloys started to change above 750°C, the largest changes were shown at 850 and 950°C as the lowest ferrite content (FC%) was recorded at 850°C for both alloys. However, the microstructures of both alloys started to recover at 1,050°C. The reduction in the hardness values was attributed to the formation of new ferrite grains, free of residual stresses. On the other hand, the microstructure of the alloy type 2304 was stable and did not show large changes due to the applied heat treatments, similarly for austenitic alloy except showing chromium (Cr) carbide precipitation.

Finding the exact heat treatments, temperature and time to recover the microstructural changes of DSS alloys.

Nanocrystalline LaB₆, NdB₆, Nd-doped LaB₆ and La-doped NdB₆ have been studied using the density functional theory (DFT) to study their electronic, optical and mechanical characteristics. The purpose of this paper is to address this issue.

Nanocrystalline LaB₆, NdB₆, Nd-doped LaB₆ and La-doped NdB₆ have been studied using the DFT to study their electronic, optical and mechanical characteristics. The calculated lattice constants of LaB₆, NdB₆, Nd-doped LaB₆ and La-doped NdB₆ were 4.157, 4.118, 4.267 and 4.449, respectively. The lattice constant of La₇Nd₁B₆ was increased when Nd is doped into LaB₆. B p comprised the uppermost valence bands (VBs), whereas B s comprised the lowermost conduction bands (CBs). The authors’ results showed that La doping reduced the work function of NdB₆ and increased its thermionic emission characteristics.

The authors’ results showed that La doping reduced the work function of NdB₆ and increased its thermionic emission characteristics.

The work function of LaB₆ was 2.7 eV, which is higher than that of La₁Nd₇B₆ (2.64 eV).

The purpose of this paper is to explore gas/liquid two-phase flow is widely existed in industrial fields, especially in chemical engineering. Electrical resistance tomography (ERT) is considered to be one of the most promising techniques to monitor the transient flow process because of its advantages such as fast respond speed and cross-section imaging. However, maintaining high resolution in space together with low cost is still challenging for two-phase flow imaging because of the ill-conditioning of ERT inverse problem.

In this paper, a sparse reconstruction (SR) method based on the learned dictionary has been proposed for ERT, to accurately monitor the transient flow process of gas/liquid two-phase flow in a pipeline. The high-level representation of the conductivity distributions for typical flow regimes can be extracted based on denoising the deep extreme learning machine (DDELM) model, which is used as prior information for dictionary learning.

The results from simulation and dynamic experiments indicate that the proposed algorithm efficiently improves the quality of reconstructed images as compared to some typical algorithms such as Landweber and SR-discrete fourier transformation/discrete cosine transformation. Furthermore, the SR-DDELM has also used to estimate the important parameters of the chemical process, a case in point is the volume flow rate. Therefore, the SR-DDELM is considered an ideal candidate for online monitor the gas/liquid two-phase flow.

This paper fulfills a novel approach to effectively monitor the gas/liquid two-phase flow in pipelines. One deep learning model and one adaptive dictionary are trained via the same prior conductivity, respectively. The model is used to extract high-level representation. The dictionary is used to represent the features of the flow process. SR and extraction of high-level representation are performed iteratively. The new method can obviously improve the monitoring accuracy and save calculation time.

Rolling bearing operation under mixed and boundary lubrication conditions may lead to heavy adhesive or abrasive wear, which may lead to wear-induced rolling bearing failure. The purpose of this paper is to investigate the wear protection capabilities of different grease compositions at varying temperatures. It is considered that the temperature influences the lubrication conditions, the behaviour of grease components, namely, bleed oil and thickener, as well as the tribofilm formation due to tribo-chemical interactions between additives and surfaces.

In this study, four different greases were produced on the basis of a mineral base oil by varying the thickener and the addition of ZDDP. Various grease-lubricated rolling bearing experiments were conducted in a wide temperature range from 0°C to 120°C. Subsequently, the wear pattern, tribofilm formation and grease structures were analysed. Thereby, the influence of the different grease thickeners and the performance of ZDDP as a common antiwear and extreme pressure additive was evaluated.

The results show a strong temperature-dependency and allow a classification of temperature ranges concerning wear protection. At low temperatures, all greases provide a very good wear protection without the evidence of additive-based tribofilm formation. In the experiments at elevated temperatures, ZDDP tribofilms were formed. The formation depends on the thickener type: in comparison to lithium thickener, polyurea thickener favours more protective tribofilms at the same temperature. The experimental results show that medium temperatures in the range of 40°C–60°C are critical concerning wear due to the insufficient tribolayer formation and limited load carrying capacity of the grease.

Temperature is a key operating parameter for grease lubrication in roller bearings. The experimental work enables consideration of different impact pathways of temperature by combining roller bearing tests and microanalysis.

The purpose of this study is to develop a method of thermodynamic and kinetic evaluation of corrosion properties of alloys.

Method of estimation of corrosion-electrochemical behaviour of multicomponent alloys is proposed. The method takes into account both thermodynamic and kinetic data and is based on mutual construction of equilibrium and polarization potential – pH diagrams. The usage of the proposed method is illustrated in the example of the structural steel 20KT.

Passivation of steel 20KT is determined by formation of oxide film based on magnetite (Fe₃O₄); silicon, manganese and copper oxides as well as manganese sulphides can be locally included into the inner side of the passivation layer. An experimental potential – pH diagram of steel 20KT is constructed. Interpreting the results of polarization measurements revealed good agreement between equilibrium and polarization potential – pH diagrams.

It is shown in the example of structural steel 20KT that for interpretation of experimental potential – pH diagrams, one should compare them with corresponding equilibrium diagrams for multicomponent alloys rather than with Pourbaix diagrams for pure metals. The corrosion properties of steel 20KT are estimated using equilibrium and polarization potential – pH diagrams.