Search results

The purpose of this paper is to investigate the performance of natural Jordanian zeolite tuff to remove ammonia from aqueous solutions using a laboratory batch method and fixed-bed column apparatus. Equilibrium data were fitted to Langmuir and Freundlich models.

Column experiments were conducted in packed bed column. The used apparatus consisted of a bench-mounted glass column of 2.5 cm inside diameter and 100 cm height (column volume = 490 cm3). The column was packed with a certain amount of zeolite to give the desired bed height. The feeding solution was supplied from a 30 liter plastic container at the beginning of each experiment and fed to the column down-flow through a glass flow meter having a working range of 10-280ml/min.

Ammonium ion exchange by natural Jordanian zeolite data were fitted by Langmuir and Freundlich isotherms. Continuous sorption of ammonium ions by natural Jordanian zeolite tuff has proven to be effective in decreasing concentrations ranging from 15-50 mg NH₄-N/L down to levels below 1 mg/l. Breakthrough time increased by increasing the bed depth as well as decreasing zeolite particle size, solution flow-rate, initial NH₄+ concentration and pH. Sorption of ammonium by the zeolite under the tested conditions gave the sorption capacity of 28 mg NH₄-N/L at 20°C, and 32 mg NH₄-N/L at 30°C.

This research investigates the performance of natural Jordanian zeolite tuff to remove ammonia from aqueous solutions using a laboratory batch method and fixed-bed column apparatus. The equilibrium data of the sorption of Ammonia were plotted by using the Langmuir and Freundlich isotherms, then the experimental data were compared to the predictions of the above equilibrium isotherm models. It is clear that the NH₄+ ion exchange data fitted better with Langmuir isotherm than with Freundlich model and gave an adequate correlation coefficient value.

This study aims to use porous concrete and mineral adsorbents (additives) for reducing the quantity and improving the quality of urban runoff.

The effects of adding mineral adsorbents and fine grains to porous concrete is tested for increasing its performance in improving the quality of urban runoff. Two levels of sand (10 and 20 per cent) and 5, 10 and 15 per cent of zeolite, perlite, LECA and pumice were added to the porous concrete. Unconfined compressive strength, hydraulic conductivity (permeability) and porosity of the porous concrete specimens were measured. Some of the best specimens were selected for testing the improvement of runoff quality. A rainfall simulator was designed and the quality of the runoff was investigated for changes in electrical conductivity (EC), total suspended solids (TSS), total dissolved solids (TDS) and chemical oxygen demand (COD).

The results of this study showed that compressive strength of the porous concrete was increased by adding fine grains to the concrete mixture. Fine grains decreased the permeability and porosity of the samples. Zeolite had the highest compressive strength. Samples having pumice own maximum permeability. Samples which had perlite, had the least compressive strength and permeability. Because of the fast flow of runoff water in the porous slab and its low thickness, sufficient time was not provided for effective functioning of the additives, and the removal percentage of the pollution parameters was low.

Porous concrete can ameliorate both quantity and quality of the urban runoff.

The purpose of this paper is to assess the water quality parameters resulting on: First, the flow direction in biofilters (ascending or descending), second, constructed wetland (CW) with local plant species and third, the combined system for the removal of organic matter and nutrients pollutants from water in arid regions.

An integrated system is presented and tested in situ with a vertical up-flow and down-flow biofilters. Two configurations schemes are followed by a three separated horizontal subsurface CWs: two planted with Phragmites australis, Typha latifolia and the third unplanted. The methodology is based on a statistical analysis of the collected data.

The present experiment demonstrated that the wetlands planted with P. australis and T. latifolia showed the highest removal. Moreover, T. latifolia performed better than P. australis for most of the parameters, notably in the first system, whereas the wetland efficiency indicated that P. australis contributed greatly to the removal of TP in the first system and NO₃-N in the second system. In general, for the highest removal efficiencies of the combined biofilters and wetlands system, the present study demonstrated that the first system performed better than the second for all the parameters.

The originality of the research is that it compares in situ two biofilter systems: vertical up-flow and down-flow biofilters. To avoid the effects of domestic wastewater that is discharged directly without treatment in the Oued Righ channel or in the lake, this integrated system can be one of the alternatives for wastewater treatment, as it reveals the need to protect aquatic ecosystems in arid regions, and can decrease the risks to human health and the environment.

This study aims to investigate the hydraulic behaviour of a pilot-scale, two-staged, vertical flow constructed wetland (VFCW) for septage treatment, in terms of factors such as hydraulic retention time and hydraulic loading rate and its influence on the treatment dynamics. Because of intermittent feeding mode of VFCW systems and variation in its loading, its hydraulic behaviour is highly variable and need to be understood to optimize its treatment performance.

Tracer test were carried out using bromide ion with varying hydraulic loading rates (HLR) of 6.82 cm/d, 9.09 cm/d and 11.40 cm/d (i.e. equivalent to 75 L/d, 100L/d and 125 L/d). Tracer data is then analysed using the Residence Time Distribution (RTD) method.

RTD analysis showed that the increase in HLR increases the average hydraulic retention time (HRT). Subsequently, the increase in HLR results in a lower recovery of effluent, resulting in poor productivity in treatment. The study also showed that the removal of nitrogen and organic matter improved with increasing HRT. However, observations show no correlation between HRT and total solids removal.

A performance evaluation method (by tracer) is proposed to understand the hydraulics of flow in constructed wetlands, which has not been widely studied. Additionally, the dynamics of treatment in VFCWs treating septage may also be revealed by the tracer method. The study can be applied to any constructed wetlands designed for treatment of wastewater, septage or sludge.

The main purpose of this study resides essentially in the development of a new tool to quantify the biomass in the bioreactor operating under steady state conditions.

Modeling is the most relevant tool for understanding the functioning of some complex processes such as biological wastewater treatment. A steady state model equation of activated sludge model 1 (ASM1) was developed, especially for autotrophic biomass (XBA) and for oxygen uptake rate (OUR). Furthermore, a respirometric measurement, under steady state and endogenous conditions, was used as a new tool for quantifying the viable biomass concentration in the bioreactor.

The developed steady state equations simplified the sensitivity analysis and allowed the autotrophic biomass (XBA) quantification. Indeed, the XBA concentration was approximately 212 mg COD/L and 454 mgCOD/L for SRT, equal to 20 and 40 d, respectively. Under the steady state condition, monitoring of endogenous OUR permitted biomass quantification in the bioreactor. Comparing XBA obtained by the steady state equation and respirometric tool indicated a percentage deviation of about 3 to 13%. Modeling bioreactor using GPS-X showed an excellent agreement between simulation and experimental measurements concerning the XBA evolution.

These results confirmed the importance of respirometric measurements as a simple and available tool for quantifying biomass.

The purpose of this paper is to provide a novel method for encapsulation of phthalocyanine blue pigment for inkjet printing inks.

Phthalocyanine blue pigment was encapsulated by emulsion polymerisation of styrene and a polymerisable dispersant, allyloxy nonyl‐phenoxy propanol polyoxyethylene ether ammonium sulphonate (ANPS). The encapsulated phthalocyanine blue pigment was further formulated into dispersion. The encapsulated phthalocyanine blue pigment was characterised with transmission electron microscopy (TEM), thermogravimetric analyses (TGA), X‐ray diffraction (XRD), Zeta potential and contact angle measurements. The encapsulated phthalocyanine blue pigment dispersion was evaluated in terms of rheological behaviour, particle size distribution and stability.

TEM and TGA proved that polymer encapsulation layer was formed onto phthalocyanine blue pigment surface. XRD indicated that the crystal structure of phthalocyanine blue pigment was not changed during the encapsulation process. The wettability of phthalocyanine blue pigment was improved after polymer encapsulation. The dispersion formulated with encapsulated phthalocyanine blue pigment had a narrow particle size distribution, excellent stability to temperature and centrifugal forces. Its rheological behaviour was close to Newtonian fluid.

The methods provided a novel and practical solution for preparing the encapsulated phthalocyanine blue pigment dispersion for formulation of inkjet printing ink.

The paper demonstrates how emulsion polymerisation technique is employed to encapsulate phthalocyanine blue pigment using a polymerisable dispersant, ANPS, which imparts to dispersion a small particle size, narrow particle size distribution and high stability.

The European Water Framework Directive is the basis of sustainable water resources management in the European Union. The required “good status” of waterbodies can be achieved only by encouraging the application of natural renewable‐energy‐driven ecological engineering. Ecotechnological methods in wastewater treatment (e.g. constructed wetlands) can remove more than 90 per cent of total N and P, and organic load. These methods also save up to 80 per cent of the cost and energy compared with central technical systems. Because ecomorphology in around 80 per cent of German streams and rivers is disturbed to a high degree, increased efforts for renaturalization are necessary. Successful control concerning first initiated measures shows that improvement of stream morphology has a remarkable positive influence on water ecology.

The purpose of this paper is to investigate the efficacy of bacterial exopolysaccharides (Eps) in reactive black 5 (RB5) textile dye wastewater bioremediation.

The Eps were produced by bacteria isolated from cotton gin trash soils collected from different cotton-growing regions in Kenya for comparison purposes. A broth medium reconstituted using molasses was assessed for its capacity to produce the Eps. RB5 textile dye wastewater was optimized for dye removal under different temperatures, times and molasses concentrations. Dye removal was studied by Lovibond-Day Light Comparator, UV–Vis spectrophotometer and FTIR.

It was found that cotton gin trash soils contained Eps-producing bacteria. Three of the Eps studied were found to have the capacity to remove at least 80% of the dye from the wastewater.

This research did not assess the efficacy of the RB5 dye removal from the wastewater by mixtures of the Eps.

Bioremediation of textile dye wastewater with Eps produced by bacteria cultured from cotton gin trash soil is significant because it will offer an effective and cleaner alternative to the chemical coagulants.

Alternative treatment of textile wastewater with the Eps would result in safer water being released into the water bodies as opposed to the chemically treated wastewater that contains remnant chemicals.

Research on the use of Eps produced by bacteria isolated from cotton gin trash soils for removal of RB5 dye from textile wastewater has not been done before.

The purpose of this study is to prepare Polystyrene grafted with Zeolite Y (Zeosty) for Uranyl ion [U(VI)] adsorption from aqueous solution. The adsorption mechanism has been explained by studying kinetic, isothermal and thermodynamic models.

Polystyrene was grafted with Zeosty by a simple hydrothermal technique. Zeosty was characterized by different techniques such as X-ray diffraction, scanning electron microscope, energy dispersive X-ray and Infrared spectroscopy to confirm its structure and its molecular composition. Zeosty was used for U(VI) adsorption from an aqueous solution in a series of batch experiments. The effects of pH, contact time, initial U(VI) concentration and temperature on the adsorption process were investigated.

The results showed that the adsorption of U(VI) on the prepared reached equilibrium at pH 6 with a removal efficiency of 98.9%. Adsorption kinetics and isotherms models are studied on the experimental data to estimate the mechanism of the adsorption reaction was chemisorption and homogenous reaction. The activity of Zeosty increased at high temperatures, resulting in the adsorption capacity increase. Thermodynamic parameters ΔGo, ΔHo and ΔSo indicate that the adsorption processes are spontaneous and endothermic. Zeosty has an effective surface and could be considered a valuable adsorbent for U(VI) removal from aqueous waste. A comparison study proves that the new adsorbent has high effective behavior in the adsorption process, and it is considered a new reliable adsorbent for U(VI) removal from wastewater.

This study is complementary to the previous study using the same technique to prove that the effective fine particle adsorbents need solid support to enhance their absorption capacities.

This paper aims to evaluate the inhibitive potential of borage flowers’ aqueous extract (BFAE), Borago officinalis L., against the corrosion of mild steel in 1.0 M phosphoric acid.

Evaluation was carried out by chemical hydrogen evolution (HE), mass loss (ML) and electrochemical potentiodynamic polarization (PDP) measurements. SEM-EDX analysis also was used to confirm the existence of the adsorbed film.

It was found that the inhibition efficiency of BFAE increases with the increase in its concentration, but decreases with the increase in temperature. The potentiodynamic polarization curves indicated that BFAE acts as a mixed-type inhibitor with a predominantly anodic action. The adsorption of BFAE on mild steel surface was found to obey Langmuir and thermodynamic-kinetic adsorption isotherms by forming a thin film on the metal surface. SEM-EDX analysis confirms the corrosion inhibition ability of BFEA in 1.0 M H₃PO₄ by forming a thin film on mild steel surface. In this study, the inhibitive action of BFAE components is discussed on the basis of the physical adsorption mechanism. The same results were obtained for both the freshly prepared extract and the one that kept in a refrigerator for one year.

This paper indicates that BFAE can act as a good inhibitor for the corrosion of mild steel in 1.0 M H₃PO₄ even after one year of preparation.