Search results

In this study, solid formaldehyde, benzoguanamine and butanol were used to synthesize butylated benzo-amino resin by one-step-two-stage method.

This research first examined the influence of solid formaldehyde content on the hydroxymethylation phase. Subsequently, the effects of butanol content, etherification time and hydrochloric acid content on the formation of benzo-amino resin during the etherification stage were studied in detail. In addition, the reaction process was further analyzed through interval sampling withdrawing during the hydroxymethylation and etherification stages. Finally, the synthesized benzo-amino resins were used in the production of high solid content polyester and acrylic coatings and the properties of that were also evaluated.

Based on the experimental findings, the authors have successfully determined the optimal process conditions for the one-step-two-stage method in this study. The hydroxymethylation stage demonstrated the most favorable outcomes at a reaction temperature of 60°C and a pH of 8.5. Similarly, for the etherification stage, the optimal conditions were achieved at a temperature of 45°C and a pH of 4.5. Furthermore, the investigation revealed that a ratio of benzoguanamine to solid formaldehyde to n-butanol, specifically at 1:5.2:15, produced the best results. The performance of the resulting etherified benzo-amino resin was thoroughly evaluated in high solid content coatings, and it exhibited promising characteristics. Notably, there was a significant enhancement in the water resistance, solvent resistance and glossiness of canned iron printing varnish coatings.

Amino resin, a versatile chemical compound widely used in various industries, presents challenges in terms of sustainability and operational efficiency when synthesized using conventional methods, primarily relying on a 37% formaldehyde solution. To address these challenges, the authors propose a novel approach in this study that combines the advantages of the solid formaldehyde with a two-stage catalytic one-step synthesis process. The primary objective of this research is to minimize the environmental impact associated with amino resin synthesis, optimize resource utilization and enhance the economic feasibility for its industrial implementation. By adopting this alternative approach, the authors aim to contribute toward a more sustainable and efficient production of amino resin.

The paper deals with the mode of film formation from urea–formaldehyde and melamine–formaldehyde resins combined with alkyd resin based on castor oil‐modified alkyd. The properties of hardened coatings (such as hardness, chemical stability, and adhesion to substrate) were followed in dependence on the ratios of reaction components. An apparatus was built for measuring the formaldehyde emissions escaping from the solid coating films. The determination was performed by the pararosaniline method. The addition of imidazolidine in a concentration up to 10 per cent can reduce the emissions of formaldehyde escaping from the solid films to a considerable amount.

Modern glues are manufactured with high moisture and water resistance; urea‐formaldehyde resins for gluing purposes are based on the fact that excellent control of the condensation reaction is possible by variation of pH, which can be applied easily at the production process. Among conclusions is that the shear stress of these resins is twice that of the unmodified type.

The inclusion of the word ‘some’ in the above title is essential. When reviewing even a fraction of all the literature dealing with current and likely future developments in the synthetic resins field, it becomes apparent that any paper adequately covering this would be far too long to be of any use in a symposium such as this. It has therefore been necessary to highlight certain aspects which are of a major nature on the one hand and more familiar to the author on the other.

The purpose of the study was to prepare melamine-urea-formaldehyde (MUF) resin that would be resistant to boiling water and high temperature and exhibit low formaldehyde emission.

The authors prepared MUF resin with different F/(M + U) and changed the amount of melamine added, through the analysis of MUF resin properties to get the best reaction parameters, and used different amino acid cure systems including NH₄Cl cured the resin.

Resin’s heat resistance and water resistance are mainly determined by the amount of melamine added, and formaldehyde emission of the plywood can be changed by adjusting F/(M + U). The peak temperature of the curing agent-cured resin increases as compared with the self-curing resin. Stronger the acidity of curing agent, faster the viscosity increased in probation period and lower the bonding strength and heat resistance of the resin.

Melamine improves the heat resistance and water resistance of the resin. When the amount of melamine is more than a certain value, water resistance of the resin decreased.

MUF resin that is resistant to boiling water and exhibits low formaldehyde emission can be used in high temperature, high humidity and strict formaldehyde emission environment and can also be combined with other materials.

It was helpful to reduce the effect of formaldehyde emission on people’s health and environmental pollution and is also beneficial for the expansion of the application range of aldehyde resin.

The originality is twofold: the influence of the acid strength of curing agent on the bonding strength of the resin adhesive and the method for preparing high performance MUF resin by following the traditional process.

Of all the resins used by paint technologists in the formulation of paints the most interesting, as a class, are the epoxy resins. This interest stems, not from their chemical composition, but from the enormous range of practical uses to which these resins can be put. An attempt has been made in this paper, read to the N.E. branch of BACE, to rationalise the common ways in which epoxy resins are used as protective film formers and to simplify the choice of systems for any particular corrosion problem.

This study aims to using Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy and scanning electron microscope/energy dispersive Xray spectrometer to identify different automotive coatings for forensic purpose.

Two four-layered samples in a hit-and-run case were compared layer by layer with three different methods. FTIR spectroscopy was used to primarily identify the organic and inorganic compositions. Raman spectrum and scanning electron microscope/energy dispersive Xray spectrometer (SEM-EDS) were further used to complement the FTIR results.

Two weak and tiny peaks in one layer found between two samples by FTIR, Raman microscope and SEM-EDS verified the result of differences. The study used the three instruments in combination and found it’s effective in sensing coatings, especially in the inorganic additives.

Using these three instruments in combination is more accurate than individually in multilayered coating analysis for forensic purpose.

The three different instruments all present unique information on the composition, and provided similar and mutually verifiable results on the two samples.

With this method, scientists could identify and discriminate important coating evidences with tiny but characteristic differences.

A well appreciated difficulty in paint formulation is the scaling‐up of laboratory data, and to obtain optimum performance on a commercial scale adjustments in p.v.c. (f) and in resin solids concentration have to be made. In the laboratory the millable p.v.c. (f) of a given formulation may be above, or more usually below, the value indicated by the flowpoint data, and depends mainly on the ability of the particular milling machine to cope with the quantity and nature of the millbase. In large‐scale manufacture using high‐speed shear impellers, a somewhat higher value than the experimentally determined p.v.c. (f) can be used, but for a ballmill it will be only slightly higher than the value millable in the laboratory. The concentration of resin solids has also to be adjusted, and here it is important to ensure that it is high enough to prevent pigment reagglomeration on let‐down.

The purpose of this study is to improve the coating properties of shellac–epoxidised novolac blends by treatment with melamine formaldehyde resin (MF) at ambient temperature for its use as a coating material.

Epoxidised-novolac resin was synthesised by epoxidation of novolac resin with epichlorohydrin. Novolac resin was synthesised by reaction of phenol with formaldehyde in acidic medium. Shellac was blended with the epoxidised-novolac resin in solution in varying ratios and treated the blends with MF resin in fixed ratio. Coating properties of the treated compositions were studied using a standard procedure. The compositions were characterised with Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA) and scanning electron microscopic (SEM) spectroscopy.

Treatment of shellac–epoxidised-novolac blends with MF resin improved water and alkali resistance of the blends, besides enhancing gloss. Gloss in all the blends was uniformly increased on treatment with MF resin. Water resistance of the blends tremendously improved after treatment with MF resin. Contact angle of the blends against water increased while decreased against ethylene glycol and dioxane. The compositions were more resistant to polar solvent than non-polar ones, suggesting that the compositions shifted to hydrophobic (lipophilic) nature on treatment with the MF resin.

A specified concentration of MF resin was used in the study. Different concentrations of the MF resin can also be tried for treatment of shellac–epoxidised-novolac blends to see the effect of the resin on the blends.

Treatment of shellac–epoxidised-novolac blend with MF resin improved the coating properties of the blends. The formulation SeNB-64 is the best with high gloss, good impact, scratch hardness and water resistance, and hence can be used as coating material for metal surfaces.

Blending of shellac with epoxidised-novolac resin and treatment of the blends with the MF resin was done for the first time. The formulation SeNB-64 can be used as coating material for metal surfaces.

To improve the efficiency of flame retardant paints for wood by using different fillers and thermoplastic and thermosetting binders.

For effective flame retardancy, various paint compositions were made by incorporating different binders and fillers. The physical and mechanical properties, of the paint films, storage stability, limited oxygen index (LOI) and differential thermal analysis were investigated.

Diammonium hydrogen orthophosphate has all the characteristics required to be used as flame retardant filler for paint, in contrary to magnesium hydroxide, Mg(OH)₂, which has undesired effect on the storage stability of paints based on alkyd resin. The values of LOI depend on the type and composition of the binder.

The flame retardancy of the prepared paints could also be evaluated using more conventional methods such as oxygen index test.

Special fillers and binders that could be used in highly efficient flame retardant paint for wood have been identified.

The fillers are non‐toxic. Different fillers obtained could be used in various thermosetting binders beside thermoplastic ones.