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Important differentiating attributes in the procedures used, the characteristic mineral composition of the binders, and the implications these have on the final long term stability and physico-mechanical performance of the concretes produced are identified and discussed, with the intent to improve transparency and clarity in the field of geopolymer concrete technologies.

This state-of-the-art review covers the area of geopolymer concrete, a class of sustainable construction materials that use a variety of alternative powders in lieu of cement for composing concrete, most being a combination of industrial by-products and natural resources rich in specific required minerals. It explores extensively the available essential materials for geopolymer concrete and provides a deeper understanding of its underlying chemical mechanisms.

This is a state-of-the-art review introducing the essential characteristics of alternative powders used in geopolymer binders and the effectiveness these have on material performance.

With the increase of need for alternative cementitious materials, identifying and understanding the critical material components and the effect they may have on the performance of the resulting mixes in fresh as well as hardened state become a critical requirement to for short- and long-term quality control (e.g. flash setting, efflorescence, etc.).

The topic explored is significant in the field of sustainable concrete technologies where there are several parallel but distinct material technologies being developed, such as geopolymer concrete and alkali-activated concrete. Behavioral aspects and results are not directly transferable between the two fields of cementitious materials development, and these differences are explored and detailed in the present study.

Demand for Geopolymer concrete (GPC) has increased recently because of its many benefits, including being environmentally sustainable, extremely tolerant to high temperature and chemical attacks in more dangerous environments. Like standard concrete, GPC also has low tensile strength and deformation capacity. This paper aims to analyse the utilization of incinerated bio-medical waste ash (IBWA) combined with ground granulated blast furnace slag (GGBS) in reinforced GPC beams and columns. Medical waste was produced in the health-care industry, specifically in hospitals and diagnostic laboratories. GGBS is a form of industrial waste generated by steel factories. The best option to address global warming is to reduce the consumption of Portland cement production and promote other types of cement that were not a pollutant to the environment. Therefore, the replacement in ordinary Portland cement construction with GPC is a promising way of reducing carbon dioxide emissions. GPC was produced due to an alkali-activated polymeric reaction between alumina-silicate source materials and unreacted aggregates and other materials. Industrial pollutants such as fly ash and slag were used as raw materials.

Laboratory experiments were performed on three different proportions (reinforced cement concrete [RCC], 100% GGBS as an aluminosilicate source material in reinforced geopolymer concrete [GRGPC] and 30% replacement of IBWA as an aluminosilicate source material for GGBS in reinforced geopolymer concrete [IGRGPC]). The cubes and cylinders for these proportions were tested to find their compressive strength and split tensile strength. In addition, beams (deflection factor, ductility factor, flexural strength, degradation of stiffness and toughness index) and columns (load-carrying ability, stress-strain behaviour and load-deflection behaviours) of reinforced geopolymer concrete (RGPC) were studied.

As shown by the results, compared to Reinforced Cement Concrete (RCC) and 100% GGBS based Reinforced Geopolymer Concrete (GRGPC), 30% IBWA and 70% GGBS based Reinforced Geopolymer Concrete (IGRGPC) (30% IBWA–70% GGBS reinforced geo-polymer concrete) cubes, cylinders, beams and columns exhibit high compressive strength, tensile strength, flexural strength, load-carrying ability, ultimate strength, stiffness, ductility and deformation capacity.

All the results were based on the experiments done in this research. All the result values obtained in this research are higher than the theoretical values.

Inefficient waste disposal technique and cement production methodology caused significant environmental impacts, leading to global warming. The purpose of the research was to invent an effective, sustainable technology to use the wastes and alternate for cement in concrete. Geopolymer technology could be the most desirable solution to use the wastes into an effective product.

The wood waste ash derived from nearby tea shops was used as an alternate binder for fly ash. The replacement of WWA with FA was varied from 0 to 100% at 10% intervals. In this research, setting and mechanical features of Geopolymer Concrete (GPC) along with Waste wood ash (WWA) was carried out. The influence of wood waste ash in the microstructure of the GPC was also assessed using scanning electron microscope and X-ray diffraction analysis.

The findings revealed that 30% replacement of wood waste ash was performed higher in all measured features. Besides, the formation of different phases was also observed with the inclusion of wood waste ash.

The demand for fly ash was increased in recent years, and the fly-based GPC has required more alkaline solution and temperature curing. Hence, there was a research gap on finding an alternative binder for fly ash.

The research novelty was to use the wood waste ash, which has inbuilt alkaline compounds on the production of sustainable geopolymer. The finding showed that the wood waste ash could be alternate fly ash that eliminates the environmental impacts and economic thrust.

The purpose of this paper is to develop an alternative new ternary geopolymer mortar (MKSP) to resolve a traditional mortar problem which exhibits several disadvantages, including poor strengths and surface microcracks and the CO₂ air pollution.

The MKSP ternary binder was produced using metakaolin (MK), slag (S), and palm oil fuel ash (POFA) activated with an alkaline mixture of sodium silicate (Na₂SiO₃) and 10 M NaOH in a mass ratio of 2.5. Seven different mix proportions of MK, slag, and POFA were used to fabricate MKSP mortars. The water-to-binder ratio was varied between 0.4 and 0.5. The mortars were heat cured for 2 h at 80°C and then aged in air. Flexural stress and strain, mortars flow and compressive strength were tested. Furthermore, the mortars were characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) analyses.

The results showed that the sample MKSP6, which contained 40 percent MK, 40 percent slag, and 20 percent POFA, exhibited high compressive strength (52 MPa) without any cracks and flexural strength (6.9 MPa) at 28 days after being cured for 2 h at 80°C; however, the MKSP7 mortar with optimal strength of 55 MPa showed some surface cracks . Further, the results of the XRD, SEM, and FTIR analyses indicated that the MKSP mortars primarily consisted of a crystalline (Si+Al) phase (70 percent) and a smaller amorphous (Si+Ca) phase (30 percent).

The MKSP ternary geopolymer mix has three limitations as an importance of heat curing for development early strength, POFA content less than 20 percent to gain high normal strength and delaying the sitting time by controlling the slag content or the alkali activator type.

The use of geopolymer materials binder in a real building is limited and it still under research, Thus, the first model of real applied geopolymer cement in 2008 was the E-Crete model that formed by Zeobond company Australia to take the technology of geopolymer concrete to reality. Zeobond Pty Ltd was founded by Professor Jannie S.J. van (van Deventer et al., 2013), it was used to product precast concrete for the building structure. The second model was PYRAMENT model in 2002 by American cement manufacturer Lone Star Industries which was produced from the development carried out on inorganic alumino-silicate polymers called geopolymer (Palomo et al., 1999). In 2013 the third model was Queensland’s University GCI building with three suspended floors made from structural geopolymer concrete containing slag/fly ash-based geopolymer (Pathak, 2016). In Australia, 2014, the newly completed Brisbane West Wellcamp airport becomes the greenest airport in the world. Cement-free geopolymer concrete was used to save more than 6,600 tons of carbon emissions in the construction of the airport. Therefore, the next century will see cement companies developing alternative binders that are more environmentally friendly from a sustainable development point of view.

Production of new geopolymer binder of mortar as alternative to traditional cement binder with high early and normal strength from low cost waste materials, less potential of cracking, less energy consumption need and low carbon dioxide emission.

The purpose of this paper is to develop methods to produce white composite pigments consisting of a silica core with a titania shell.

Silica cores were coated with titanium dioxide (TiO₂) via forced hydrolysis of a solution prepared from titanium tetrachloride (TiCl₄). The morphology, surface charge and particle size of obtained composite particles were studied.

Dispersions of well‐dispersed composite particles, having silica cores of uniform size in the range from 300 to 500 nm with a homogeneous titania coating are obtained. The coating thickness corresponded to 150‐400 per cent by weight of titania based on the core. Modification of the silica core by incorporation of 1.5 aluminosilicate sites per square nanometre of core surface proves to be favourable in achieving a homogeneous coating on the silica core. Deposition of such titania coating is also favoured by agitating the dispersion well, keeping electrolyte content low, maintaining pH at 2.0 and the temperature at 75°C during the coating process.

Only TiCl₄ is used as titania source. In addition, only silica cores obtained by Stöber synthesis are used while commercially available silica solutions made from sodium silicate are not used.

The process offers a method of producing a white composite pigment with a narrow particle size distribution in order to maximise light scattering as well as using a core with lower density than the shell. This kind of particle would be of interest for coating applications and white inorganic inks.

The developed method provides a straightforward process to produce well‐defined composite particles.

This paper aims to investigate the effect of delayed water curing on the mechanical and microstructural properties of fly ash-based geopolymer paste-blended with Ground Granulated Blast Furnace Slag (GGBS) with different rest periods.

The blended geopolymer paste was composed of GGBS (15 per cent of the total weight) and the base material, Fly Ash (FA). The blended mix was activated by activator solution (Sodium hydroxide and Sodium silicate) containing 6 per cent Na₂O of total base material. The effect of delayed water curing has been studied by gradually increasing the aging period (Rest Period) from 2 hours to 24 hours in the formation of activated outcome along with Calcium Silicate Hydrate (CSH). To analyze the mechanical and microstructural properties of the resultant blended geopolymer paste, compressive strength test, FESEM and XRD have been carried out. Moreover, a long-term durability test subjected to sulphate exposure has been performed to evaluate the durability of the designed sustainable geopolymer paste.

The present paper shows that the delayed water curing incorporates secondary heat input enhancing the partial polymer formation along with CSH. Slag-blended AAFA-based geopolymer paste is seen to exhibit quick setting property. Also, AAFA-based geopolymer paste samples subjected to longer rest period show early strength gain at a high rate under water curing as compared to those subjected to the shorter rest period.

To the best of authors’ knowledge, the effect of delayed water curing on the mechanical and microstructural properties of slag-blended AAFA-based geopolymer paste has not been studied before.

The purpose of this study is to investigate the using of rice husk (RH) which is a green material derived from agricultural waste with the ability to absorb heavy metal. It has been used in wastewater treatment. In this research, a kaolin-based green ceramic water filter (CWF) incorporated with two different additives (RH and zeolite-based RH ash [RHA]) was successfully fabricated.

The weight ratio of kaolin:additive was varied (90:10, 80:20 and 70:30) and fabricated via the slip-casting technique. The green CWFs were dried (60°C for 1 h), followed by sintering (1,200°C).

The green CWF of kaolin:RH with a weight ratio of 70:30 showed the best properties and satisfactory performance with a porous cross-section microstructure, highest porous area (4.58 µm²), good structure, lowest shrinkage (8.00%), highest porosity (45.10%), lowest density (1.79 g cm⁻³), highest water absorption (55.50%) and hardness (241.40 Hv). This green CWF has also achieved good permeability (42.00 L m⁻²h⁻¹) and removal of the textile dye (27.88%). The satisfactory characterization and good textile dye removal performance (75.47%) were also achieved from green CWF with kaolin:zeolite at a weight ratio of 80:20.

This research is focused on green CWF and zeolite at a certain amount with the specific characterization analysis methods.

The use of low-cost waste materials to treat dye wastewater from agricultural by-products/wastes sources in treating the dye will enhance the using of green material.

Avoiding the waste sludge that can pollute the environment can create a health issue. The use of low-cost waste materials to treat dye wastewater from agricultural by-products/wastes sources in treating the dye can avoid the waste sludge that can pollute the environment and create serious health issue.

All the kaolin-based green CWFs incorporated with two different additives (RH and zeolite-based RHA) fabricated using a simple slip-casting technique have shown the potential to be used as a filter in wastewater treatment applications.

The purpose of this study is to investigate the effect of various heat conditions on the durability of eggshell powder (ESP)–flyash (FA) geopolymer subjected to wetting–drying cycles.

In this study, two waste materials, ESP and FA, which are destined for landfills, were used as precursors to produce geopolymers in a sustainable manner. The mixture of Na₂SiO₃ and NaOH was used as a liquid alkaline activator in geopolymerization. The ESP and FA content were varied as 30, 50 and 70% and Na₂SiO₃/NaOH ratios were varied as 0.5, 1 and 2. Geopolymer samples were cured at three heat conditions: 25°C (ambient temperature), 50°C and 80°C for seven days prior to durability tests.

The results of this study revealed that the strength loss of the geopolymer decreases with an increase in curing temperature up to 50°C and then increases for higher temperature up to 80°C. Further, the strength loss of the geopolymer decreases with an increase in FA replacement and Na₂SiO₃/NaOH ratio. Geopolymer composites exhibited early strength development because of the inclusion of calcium-rich ESP. The weight loss of the ESP–FA geopolymer follows a similar pattern of strength loss. Geopolymer samples previously cured at optimum heat condition of 50°C for seven days exhibited higher durability.

The inclusion of calcium-rich ESP in FA-based geopolymer is novel research. As ESP–FA geopolymer composites show higher mechanical strength and higher durability compared to Indian standards, the potential use of this geopolymer can be in road subbases/subgrades.

This study aims to practically determine the optimum proportion of aggregates to attain the desired strength of geopolymer concrete (GPC) and then compare the results using established analytical particle packing methods. The investigation further aims to assess the influence of various amounts of recycled aggregate (RA) on properties of low-calcium fly ash-based GPC of grade M25.

Fine and coarse aggregates were blended in various proportions and the proportion yielding maximum packing density was selected as the optimum proportion and they were compared with analytical models, such as Modified Toufar Model (MTM) and J. D. Dewar Model. RAs for this study were produced in laboratory and they were used in various amounts, namely, 0%, 50% and 100%. 12M NaOH solution was mixed with Na₂SiO₃ in the ratio of 1:2. The curing of concrete was done at the temperatures of 60° and 90 °C for 24, 48 and 72h.

The experimentally obtained optimum proportion of coarse to fine aggregate was 60:40 for all amounts of RA. Meanwhile, MTM and Dewar Model resulted in coarse aggregate to fine aggregates as 40:60, 45:55, 55:45 and 55:45, 35:65, 60:40, respectively, for 0% 100% and 50% RAs. The compressive strength of GPC elevated with the increase in curing regime. In addition, the ultrasonic pulse velocity also displayed a similar trend as that of strength.

The GPC with 50% RAs may be considered for use, as it exhibited superior properties compared to GPC with 100% RAs and was comparable to GPC with natural aggregates. Furthermore, compressive strength is correlated with split tensile strength and ultrasonic pulse velocity.

Traditional simulation research of geological and similar engineering models, such as landslides or other natural disaster scenarios, usually focuses on the change of stress and the state of the model before and after destruction. However, the transition of the inner change is usually invisible. To optimize and make models more intelligent, this paper aims to propose a perceptible design to detect the internal temperature change transformed by other energy versions like stress or torsion.

In this paper, micron diamond particles were embedded in 3D printed geopolymers as a potential thermal sensor material to detect the inner heat change. The authors use synthetic micron diamond powder to reinforced the anti-corrosion properties and thermal conductivity of geopolymer and apply this novel geopolymer slurry in the direct ink writing (DIW) technique.

As a result, the addition of micron diamond powder can greatly influence the rheology of geopolymer slurry and make the geopolymer slurry extrudable and suitable for DIW by reducing the slope of the viscosity of this inorganic colloid. The heat transfer coefficient of the micron diamond (15 Wt.%)/geopolymer was 50% higher than the pure geopolymer, which could be detected by the infrared thermal imager. Besides, the addition of diamond particles also increased the porous rates of geopolymer.

In conclusion, DIW slurry deposition of micron diamond-embedded geopolymer (MDG) composites could be used to manufacture the multi-functional geological model for thermal imaging and defect detection, which need the characteristic of lightweight, isolation, heat transfer and wave absorption.