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Acrylic resins are formulated into protective coatings in several ways. Most important volumewise are waterborne formulations based either on pure acrylics or on acrylic‐vinyl copolymers. Second most important are solvent‐based enamels and lacquers widely used for product finishes particularly in the automotive and appliance industries. An innovation of a decade or so ago is proving popular in this area, namely two component coatings based on hydroxyl‐containing acrylics and di‐ or polyisocyanates. These combine many of the good features of acrylics and urethanes and provide hard thermoset coatings. Yet they cure at temperatures as low as ambient.

A clean, dry compressed air supply from an Ingersoll‐Rand ML‐5.5 SSR compressor is critical for a new method of powder coating being used for the first time in the world to glaze pottery at Stoke‐based Just Cats & Co. Installed by Chesterfield‐based AE Industrial, the local authorised distributer for Ingersoll‐Rand, the compressor supplies air to a modified version of a powder coating process from Simple Heat of Bury St Edmunds in Suffolk.

Adhesion promoters: Some oleochemicals can promote the adhesion of polymers to various surfaces, e.g. stearic acid can increase the adhesion of polyolef ins to metals and to the surfaces of other polymers. Erucamide is effective in the lamination of cellophane to polyethylene films, and alumina‐modified iron stearate has been found effective in aiding the adhesion of polyethylene to steel surfaces. The effect of oleamide on the adhesion of polyethylene to aluminium and to nylon 6 has been studied. Stearic acid had an adhesion promoting role in polyethylene/aluminium laminated packaging film. Barium stearate can effect the adhesiveness of poly(vinyl chloride).

BASF has supplemented its range of Lurafix dyes for the production of transfer printing inks (gravure, flexographic, letterpress, offset) with two new products:

Emulsion adhesives can be subdivided on the basis of chemistry to acrylics, styrene‐butadiene latices, styrene‐butadiene/natural rubber blends, vinyl acetate copolymers and natural rubber latices. Acrylics have the advantages of being easily modified by changing the type and amount of polar comonomers. They have excellent ageing characteristics.

Acryclic copolymers from methacrylic acid‐ethyl acrylate or butylacrylate were prepared and incorporated into the castor oil alkyd structure. The neutralised product was water soluble. Water soluble hexamethoxy methyl melamine resin was prepared and used as curing agent. Several proportions of water soluble acrylic modified alkyds and hexamethoxy methyl melamine resin were examined at various baking schedules. It was established that 30% of the curing agent gave most satisfactory properties after baking at 150°C for 30 minutes. It was found that ethyl acrylate modified compositions had better scratch hardness and acid resistance than those of the butyl acrylate modified composition. However, the latter had better alkali resistance. These surface coating compositions have been recommended as industrial primers.

Motivated by the globally increasing concern over environmental protection, the interest of a large part of the scientific community focuses on the development of green surfactants aiming to replace traditional toxic surfactants-based alternatives. The purpose of this paper is to prepare acrylate copolymer latex modified with fluorine and silicone monomer, which is emulsified with the green surfactants of sodium rosinate and alkyl polyglycoside (APG).

A series of acrylic copolymer latexes containing fluorine–silicon have been prepared by semi-continuous seed emulsion polymerisation of mixed monomers of methyl methacrylate (MMA), butyl acrylate (BA), hexafluorobutylmethacrylate (HFMA) and vinyltriethoxysilane (VTES) and emulsified by green mixed surfactants of sodium rosinate and APG.

The optimum recipe of preparing the emulsion is as follows: the amount of emulsifiers is 6 per cent and the mass ratio of sodium rosinate to APG is 1:3. The amount of initiator is 0.4 per cent, and the amounts of the silicon monomer and fluorine monomer are 5 and 7 per cent, respectively. In comparison with the acrylate latex prepared without fluorine monomer and silicon monomer, the thermal stability and the water resistance of the film of the resultant latex clearly improved.

The acrylic copolymer latexes containing fluorine–silicon emulsified with green surfactants can be used in the coatings, adhesives, finishing agents and so on.

The acrylic copolymer latexes containing fluorine–silicon have been prepared by semi-continuous seed emulsion polymerisation. The green mixed surfactants of sodium rosinate and APG have been used as the emulsifiers to replace traditional toxic surfactants-based alternatives.

The analysis of acetate acrylic and acrylic copolymers systems is described. Much useful information is rapidly obtained by infra‐red spectrophotometry and pyrolysis gas chromatography, however quantitative analyses generally require the polymer material to be cleaved by chemical means with subsequent identification of the fragments by gas chromatography.

BIP of Oldbury in the West Midlands and part of T&N plc for over 30 years, celebrates its centenary this year. Now two sister companies, BIP Plastics and BIP Speciality Resins share the 11 hectare site straddling Tat Bank Road and bordered by Popes Lane and Rood End Road.