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The composition and thickness of surface oxide of solder particles is extremely important to the quality of interconnect and reliability of packaged system. The purpose of this paper is to develop an observable measurement to research the issue.

AES (Auger electron spectroscopy), XPS (X‐ray photoelectron spectroscopy), TEM (transmission electron microscopy) and STEM (scanning transmission electron microscopy) were employed to examine the oxide layer on microscale solder powders. Conventional techniques and FIB (Focus Ion Beam) were employed for the TEM sample preparation. High angle annular dark field (HAADF) pattern was applied to distinguish the oxide layer and the solder matrix by the contrast of average atomic number. The results were confirmed by AES and XPS measurement.

The solder powders were exposed to air (70% relative humidity) at 150°C for 0, 120 and 240 h for the accelerated growth of oxide. The surface oxide thickness was 6 nm and 50 nm measured by TEM for 0 h and 120 h samples, respectively. It was found that the increase in surface oxide thickness of solder particles is proportional to the rooting of time. The elemental distribution along the oxide was quantified by line scanning using STEM and the atomic ratio of Sn to O in the oxide layer nearer to the outer, the middle, and the inner (adjacent to the solder matrix) was found to be 1:2, 2:3 and 1:1, respectively. The result was validated using XPS which gave Sn to O ratio of 1:2 at 5 nm depth of surface oxide.

This is the first time FIB technology has been used to prepare TEM specimens for solder particles and TEM pictures shown of their surface oxide layer. Though requiring more care in sample preparation, the measurements by TEM and STEM are believed to be more direct and precise.

Conventional wear models cannot satisfy the requirements of electrical contact wear simulation. Therefore, this study aims to establish a novel wear simulation model that considered the influence of thermal-stress-wear interaction to achieve high accuracy under various current conditions, especially high current.

The proposed electrical contact wear model was established by combining oxidation theory and the modified Archard wear model. The wear subroutine was written in FORTRAN, and adaptive mesh technology was used to update the wear depth. The simulation results were compared with the experimental results and the typically used stress-wear model. The temperature of the contact surface, distribution of the wear depth and evolution of the wear rate were analyzed.

With the increase in the current flow, the linear relationship between the wear depth and time changed to the parabola. Electrical contact wear occurred in two stages, namely, acceleration and stability stages. In the acceleration stage, the wear rate increased continuously because of the influence of material hardness reduction and oxidation loss.

In previous wear simulation models, the influence of multiple physical fields in friction and wear has been typically ignored. In this study, the oxidation loss during electrical contact wear was considered, and the thermo-stress-wear complete coupling method was used to analyze the wear process.

The most reliable, inexpensive, and trouble‐free shielding method known at the present is spray coating using paints containing conductive metal particles. The best metals are those which do not lose conductivity due to oxidation. These consist of gold, platinum, palladium, iridium, silver and osmium. The least expensive is silver. A coating containing fine silver particles is an excellent conductor and shield. Paints containing fine silver particles have been available a long time but are very happy and very expensive. Their performance is, however, excellent.

Aluminium and its alloys are the most preferred material in aerospace and automotive industries because of their high strength-to-weight ratio. However, these alloys are found to be low wear resistance. Hence, the incorporation of ceramic particles with the aluminium alloy may be enhanced the mechanical and tribological properties. The purpose of this study is to optimize the specific wear rate and friction coefficient of titanium dioxide (TiO₂) reinforced AA7075 matrix composites. The four wear control factors are considered, i.e. reinforcement (Wt.%), applied load (N), sliding velocity (m/s) and sliding distance (m).

The composites were fabricated through stir casting route with varying weight percentages (0, 5, 10 and 15 Wt.%) of TiO₂ particulates. The mechanical properties of the composites were studied. The specific wear rate and friction coefficient of the newly prepared composites was determined by using a pin-on-disc apparatus under dry sliding conditions. Experiments were planned as per Taguchi’s L16 orthogonal design. Signal-to-noise ratio analysis was used to find the optimal combination of parameters.

The mechanical properties such as yield strength, tensile strength and hardness of the composites significantly improved with the addition of TiO₂ particles. The analysis of variance result shows that the applied load and reinforcement Wt.% are the most influencing parameters on specific wear rate and friction coefficient during dry sliding conditions. The scanning electron microscope morphology of the worn surface shows that TiO₂ particles protect the matrix from more removal of material at all conditions.

This paper provides a solution for optimal parameters on specific wear rate and friction coefficient of aluminium matrix composites (AMCs) using Taguchi methodology. The obtained results are useful in improving the wear resistance of the AA7075-TiO₂ composites.

The purpose of this paper is to develop high-performance Au-coated Ag alloy wires (ACAA wires) and demonstrate the effect of Au coating layers on the bonding performance and oxidation resistance for stable and reliable electronic packaging applications.

ACAA wire with a diameter of approximately 25 µm and Au layer thickness of approximately 100 nm were prepared by the continuous casting, plating and wire drawing method. The bonding performance of the ACAA wires were studied through bonding on 3,535 chips. The oxidation resistance of ACAA wires and Ag alloy wires (AA wires) were comparatively studied by means of chemical oxidation tests, accelerated life tests and electrochemical tests systematically.

ACAA wires could form axi-symmetrical spherical free air balls with controllable diameter of 1.5∼2.5 times of the wire diameter after electric flame-off process. The ball shear strength of ACAA wire was higher than that of AA wires. Most importantly, because of the surface Au coating layer, the oxidation resistance of ACAA wires was much enhanced.

ACAA wires with different lengths of heat affected zone were not developed in this study, which limited their application with different loop height requirements.

With higher bonding strength and oxidation resistance, ACAA wires would be a better choice than previous reported AA wire in chip packaging which require high stability and reliability.

This paper provides a kind of novel ACAA wire, which possess the merits of high bonding strength and reliability, and show great potential in electronic packaging applications.

To evaluate the oxide formation characteristics of tin (Sn) as a function of conditioning treatment and define a conditioning methodology that rapidly produces a tin oxide thickness and oxide species morphology similar to those formed in ambient oxidation.

Electrochemical reduction analysis and scanning electron microscopy techniques were utilized to identify tin oxide species and oxide quantities on tin samples which were subjected to a variety of conditioning methodologies.

Tin oxide species were identified and oxide quantities measured. Comparisons of tin oxide species/quantities were completed for the different conditioning methodologies used and for other industry oxide investigations. The following conclusions were reached: all conditioning methodologies produced both SnO and SnO₂ tin oxide species; steam conditioning produced the thickest oxides; the conditioning methodologies investigated were found to produce oxide thicknesses similar to those formed under ambient conditions.

Further investigation would be beneficial using this study as a foundation. Additional conditioning methodologies and a larger selection of various tin surfaces would provide a future understanding of the impact of oxide species and thickness on solderability.

The electronics industry has attempted to “predict” a surface's susceptibility to oxidation by using accelerated conditioning techniques. An understanding of the formation of tin oxidation products created by accelerated conditioning techniques could be highly beneficial to the electronics industry. The standardization and use of a realistic accelerated conditioning technique would reduce testing cycle time, increase the predictability and consistency of test results, and lower testing costs.

This paper was incorporated into an original electronics manufacturer's solderability testing/analysis procedures, and the results are being utilized by the electronics industry solderability specification task groups/committees.

This paper aims to investigate the thermal oxidation behavior of trimethylolpropane trioleate (TMPTO) base oil when exposed to Fe surfaces.

Samples of TMPTO bulk oil were placed in Fe vessels and heated in an oven to accelerate the oxidation at different time intervals, while others were placed in glass vessels and used as experimental controls. Subsequently, the physicochemical properties of the oxidized TMPTOs, including the kinematic viscosity and acid value, were measured and a structural analysis was conducted using the Raman and Fourier transform infrared (FTIR) techniques.

The results demonstrate that the TMPTO bulk oil exhibited an exponential increase in the kinematic viscosity along with the increasing acid value over the oxidation time. The Fe surface significantly increased the kinematic viscosity of TMPTO, while only mildly impacting its acid value compared with the experimental controls. The structural analysis results of the TMPTO suggest that the C = C and = C-H bonds were the vulnerable sites. Furthermore, the results suggest that the Fe surface evidently accelerates the chemical reactions of the C = C and the = C-H bonds, and less alcohols and more carbonyl products were identified in the oil samples that were heated in the Fe vessels.

The results demonstrate that the Fe surfaces affected the oxidation behavior of the TMPTO base oil, and an interaction mechanism between the Fe and the TMPTO is developed.

The first part of this paper appeared in our November/December issue and dealt with fretting wear behaviour of mild steel from room temperature to 600°C in air. The general mechanism for fretting is discussed at all temperatures where normal oxidative processes become involved. The nature of fretting wear is also covered and the effects of temperature are described. In this part of the paper, the discussion is continued to include triboxidation, delamination theory, atmospheric environment, transition temperatures, activitation energy and other factors affecting the influence of temperature on fretting.

This paper aims to find a way to improve the surface insulation, corrosion resistance and mechanical properties of Fe-Cr-Al electrothermal alloy, exploring the best oxidation condition and analyzing the oxidation mechanism.

Electrochemical workstation was used for anodic oxidation, and the effect of current density, ethylene glycol concentration and oxidation time on properties of the film were investigated by resistivity test, scanning electron microscope, electrochemical tests (potentiodynamic polarization and electrochemical impedance spectroscopy) and mechanical tests, and the oxidation process was analyzed by X-ray photoelectron spectroscopy (XPS).

According to the potential-time curves of anodic oxidation and the analysis of XPS, the whole oxidation process can be divided into four stages. When the current density is 0.8 A/dm², the ethylene glycol concentration is 10%, and the oxidation time is 60 min, the film has the best corrosion protection, mechanical properties and surface morphology. The resistivity of the samples is about 13 orders magnitude than that of the matrix.

In this paper, a protective electrically insulating film was prepared by anodic oxidation in an alkaline electrolyte solution. The oxidation conditions were optimized and the oxidation mechanism was analyzed.

This paper aims to investigate the thermal oxidation characteristics of the unsaturated bonds (C=C) of trimethylolpropane trioleate (TMPTO) and to reveal the high temperature oxidation decay mechanism of unsaturated esters and the nature of the anti-oxidation properties of the additives.

Using a DXR laser microscopic Raman spectrometer and Linkam FTIR600 temperature control platform, the isothermal oxidation experiments of TMPTO with or without 1.0 wt. % of different antioxidants were performed.

The results indicated that the Raman peaks of =C-H, C=C and -CH₂- weaken gradually with prolonged oxidation time, and the corresponding Raman intensities drop rapidly at higher temperatures. The aromatic amine antioxidant can decrease the attenuation of peak intensity, as it significantly reduces the rate constant of C=C thermal oxidation. The hindered phenolic antioxidant has a protective effect during the early stages of oxidation (induction period), but it may accelerate the oxidation of C=C afterwards.

Research on the structure changes of synthetic esters during oxidation by Raman spectroscopy will be of great importance in promoting the use of Raman spectroscopy to analyze the oxidation of lubricants.