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1 – 10 of 76P. Sathiya, S. Aravindan and A. Noorul Haq
Friction welding is a solid state bonding process, where the joint between two metals has been established without melting the metal. The relative motion between the faying…
Abstract
Friction welding is a solid state bonding process, where the joint between two metals has been established without melting the metal. The relative motion between the faying surfaces (surfaces to be joined) under the application of pressure promotes surface interaction, friction and heat generation which subsequently results in joint formation. Stainless steel is an iron based alloy, contains various combinations of other elements to give desired characteristics, and found a wider range of applications in the areas such as petro‐chemical, fertilizer, automotive, food processing, cryogenic, nuclear and beverage sectors. In order to exploit the complete advantages of stainless steels, suitable joining techniques are highly demanded. The Friction welding is an easily integrated welding method of stainless steel, which considered as non‐weldable through fusion welding. Grain coarsening, creep failure and failure at heat‐affected zone are the major limitations of fusion welding of similar stainless steels. Friction welding eliminates such pitfalls. In the present work an attempt is made to investigate experimentally, the mechanical and metallurgical properties of friction welded joints, namely, austenitic stainless steel (AISI 304) and ferritic stainless steel (AISI 430). Evaluation of the characteristics of welded similar stainless steel joints are carried out through tensile test, hardness measurement and metallurgical investigations.
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Anand Sharma, Sourabh Shukla, Manish Thombre, Ankur Bansod and Sachin Untawale
The purpose of this study is to examine the effects of sensitization on the metallurgical characteristics of weld joints made up of austenitic stainless steel (AISI 316L) and…
Abstract
Purpose
The purpose of this study is to examine the effects of sensitization on the metallurgical characteristics of weld joints made up of austenitic stainless steel (AISI 316L) and ferritic stainless steel (AISI 430), using the gas tungsten arc welding (GTAW) process with ER316L filler wires.
Design/methodology/approach
A non-consumable tungsten electrode with a diameter of 1.6 mm was used during the GTAW procedure. The filler wire, ER316L, was selected based on the recommendation provided in literature. To explore the interconnections among the structure and properties of these weldments, the techniques including scanning electron microscopy and optical analysis have been used. In addition, the sensitization behaviour of the weldments was investigated using the double loop electrochemical potentio-kinetic reactivation (DLEPR) test.
Findings
Microstructural analyses revealed the occurrences of coarsened grains with equiaxed columnar grains and migrating grain boundaries in the weld zone. The results of the DLEPR test demonstrated that heat affected zone (HAZ) of AISI 430 was more susceptible to sensitization than HAZ of AISI 316L. Microstructure analysis also revealed the precipitation of large amounts of chromium carbide at the grain boundaries region of AISI 430 welded steel, causing more sensitization and, as a result, more failure or breaking at the side of AISI 430 weld in the dissimilar weldment of AISI 316L–AISI 430.
Originality/value
The present work has been carried out to determine the appropriate welding conditions for joining AISI 316L and AISI 430, as well as the metallurgical properties of the dissimilar weldment formed between AISI 316L and AISI 430. Owing to the difficulties in measuring the performance of these types of dissimilar joints given their unique mechanical and microstructural characteristics, research on the subject is limited.
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Hairen Wang, Minya Li, June Qu, Zhiyong Cao, Geng Chen and Yang Zhou
The purpose of this paper is to construct a self-assembled double layer of organosilane on the surface of stainless steel and to investigate its corrosion inhibitive capability…
Abstract
Purpose
The purpose of this paper is to construct a self-assembled double layer of organosilane on the surface of stainless steel and to investigate its corrosion inhibitive capability.
Design/methodology/approach
A monolayer of 3-glycidoxypropyltrimethoxysilane (GPTMS) was grafted onto an oxidized AISI 430SS (AISI 430 stainless steel) surface substrate from dry toluene solution. The hydrolysis of 1H,1H,2H,2H-perfluorodecyltriethoxysilane (PFDS) molecules was used to anchor a second organic layer from mixed water-ethanol solution. The adsorption behavior and corrosion inhibition properties of the monolayer and also the bilayer were investigated by potentiodynamic polarization, scanning electron microscope (SEM), Fourier transformed infrared spectroscopy (FTIR) and contact angle measurements.
Findings
The GPTMS/PFDS bilayer was successfully deposited onto the oxidized AISI 430SS surface. The optimal assembling time for the filming of the first GPTMS monolayer is 6 hours. Suitable values of pH and temperature of the PFDS self-assembly solution were pivotal to the successful deposition of the second layer. Compared to the GPTMS monolayer, the GPTMS/PFDS bilayer exhibited a significant enhancement of the corrosion inhibition performance of AISI 430SS in NaCl solution.
Research limitations/implications
The contact angle value measured on the bilayer-modified surface was somewhat lower than the reported value of a complete fluorinated surface. However, further optimization of the assembling condition is needed to obtain more orderly and denser films.
Originality/value
This paper provides useful information regarding the preparation of an organosilane bilayer on the surface of stainless steel and its corrosion inhibition properties in NaCl solution. It illustrates potential application prospects of GPTMS/PFDS bilayers for surface treatment of stainless steel.
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Fupeng Cheng, Jinglong Cui, Shuai Xu, Hongyu Wang, Pengchao Zhang and Juncai Sun
The purpose of this paper is to improve the surface electrical conductivity and corrosion resistance of AISI 430 stainless steel (430 SS) as bipolar plates for proton exchange…
Abstract
Purpose
The purpose of this paper is to improve the surface electrical conductivity and corrosion resistance of AISI 430 stainless steel (430 SS) as bipolar plates for proton exchange membrane fuel cells (PEMFCs), a protective Nb-modified layer is formed onto stainless steel via the plasma surface diffusion alloying method. The effect of diffusion alloying time on electrochemical behavior and surface conductivity is evaluated.
Design/methodology/approach
In this work, the surface electrical conductivity and corrosion resistance of modified specimen are evaluated by the potentiodynamic and potentionstatic polarization tests. Moreover, the hydrophobicity is also investigated by contact angle measurement.
Findings
The Nb-modified 430 SS treated by 1.5 h (1.5Nb) presented a lower passivation current density, lower interfacial contact resistance and a higher hydrophobicity than other modified specimens. Moreover, the 1.5 Nb specimen presents a smoother surface than other modified specimens after potentionstatic polarization tests.
Originality/value
The effect of diffusion alloying time on electrochemical behavior, surface conductivity and hydrophobicity of modified specimen is evaluated. The probable anti-corrosion mechanism of Nb-modified specimen in simulated acid PEMFC cathode environment is presented.
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Fupeng Cheng, Jinglong Cui, Shuai Xu, Song Li, Pengchao Zhang and Juncai Sun
The purpose of this study is to improve the performance of AISI 430 stainless steel (430 SS) in increasing its oxidation resistance, suppressing coating spalling and cracking…
Abstract
Purpose
The purpose of this study is to improve the performance of AISI 430 stainless steel (430 SS) in increasing its oxidation resistance, suppressing coating spalling and cracking, sustaining appropriate conductivity and blocking Cr evaporation as an interconnect material for intermediate temperature solid oxide fuel cells; a protective co-contained coating is formed onto stainless steel via the surface alloying process and followed by thermal oxidation.
Design/methodology/approach
In this work, oxidation behavior of coated specimen is studied during isothermal and cyclic oxidation measurements. Moreover, the conductivity is also investigated by area specific resistance (ASR) measurement.
Findings
Co-contained spinel layer shows an outstanding performance in preventing oxidation and improving conductivity compared with uncoated specimens. The protective spinel coating also reduces the ASR for coated specimen (0.0576O cm2) as compared to the uncoated specimen (1.87296O cm2) after isothermal oxidation.
Originality/value
The probable mechanism of co-contained alloy converting into spinel and the spinel transfer electron is presented.
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Jixin Han, Haibang Zhang, Juncai Sun, Wenyuan Zhao and Jinlong Cui
The purpose of this study is to improve the surface electrical conductivity and corrosion resistance of AISI430 stainless steel (430 SS) as bipolar plates for direct formic acid…
Abstract
Purpose
The purpose of this study is to improve the surface electrical conductivity and corrosion resistance of AISI430 stainless steel (430 SS) as bipolar plates for direct formic acid fuel cell (DFAFC).
Design/methodology/approach
The niobium diffusion layers have been successfully synthesized on 430 SS substrate by the plasma surface diffusion alloying technique under different diffusion alloying time.
Findings
The surface morphology of Nb-modified 430 SS prepared under the diffusion alloying time of 2 h is more homogeneous, relatively sleek and compact without surface micropore and other common surface blemishes. The potentiostatic and potentiodynamic polarization measurements manifest that Nb-modified 430 SS prepared under the diffusion alloying time of 2 h enormously ameliorate the corrosion resistance of bare 430 SS compared with other Nb-modified 430 SS samples and its corrosion current density is maintained at −1.4 µA cm−2 in simulated anodic environment of DFAFC (0.05 M H2SO4 + 2 ppm HF + 10 M formic acid at 50 °C).
Originality/value
The effect of diffusion alloying time on the corrosion resistance and surface conductivity of Nb-modified 430 SS has been carefully studied. The Nb-modified 430 SS samples prepared at the diffusion alloying time of 2 h have the best surface electrical conductivity and corrosion resistance in the simulated anodic environment of DFAFC.
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Pramod Kumar and Amar Nath Sinha
The present research work aims to study the effect of average beam power (laser process parameters) on the overlapping factor, depth of penetration (DOP), weld bead width, fusion…
Abstract
Purpose
The present research work aims to study the effect of average beam power (laser process parameters) on the overlapping factor, depth of penetration (DOP), weld bead width, fusion zone and heat affected zone (HAZ) in laser welding of 304L and st37 steel. Back side and top surface morphology of the welded joints have also been studied for varying average beam power.
Design/methodology/approach
Laser welding of austenitic stainless steel (304L) and carbon steel (st37) was carried out using Nd:YAG laser integrated with ABB IRB 1410 robot in pulse mode. The selection of laser process parameters was based on the specification of available laser welding machine. Dissimilar laser welding of 304L and st37 carbon steel for full depth of penetration have been performed, with varying average beam power (225-510W) and constant welding speed (5mm/s) and pulse width (5ms).
Findings
Recrystallized coarse grains were observed adjacent to the fusion zone and nucleated grains were seen away from the fusion zone towards carbon steel. Overlapping factor and HAZ width st37 side increases with increase in average beam power whereas top weld bead width increases first, attains maximum value and then subsequently decreases. Bottom weld bead width increases with increase in average beam power. The mechanical properties namely microhardness and tensile strength of the welded joints have been investigated with varying average beam power.
Originality/value
In the recent development of the automobile, power generation and petrochemical industries the application of dissimilar laser welding of austenitic stainless steel (304L) and carbon steel (st37) are gaining importance. Very limited work have been reported in pulsed Nd:YAG dissimilar laser welding of austenitic stainless steel (304L) and carbon steel (st37) for investigating the effect of laser process parameters on weld bead geometry, microstructural characterization and mechanical properties of the welded joint.
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For many years the effect of sulphuric anhydride in the atmosphere has been recognised, such as in the report by Thomson. As an example of this, consider some of the work reported…
Abstract
For many years the effect of sulphuric anhydride in the atmosphere has been recognised, such as in the report by Thomson. As an example of this, consider some of the work reported by Hudson and Stanners, who exposed iron and steel to copper in a variety of environments. When they studied the results, they found a close relationship between the degree of corrosion and the amount of SO2 present, whereas the effect of chlorides was restricted to a narrow test area close to the sea.
Yamid Núñez, Marcio Mafra, Rigoberto E. Morales, Paulo César Borges and Giuseppe Pintaude
This study aims to assess the performance of SAF 2205 duplex stainless steel against pure wear, tribo-corrosion, corrosion and the synergism between wear and corrosion. The effect…
Abstract
Purpose
This study aims to assess the performance of SAF 2205 duplex stainless steel against pure wear, tribo-corrosion, corrosion and the synergism between wear and corrosion. The effect of plasma nitriding conducted at low temperature (380°C) on SAF 2205 steel was analyzed.
Design/methodology/approach
Three systems were used for assessing the synergism between wear and corrosion: tribo-corrosion – wear tests conducted using the micro-scale abrasion test, performed under a slurry of alumina particles containing 3.5% NaCl; pure wear – tests conducted using the previous system but isolated in a glovebox with a 99% N2 atmosphere; and cyclic polarization under 3.5% NaCl solution. A hard nitrided layer of 3 µm thickness was characterized using X-ray diffraction, presenting expanded austenite.
Findings
The wear mode after micro-scale abrasion tests changed in the absence of an oxygen atmosphere. During pure wear, a mixed mode was identified (rolling + grooving), with the grooving mode more intense for the untreated steel. For tribo-corrosion tests, only rolling wear was identified. For all cases, the nitrided samples presented less wear. The corrosion results indicated a higher repassivation potential for the nitrided condition.
Practical implications
The synergism was more positive for the nitrided sample than for the untreated one, which can be considered for surface treatments of duplex stainless steels in practical applications.
Originality/value
A detailed description of wear mechanisms showed a significant change in the presence of oxygen atmosphere, a new approach for isolating pure wear.
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Yinhui Yang and Biao Yan
The aim of this paper was to investigate the effect of strain rate on microstructure and corrosion behavior of 2205 duplex stainless steel, after high-temperature compression…
Abstract
Purpose
The aim of this paper was to investigate the effect of strain rate on microstructure and corrosion behavior of 2205 duplex stainless steel, after high-temperature compression tests.
Design/methodology/approach
The specimens were prepared using a Gleeble3800 thermo-simulation machine over a range of temperatures from 850 to 1,250°C and strain rates from 0.005 to 5 s−1, and the corresponding flow curves and deformation microstructure obtained were further analyzed. To evaluate the effect of strain rate on corrosion behavior, potentiodynamic polarization tests and double-loop electrochemical potentiodynamic reactivation (DL-EPR) were used to characterize the electrochemical performance.
Findings
Compared with strain rate of 0.5 s−1, the worst corrosion resistance behavior from the potentiodynamic polarization test results after deformation at 0.005 s−1 was attributed to more austenite (γ) and ferrite (δ) grain boundaries or δ/γ phase interface formation due to the better effect of γ dynamic recrystallization (DRX) or δ dynamic recovery (DRV). Increasing strain rate to 5 s−1 lowered the corrosion resistance, due to the increase in dislocation density. At the low strain rate of 0.005 s−1, the susceptibility to intergranular corrosion (IGC) was comparatively high after deformation at 1050 and 1150°C with more γ/γ grains and δ/γ phase boundary formation, which was lowered with the strain rate increase to 0.5 s−1, due to suppressing effect of γ DRX.
Originality/value
The paper provides the scientific basis for the practical application of hot working of 2205 duplex stainless steel.
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