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Article
Publication date: 31 January 2020

Hailing Li, Hongxia Wan, Shengrong Wang, Cuiwei Du and Dawei Zhang

This paper aims to investigate the effect of alternating current (AC) on corrosion, it is not yet clear about the exact mechanism of the corrosion induced by AC. Previous reports…

Abstract

Purpose

This paper aims to investigate the effect of alternating current (AC) on corrosion, it is not yet clear about the exact mechanism of the corrosion induced by AC. Previous reports indicated that AC corrosion was similar to the effect of continuous cathodic and anodic polarization on the corrosion process of the metals. Wan et al. studied the effect of negative half-wave AC on stress corrosion cracking behavior and mechanism of X80 pipeline steel in near-neutral solution.

Design/methodology/approach

This study attempted to understand the AC-induced corrosion by imposing the half-cycle AC on the X80 pipeline steel in an acid bicarbonate solution. The AC corrosion mechanism was determined by weight loss and potentiodynamic polarization curve measurements, as well as surface characterization.

Findings

The results show that the positive half-cycle AC accelerated the uniform corrosion in the NaHCO3 solution, the negative half-cycle AC would decrease the uniform corrosion and local corrosion was increased and some Ca and Mg deposited on the surface of X80 steel, so the corrosion rate decreased by negative half-cycle AC. The corrosion product was composed of α-FeOOH under the application of positive half-cycle AC. The oxygen reduction led to a local increase of pH near the electrode surface and led to the formation of α-FeOOH, which enhanced the protectability of corrosion products.

Originality/value

Researchers studied the effect of negative half-wave AC on stress corrosion cracking behavior and mechanism of X80 pipeline steel in near-neutral solution. However, the AC behavior and corrosion mechanism in acid solution are unknown. So to make clear about the corrosion behavior of metals in different polarization states and the mechanism involved, diode technology was used to research the AC corrosion, half-wave AC was applied on the metals after the full-wave rectified.

Details

Anti-Corrosion Methods and Materials, vol. 67 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 6 November 2017

Yanbao Guo, Hai Tan, Deguo Wang and Tao Meng

With the rapid development of rail transportation and energy-delivery systems, such as buried oil and gas pipelines and high-voltage transmission lines, the alternating current (AC

Abstract

Purpose

With the rapid development of rail transportation and energy-delivery systems, such as buried oil and gas pipelines and high-voltage transmission lines, the alternating current (AC) corrosion of buried steel pipelines is becoming more serious. This paper aims to study the corrosion behaviours of Q235 buried steel pipelines induced by the alternating stray current, with a set of indoor simulated experiment apparatuses.

Design/methodology/approach

The corrosion of the coating holidays of the buried steel pipelines at various AC current densities from 0 to 200 A/m2 in the soil-simulating environment was revealed by the electrochemical and weight-loss methods.

Findings

The results showed that the corrosion potential of the steel shifted negatively obviously and the corrosion rate of the steel increased with the increasing of AC current density. At a low AC current density, the negative deviation of the corrosion potential of the steel was small and the increase of corrosion rate was slight. However, the negative deviation of the corrosion potential was remarkable and the corrosion rate was greatly increased at a relative higher AC current density. The geometrical shape of the corrosion images indicated the corrosion forms changed from uniform corrosion to local corrosion due to the increase of AC interference.

Originality/value

Investigation results are of benefit to provide a new strategy to forecast and evaluate the AC-induced corrosion of the buried pipelines which could improve the safety of pipeline transportation.

Details

Anti-Corrosion Methods and Materials, vol. 64 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 4 October 2019

Yu Fu, Jie Kou and Cuiwei Du

Pipelines are seriously corroded due to the close distance between pipelines and high voltage transmission lines. The purpose of this paper is to study the influence of…

Abstract

Purpose

Pipelines are seriously corroded due to the close distance between pipelines and high voltage transmission lines. The purpose of this paper is to study the influence of alternating current (AC) on corrosion behavior of X80 pipeline steel in coastal soil solution.

Design/methodology/approach

The corrosion behavior of X80 steel under different AC densities in coastal soil solution was investigated by electrochemical measurements and image processing technology. Furthermore, a quantitative description model of AC corrosion through fractal dimension of corrosion image was established.

Findings

The results show that under low AC density the X80 steel is mainly uniform corrosion, and once AC density reaches 150 A/m2, the corrosion morphology gradually turns to pitting corrosion with irregular circle. For another aspect, the fractal dimension of corrosion images shows that the two/three-dimensional fractal dimension increase with the increase of AC density, presenting a linear and an exponential relationship respectively. In addition, the variation of the three-dimensional fractal dimension is the same as that of average corrosion rate. The threshold of the increasing trend of fractal dimension as well as corrosion type is 150 A/m2.

Originality/value

The investigation provides a quantitative method to describe AC corrosion morphology through fractal dimension. Furthermore, the method is of benefit to process corrosion images automatically.

Details

Anti-Corrosion Methods and Materials, vol. 66 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 1 August 2001

Erwan Collet, Bernard Delores, Michel Gabillard and Isabelle Ragault

Shows how observations (1993‐1999) and on‐site and laboratory measurements (1993‐1996) have made it possible to define certain prevalent parameters concerning AC corrosion risks…

Abstract

Shows how observations (1993‐1999) and on‐site and laboratory measurements (1993‐1996) have made it possible to define certain prevalent parameters concerning AC corrosion risks. These are from the evaluation and prevention of AC corrosion risks as practised by Gaz de France.

Details

Anti-Corrosion Methods and Materials, vol. 48 no. 4
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 3 September 2019

Qingmiao Ding, Zili Li, Tao Shen and Gan Cui

This paper aims to research the corrosion behavior of the metal under the disbonded coatings interfered with AC through electrochemical method.

Abstract

Purpose

This paper aims to research the corrosion behavior of the metal under the disbonded coatings interfered with AC through electrochemical method.

Design/methodology/approach

The corrosion behavior of the metal under disbond coating interfered with alternate stray current (AC) was studied by electrochemical methods using the rectangular coating disbonded simulator. The obtained data from electrode potential test, electrochemical impedance spectroscopy (EIS) and polarization curves in simulated soil solution indicated that under the natural corrosion condition, the self-corrosion potential and the corrosion current density of the metal at different depths under disbond coating had obviously changed if there was AC interference.

Findings

The self-corrosion potential of the metal at the same depths under disbond coating shifted negatively with the rising of the AC voltage. Under the condition of cathode polarization, there was still obvious potential gradient with the extension of the deep peeling of the coating gap, and the corrosion current density of the test points was minimum, and the protection effect was best when the cathode protection potential was −1.0 V. When the metal was applied with over-protection, the corrosion rate of the metal increased as AC stray current flowing through it increased.

Originality/value

This paper used the rectangular aperture device to study the corrosion behavior of X80 steel under the disbonded coatings through electrochemical methods when the AC stray current interference voltage was 0V, 1V, 5V or 10V and the protection potential was 0V, −0.9V, −1.0V, −1.2V or −1.3V, respectively. There is great significance to the safe operation and long-term service of pipeline steel in soil environment.

Details

Anti-Corrosion Methods and Materials, vol. 66 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 7 August 2021

Yanbao Guo, Zhenyuan Liu, Hui Huang, Deguo Wang and Renyang He

The corrosion of buried steel pipelines is becoming more serious because of stress corrosion, stray current corrosion and other reasons. This paper aims to study the various…

Abstract

Purpose

The corrosion of buried steel pipelines is becoming more serious because of stress corrosion, stray current corrosion and other reasons. This paper aims to study the various alternating current (AC) interference densities on the stress corrosion cracking behaviors of X80 steel samples under cathodic protection (CP) in the simulated soil electrolyte environment by using an electrochemical method.

Design/methodology/approach

The change of corrosion rate and surface morphology of the X80 steel samples at various AC current densities from 0 to 150 A/m2 or CP potential between −750 and −1,200 mV in the soil-simulating environment was revealed by the electrochemical methods and slow strain rate testing methods.

Findings

The results revealed that with the increase of interference density, the corrosion potential of the X80 steel samples shifted to the negative side, and the corrosion pitting was observed on the surface of the sample, this may cause a danger of energy leak. Moreover, the corrosion rate was found to follow a corresponding change with the stress–strain curve. Besides, with the introduction of the CP system, the corrosion rate of the X80 steel working electrode decreased at a low cathodic potential, while showed an opposite behavior at high cathodic potential. In this study, the correlation between AC stray current, cathodic potential and stress was established, which is beneficial to the protection of oil and gas pipeline.

Originality/value

Investigation results are of benefit to provide a new CP strategy under the interference of AC stray current corrosion and stress corrosion to reduce the corrosion rate of buried pipelines and improve the safety of pipeline transportation.

Details

Anti-Corrosion Methods and Materials, vol. 68 no. 4
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 29 March 2021

Ailing Wang, Yong Deng, Kaihong Li, Wenlei Li, Dongliang Yu, Gan Cui, JianGuo Liu and Zili Li

Alternating current (AC) corrosion is a type of corrosion that occurs in buried pipelines under AC stray current interference, which can increase the hydrogen embrittlement…

Abstract

Purpose

Alternating current (AC) corrosion is a type of corrosion that occurs in buried pipelines under AC stray current interference, which can increase the hydrogen embrittlement sensitivity of pipelines. However, rare research works have been conducted on the hydrogen permeability characteristics of pipeline steel under AC stray current interference. The purpose of this paper is to study hydrogen permeation behavior of X80 steel under AC stray current interference.

Design/methodology/approach

In this paper, the hydrogen permeation behavior of X80 steel under AC interference is studied by AC hydrogen charging experiment in a dual electrolytic cell. The relationship between hydrogen evolution rate and hydrogen permeation flux is studied using the gas collection method. The difference between AC hydrogen permeability and direct current (DC) hydrogen permeability is also discussed.

Findings

The anodic dissolution caused by AC corrosion promotes the chemical desorption reaction of the adsorbed hydrogen atoms on the surface, reducing the hydrogen atom absorption ratio by 70%. When the AC is smaller than 150░ A/m2, the hydrogen permeation process is controlled by the hydrogen atom generation rate, and the hydrogen permeation flux increases with the increase in hydrogen atom generation rate. When the AC exceeds 400░ A/m2, the hydrogen permeation process is controlled by the absorption ratio. The hydrogen permeation flux decreases with the decrease in the absorption ratio. Under AC interference, there is a maximum hydrogen permeation flux that linearly correlates to the H+ concentration in the solutions.

Originality/value

The high-strength steel is very sensitive to hydrogen embrittlement, and X80 steel has been widely used in oil and gas pipelines. To date, no research has been conducted on the hydrogen permeation behavior of pipeline steel under AC interference, and the hydrogen permeability characteristics of pipeline steel under AC interference are not clear. The research results of this paper are of great significance for ensuring the intrinsic safety of high-strength pipelines under AC stray current interference.

Details

Anti-Corrosion Methods and Materials, vol. 68 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 1 February 1992

Donald V. Lackey

Ongoing reductions in dielectric thickness for metallized AC capacitors, has resulted in a shift away from pure aluminium coatings for capacitor materials to be used in higher…

Abstract

Ongoing reductions in dielectric thickness for metallized AC capacitors, has resulted in a shift away from pure aluminium coatings for capacitor materials to be used in higher voltage applications. Metallized electrodes such as zinc with silver prenucleation, zinc/aluminium composites and aluminium bilayers are now required for AC capacitors. This paper will discuss the design aspects of a vacuum web coater to provide this wider range of requirements.

Details

Anti-Corrosion Methods and Materials, vol. 39 no. 2
Type: Research Article
ISSN: 0003-5599

Article
Publication date: 4 November 2013

Qingmiao Ding, Zili Li and Hongna Hao

The presence of alternating current (AC) causes serious damage on buried pipelines even when the off potential matches the −0.85 V/CSE criterion. The optimum cathodic protection…

Abstract

Purpose

The presence of alternating current (AC) causes serious damage on buried pipelines even when the off potential matches the −0.85 V/CSE criterion. The optimum cathodic protection potential (OCPP) is more accurate for cathodic protection. The paper aims to study how to get the optimum cathodic protection by electrochemical impedance spectroscopy (EIS) and the effects of AC on the OCPP.

Design/methodology/approach

This paper describes the application of EIS to investigate the OCPP of X70 steel in a soil simulating solution with different AC interferences.

Findings

The experimental results indicate that AC interference makes the OCPP decrease and the −0.85 V/CSE criterion is not reasonable when there is AC interference. When the AC voltage is less than 6 V, the OCPP is approximately −900 mV/SCE, and when AC voltage is more than 7 V, the OCPP is roughly −1,000 mV/SCE.

Originality/value

There have been some researches on the OCPP, and the paper is the first one to study the AC effects on the OCPP and found that the OCPP changed when there was AC interference.

Details

Anti-Corrosion Methods and Materials, vol. 60 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 1 October 2002

N. Kouloumbi, G. Batis, N. Kioupis, N. Kioupis and P. Asteridis

The aim of this fieldwork was the study of the effect of 50Hz AC, induced by high‐voltage power lines, on the cathodic protection system of a natural gas pipeline. The…

1269

Abstract

The aim of this fieldwork was the study of the effect of 50Hz AC, induced by high‐voltage power lines, on the cathodic protection system of a natural gas pipeline. The effectiveness of cathodic protection was checked through in situ long‐term monitoring and analysis of pipeline electrical parameters. The results gave an insight into the problems of the cathodic protection system operation, caused by AC interference. An AC and DC potential interdependence was observed, that previously has hardly been reported, and was scrutinized in relation to cathodically protected pipelines. The effects of the AC‐interference and low frequency DC potential fluctuations, as well as the potential deviations from the protection potential, are examined. These phenomena are associated with corrosion susceptibility and difficulties in obtaining reliable cathodic protection measurements.

Details

Anti-Corrosion Methods and Materials, vol. 49 no. 5
Type: Research Article
ISSN: 0003-5599

Keywords

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