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This paper aims to investigate the structural, corrosion and the study of tribocorrosion features of the AA7075 aluminum alloy with and without the application of electroless Ni-P/Ni-B duplex coating with a thickness of approximately 40 microns.

Surface characterization of the samples was made by structural surveys (light optic microscope, scanning electron microscopic examinations and X-ray diffraction analyses), hardness measurements, corrosion and tribocorrosion tests.

Results of the experiments showed that upper Ni-B coating deposited on the surface of first Ni-P layer by duplex treatment caused remarkable increment in the hardness, corrosion resistance and tribocorrosion performance as compared to the AA7075 aluminum alloy.

This study can be a practical reference and offers insight into the effects of duplex treating on the increase of hardness, corrosion and tribocorrosion performance.

The purpose of this paper is to join a sheet of the AA7075 with the high-density polyethylene (HDPE) by a lap joint using friction spot processing and investigate the temperature distribution of joint during this process using the finite element method (FEM).

A semi-conical hole was manufactured in the AA7075 specimen and a lap joint configuration was prepared with the HDPE specimen. A rotating tool was used to generate the required heat to melt the polymer by the friction with the AA7075 specimen. The applied tool force moved the molten polymer through the hole. Four parameters were used: lower diameter of hole, rotating speed, plunging depth and time. The results of shear test were analyzed using the Taguchi method. A FEM was presented to estimate the temperature distribution of joint during the process.

All specimens failed by shearing the polymer at the lap joint region without dislocation. The specimens of the smallest diameter exhibited the highest shear strength at the lap joint. The maximum ranges of temperature were recorded at the contact region between the rotating tool and the AA7075 specimen. The tool plunging depth recorded the highest effect on the generated heat compared with the rotating speed and plunging time.

For the first time, the AA7075 sheet was joined with the HDPE sheet by friction spot processing. The temperature distribution of this joint was simulated using the FEM.

This paper aims to overcome the corrosion in AA7075 by incorporating the dual-reinforcements like Al2O3 and SiC through friction stir processing (FSP). In recent days, an automotive monocoque structure undergoes corrosion because of changes in environmental conditions.

Surface hybrid composites (SHCs) of AA7075 with different weight ratios of Al₂O₃ and SiC were fabricated at a rotating speed of 1000 rpm, traveling speed of 56 mm/min and tool tilt angle of 2º with two passes. Surface regions were observed using optical microscopy, and the potentiodynamic corrosion test was performed under a 3.5 per cent NaCl environment at room temperature. Then, the surface morphology analysis of corroded samples and their structural properties were also investigated through scanning electron microscopy (SEM), X-ray diffraction (XRD) and electron dispersive spectroscopy (EDS).

Through FSP, an improved interface between the reinforced particles and the AA7075 base matrix was observed because of the severe plastic deformation. Potentiodynamic polarization tests confirmed that the AA7075 matrix with a higher concentration of Al₂O₃ and a lower concentration of SiC (Al₂O₃ – 75 per cent and SiC – 25 per cent) possesses a lower corrosion rate than other specimens. This result is because of the combined effect of stable passive film formation and the resistance produced by hard SiC particles. In addition, the formation of a stronger interface between the reinforcements and the base matrix impedes the NaCl solution attack. The SEM micrograph depicts the film crystallinity variations with an increase in Al₂O₃ content. Debonding between the layers was observed on increasing the SiC content in the base matrix. XRD shows the peaks of reinforcing elements that influence the corrosion behavior. These observations suggest that the AA7075 reinforced with a higher concentration of Al₂O₃ and a lower concentration of SiC through FSP affords a suitable solution for automotive monocoque applications.

The corrosion rate has been identified for AA7075 SHCs with various concentrations of Al₂O₃ and SiC and has been compared with that of the base metal and the friction stir processed specimen without reinforcement.

Dissimilar materials found applications in the structural fields to withstand the different types of loads and provide multi-facet properties to the final structure. Aluminum alloy materials are mostly used in aerospace and marine industries to provide better strength and safeguard the material from severe environmental conditions. The purpose of this study is to develop new material with superior strength to challenge the severe environmental conditions.

In the present investigation, friction stir welding (FSW) dissimilar joints were prepared from AA6061 and AA5083 aluminum alloys, and the weld nugget (WN) was reinforced with hard reinforcement particles such as La₂O₃ and CeO₂. The tribological and mechanical properties of the prepared materials were tested to analyze the suitability of material in the aerospace and marine environmental conditions.

The results showed that the AA6061–AA5083/La₂O₃ material exhibited better mechanical and tribological characteristics. The FSW dissimilar AA6061–AA5083/La₂O₃ material exhibited lower wear rate of 7.37 × 10⁻³ mm3/m and minimum friction coefficient of 0.31 compared to all other materials owing to the reinforcing effect of La₂O₃ particles and the fine grains formed by FSW process at WN region. Further, FSW dissimilar AA6061–AA5083/La₂O₃ material displayed a maximum tensile strength and hardness of 378 MPa and 118 HV, respectively, among all the other materials tested.

This work is original and novel in the field of materials science engineering focusing on tribological characteristics of friction stir welded dissimilar aluminum alloys by the reinforcing effect of hard particles such as La₂O₃ and CeO₂.

This study aims to discuss the influences of surface severe plastic deformation (S²PD) on the electrochemical corrosion, pitting corrosion, intergranular corrosion, stress corrosion cracking of aluminum (Al) alloys and attempt to correlate the microstructural/compositional changes with the performances.

This study provides a novel gradient design of structure/composition caused by S²PD for the purpose of enhancing Al alloys’ corrosion resistance.

S²PD has a significant effect on corrosion behavior of Al alloys through tuning the grain size, residual stress, composition, grain boundary phase and second phase particle distribution.

Although Al alloys are known to form a protective Al₂O₃ film, corrosion is a major challenge for the longevity of Al structures across numerous industries, especially for the infrastructures made of high-strength Al alloys. Traditional strategies of improving corrosion resistance of Al alloys heavily relied on alloying and coatings. In this review, gradient design of structure/composition caused by S²PD provides a novel strategy for corrosion protection of Al alloys, especially in the enhancement of localized corrosion resistance.

In-situ aluminum metal matrix composites (AMMC) have taken over the use of ex-situ AMMC due to the generation of finer and thermodynamically stable intermetallic compounds. However, conventional processing routes pose inevitable defects like porosity and agglomeration of particles. This paper aims to study current state of progress in in-situ AMMC fabricated by Friction Stir Processing.

Friction stir processing (FSP) has successfully evolved to be a favorable in-situ composite manufacturing technique. The dynamics of the process account for a higher plastic strain of 35 and a strain rate of 75 per second. These processing conditions are responsible for grain evolution from rolled grain → dislocation walls and dislocation tangles → subgrains → dislocation multiplication → new grains. Working of matrix and reinforcement under ultra-high strain rate and shorter exposure time to high temperatures produce ultra-fine grains. Do the grain evolution modes include subgrain boundaries → subgrain boundaries and high angle grain boundaries → high angle grain boundaries.

Further, the increased strain and strain rate can shave and disrupt the oxide layer on the surface of particles and enhance wettability between the constituents. The frictional heat generated by tool and workpiece interaction is sufficient enough to raise the temperature to facilitate the exothermic reaction between the constituents. The heat released during the exothermic reaction can even raise the temperature and accelerate the reaction kinetics. In addition, heat release may cause local melting of the matrix material which helps to form strong interfacial bonds.

This article critically reviews the state of the art in the fabrication of in-situ AMMC through FSP. Further, FSP as a primary process and post-processing technique in the synthesis of in-situ AMMC are also dealt with.

This paper aims to investigate the effects of second phase precipitate size on microstructure, hardness, density, corrosion and electrical conductivity of 7075 aluminum alloy fabricated by the powder metallurgy method and aged at 120°C for various aging periods.

For the aging process (T6), these alloys were solution-treated at 485°C for 2 h, quenched, aged at 120°C for four various periods and finally air cooled. After the aging process, these alloys were examined with scanning electron microscope, X-ray diffraction, density and hardness measurements. The corrosion tests were carried out using the potentiodynamic polarization technique; electrical conductivity values were measured as IACS%.

Results showed that the precipitate size increased with increasing aging period and the maximum precipitate size was achieved for the sample aged for 28 h. The maximum hardness was attained for the sample aged for 24 h, while the same specimen obtained the lowest electrical conductivity and corrosion resistance.

In this research, second phase precipitates of heat treatment processing affected the electrical conductivity and corrosion behavior of the 7075 aluminum alloy. Also it is understood that the heat treatment period is an effective parameter on these properties.

This paper aims to focus the synchronous chemical conversion technology–based titanium/zirconium composite on 6061, 7075 aluminum alloys and galvanized steel.

The effects of pH, temperature, reaction time and other process parameters on the corrosion resistance of the three metal surface coatings were investigated by copper sulfate drop and electrochemical corrosion performance tests under a certain content of H2TiF6 and H2ZrF6. The surface morphology and element distribution of the conversion coating were analyzed by scanning electron microscope and X-ray photoelectron spectroscopy.

The results show that the optimal synchronization chemical conversion conditions of 6061/7075 aluminum alloys/galvanized steel are controlled as follows: H2TiF6 2.2 mL/L, H2ZrF6 1 mL/L, pH 3.9, conversion temperature 35°C and conversion time 120 s.

Multi-metals chemical conversion coating can be obtained simultaneously with uniform corrosion resistance and surface morphology. The presence of microdomain features in multiple metals facilitates simultaneous chemical conversion into coatings.

This paper aims to monitor, evaluate and adjust the joint quality of dissimilar friction stir welded AA2024-T3 and AA7075-T6 Al alloys.

Taguchi analysis for design of experiments and ANOVA analysis were applied. Tensile test, visual inspection and macro and microstructure investigations were carried out at each welding condition. In addition, the grain size of stir zone and the value of heat input were measured.

Using Taguchi analysis, the optimum values of tool rotary speed, welding speed and axial load were 1,200 rpm, 100 mm/min and 1,300 kg, respectively, yielding the maximum tensile strength of the joints of 427 MPa. ANOVA analysis indicated that the most significant parameter on the joint strength is the tool rotary speed, followed by welding speed and axial load, with contributions of 67, 27 and 2 per cent, respectively. Best mixing between Al alloys in the stir zone with no defects was observed at moderate speeds because of proper heat input and grain size, resulting in high strength.

A relation between structure characteristics of the joint, the process parameters and the joint strength was established to control the joint quality.

A chromate conversion coating was prepared on the surface of bare AA2024 aluminum alloy by direct immersion in the chromating treatment bath, and the corrosion behavior of chromated AA2024 aluminum alloy in 3.5 per cent NaCl solution was studied by electrochemical measurement and microstructural observation.

According to the polarization curve test and the scanning electron microscope observation, the corrosion evolution of chromated AA2024 in 3.5 per cent NaCl solution was divided into the following three stages: coating failure, pitting corrosion and intergranular corrosion (IGC).

In the first stage, the chromate coating degraded gradually due to the combined action of chloride anions and water molecules, resulting in the complete exposure of AA2024 substrate to 3.5 per cent NaCl solution. Subsequently, in the second stage, chloride anions adsorbed at the sites of θ phase (Al2Cu) and S phase (Al2CuMg) on the AA2024 surface preferentially, and some corrosion pits initiated at the above two sites and propagated towards the deep of crystal grains. However, the propagation of a pit terminated when the pit front arrived at the adjacent grain boundary, where the initiation of IGC occurred.

Finally, in the third stage, the corrosion proceeded along the continuous grain boundary net and penetrated the internal of AA2024 substrate, resulting in the propagation of IGC. The related corrosion mechanisms for the bare and the chromated AA2024 were also discussed.