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Coral aggregate seawater concrete (CASC) is a new type of lightweight aggregate concrete that is becoming widely used in reef engineering. To investigate the corrosion behavior of different kinds of rebar in CASC exposed to simulated seawater for 0-270 d, the electrochemical techniques, including linear polarization resistance (LPR) technique and the electrochemical impedance spectroscopy (EIS), were used in the present work.

The electrochemical techniques, including LPR technique and the EIS, were used in the present work.

Based on the time-varying law of linear polarization curves, self-corrosion potential (E_corr), polarization resistance (R_p), corrosion current density (I_corr), corrosion rate (i), and the characteristics of EIS diagrams for different types of rebar in CASC, it can be found that the anti-corrosion property of them can be ranked as epoxy resin coated steel > 2205 duplex stainless steel (2205S) > 316 L stainless steel (316 L) > organic coated steel > ordinary steel. Additionally, the linear regression equation between R_p and charge transfer resistance (R_ct) was established. Finally, the EIS corrosion standard of rebar was established from the LPR corrosion standard, which provides a direct standard for the EIS technique to determine the condition of rebar in CASC.

The linear regression equation between polarization resistance and charge transfer resistance was established. And the EIS corrosion standard of rebar was established from the LPR corrosion standard, which provides a direct standard for the EIS technique to determine the condition of rebar in CASC.

The purpose of this paper is to study the variations of composition and properties of the passive film on 316 L stainless steel surface in 80°C, 0.5 mol L-1 H2SO4 + 2 mg L-1 NaF solution, is helpful to understand the mechanisms of corrosion resistancethe of plated Pd on 316 L ss.

The variations of composition and properties of the passive film on 316 L stainless steel surface in 80°C, 0.5 mol L-1 H2SO4 + 2 mg L-1 NaF solution after connected to Pd electrode were studied with methods of potential monitor, X-ray photoelectron spectroscopy analysis and electrochemical impedance spectrum (EIS) measurement.

By connecting to a Pd electrode, the potential of the SS sample increased from the active region to the passive region. By connecting to the Pd electrode, the contents of Cr, Cr(OH)3 and Fe3O4 in passive film increased obviously. With increased Pd/SS area ratio, the Cr(OH)3 content in passive film increased but the Fe3O4 content changed little. The results show that after connecting to Pd the corrosion resistance of the passive film on 316 L stainless steel increases obviously, which may be attributed to the more compact passive film because of higher Cr, Cr(OH)3 and Fe3O4 contents and less point defects in the film.

The effects and mechanism of Pd on passivation of SS was studied.

Fused filament fabrication (FFF) technique using metal filled filaments in combination with debinding and sintering steps can be a cost-effective alternative for laser-based powder bed fusion processes. The mechanical behaviour of FFF-metal materials is highly dependent on the processing parameters, filament quality and adjusted post-processing steps. In addition, the microstructural material properties and geometric characteristics are inherent to the manufacturing process. The purpose of this study is to characterize the mechanical and geometric performance of three-dimensional (3-D) printed FFF 316 L metal components manufactured by a low-cost desktop 3-D printer. The debinding and sintering processes are carried out using the BASF catalytic debinding process in combination with the BASF 316LX Ultrafuse filament. Special attention is paid on the effects of build orientation and printing strategy of the FFF-based technology on the tensile and geometric performance of the 3-D printed 316 L metal specimens.

This study uses a toolset of experimental analysis techniques [metallography and scanning electron microcope (SEM)] to characterize the effect of microstructure and defects on the material properties under tensile testing. Shrinkage and the resulting porosity of the 3-D printed 316 L stainless steel sintered samples are also analysed. The deformation behaviour is investigated for three different build orientations. The tensile test curves are further correlated with the damage surface using SEM images and metallographic sections to present grain deformation during the loading progress. Mechanical properties are directly compared to other works in the field and similar additive manufacturing (AM) and Metal Injection Moulding (MIM) manufacturing alternatives from the literature.

It has been shown that the effect of build orientation was of particular significance on the mechanical and geometric performance of FFF-metal 3-D printed samples. In particular, Flat and On-edge samples showed an average increase in tensile performance of 21.7% for the tensile strength, 65.1% for the tensile stiffness and 118.3% for maximum elongation at fracture compared to the Upright samples. Furthermore, it has been able to manufacture near-dense 316 L austenitic stainless steel components using FFF. These properties are comparable to those obtained by other metal conventional processes such as MIM process.

316L austenitic stainless steel components using FFF technology with a porosity lower than 2% were successfully manufactured. The presented study provides more information regarding the dependence of the mechanical, microstructural and geometric properties of FFF 316 L components on the build orientation and printing strategy.

The purpose of this paper is to address the concern of some stainless steel users. To understand the effect of surface white spots on corrosion performance of stainless steel.

White spots appeared on some component surfaces made of 316 L stainless steel in some industrial applications. To address the concern about the pitting performance in the spot areas, the pitting corrosion potential and corrosion resistance were measured in the spot and non-spot areas by means of potentiodynamic polarization and electrochemical impedance spectroscopy and the two different surface characteristics were analytically compared by using optical microscopy, laser confocal microscopy, scanning electron microscopy, x-ray diffraction, energy dispersive spectroscopy and auger energy spectroscopy. The results indicated that the pitting performance of the 316 L stainless steel was not negatively influenced by the spots and the white spots simply resulted from the slightly different surface morphology in the spot areas.

The white spots are actually the slightly rougher surface areas with some carbon-containing species. They do not reduce the pitting resistance. Interestingly, the white spot areas even have slightly improved general corrosion resistance.

Not all surface contamination or roughening can adversely affect the corrosion resistance of stainless steel.

Stainless steel components with such surface white spots are still qualified products in terms of corrosion performance.

The surface spot of stainless steel was systematically investigated for the first time for its effect on corrosion resistance and the conclusion was new to the common knowledge.

This paper aims to investigate the galvanic corrosion of titanium/L 316 stainless steel, by electrochemical noise (EN), electrochemical impedance spectroscopy (EIS), and anode/cathode area ratio effect on the galvanic behavior of the couple.

The EN measurement was employed to examine effects of anode to cathode area ratio on the galvanic corrosion behavior between stainless steel L 316 and titanium in artificial seawater. Current noise and potential noise were monitored simultaneously using a three‐electrode configuration under open‐circuit condition. The noise resistance was evaluated as the ratio of the standard deviation of the potential to that of the current noise after removing the DC component. The time‐series noise patterns were transformed into frequency domain by fast Fourier transformation and then their power spectrum densities (PSDs) at specified frequency were determined and compared with the EIS and polarization results.

The EN, EIS and polarization results were in agreement. Galvanic corrosion density increase and galvanic potential moved slowly to negative direction with decrease in anode/cathode area ratio. The results showed that the slope of PSD of the current (i.e the “roll off”) was rising slowly where the anode/cathode area ratio was declined. The relationship between polarization resistance (Rp) and noise resistance (Rn) was investigated. Rt was determined by EIS for samples, and its value compared with Rp and Rn. The result indicates that galvanic corrosion has an inversely relation with anode/cathode area ratio that exposed to aggressive environment.

This paper presents the application of noise analysis to demonstrate galvanic corrosion and the effect of area ratio anode/cathode on current density and galvanic potential.

An experimental and numerical study of thermal profiles of 316 L stainless steel during selective laser melting (SLM) was developed. This study aims to present a novel approach to determine the significance and contribution of thermal numerical modeling enhancement factors of SLM.

Surface and volumetric heat models were proposed to compare the laser interaction with the powder bed and substrate, considering the powder size, absorptance and propagation of the laser energy through the effective depth of the metal layer. The approach consists in evaluating the contribution of the thermal conductivity anisotropic enhancement factors to establish the factors that minimized the error of the predicted results vs the experimental data.

The level of confidence of the carried-out analysis is of 97.8% for the width of the melt pool and of 99.8% for the depth of the melt pool. The enhancement factors of the y and z spatial coordinates influence the most in the predicted melt pool geometry.

Nevertheless, the methodology presented in this study is not limited to 316 L stainless steel and can be applied to any metallic material used for SLM processes.

This study is focused on 316 L stainless steel, which is commonly used in SLM and is considered a durable material for high-temperature, high-corrosion and high-stress situations.

The additive manufacturing (AM) technology is a relatively new technology becoming global. The AM technology may have health benefits when compared to the conventional industrial processes, as the workers avoid extended periods of exposure present in conventional manufacturing.

This study presents a novel approach to determine the significance and contribution of thermal numerical modeling enhancement factors of SLM. It was found that the volumetric heat model and anisotropic enhancement thermal approaches used in the present research, had a good agreement with experimental results.

The purpose of this paper is to fill the knowledge gap in the microscopic origin of high corrosion resistance in the passivated 316 L stainless steel.

Here, the pitting corrosion potential of the passivated 316 L stainless steel is measured, as well as the non-passivated one. Using the aberration-corrected scanning transmission electron microscopy, the microstructure of the passive film is unambiguously revealed. Combining the electron energy loss spectroscopy with the X-ray photoelectron spectroscopy, the depth profiling analysis is conducted and the variations in composition from the very surface of the passive film to the internal steel are clarified.

By optimizing the passivation treatment process, the authors significantly increase the pitting corrosion potential of the passivated 316 L stainless steel by 300 mV, compared with the non-passivated one. The passive film features a unique amorphous multilayer structure. On the basis of the depth profiling analysis, the origin of the high corrosion resistance achieved is unraveled, in which the redistribution of elements in the multilayer passive film, especially the enrichment of Cr in the topmost layer and Ni at the film-metal interface, prevent the oxidization of the inner iron of the steel.

This study advances understanding of the nature of the passive film from a microscopic view, which can be helpful for the further improvement of the corrosion resistance performance.

This study introduces a model for the multilayer structure of passive films that reveals the reconstitution of the passive films after the opportune passivation treatments. Due to the redistribution of elements caused by passivation, the enrichment of Cr in the outer layer and Ni near the film-metal interface leads to enhance corrosion resistance performance.

The purpose of this paper is to predict and control the composition during laser additive manufacturing, since composition control is important for parts manufactured by laser additive manufacturing. Aluminum and steel functionally graded material (FGM) were manufactured by laser metal deposition, and the composition was analyzed by means of spectral analysis simultaneously.

The laser metal deposition process was carried out on a 5 mm thick 316L plate. Spectral line intensity ratio and plasma temperature were chosen as two main spectroscopic diagnosis parameters to predict the compositional variation. Single-trace single-layer experiments and single-trace multi-layer experiments were done, respectively, to test the feasibility of the spectral diagnosis method.

Experiment results showed that with the composition of metal powder changing from steel to aluminum, the spectral intensity ratio of the characteristic spectral line is proportional to the elemental content in the plasma. When the composition of deposition layers changed, the characteristic spectrum line intensity ratio changed obviously. And the linear chemical composition analysis results confirmed the gradient composition variation of the additive manufacturing parts. The results verified the feasibility of composition analysis based on spectral information in the laser additive manufacturing process.

The composition content of aluminum and steel FGM was diagnosed by spectral information during laser metal deposition, and the relationship between spectral intensity and composition was established.

The effect of processing parameters on the microstructure of steel produced by laser-based powder bed fusion (LPBF) is a recognized opportunity for property design through microstructure control. Because the LPBF generates a textured microstructure associated with high anisotropy, it is of interest to determine the fabrication plane that would generate the desired property distribution within a component.

The microstructure of 316 L produced by LPBF was characterized experimentally (optical, scanning electron microscopy, glow discharge emission spectrometry and X-ray diffraction), and a finite element method was used to study the microstructure features of grain diameter, grain orientation and thermal parameters of cooling rate, thermal gradient and molten pool dimensions.

The computational tool of Ansys Additive was found efficient in reproducing the experimental effect of varying laser power, scanning speed and hatch spacing on the microstructure. In particular, the conditions for obtaining maximum densification and minimum fusion defects were consistent with the experiment, and the features of higher microhardness near the component’s surface and distribution of surface roughness were also reproduced.

To the best of the author’s knowledge, this paper is believed to be the first systematic attempt to use Ansys Additive to investigate the anisotropy of the 316 L SS produced by LPBF.

dding dopants to a powder bed could be a cost-effective method for spatially varying the material properties in laser powder bed fusion (LPBF) or for evaluating new materials and processing relationships. However, these additions may impact the selection of processing parameters. Furthermore, these impacts may be different when depositing nanoparticles into the powder bed than when the same composition is incorporated into the powder particles as by ball milling of powders or mixing similarly sized powders. This study aims to measure the changes in the single bead characteristics with laser power, laser scan speed, laser spot size and quantity of zirconia nanoparticle dopant added to SS 316 L powder.

A zirconia slurry was inkjet-printed into a single layer of 316 SS powder and dried. Single bead experiments were conducted on the composite powder. The line type (continuous vs balling) and the melt pool geometry were compared at various levels of zirconia doping.

The balling regime expands dramatically with the zirconia dopant to both higher and lower energy density values indicating the presence of multiple physical mechanisms that influence the resulting melt track morphology. However, the energy density required for continuous tracks was not impacted as significantly by zirconia addition. These results suggest that the addition of dopants may alter the process parameter ranges suitable for the fabrication of high-quality parts.

This work provides new insight into the potential impact of material doping on the ranges of energy density values that form continuous lines in single bead tests. It also illustrates a potential method for spatially varying material composition for process development or even part optimization in powder bed fusion without producing a mixed powder that cannot be recycled.