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Eco-friendly polyfunctional ceramic pigments: an approach

Guillermo Monrós (Department of Inorganic and Organic Chemistry, Jaume I University, Castelló, Spain)
Mario Llusar (Department of Inorganic and Organic Chemistry, Jaume I University, Castelló, Spain)
José Antonio Badenes (Department of Inorganic and Organic Chemistry, Jaume I University, Castelló, Spain)

Pigment & Resin Technology

ISSN: 0369-9420

Article publication date: 11 April 2023

Issue publication date: 29 November 2024

71

Abstract

Purpose

The purpose of this study is the synthesis and characterization of a CMYK palette (cyan of Cr-BiVO4, magenta of Pr-CeO2, yellow of Bi-(Ce,Zr)O2 composite and black of YMnO3) as an eco-friendly polyfunctional palette that combines (a) high near-infrared reflectance (cool pigments) that allows moderate temperatures in indoor environments and the urban heat island effect; (b) photocatalytic activity for the degradation of organic contaminants of emerging concern of substrates in solution (such as Orange II or methylene blue) and gaseous (NOx and volatile organic compounds such as acetaldehyde or toluene); (c) X-ray radiation attenuators associated with bismuth ions; and (d) biocidal effect combined with co-doping with bactericidal agents.

Design/methodology/approach

Pigments were prepared by a solid-state reaction and characterized by X-ray diffraction, diffuse reflectance spectroscopy, photocatalytic activity over Orange II and scanning electron microscopy.

Findings

The behaviour of the proposed palette was compared to that of a commercial inkjet palette, and an improvement in all functionalities was observed.

Social implications

The functionalities of pigments allow the building envelope and indoor walls to exhibit temperature-moderating effects (with the additional effects of moderating global warming and increasing air conditioning efficiency), purification and disinfection of both indoor and outdoor air, and radiation attenuation.

Originality/value

The proposed palette and its polyfunctional characterization are novel.

Keywords

Acknowledgements

Ethics statement: This research work entitled “New eco-friendly polyfunctional ceramic pigments” was designed and planned by the Environmental Inorganic Chemistry and Ceramic Materials Research Group of Jaume I University to be carried out in strict adherence to the research methodology and standards of research ethics in ceramics and the environment.

The authors gratefully acknowledge the financial support of the Universitat Jaume I (UJI B2021-73 Project).

Citation

Monrós, G., Llusar, M. and Badenes, J.A. (2024), "Eco-friendly polyfunctional ceramic pigments: an approach", Pigment & Resin Technology, Vol. 53 No. 6, pp. 716-729. https://doi.org/10.1108/PRT-04-2022-0038

Publisher

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Emerald Publishing Limited

Copyright © 2023, Emerald Publishing Limited

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