Time, temperature and environment interactions in carbon steel

Abstract

Carbon steels are abundantly employed in our day‐to‐day engineering services, the automotive industry, and in various domestic usages. Service life of carbon steel assumes importance, as faults bring either costly industrial downtime or embarrassing domestic inconvenience. It appears that these materials are dependent completely on the solubility of carbon in their solid‐solutions. Instabilities and destabilization mainly occur due to separation of various forms of carbides, which embrittles the matrix in the time domain. The presence of residual stress which is trapped inside the matrix, having originated from the previous deformation stresses of the wrought products, accelerates such precipitation. Thermal treatment, such as the subcritical stress relieving process, may also accelerate such an embrittlement process, although this exercise is meant for the relief of the matrix residual stresses only. Concludes that there is simultaneous precipitation of brittle phases and also deactivation of the matrix, owing to stress relieving. A surface becomes electrochemically more active when the precipitation component more than compensates the deactivation component and vice versa. Improvement of the matrix ductility also works against such deterioration processes. Suggests that imposition of the environmental constraints, such as aggressive and corrosive media, can only accelerate deterioration, by activating the brittle precipitation cycle.

Citation

Mukherjee, D. (1996), "Time, temperature and environment interactions in carbon steel", Anti-Corrosion Methods and Materials, Vol. 43 No. 5, pp. 10-14. https://doi.org/10.1108/eb007400